XRF Core Scanning Research Articles

Imprints of Holocene aridity variability in the Aegean Sea and interconnections with north-latitude areas

The analysis of the ASTC1 sediment core from the south Aegean Sea region offers critical insights into the complex interplay of geological and climatic factors over the Holocene period. The data reveals fluctuating climatic conditions during the last 8.7 ka as seen through the elemental concentrations obtained by XRF core scanning combined with a qualitative mineral analysis within a robust chronological framework. Short-term fluctuations in both Ti/Al and Zr/Si ratios suggest brief oscillations of increased aridity which partially coincide with the Holocene “Rapid Climate Change” events (RCCs). Among them, the most pronounced in our record are those centered between 8.5–8 ka, 3–2.5 ka (Greek Dark Ages), and 0.6–0.3 ka (Little Ice Age). The arid and humid events identified in the sediment record align with major archaeological periods in Greece, suggesting a potential influence of climatic conditions on the development and decline of civilizations in the region. Moreover, a general arid trend as of 6 ka toward the present was evidenced in our record and aligns with other high-resolution climatic data from the Northern Hemisphere, suggesting climatic teleconnections. Spectral analysis of the ASTC1 record reveals cyclical climate patterns with periodicities of approximately 2500, 1200, and 550 years, which coincide with the Bond and Hallstatt cycles. The phase relation of these cycles in our record, the Greenland ice record, and the North Atlantic Drift ice indices show that colder conditions in the higher latitudes are expressed as events of enhanced aridity in our record and generally in the lower latitudinal regions.

Extremely high resolution XRF core scanning reveals the Early Triassic depositional history of the Montney Formation in northeastern British Columbia, Canada

The Montney Formation is a laterally extensive, fine-grained sedimentary unit in western Alberta and northeastern British Columbia, and a major target of hydrocarbon exploration. It also retains a complete record of the Early Triassic epoch, a time when the biosphere was recovering from the effects of the end-Permian mass extinction. An industry well provides a full-diameter core of the complete distal Montney Formation in northeastern British Columbia (over 350 m thick), with stratigraphic age control provided by conodont biostratigraphy and regional correlations. For this study, the core was scanned using an ITRAX X-ray fluorescence spectrometer, at centimeter-scale resolution. The resulting dataset (over 37,000 individual measurements) provides an extremely high level of resolution for a deep-time geochemical study. While the data generated by this instrument are semiquantitative, they can be calibrated by correlating them with more conventional ICP-MS and XRF measurements of select samples. Using this method, we assessed the reliability of each of the elemental data series, and where possible converted them to quantitative geochemical measurements. These calibrated measurements serve as the basis for our detailed reconstruction of the Montney Formation's depositional history.The distal Montney depositional basin, including the location of the c-65-F core, was euxinic immediately following the end-Permian mass extinction, and accumulated sediments from the rapidly eroding margin of western North America. Conditions stabilized somewhat in the Dienerian, with oxic bottom water and a trend toward more compositionally mature sediment, but conditions of widespread euxinia and rapid erosion of the North American craton recurred in the early Smithian, earlier than this global crisis has been recognized elsewhere. Above the middle-upper Montney sequence boundary, in the overlying Spathian succession, local effects predominate. Coastal upwelling resumed in the basal Spathian, though the Montney depositional basin was soon cut off from the global ocean by uplift of the Yukon-Tanana arc bounding the basin to the west. Restricted conditions, with euxinic bottom water, were punctuated by oxic intervals, when rising sea level allowed the basin to freely exchange water with the open ocean. Intervals of restriction became progressively less acute in the upper Spathian.

