Zircon Xenocrysts Research Articles

Petrogenesis of the unbrecciated pigeonite cumulate eucrite Northwest Africa 8326: Bridging the gap between eucrites and diogenites

Understanding of the diversity and petrogenesis of achondrites is critical for deciphering magmatic processes and the early evolution of planets and asteroids. Here, we report the detailed petrologic, mineralogical, geochemical, and chronological features of the unbrecciated Vestan meteorite Northwest Africa (NWA) 8326. We found that NWA 8326 is composed of coarse-grained orthopyroxene (∼74 vol%), plagioclase (∼19 vol%), fine-grained augite (∼5 vol%), and many accessory minerals such as chromite, ilmenite, Fe-sulfide, silica phases, K-feldspar, Ca-phosphate phases, zircon, baddeleyite, rutile, and primary Si,Al,K-rich glass, differing from typical howardite-eucrite-diogenite meteorites. Based on textural feature and compositional calculation of pyroxene, we suggest that the coarse-grained orthopyroxene was inverted from primary pigeonite and NWA 8326 should be classified as a pigeonite cumulate eucrite. The oxygen and chromium isotope data (Δ17O = − 0.254 ± 0.009 ‰; ε54Cr = − 0.60 ± 0.06) support this classification. A few zircon aggregates are observed in NWA 8326 and the grains therein show a core-mantle zoned texture in cathodoluminescence (CL) images, with the cores being dark and Al-rich while the mantles being bright and Al-poor. We interpret that the CL-dark cores are xenocrystic zircon grains derived from eucrites, whose presence indicates that NWA 8326 should have formed through partial melting of the Vestan mantle, with assimilation of eucritic material. The presence of xenocrystic zircon and primary Si,Al,K-rich glass and the large compositional variation of plagioclase indicate that NWA 8326 is an unequilibrated cumulate eucrite and hence the zircon 207Pb/206Pb age of 4559.2 ± 5.2 (2σ) Ma represents the crystallization of NWA 8326. Reconciling the cumulative texture with the presence of the chemically evolved glass, NWA 8326 would be excavated during the late stage of its crystallization and escaped the prevalent crustal thermal metamorphism of the eucrite parent body. The Mg isotopic composition of NWA 8326 is higher than most diogenites, which suggests that the parent magma of such a pigeonite cumulate eucrite was derived from a source region with heavier magnesium isotopic composition (μ25Mg: −90 to − 96 ppm).

Zircon Xenocrysts From Easter Island (Rapa Nui) Reveal Hotspot Activity Since the Middle Jurassic

AbstractWe report the finding of mantle‐derived zircon grains retrieved from red soils, regoliths, and beach sands from Easter Island, that are much older than the island volcanism (0–2.5 Ma) and its underlying lithosphere (Pliocene, 3–4.8 Ma). A large population of 0–165 Ma old zircons have coherent oxygen (δ18O 3.8–5.9‰) and hafnium (εHf(t)+3.5–+12.5) mantle isotopic signatures. These results are consistent with the crystallization of zircon from plume‐related melts. In addition, a chemically diverse population with ages from the Paleozoic to the Archean was found. These older populations are enigmatic but they could represent remnants of ancient subducted sediments. Meanwhile, the ∼0–165 Ma population is interpreted as plume‐derived, suggesting that the hotspot started at least ∼165 Ma ago. A spike of ∼164–160 Ma zircons could represent a Large Igneous Province (LIP) stage upon the first arrival of the plume. We use plate reconstructions to show that such a LIP would have formed on the Phoenix Plate and would have subducted below the Antarctic Peninsula around 100–105 Ma. There, LIP subduction would offer a solution for the enigmatic Palmer Land deformation event, previously proposed to result from a collision with an unknown indenter. The here‐reported “ghost” of a prolonged hotspot activity suggests that fragments of the Easter plume and of the ambient sub‐lithospheric mantle stored and re‐sampled zircon xenocrysts due to convective (re)circulation at the scale of the plume head. Our study demonstrates how zircon geochronology and geochemistry provide novel insights into global‐scale geodynamics, offering new perspectives on the dynamics of mantle plumes and hotspot activity.

Geochronology and Origin of Quaternary Dacites from the Daliuchong Volcano in the Tengchong Volcanic Field (TVF), SE Tibetan Plateau

Quaternary volcanoes from the southeastern Tibetan Plateau occur at the Tengchong volcanic field (TVF). The Daliuchong volcano is the largest volcano in the TVF, which has the most felsic compositions with explosive eruptions. The eruption history and origin of the Daliuchong volcano are a matter of debate. In the present paper, we report the groundmass K-Ar ages, whole-rock Sr-Nd-Pb-Hf isotopes, zircon U-Pb ages, and Hf-O isotopic compositions for the Daliuchong volcano to constrain its eruption history and petrogenesis. The groundmass K-Ar ages and zircon U-Pb ages indicate mid-Pleistocene (0.6 Ma to 0.3 Ma) eruptions. The presence of zircon phenocrysts with enriched mantle-like O-Hf isotopes (δ18O < 6‰, and εHf about −2) suggests the involvement of mantle-derived basaltic magmas. The whole-rock Pb isotope compositions and Sr-Nd isotope modeling reveal the involvement of magma from the lower crust. The zircon xenocrysts reveal previously unrecognized 20-Ma magmatic activity at the TVF and contamination of late Cretaceous (66–80 Ma) S-type granites during the formation of the Daliuchong dacites. The dacite magma at Daliuchong was formed by mixing of the mantle-derived magma and lower-crust-derived magma and subsequently contaminated by upper crustal materials, including late Cretaceous S-type granitic rocks.