Investigating the impact of sample desiccation on Itrax XRF core scanner signal reproducibility

AbstractSediment samples tend to dry out during storage and are, therefore, stored refrigerated at about 4°C after wrapping in plastic foil. During XRF core scanning however, the samples must be taken out of their cover, increasing the risk of drying and formation of desiccation cracks on the surface. Because scan times can often amount to several hours and at highest resolution may take over a day to complete, the core will progressively dry out during scanning. With this study we aim to increase our understanding of how this slow drying of the samples during scanning and storage influences the XRF signal because of changes in water content, sediment surface topography, and the development of small, but slowly expanding cracks in the sediment core. Results show that the desiccation of samples during scanning and storage influence the XRF measurements in several ways. Most importantly, slow desiccation of the cores results in both a general lowering of the sample surface, and a shortening of the core due to shrinkage. Larger distance between sediment surface and detector leads to increased noise levels and poor reproducibility for many elements, while the shrinking of cores may shift individual data points between runs, resulting in poor reproducibility and offsets between datasets obtained at different times. Moreover, the loss of light elements, such as hydrogen and oxygen, can influence the matrix effect, especially for organic‐rich sediment. Because the XRF signals of individual elements are affected to different degrees, these changes may induce artificial shifts and biases in many elemental ratios commonly used for paleoenvironmental reconstruction.

Sea level controls on the provenance of fine-grained sediments in the Xisha Trough, northwestern South China Sea over the last ~30 ka

The Xisha Trough situated in the northwestern South China Sea (SCS), plays a pivotal role in transporting sediments from the Red River into the deep-sea basin of the SCS, and thus is a critical place to examine variations in source-to-sink process of the Red River-derived sediments associated with past climate and oceanography changes. In this study, we analyzed clay minerals, grain size composition, and specific XRF core scanning elements of sediment core XT-1, retrieved from the northern slope of the Xisha Trough, to assess changes in sediment provenance and their primary influencing factors in the studied area over the last ~30 ka. The results show that clay minerals are primarily composed of illite+chrolite with a mean of 89%, followed by kaolinite with a mean of 9%; smectite occurs as a minor component. The mean grain size and XRF core scanning elements exhibit a three-phase change that corresponds well to variations in sediment source since the last glacial period. Over the last 29.8 ka, sea level fluctuations are the primary factor controlling changes in provenances and their contributions in the northern slope of the Xisha Trough. During the last glacial from 29.8 to 20.2 ka with lower sea levels, both the Red River and Taiwan were the primary contributors of fine-grained sediments in the lower continental slope of the Xisha Trough. However, with marine transgressions from the last deglaciation, Taiwan gradually became the dominant source of fine-grained sediments, followed by the Red River. Additionally, during the Last Glacial Maximum and the early to middle Holocene periods, the strengthened deep-water current (DWC) and East Asian summer monsoon, respectively, exerted strong impacts on the contribution of Taiwanese sediments to the Xisha Trough. The changing pattern of primary provenance in the studied core is roughly in line with those observed in the northern SCS, while differing from those in the southern regions of the western Xisha Trough. This discrepancy is likely caused by varying influences of the DWC on these regions.

Environmental significance of kaolinite variability over the last centuries in crater lake sediments from Central Mexico

Environmental conditions have a notable impact on clay minerals, primarily because of the chemical reactions they undergo with their immediate environment. These reactions are more pronounced in hot and humid tropical regions, and therefore, the study of clays deposited at the bottom of lakes in tropical regions can yield valuable insight into past environmental conditions. Here we present multiproxy records, including physical (magnetic susceptibility, grey-scale level and grain size), mineralogical (X-ray diffraction, Simultaneous Thermal Analysis, Fourier-Transform Infrared Spectroscopy), and geochemical (elemental composition by XRF-core scanner, organic geochemistry by IRMS) data, from three 210Pb-dated sediment cores (spanning recent centuries < 1470 CE) retrieved from crater lakes Los Espinos, Tacámbaro and Teremendo in the Trans-Mexican Volcanic Belt (TMVB), central Mexico. The mineralogical results showed that disordered kaolinite, formed by hydrolysis and hydrothermal alteration, was the predominant mineral in the sediments of the three lakes. The abundance of kaolinite changed in line with organic carbon and organic matter-related elements (Br, S and Ni) and showed opposite trends with lithogenic elements (Ti, K, and Fe). The geochemical data further suggested that increases in kaolinite abundance are linked to the formation of organo-mineral aggregates related to periods of elevated lake productivity that in turn may reflect lake level changes in the closed basins. In Lake Tacámbaro, following the construction of a canal in the early 20th century and subsequent regulation of lake level, the relationship between organic material and kaolinite was no longer present.

Estimating Layer Boundaries of Mixed-layer Tsunami Deposits with a XRF Core Scanner

Estimating Layer Boundaries of Mixed-layer Tsunami Deposits with a XRF Core Scanner

Freshwater input variability in a west coastal area of Korea and its links to the global monsoon and ITCZ shifts during the period 8500–7800 cal yr BP

In East Asia, freshwater inputs in coastal areas are mainly controlled by rainfall occurring during the East Asian summer monsoon (EASM), which is linked to seasonal latitudinal shifts in the intertropical convergence zone (ITCZ). To investigate the centennial-time-scale relationship between those inputs and the seasonal shifts in the ITCZ, we examined the behaviors of terrestrial input proxies in coastal sediments of western Korea, including grain size, elemental ratios from XRF core scanning (e.g., Zr/Ti and Si/Al), and C/N ratios. Correlation tests linked these proxies to past freshwater input variability, suggesting that elemental ratios can serve as a proxy for past EASM changes. During the period 8500–7800 cal yr BP, the stronger EASMs described by high-resolution peaks of Zr/Ti ratios corresponded to periods of intensified Indian summer monsoons (ISMs) and weakened South American summer monsoon (SASMs), supporting the existence of synchronous global monsoon (GM) events induced by a northward ITCZ shift. This study also shows that the 8.2-ka cooling event recorded in Greenland ice cores synchronously influenced the GM through a southward shift in the ITCZ, resulting in a weakened EASM and ISM in the Northern Hemisphere and an intensified SASM in the Southern Hemisphere. Our study thus demonstrates that the elemental ratios in coastal sediments measured using an XRF core scanner can be utilized to trace high-resolution (at least centennial-time-scale) variability in the EASM in terms of GM-ITCZ coupling.

An improved method for paleoflood reconstruction from core sediments in the upper Yellow River

Fluvial deposits represent a sedimentary archive of paleohydrological information, which can be utilized to reconstruct unrecorded floods. A multi-index (grain size, end-member model, and geochemistry elements) approach of core sediments from the upper Yellow River was used to reconstruct its flood history. A high-resolution geochemical profile of the 20.71-m-deep core was obtained by an XRF core scanner. A comparison of sediment grain size with geochemical element ratios indicated that ln(Zr/Ti) can be used as a grain size proxy for the core sediment. Combined with the end-member modeling analysis, the flood energy index (FEI) was constructed to highlight the flood signals and their similar trends with sediment ln(Zr/Ti). Coarsened grain size and increased ln(Zr/Ti) suggested that a high-frequency flood phase appeared to occur in the early Holocene (11–6.5 ka) and late Holocene (3.5–0 ka), while low-frequency floods occurred in the middle Holocene (6.5–3.5 ka). An extreme hydrological phase occurred during 5.8 ka–5.9 ka, which coincided with a sharp increase in sedimentation rates from 0.14 mm/yr to 0.48 mm/yr. The flood activities at the upper reach of the Yellow River are considered to respond to climate variability with the monsoonal shift.

As and S speciation in a submarine sulfide mine tailings deposit and its environmental significance: The study case of Portmán Bay (SE Spain)