Origin of discordant U[sbnd]Pb dates in non-metamict zircons in intrusives deformed at granulite facies: Grain scale processes, and relevance to Cambrian orogeny, Eastern Ghats Belt, India

Interpreting the origin of UPb discordance in zircons in intrusives that experience high-T metamorphic-deformation events is challenging. We investigate in depth the origin of UPb dates obtained from garnet-bearing border zone granitoids and a sheared ferrodiorite dyke bordering the Balangir anorthosite pluton, eastern India. The crustal domain is known for discordant ages resulting in disputes regarding the age of intrusion and multiple granulite facies events. We shed light on the origin of the discordant dates utilizing CL imaging, electron backscatter diffraction analysis, trace element mapping in zircons, and Ti-in-zircon thermometry.Zircons in the foliated border zone granitoids (BZG) comprise (a) embayed cores with varying Y, U and Hf oscillatory zones, and (b) well-faceted chemically-homogeneous mantles crystallographically continuous with the cores, which truncate the oscillatory zones. In the intensely sheared ferrodiorite, cauliflower-shaped zircons possess profuse micropores and micro-fractures. Ti-in-zircon temperatures (700–950 °C) overlap in the texturally-distinct zircons, but are somewhat lower in the mantles/cauliflower-shaped zircons relative to the oscillatory-zoned cores in BZGs.LA-ICP-MS dates of zircons in four samples constitute a near-unique discordia line with the upper and lower intercepts at ca. 980 Ma and 495 Ma. Interestingly, dates from the mantles are highly variable with no correlation between age decrease and distance to the cores. The lack of concordant dates at the two intercepts, and the increase in discordance away from the intercepts preclude episodic zircon growth, and suggests a single-stage granulite facies event (ca. 495 Ma) that modified the ∼980 Ma zircon xenocrysts entrained from protoliths into the intrusives. We propose the age discordance was caused by melt-mediated high-T interface coupled dissolution-precipitation processes at ∼495 Ma. Variable inheritance of isotopic signatures of ∼980 Ma zircon xenocrysts in the younger zircons contributed to discordance in UPb systematics; the effect of variable inheritance of ∼980 Ma isotope signatures is less pronounced in the cauliflower-shaped zircons from the HFSE enriched ferrodiorite residual melts from high degree of plagioclase fractionation.Our results are consistent with a distinct Cambrian (∼495 Ma) orogeny involving emplacement of anorthosite pluton and related intrusives and high-T granulite-facies deformation-metamorphism in the ∼980 Ma Eastern Ghats Province, and are a direct record of Cambrian collision between the Eastern Ghats Province and the Archean cratonic nucleus.

Late Paleozoic potassic igneous rocks of the Kensu and Dzholkolot plutons in the eastern Kyrgyz Tien Shan: Petrology, geochemistry, U-Pb zircon geochronology, and related skarn-porphyry W-Mo-Cu-Au mineralization

The Kensu and Dzholkolot multiphase intrusions are situated in the eastern part of the “Main Structural Line of Tien Shan”, or the “Nikolaev Line”. The plutons comprise mafic to intermediate (monzogabbro, monzonite, syenite, quartz syenite) and silicic (quartz monzonite, monzogranite, and leucogranite-alaskite) members, together with the interim (camptonite) and final monzodiorite-porphyry dikes. Geochemical signatures of the igneous rocks correspond to high-K calc-alkaline to shoshonitic series intrusions, with a strong A-type affinity, emplaced in post-collisional setting. Magmatic evolution included a generation of shoshonitic magma by a low-degree partial melting of the metasomatically-enriched upper mantle, followed by amphibole fractionation in a deep (lower crustal?) magma chamber. This was followed by a generation of mantle-induced granitic magmas in a crustal protolith, with possible mixing/mingling of various magmas. The rocks crystallized at shallow levels, in an oxidized environment, under decreasing pressure and temperature toward the younger (granitic) intrusion phases.Isotopic U-Pb (LA-ICP-MS) zircon dating of the igneous rocks indicates their Late Carboniferous age (ca. 325–302 Ma). The magma emplacement included a number of intrusion phases from monzogabbro (321 ± 4 Ma), monzonite (319 ± 4 Ma), and camptonite (306 ± 4 Ma), to quartz syenite (305.5 ± 2 Ma to 302 ± 3.7 Ma), quartz monzonite (305 ± 3 Ma) and subsequent granitic phases. Although the ages identified correspond to those of the subduction-related magmatism in the western part of the Middle Tien Shan, geochemical characteristics of the rocks supporting rather post-collisional setting of the plutons are in agreement with a “scissor-like” closure of the Turkestan paleoocean, starting from the east. Zircon xenocrysts dated at ca. 1.9 Ga suggest the presence of an underlying old continental crust.The skarn-porphyry W-Mo(−Cu-Au) mineralization complements the group of similar deposits associated with high-K calc-alkaline to shoshonitic series intrusions in the Middle Tien Shan and globally. The high endowment in W and Mo can be related to the fertilization of subduction-modified subcontinental lithospheric mantle in these metals, together with more common fertilization in Cu and Au, with its subsequent involvement in the magma generation in post-collisional setting. The endowment in W and Mo can also reflect a greater involvement of an ancient continental crust as the magma source(s). The oxidized paragenesis of hydrothermal alteration assemblages and mineralization corresponds to the respective affinities of the igneous rocks.