The dumping of an estimated amount of 57 million tons of hazardous sulfide mine waste from 1957 to 1990 into Portmán's Bay (SE Spain) caused one of the most severe cases of persistent anthropogenic impact in Europe's costal and marine environments. The resulting mine tailings deposit completely infilled Portmán's Bay and extended seawards on the continental shelf, bearing high levels of metals and As. The present work, where Synchrotron XAS, XRF core scanner and other data are combined, reveals the simultaneous presence of arsenopyrite (FeAsS), scorodite (FeAsO₄·2H₂O), orpiment (As2S3) and realgar (AsS) in the submarine extension of the mine tailings deposit. In addition to arsenopyrite weathering and scorodite formation, the, the presence of realgar and orpiment is discussed, considering both potential sourcing from the exploited ores and in situ precipitation from a combination of inorganic and biologically mediated geochemical processes. Whereas the formation of scorodite relates to the oxidation of arsenopyrite, we hypothesize that the presence of orpiment and realgar is associated to scorodite dissolution and subsequent precipitation of these two minerals within the mine tailings deposit under moderately reducing conditions. The occurrence of organic debris and reduced organic sulfur compounds evidences the activity of sulfate-reducing bacteria (SRB) and provides a plausible explanation to the reactions leading to the formation of authigenic realgar and orpiment. The precipitation of these two minerals in the mine tailings, according to our hypothesis, has important consequences for As mobility since this process would reduce the release of As into the surrounding environment. Our work provides for the first time valuable hints on As speciation in a massive submarine sulfide mine tailings deposit, which is highly relevant for similar situations worldwide.

Climate changes during the Late Glacial in southern Europe: new insights based on pollen and brGDGTs of Lake Matese in Italy

Abstract. The Late Glacial (14 700–11 700 cal BP) is a key climate period marked by rapid but contrasted changes in the Northern Hemisphere. Indeed, regional climate differences have been evidenced during the Late Glacial in Europe and the northern Mediterranean. However, past climate patterns are still debated since temperature and precipitation changes are poorly investigated towards the lower European latitudes. Lake Matese in southern Italy is a key site in the central Mediterranean to investigate climate patterns during the Late Glacial. This study aims to reconstruct climate changes and their impacts at Matese using a multi-proxy approach including magnetic susceptibility, geochemistry (XRF core scanning), pollen data and molecular biomarkers like branched glycerol dialkyl glycerol tetraethers (brGDGTs). Paleotemperatures and paleo-precipitation patterns are quantitatively inferred from pollen assemblages (multi-method approach: modern analogue technique, weighted averaging partial least-squares regression, random forest and boosted regression trees) and brGDGT calibrations. The results are compared to a latitudinal selection of regional climate reconstructions in Italy to better understand climate processes in Europe and in the circum-Mediterranean region. A warm Bølling–Allerød and a marked cold Younger Dryas are revealed in all climate reconstructions inferred from various proxies (chironomids, ostracods, speleothems, pollen, brGDGTs), showing no latitudinal differences in terms of temperatures across Italy. During the Bølling–Allerød, no significant changes in terms of precipitation are recorded; however, a contrasted pattern is visible during the Younger Dryas. Slightly wetter conditions are recorded south of 42∘ N, whereas dry conditions are recorded north of 42∘ N. During the Younger Dryas, cold conditions can be attributed to the southward position of North Atlantic sea ice and of the polar frontal jet stream, whereas the increase in precipitation in southern Italy seems to be linked to relocation of Atlantic storm tracks into the Mediterranean, induced by the Fennoscandian ice sheet and the North European Plain. By contrast, warm conditions during the Bølling–Allerød can be linked to the northward position of North Atlantic sea ice and of the polar frontal jet stream.

Volcanic, tectonic and climate controls on lacustrine sedimentary supplies over the last millenia in NE Chilean Patagonia (Lake Esponja, Aysen, 45°S)

The environmental variability of Northern Chilean Patagonia during the last millennia is evaluated using a multi-proxy analysis of sediment cores from Lake Esponja (45°S 72°W) to decipher if the sediment deposition is controlled by volcanic eruptions, landslides induced by earthquake or heavy rainfall. The lake is located in a glacio-tectonic valley in Patagonia. The organic-rich clayey silt sediment with low biogenic silica content was analysed for grain size, magnetic susceptibility, organic matter, biogenic silica content and diatom assemblages, mineralogy (X-ray diffraction), organic (IRMS C and N analyses) and inorganic (XRF core-scanner) geochemistry and glass shard major composition (Microprobe, SEM). The combination of 210Pb, 137Cs, 14C and tephrochronology indicates an averaged accumulation rate of 0.4 mm/year, leading to a record of ~3.5 kyr within 154 cm. The sedimentary geochemistry records changes in volcanic supplies, diatom productivity and detrital inputs. The sediments were interrupted by millimetric to centimetric layers corresponding to tephra deposition related to explosive eruptions of nearby volcanoes Macá, Melimoyu and Hudson. Concerning the diatoms, the dominant planktonic species (80–150 cm) are replaced by benthic species in a transition interval (55–80 cm) and then by Surirella spp. in the upper core. This last genus indicates a closure of the basin ~2 ka ago, probably related to an uplift linked to a rejuvenation of the Mañihuales fault. This local change could reflect regional tectonic instability. Indeed, a partial earthquake rupture occurred around ~AD100 along the southern part of the Valdivia segment, recorded as a mass transport deposit in Aysén fjord sedimentation. The fine detrital input varies over time with more variable Si/Al values in the lower part of the LEs14 core than in the upper 80 cm. The higher values may reflect wetter conditions, leading to an higher lake level and more turbid conditions in agreement with changes in diatom assemblages.

Tracking the legacy of early industrial activity in sediments of Lake Zurich, Switzerland: using a novel multi-proxy approach to find the source of extensive metal contamination

Historical industrial activities at the Horn Richterwil, on the shore of Lake Zurich (Switzerland), caused widespread metal contamination on land and in the adjacent lake sediments. This study provides an estimation of the age and source of the contamination by using XRF core scanning, ICP-OES, and Hg-AFS for quantitative measurements of trace metals and MC-ICP-MS for the stable isotope analysis of mercury. Radiometric dating (^{137}Cs, ^{210}Pb, and Pu dating) of two proximal cores and varve chronology in a distal core suggest two different contaminations, one stemming from around 1960 (Zn, Cd) and an earlier one from 1880 (Cr, Cu, Hg, Pb, Sn). The XRF data suggest two different contamination pathways: one by landfill of contaminated soil and another one by industrial wastewater effluents. Maximum concentrations found within all samples are in the range of per mil (dry weight) for Cr, Cu, Hg, Pb, Sn, and Zn and lie within the top 10 cm of the sediment cores. The analysis of the mercury isotopic composition (delta ^{202}Hg and Delta ^{199}Hg) shows a significantly different signature for one of the cores, indicating a second mercury source. We could not identify the exact source or process leading to the isotopic fractionation of mercury, but the isotopic data confirm two different sources.

A near-continuous record of climate and ecosystem variability in Central Europe during the past 130 kyrs (Marine Isotope Stages 5–1) from Füramoos, southern Germany

Due to a general scarcity of archives and a lack of temporally highly resolved records, the response of Central European ecosystems to abrupt climate change during the Late Pleistocene – and notably the Last Glacial – has remained insufficiently explored. To contribute to a better understanding of the impact of short-term climate variability on ecosystems in Central Europe north of the Alps during that time, we present a new, near-continuous pollen record from Füramoos, southern Germany. Except for a hiatus from 28 to 20 ka BP, the record spans the past 130 kyrs in centennial-scale resolution. Our pollen dataset is augmented by sedimentological (i.e., XRF core scanning, loss on ignition, and maceral analysis) and macrobotanical data. This new record represents the yet most complete, temporally highest resolved reconstruction of terrestrial ecosystem dynamics in Central Europe for the Last Glacial period.Our results show that temperate forests thrived at Füramoos during full interglacial conditions (i.e., MIS 5e and MIS 1), boreal forests developed during the early glaciation (MIS 5 d–5a), and a tundra vegetation prevailed during full glacial conditions (MIS 4–2). Fourteen transient expansions (contractions) of tree and shrub populations that are synchronous with increases (decreases) in weathering intensity can be firmly attributed to specific Greenland Interstadials (Greenland Stadials) of the NGRIP ice-core record. By comparing individual expansions/contractions of tree and shrub populations with Greenland δ18Oice ice-core and North Atlantic sea-surface temperature (SST) data, we show that during interstadials vegetation dynamics in Central Europe were closely linked to SSTs in the North Atlantic and decoupled from the climate recorded in Greenland; during stadials, the opposite pattern prevailed. We attribute these patterns to changes in AMOC strength and associated latitudinal shifts of the polar front.