Carbonatite Metasomatism in a Subvolcanic Setting: Breccia at the Badou Carbonatite in the North China Craton and Implications for Magmatic Evolution and Eruptive Style

Abstract The genesis and primary compositions of carbonatite melts are enigmatic owing to their reactivity and resulting contamination in the mantle and crust. This overprints earlier uncontaminated compositions and obscures their origins. The subvolcanic Badou carbonatite in the North China Craton is characterized by brecciated textures and comprises pristine clinopyroxene, mica, and apatite phenocrysts in a mixed, carbonate–silicate matrix. Here, we provide mineralogical, textural, and major and trace elemental results to reveal the mantle derivation of the Badou carbonatite melt, and its compositional modification during interaction with crustal materials. Clinopyroxene and apatite phenocrysts have initial Sr isotopes (0.70920–0.71037) similar to brecciated calcite (0.71028–0.71159) and the whole rock (0.70953–0.71061), indicating a common source. Rare Mg-rich clinopyroxene and mica contain high Cr and Ni contents, recording direct mantle derivation without immiscibility from silicate melts. Abundant feldspars and aegirine, occurring as both phenocrysts and fine-grained matrix, formed an antiskarn at relatively low temperatures indicating extensive silica contamination upon crustal emplacement. Silica contamination is further indicated by britholite-rich apatite rims and relict quartz cores in clinopyroxene. Zircon xenocrysts were partly assimilated, indicated by Zr and Hf enrichment in late-stage silicates, and partly underwent decomposition to baddeleyite in a decreasing silica activity environment. The assimilation process consumed the carbonate melt, forming refractory silicate minerals and CO2 vapor, leading to near-surface gas overpressure with a decrease in magma viscosity. This elevates the potential for explosive activity, which, in turn, provides a positive feedback mechanism for silica assimilation. The complex evolution of the carbonatite melt in the crust might be responsible for the compositional gap between the natural rocks and experimental outcomes, and results in different eruption styles.

Zircon U[sbnd]Pb geochronology and geochemistry of hot subduction volcanic suite in the deep bore-hole well-core KBH-5: Evidence of Neoarchean Shimoga greenstone belt beneath the Cretaceous Deccan Traps, India

The continents across Earth have grown through accretion and amalgamation of plume-generated oceanic plateaux and subduction-originated magmatic arcs. The evidence of such evolutionary processes is well preserved in the greenstone belts of Canada, South Africa, China, Australia and India. Unlike accretion that leads to lateral growth of the continents, flood basalt volcanism results in the superposition of large volumes of dense mafic material above relatively less dense sialic upper continental crust. The resulting density inversion is liable to generate tectonic stresses resulting in faulting of under burden along weak planes. The nature of the crust obscured beneath flood basalt provinces that have accumulated over the past 500 My in Large Igneous Provinces (LIPs) has remained enigmatic, largely because of the voluminous lava pile that deters access to the concealed basement, unless otherwise retrieved through deep continental drilling. Here, we present in situ zircon UPb geochronology and bulk-rock geochemistry of a volcanic sequence discovered at −400 m m.s.l in the deep bore-hole well-core KBH-5 of the southwestern Deccan Traps, India. The ∼300 m thick metavolcanic succession includes a basalt – Nb-enriched basalt – andesite – Mg-andesite – dacite – adakite suite. The zircons yielded a 2.58 Ga U-Pb age for the suite, which also incorporates entrained zircon xenocrysts of 2.7 Ga age from a preexisting juvenile material during its emplacement. The bore-hole KBH-5 is located on an NNW-SSE trending normal fault, paralleling a series of major faults west of the Western Ghat Escarpment. Although the crustal block plummeted ∼1000 m downward along the fault plane, the geochemical attributes of the metavolcanic rocks are thoroughly comparable to those reported in the Medur Formation of the Shimoga greenstone belt, ∼300 km south of KBH-5 in the western Dharwar craton. Our study provides the first physical evidence of Dharwar greenstone belt(s) extending further beneath the Deccan Traps, which was previously only speculative based on short-wavelength gravity highs. The metavolcanic sequence evolved in a subduction-related back-arc tectonic regime and accreted to the active continental margin of India in the Neoarchean. Unveiling of potentially similar scenarios in cratons elsewhere entrapped beneath the vast canopy of continental flood basalts, would reveal new crustal growth events during the Archean -Proterozoic transition across the Earth.

Xenoliths of the bode dike system: evidence for early Devonian arc-type magmatism and late Carboniferous–Permian crust reworking beneath the eastern Harz Mountains (Germany)

Xenoliths recovered from the post-Variscan Bode dike system of the eastern Harz Mountains provide evidence for the existence of an Early Devonian magmatic arc system hidden beneath very low-grade metasedimentary rocks of the Rhenohercynian Zone, but also for Late Carboniferous–Early Permian crust reworking. This interpretation is based on petrographic observations and whole-rock geochemical analyses of granite xenoliths, in addition to results of zircon U–Pb dating and Hf isotope analyses. Zircon grains recovered from variably deformed granite xenoliths yield ages between 419 and 393 Ma, interpreted to reflect the timing of granite intrusion. Rare zircon xenocrysts of Archean (ca. 2.92–2.65 Ga) and Proterozoic age (ca. 1.5 to 0.56 Ga), all with subchondritic εHf420 Ma values (− 0.8 to − 5.5) indicate reworking of older crust. Compilation of age-Hf isotope data further suggests that the pre-Variscan granitoids beneath the Harz Mountains belong to the same magmatic arc system exposed widespread in the adjacent Mid-German Crystalline Zone, and interpreted to result from NW-ward subduction of the Rheic Ocean beneath Avalonia-Baltica. Zircon in xenoliths with granophyric texture yields ages at 400 Ma and 295–310 Ma, indicating re-melting of Devonian granitoid basement during post-Variscan rift-related magmatism, immediately prior to Bode dike intrusion.Graphical abstractLeft: Late Devonian intrusion of magmatic arc granites during NW-ward subduction of the Rheic ocean beneath Avalonia-Baltica. Right: Formation of the Bode dike system and Harz granites during Late Carboniferous-Permian extension.

Zircon Petrochronology of Au-Rich Porphyry and Epithermal Deposits in the Golden Quadrilateral (Apuseni Mountains, Romania)

Abstract The Golden Quadrilateral of the Apuseni Mountains (Romania) represents the richest Au(-Cu-Te) porphyry and epithermal district of Europe and the Western Tethyan metallogenic belt. The Au(-Cu-Te) mineralization is associated with Neogene calc-alkaline magmatism along graben structures growing during the late stages of the Alpine-Carpathian orogeny. We use zircon petrochronology to study the time-space distribution, sources, composition, and timescales of the Au(-Cu-Te)-mineralizing magmatism and explore its link to regional tectonics. Our own and published U-Pb zircon ages document ore-forming magmatic activity between ~13.61 and 7.24 Ma. In combination with available paleomagnetic data, the new zircon ages corroborate the hypothesis that the magmatism in the Golden Quadrilateral evolved in a tectonic environment dominated by major (up to 70°) crustal block rotation. Hafnium isotope composition of Neogene zircon (εHf between –2 and 10) supports the predominant origin of the magmas from a heterogeneous lithospheric mantle, which may have been fertilized during an earlier Cretaceous subduction event and possibly by concurrent Miocene subduction. Xenocrystic zircon shows involvement of crustal sources resembling European continental basement. Fertility indicators, including Eu/Eu* and oxygen fugacity based on zircon composition, show no systematic correlation with the mineralizing events and/or age. High-precision (isotope dilution-thermal ionization mass spectrometry) U-Pb zircon geochronology demonstrates that the magmatic systems exposed at district scale evolved over less than ~100 k.y. and that durations of hydrothermal mineralization pulses were even shorter.

Petrogenesis, geochronology, and tectonic setting of the Calymmian 1.45–1.50 Ga basic magmatism in the Southern Ribeira Belt, Brazil: evidence of intracontinental rifting and Columbia break-up

ABSTRACT We present new petrographic, whole-rock geochemistry, and SHRIMP U – Pb zircon geochronological data of metabasic rocks interlayered as sills in the metasedimentary units of the Perau and Betara formations, Votuverava Group, Southern Ribeira Belt, Brazil. These formations overlie ~ 1.8 Ga Paleoproterozoic metagranitoids that represent basement inliers from the Paranapanema Craton. Petrography and whole-rock geochemistry allow the recognition of four groups, ranging from primitive to evolved compositions: i) cumulatic metadolerites (G1), ii) isotropic metadolerites (G2), iii) ortho-amphibolites (G3); and iv) ferroan ortho-amphibolites (G4). They exhibit tholeiitic subalkali basaltic composition, near-flat REE patterns, and signatures between N- and E-MORB. Fractional crystallization under low fO2 conditions is the main petrogenetic process controlling the magmatic evolution, as observed by Ti/V and Cr/Y ratio and tholeiitic trends. Crustal contamination signatures are observed through negative Nb anomaly, Th/Nb-Ti/V proxies trends, LILE enrichment, and, also, assimilated xenocryst zircons aged ~ 2.2 Ga. REE and trace element systematics indicate that the basic magmas were generated by ~ 20–10% partial melting of a model asthenospheric mantle source within spinel facies. TiO2/Yb-Nb/Yb and Nb/Yb-Zr/Yb ratio proxies and P-MORB metabasic rocks, previously described in the literature within the Votuverava Group, suggest a plume-influenced melt. A new SHRIMP U – Pb zircon age of 1448 ± 11 Ma was determined for an ortho-amphibolite sample (G3 group). We propose an intracontinental tectonic setting for the genesis of the metadolerites whitin the Perau and Betara formations, suggesting that this extensional event is associated with the Paranapanema Craton rifting. Furthermore, the genesis of the studied metabasic rocks could be associated with a regional extensional event during Calymmian times (~1.5–1.45 Ga), which generated basic magmatism in several other cratons, such as the Congo, São Francisco, Siberian, Laurentian, and China cratons, linked to the break-up of the Columbia Supercontinent.