MOW strengthening and contourite development over two analog climate cycles (MIS 12–11 and MIS 2–1) in the Gulf of Cadíz: An impact on North Atlantic climate during deglaciation V and MIS 11?

High-resolution records from International Ocean Discovery Program (IODP) sites U1386 and U1387 drilled during IODP Expedition 339 into the Faro drift, made it possible to assess the impact of intensifications of the upper core (MOWU) of the Mediterranean Outflow Water (MOW) and of changes in sediment supply on the sedimentation in the northern Gulf of Cadíz since the Middle Pleistocene. This work focuses on the comparison of records covering Marine Isotope Stage (MIS) 2–1 and MIS 12–11, in order to investigate the behaviour and circulation regime of the MOWU over two climatic cycles of similar astronomical configurations and their associated deglaciation. The analysis of facies established on the basis of grain size, XRF core-scanning, and carbonate content revealed contourite beds formed by the MOWU during MIS 11 and MIS 1 and deglaciations (deglaciation V and I). Contourite sequences show that MOWU velocity at the seabed was higher during MIS 2–1 than during MIS 12–11, and that sediment supply was different between these two climatic cycles. While overall low during MIS 12–11, MOWU intensity increased during deglaciation V and MIS 11 and preceded large ice rafted events and cooling in the North Atlantic Ocean. As a major element of the MOW, MOWU strengthening during deglaciation V likely contributed to higher heat and moisture transport towards the high latitudes inducing a slight increase of calving and size of boreal ice sheets. The MOW-derived injection of heat and salt in the North Atlantic Ocean during deglaciation V might have contributed, through reactivation of the upper AMOC, to the switch of the Atlantic thermohaline circulation from a glacial to an interglacial mode.

Multiple glacio-eustatic cycles and associated environmental changes through the Hirnantian (Late Ordovician) in South China

The Hirnantian glaciation, which was the first in the Phanerozoic to occur with elevated CO 2 levels, caused severe mass extinctions and disrupted biogeochemical cycling in the latest Ordovician. Previous research that aimed at exploring the triggers and consequences (both abiotic and biotic) of this glacial event have largely been based on condensed or incomplete sections. However, there is much debate over the detailed glacio-eustatic processes, and especially over the possible existence and characterization of multiple glacial cycles. Herein we conduct high-resolution geochemical analyses (via XRF core scanning and ICP-OES/MS) and a sedimentological study of three continuous upper Katian – lower Rhuddanian drill cores (Well Huangge-1, Well Shuanghe-1 and Well Yiwan-1), which represent a combination of nearshore and offshore facies in South China. The geochemical and sedimentological evidences reveal for the first time three glacio-eustatic cycles encompassed within a major sea level cycle through the upper Katian and Hirnantian. Each glacio-eustatic cycle comprises a combination of regressive and transgressive systems tracts, with the third one denoting the largest sea level fall and the glacial maximum. This pattern of sea level changes can be correlated with both the glacial sedimentary records and geochemical signals in North Gondwana, Laurentia and Baltica. These glacio-eustatic changes likely led to perturbations in regional marine nutrient cycling and formed a redox landscape that is depicted herein as somewhat different from previous models. We also present the glacio-eustatic effects at a basin scale, and a refined constraint for the tempo of polar ice sheet advances and retreats. It also calls for a re-evaluation of the mechanisms whereby a multi-cycle glaciation led to the Hirnantian biotic crisis, a relationship that may be much more complicated than the simplified cause-and-effect relationship proposed before. • Core scanning data revealed three glacio-eustatic cycles for the Hirnantian glaciation. • New pattern of glacial cycles correlates well with other records among different blocks. • Glacio-eustatic changes formed the redox landscape both temporally and spatially.