Petrogenesis and zircon U-Pb ages of the Late Paleozoic high-potassic Sonkul and Kokturpak plutons in Kyrgyz Tien Shan, with implications for related skarn-porphyry W-Au(-Cu-Mo) mineralization

ABSTRACT The Sonkul and adjacent Kokturpak multiphase plutons are situated along the ‘Major Structural Line of Tien Shan’ (known also as the ‘Nikolaev Line’) that extends for over 500 km and divides the terranes of the Middle and Northern Tien Shan. The plutons comprise a broad variety of high-potassic igneous rocks including the early olivine gabbro, intermediate monzonite to quartz monzonite, and later granodiorite, monzogranite, and leucogranite-alaskite, in turn followed by the late mafic dikes. U-Pb dating of zircon grains yields ages of 299 ± 2 Ma (olivine gabbro), 300 ± 3 Ma to 298 ± 3 Ma (monzonite to quartz monzonite), 299 ± 3 Ma to 298 ± 4 Ma to 297 ± 4 Ma (granodiorite), and 289 ± 4 Ma to 285 ± 2 Ma (monzogranite). These consecutive intrusive phases appear to have been produced by partial re-melting of a partially crystallized (mush) magma batch at deeper levels, which is evident by the presence of zircon antecrysts dated at some 306–311 Ma (up to 323 Ma?). Geochemical signatures of the igneous rocks correspond to high-K calc-alkaline to shoshonitic series intrusions emplaced in a transitional subduction-related to post-collisional setting. A low-degree partial melting of the metasomatically enriched upper mantle can be envisioned as the leading process of shoshonitic magma generation; this was followed by amphibole fractionation in a deep (lower crustal ?) magma chamber and possibly a mantle-induced generation of granitic magmas in the crustal protolith. Further mixing/mingling of the mafic magma and crustal granitic magma was followed by the magma fractionation and emplacement at shallow crustal levels. Assimilation of the old continental crust is consistent with the presence of ancient xenocrystic zircons (dated at ca. 1.5 to 2.5 Ga) in the studied rocks. The Late Carboniferous to Early Permian age and high-K calc-alkaline to shoshonitic composition are similar to those of highly mineralized intrusions of the other segments of the Middle Tien Shan. In this regard, several magmatic pulses of high-potassic intrusions and corresponding metallogenic pulses can be suggested in this region. Whereas the early (ca. 337 to 315 Ma) igneous suites accompanied by dominantly porphyry Cu-Au-Mo mineralization, the later (ca. 305 to 285 Ma) suites including the Sonkul and Kokturpak plutons are accompanied by W- and/or Au-dominant mineralization. This mineralization appears to pre-date more substantial intrusion-related to orogenic-type Au mineralization.

Abundant 2480 Ma Detrital Zircons in ∼1740 Ma Vishnu Schist in Northwestern Arizona: Derivation From the Matachewan Large Igneous Province?

Detrital zircon grains in the ∼1740–1750 Ma Vishnu Schist and similar rock units in northwestern Arizona consist of up to 30% grains dated by U-Pb isotopic analysis at 2470–2490 Ma. These zircon grains are distributed over ∼40,000 km2 and define an age peak at 2480.0 ± 27.3 Ma (2SE). These grains have yielded unusually consistent 207Pb/206Pb dates, with generally smaller analytical uncertainty and greater concordance to ideal U-Pb evolution than grains of other ages. A weighted mean age of 2480 ± 0.9 Ma (2SE) for this zircon population reflects consistent analytical results and high analytical precision but not the accuracy of the age. The source of these zircons has not been identified. To better characterize the unidentified source, we analyzed 45 of these grains for trace and rare-earth elements by laser-ablation mass spectrometry and scanned 16 grains with an electron microprobe to identify mineral inclusions. Mass spectrometer determinations of Sc/Yb and Nb/Sc support derivation from an oceanic-island igneous source. Electron microprobe scans revealed quartz in 5 of 16 grains, indicating a felsic source. The low variability in 207Pb/206Pb dates and a generally linear relationship between U and Th support zircon derivation from a single igneous unit or closely related set of units without xenocrystic zircons. A literature search for other zircon populations with similar age and U/Th ratios identified ∼2480 Ma zircons in a Mesoproterozoic(?) metapsammite and conglomerate in southwestern Montana. This sandstone was deposited near the margin of the Wyoming craton and contains almost entirely 2400–3600 Ma zircons, unlike zircon grains in Vishnu Schist which include a large population of 1730–1900 Ma zircons. From this relationship we infer that the 2480 Ma zircons in both areas were derived from a source in the Wyoming craton. We conclude that the 2480 Ma Vishnu zircons were derived from a felsic batholith that formed above and from hotspot magma related to the ∼2450–2480 Ma Matachewan Large Igneous Province, that this batholith formed by mixing between a mantle-derived hotspot magma and assimilated Archean continental crust, and that the source rock was emplaced during initial rifting between the Wyoming craton and the Superior province.

Late Paleozoic potassic igneous rocks of the Adyrtor intrusions in the eastern Kyrgyz Tien Shan: geochemistry, isotope U-Pb zircon geochronology, and related W-Mo(-Cu-Au) mineralization

ABSTRACT The Adyrtor multiphase pluton is situated in the easternmost part of the ‘Main Structural Line of Tien Shan’, or the ‘Nikolaev Line’, and intrudes the Paleoproterozoic metamorphic sequence representing the oldest (1.8–2.5 Ga) continental basement fragment in the Tien Shan orogenic belt. The intrusions comprise mafic to intermediate (monzodiorite, monzonite, quartz syenite) and silicic (quartz monzonite, monzogranite, and leucogranite-alaskite) rocks. Geochemical signatures of the igneous rocks correspond to high-K calc-alkaline to shoshonitic series intrusions, with a strong A-type granite affinity, emplaced in post-collisional setting. Based on the isotopic U-Pb data, quartz syenite from the Adyrtor intrusions crystallized at 330.7 ± 4.3 Ma, and quartz monzonite – at 329.5 ± 5.8 Ma. Although the ages identified correspond to those of the subduction-related magmatism in the western part of the Middle Tien Shan, geochemical characteristics of the rocks support rather post-collisional setting of the plutons, principally due to a ‘scissor-like’ closure of the Turkestan paleoocean, starting from the east. Magmatic evolution included a generation of shoshonitic magma by low-degree partial melting of the metasomatically-enriched upper mantle, followed by amphibole fractionation in a deep (lower crustal ?) magma chamber. Then, under the influence of mantle-supplied fluids and heat, granitic magmas in the crustal protolith could have been generated, with further mixing/mingling of the mantle-derived mafic (shoshonitic) magma and mantle-induced crustal granitic magma, followed by the magma fractionation and emplacement at shallower crustal levels. Assimilation of an old continental crust is also envisioned, consistent with the presence of the xenocrystic zircons dated at ca. 1.6 Ga to 2.5 Ga and the A-type granitoid affinity of the igneous rocks. The associated skarn-porphyry W-Mo(-Cu-Au) mineralization is consistent with post-collisional setting of the productive intrusions. This mineralization complements the group of similar deposits and occurrences associated with high-K calc-alkaline to shoshonitic series intrusions in the Middle Tien Shan and globally. The high endowment in W and Mo can be explained by the fertilization of subduction-modified subcontinental lithospheric mantle in these metals, with its further involvement in the magma generation in post-collisional setting. Also, a stronger W-Mo mineralization can reflect a greater role of a crustal protolith in the magma generation, as revealed by the distinct A-type affinity of the igneous rocks.

Refining granite generation by interrogation of zircon and monazite U-Th-Pb and Hf/Nd-O isotopes

In-situ geochemical and isotopic analyses of zircon and monazite can provide compelling and detailed insights into the source and evolution of their hosting granite. Here we investigated the U-Th-Pb and Hf/Nd-O isotopic signatures of zircon and monazite in two petrological zones (i.e., fine- to medium-grained zone and medium-grained zone) of the Laojunshan granite pluton in the Qinling Orogen, central China, to better constrain their source nature and evolution processes. Co-existing magmatic zircon and monazite in both zones gave identical crystallization ages of ca. 113 Ma. In the fine- to medium-grained zone, both magmatic and xenocrystic zircons were identified, which respectively have εHf(t) values of −6.5 to −5.0 and − 17.4 to +5.1, and δ18OVSMOW values of +5.25‰ to +5.78‰ and + 5.17‰ to +9.15‰. The age distribution pattern and HfO isotopic characteristics of the xenocrystic zircons are similar to those of detrital zircons from the wall rock, i.e., meta-sedimentary rocks in the Kuanping unit. Monazite grains in this zone have relatively low SiO2, ThO2 but high CaO contents, dominated by cheralite-type substitution. These monazites have εNd(t) values of −5.8 to −4.6 and δ18O values of +3.79‰ to +5.66‰, except one grain (εNd(t) = −10.4 to −9.6, δ18O = +9.22‰ to +9.81‰), which is likely a xenocrystic crystal assimilated from wall rocks. The identical UPb age but contrasting NdO isotopic compositions between the xenocrystic monazite and the magmatic monazite grains indicate that the former might have experienced solid-state recrystallization process and completely lost radiogenic Pb. Both zircon and monazite geochemical and isotopic signatures consistently indicate that crustal assimilation occurred in the fine- to medium-grained granite zone. In contrast, in the medium-grained zone, only magmatic zircons and monazites were identified. The magmatic zircons have εHf(t) values of −3.2 to +2.7, and δ18O values of +4.65‰ to +6.36‰. The magmatic monazites are characterized by huttonite-type substitution with high SiO2, ThO2 but low CaO contents. Their εNd(t) values vary from −5.7 to +1.6 (mostly < −4.4) and δ18O values from +4.65‰ to +6.36‰. Given that the isotopic features of zircons and monazites in this zone are consistent with their whole-rock isotope features and no inherited/xenocrystic grains were observed, the zircons and monazites should record the source isotope compositions. The presence of highly radiogenic Nd isotopes in monazite coupled with its normal mantle-like O isotopes suggest minor involvement of juvenile mantle-derived components in the magma source. Accordingly, we advocate combined study of zircon and monazite, which can better track granite source nature and evolution processes than individual mineral.

Zircon U-Pb-Hf constraints on the geological evolution of the Bihar Mica Belt, Central Indian Tectonic Zone, and its link to Columbia assembly