Palaeohydrological changes recorded from a small Moroccan Middle Atlas pond during the last 6000 cal. yr BP: a multi-proxy study

The perennial and seasonal wetland diversity of the Moroccan Middle Atlas region provides a valuable “test-bed” for understanding the response of different hydrosystems to climatic variations. A multiproxy study, based on sedimentological descriptions, together with mineralogy, carbonate content, XRF core scanning and biological proxies supported by AMS 14C dates, were applied to the 3-m-long core extracted from “Flowers Marsh”, a small Middle Atlas pond. This approach provides evidence for a continuous paleohydrological and paleoenvironmental record during the Mid- to Late Holocene. The investigated aquatic system evolved from a dry or very shallow waterbody towards a system with a progressively rising water level. The dominance of the detrital fraction with poor preservation of bioindicators and eroded pollen, indicate the existence of an ephemeral waterbody from 6000 cal. yr BP until a transitional phase characterized by new sedimentological facies and the appearance of ostracods around 2300 cal. yr BP. This transition, ending at 2000 cal. yr BP, is interpreted as a flooding phase leading to an ephemeral lake. It is certainly fed by the excess water from the nearby Aguelmam Azigza Lake during its high level period. Afterwards, enhanced organic matter deposition and the appearance of well-preserved diatoms until 1400 cal. yr BP corroborate a high water-level trend. Endogenic carbonate to detrital fraction ratios indicate fluctuating, but generally shallow, water levels from 1400 cal. yr BP until 650 cal. yr BP when a relatively rapid rise in water level occurred. Flowers Marsh data are, generally, consistent with most of the existing regional records. The highstand period recorded between 2000 and 1400 cal. yr is a common feature extending to more distant sites from the northern Mediterranean. It corresponds to the wetter Iberian-Roman period. Fluctuating shallow water levels recorded since 1400 cal. yr BP to now could be linked to drier/wetter phases associated with the Medieval Climate Anomaly and the Little Ice Age (650– 150 cal. yr BP) respectively, in the western Mediterranean realm. The present study demonstrates the ability of Flowers Marsh to record valuable palaeohydrological changes since the Mid-Holocene and confirms the high sensitivity of Middle Atlas hydrosystems to climatic changes.

Processes driving seagrass soils composition along the western Mediterranean: The case of the southeast Iberian Peninsula

Seagrasses are distributed all along the coast of the Mediterranean Sea being Posidonia oceanica and Cymodocea nodosa the most common species. They promote sedimentation, leading to the formation of well-structured soils. Over the last decade, a growing attention has been paid to their role as CO2 sinks in the form of organic carbon (Corg) and to their use as environmental archives. However, most of the knowledge about pedogenetic processes in these soils refer to the rhizosphere. This study aims to understand seagrass soils biogeochemistry in the rhizosphere and below, which in turn can help to understand their long term formation processes. Fifteen cores were strategically sampled along a 350 km stretch of the Southeast Iberian coast, and analyzed for elemental composition (XRF core-scanning), magnetic susceptibility, Corg content and gran size distribution. The cores were dated by 210Pb and 14C-AMS techniques to estimate soil accretion. Principal component analysis was used to explore the main geochemical processes linked to soil formation. The results showed that terrestrial runoff plays a key role in meadow soil composition. Furthermore, Corg accumulation did not follow any general depth trend in our soil records, suggesting that temporal variation in Corg inputs is an important factor in determining carbon depth distribution within the soil. We obtained evidence that the establishment of well-developed, stable C. nodosa meadows in the Mediterranean Sea may be promoted by adverse environmental conditions to P. oceanica settlement. Metal's behavior within the meadow deposit and their interaction with organic matter and carbonates is unclear. The results presented in this paper highlight the importance of the influence of land-based inputs in the characteristics of seagrass meadow deposits, highly determining their Corg content, as well as the need for further studies on metal behavior, to understand their full potential as environmental records.