In this study, U-Pb-Hf isotope composition and trace element chemistry of zircon from basement gneisses and quartzites of the Bihar Mica Belt (BMB), a belt of supracrustal rocks within the Central Indian Tectonic Zone, is used to constrain crustal growth and reworking. The protoliths of BMB gneisses were emplaced at 1651 ± 5 Ma. The magmas were derived from juvenile and 1747 ± 7 Ma I-type long-lived felsic precursors that survive as xenocrystic cores. Zircon grains from quartzites display two distinct morphologies. Grains with little rounding of edges have internal structures comprising 1750 ± 5 Ma inherited cores mantled by 1657 ± 4 Ma igneous zones that are identical to those from the granite gneisses. The εHf (t) and trace element composition of both the xenocrystic cores and the igneous mantles in these detrital grains are identical to those of zircon in the gneisses. They constitute molasse-like sediments derived from the nearby basement. More rounded grains furnish age clusters between 1857 and 2848 Ma, suggestive of long-distance transport and derivation from multiple sources. In-situ formed metamorphic rims around zircons in gneisses and quartzites furnish 1476–1466 Ma ages, dating the earliest metamorphic overprint. The age of sedimentation is bracketed between 1657 Ma and 1466 Ma. The 1651 ± 5 Ma gneisses and its 1747 ± 7 Ma felsic precursor were I-type, and emplaced in an arc setting. They constitute part of the expansive suite of Paleoproterozoic gneisses of the Chhota Nagpur Gneiss Complex emplaced during protracted period of arc-magmatism between 1.75 Ga and 1.65 Ga. Strongly positive εHf(t) of 2.0–2.85 Ga detrital zircons conforms to the global trend of positive εHf(t) excursions and high dT/dP gradients, and may correspond to passive margin juvenile magmatism associated with the break-up of Archean supercratons prior to Columbia assembly. The 1.86 Ga and 1.75 Ga detrital and xenocrystic zircons from the BMB have enriched εHf(t), in accordance with negative excursions seen in global zircon between 2.0 Ga and 1.70 Ga, reflecting progressive assembly of Columbia through collisional orogenesis. An excursion to strongly positive εHf(t), coinciding with low dT/dP gradients at ca. 1.65 Ga, reflects wide-spread formation of arcs linked to accretionary growth of Columbia.

Spatiotemporal distribution of magmatism and crustal inheritance within an extensional–rotational environment: an updated geochronology of the Miocene and Quaternary magmatism of the South Apuseni Mountains

Extension-related magmatism with arc-like features was active in the South Apuseni Mountains, Romania during the Neogene and Quaternary. The current chronological framework is primarily restricted to K–Ar dates. We present here new laser ablation inductively coupled plasma mass spectrometry U–Pb zircon age data for 20 subvolcanic and volcanic rocks from eight different Cenozoic volcanic–intrusive complexes and from Jurassic and Cretaceous lava flows. Our results support magmatic ages between c. 14 and c. 7 Ma, with Uroi, an alkaline intrusion, occurring significantly later at c. 1.5 Ma. Revising the timeline for the South Apuseni Mountains palaeomagnetic rotations shows that most of the clockwise vertical-axis rotation of these mountains (54.4° ± 10.7°) took place between c. 14 and 11 Ma, the age interval when the majority of the magmas were emplaced. Xenocrystic zircon dates show differences in the age populations between individual volcanic–intrusive complexes. A Permo-Triassic population is almost ubiquitous, indicating that basement Permo-Triassic igneous rocks are more widespread than previously thought, or that they were significantly involved in the generation of Neogene magmas. However, other observed age populations, such as Triassic or Paleogene, have no clear correspondence in the known geological record, indicating the presence of a cryptic component interacting with Neogene magmas. Supplementary material: Full analytical details and age calculations for the U–Pb age data collected during this study, rock samples and separated zircon fraction descriptions and the palaeomagnetic and age databases are available at https://doi.org/10.6084/m9.figshare.c.6951429

Magmatic and rare Eocene to Precambrian xenocrystic zircons in Dominica reveal discrete crystallization episodes and multiple sediment sources

The effects of sediment contribution to the Lesser Antilles island arc have been well explored with whole-rock trace-element chemistry and isotopic studies. To better understand the source of these sediments, we analyzed &amp;gt;400 zircons for U-Pb ages and trace-element chemistry in eight andesitic-dacitic ignimbrites and lavas younger than 100 ka from the island of Dominica in the central Lesser Antilles arc. The overwhelming majority of the zircons analyzed were magmatic in origin, with U-Pb ages younger than 10 Ma, but predominantly younger than 300 ka. Zircon trace-element chemistry is consistent with derivation from an oceanic-island arc, and positive εHf(t) values (+5 to +15) support a juvenile depleted mantle source. Rare Precambrian to Eocene xenocrystic zircons (36) were also found in the Dominican volcanics and record sediment dispersal from several different terranes as the Caribbean plate migrated eastward along the northern margin of South America. Although some previous detrital zircon studies in the region suggested zircons younger than 100 Ma were derived from the Great Arc of the Caribbean, the younger Dominican zircon xenocrysts (300−50 Ma) have elevated Th/Yb and U/Yb, as well as variable positive/negative εHf(t) values, inconsistent with an oceanic arc origin. These zircons in Dominica were most likely derived from the Eastern and Central Cordillera of the Andes, which experienced a flare-up in magmatism ca. 65−45 Ma. As the Great Arc of the Caribbean traversed along the South American margin, terrigenous sediments transported via river systems and turbidites accumulated in the forearc basin. Older zircons (1800−300 Ma) have a slightly different chemistry and equivocal source(s), including the Andes, northern Venezuelan coastal ranges, and/or the Guyana Shield.

The Cerro Guacha Caldera complex, SW Bolivia: A long-lived, multicyclic, resurgent caldera complex in the Altiplano-Puna Volcanic Complex of the Central Andes