XRF and hyperspectral analyses as an automatic way to detect flood events in sediment cores

Long-term changes in flood activity have often been reconstructed to understand their relationships to climate changes. This requires identification of flood layers according to certain characteristics (e.g., texture, geochemical composition, grain-size) and then to count them using naked-eye observation. This method is, however, time-consuming, and intrinsically characterized by a low resolution that may lead to bias and misidentification. To overcome this limitation, high-resolution analytical approaches can be used, such as X-ray fluorescence spectroscopy (XRF), X-ray computed tomography, or hyperspectral imaging (HSI). When coupled with discriminant algorithms, HSI allows for automatic identification of event layers. Here, we propose a new method of flood layers identification and counting based on the combination of both HSI and XRF core scanner analyses, applied to a Lake Bourget (French Alps) sediment sequence. We use a hyperspectral sensor from the short wave-infrared spectral range to create a discrimination model between event layers and continuous sedimentation. This first step allows the estimation of a classification map, with a prediction accuracy of 0.96, and then the automatic reconstruction of a reliable chronicle of event layers (including their occurrence and deposit thicknesses). XRF signals are then used to discriminate flood layers among all identified event layers based on site-specific geochemical elements (in the case of Lake Bourget: Mn and Ti). This results in an automatically generated flood chronicle. Changes in flood occurrence and event thickness through time reconstructed from the automatically generated floods chronicle are in good agreement with the naked-eye-generated chronicle. In detail, differences rely on a larger number of detected flood events (i.e., increase of 9% of the number of layers detected) and a more precise layer thickness estimation, thanks to a higher resolution. Therefore, the developed methodology opens a promising avenue to increase both the efficiency (timesaving) and robustness (higher accuracy) of paleoflood reconstructions from lake sediments. Also, this methodology can be applied to identify any specific layers (e.g., varve, tephra, mass-movement turbidite, tsunami) and, thereby, it has a direct implication in paleolimnology, paleoflood hydrology and paleoseismology from sediment archives.

Holocene records of eolian dust deposition from high‐elevation lakes in the Uinta Mountains, Utah, USA

ABSTRACTRadiocarbon‐dated sediment cores from subalpine lakes were used to investigate post‐glacial dust deposition in the Uinta Mountains (Utah, USA). Lake sediments were geochemically characterized with ICP‐OES, ICP‐MS and XRF core scanning. Collections from passive samplers constrain the properties of modern dust, and samples of regolith constrain properties of the local material within the watershed. Ca and Eu are more abundant in dust, whereas Ti and Zr are more abundant in local regolith. As a result, the Ca/Ti and Eu/Zr ratios are indices for the dust content of lake sediment. In all records, the dust index rises in the early Holocene as watersheds became stabilized with vegetation, reducing the influx of local material. After this point, values remained above average through the middle Holocene, consistent with an increased dust content in the sediment. Dust index values drop in the late Holocene in most lakes, suggesting a decrease in dust abundance. Generally synchronous shifts in dust index values in cores from lakes in different parts of this mountain range are evidence of enhanced dust deposition in this region during the middle Holocene, and are consistent with a variety of records for increased aridity in the south‐western USA at this time.

Intercomparison of XRF Core Scanning Results From Seven Labs and Approaches to Practical Calibration

AbstractX‐ray fluorescence (XRF) scanning of marine sediment has the potential to yield near‐continuous and high‐resolution records of elemental abundances, which are often interpreted as proxies for paleoceanographic processes over different time scales. However, many other variables also affect scanning XRF measurements and convolute the quantitative calibrations of element abundances and comparisons of data from different labs. Extensive interlab comparisons of XRF scanning results and calibrations are essential to resolve ambiguities and to understand the best way to interpret the data produced. For this study, we sent a set of seven marine sediment sections (1.5 m each) to be scanned by seven XRF facilities around the world to compare the outcomes amidst a myriad of factors influencing the results. Results of raw element counts per second (cps) were different between labs, but element ratios were more comparable. Four of the labs also scanned a set of homogenized sediment pellets with compositions determined by inductively coupled plasma‐optical emission spectrometry (ICP‐OES) and ICP‐mass spectrometry (MS) to convert the raw XRF element cps to concentrations in two ways: a linear calibration and a log‐ratio calibration. Although both calibration curves are well fit, the results show that the log‐ratio calibrated data are significantly more comparable between labs than the linearly calibrated data. Smaller‐scale (higher‐resolution) features are often not reproducible between the different scans and should be interpreted with caution. Along with guidance on practical calibrations, our study recommends best practices to increase the quality of information that can be derived from scanning XRF to benefit the field of paleoceanography.