Measuring ∼50 × 30 km, the Cerro Guacha Caldera Complex (CGCC) is a polycyclic, nested caldera complex within the Altiplano Puna Volcanic Complex (APVC) of the Central Andes. Previous work had established that CGCC was built in three stages. Catastrophic supereruptions of the 1300 km3 (DRE - Dense Rock Equivalent) Guacha ignimbrite at ca. 5.65 Ma and the 800 km3 (DRE) Tara ignimbrite at ca. 3.49 Ma resulted in two nested caldera collapses that define the first two stages (G1C and G2C) of the CGCC. The third stage, G3C, initiated ∼1.8 Ma with the eruption of the Puripica Chico ignimbrite and associated lavas. The only previous detailed systematic study of the CGCC was of the G2C (Grocke et al., 2017a, 2017b). In this work we provide new field, petrochemical and geochronological data on the first and third cycles that now allow us to present the first comprehensive account of the eruption history, as well as the magmatic and volcanological evolution of the CGCC as a long-lived caldera complex.Erupted compositions during the G1C and G3C cycles are dominantly high-K, calc-alkaline dacites and minor andesites and these fall within the andesite to rhyolite compositional array previously defined for the G2C. In the CGCC as a whole, dacitic compositions account for over 90% of the ∼2200 km3 of magma erupted. These data reveal a consistency of magma composition, storage and evolution throughout the >4 Ma history of the CGCC.New UPb in zircon ages reveal distinct zircon age distributions that indicate that each caldera cycle represented new magmatic cycles that accumulated 10's to 100's of thousands of years prior to eruption. We find zircon antecrysts in all eruptive stages which we interpret as assimilation of non-erupted progenitors of earlier magmatic cycles. Occassional zircon xenocrysts and cores are interpreted as assimilation of upper crustal basement lithologies, supporting previous interpretations of upper crustal open system magmatic evolution for the G2C to the entire CGCC.Both the G1C and G2C calderas are west-hinged trap-door style collapses. Of these, the 5.65 Ma G1C caldera measures ∼50 km × 30 km, whereas the 3.49 Ma G2C is 30 × 20 km and is nested within the G1C. Resurgent uplift in both the calderas reveals at least a kilometer thickness of intracaldera ignimbrite. Outflow ignimbrites from the CGCC extend 100 km N-S and 40 km E-W around CGCC and were topographically limited. Intracaldera ignimbrite volume dominates outflow volumes by a ratio of ∼5:1. Repose periods between successive stages are now calculated to be 2.1 (G1C to G2C) and 1.8 (G2C to G3C) Myr respectively.The evolution of the CGCC parallels other APVC calderas and is closely linked to the history of the APVC flare-up. The two supereruptions at 5.65 Ma (Guacha Ignimbrite) and 3.49 Ma (Tara Ignimbrite) coincide with the peak of the flare-up and its eruptive and magmatic tempo correlate with the regional tempo. The eruptive and magmatic histories connote a composite granodioritic subcaldera pluton of significant extent accumulated in the upper crust beneath the CGCC.

Geochemistry and U–Pb zircon geochronology of S-type granites in the Karagwe Ankolean Belt, northwestern Tanzania: Implications for rare-metals mineralization

The Mesoproterozoic Karagwe Ankolean Belt in the Central Eastern Africa region hosts suites of granites that intruded supracrustal rocks and are associated with Sn–W mineralization. In northwestern Tanzania, the granites are S-type, peraluminous and calc-alkalic to alkalic-calcic in composition. Geochemical analyses of the granites reveal the following concentrations: SiO2 (71–77 wt%), Al2O3 (11–15 wt%), K2O (3–7 wt%), MgO (0.06–0.86 wt%), TiO2 (0.07–0.36 wt%) and Fe2O3T (0.71–2.40 wt%). The SiO2 contents correlate negatively with MgO, CaO and K2O and positively correlate with Nb, Ta, Zr, Sr, Ba, Hf, Th and the REE (Eu, Ce and Sm). Primitive mantle normalized spider plots show elevated LILE against depletions in Ba, Nb, Ti and La, suggesting inherited arc-magmatic signatures from the protolith. Chondrite-normalized REE spider plots show elevated LREE and relatively flat MREE and HREE as indicated by (La/Yb)cn = 2–9 and negative Eu* anomalies (0.05–0.24). Modelling of nearby Uha group sedimentary rocks partial melts, supports fractional crystallization and upper crustal contamination for generation of the KAB granites. Trace elemental ratios of Y/Nb, Nb/Ta, Zr/Hf and P205 suggest the granites are weakly mineralized to barren in Sn–W.The U–Pb zircon ages point to two successive and overlapping periods: from 1418 ± 15 Ma to 1395 ± 6 Ma (mean = 1406 Ma) and from 1385 ± 8 Ma to 1376 ± 11 Ma (mean = 1381 Ma). Inheritance U–Pb dates of xenocryst zircons, comprise early to late Paleoproterozoic ages ranging from 2376 ± 30 Ma, 2000 ± 27 Ma to 1901 ± 39 Ma, and from 1795 ± 7 Ma to 1738 ± 7 Ma, implying the participation of the Paleoproterozoic sedimentary rocks in the petrogenesis of the granites. A zircon rim overgrowth age of 1015 ± 26 Ma is interpreted to date a metamorphic/anatexis event that coincided with the c.1000 Ma amalgamation of the supercontinent Rodinia and the emplacement of Sn–W enriched granites. The ages of S-type granite magmatism (1418–1376 Ma) obtained from this study are restricted to the Mesoproterozoic within the widespread bimodal magmatism event c.1375 Ma.

Zircon xenocryst geochronology and implications for the Lhasa terrane evolution: Insights from Cenozoic volcanic rocks (Coqen, Tibet)

The Cenozoic volcanic rocks of Coqen are located in the western central Lhasa subterrane, where knowledge of the regional lithospheric architecture and related magmatic processes is still lacking. To address this issue, we used in situ U–Pb dating, Lu–Hf isotopic and mineral inclusion analysis in zircon xenocrysts among trachyandesite. These zircons from volcanic samples yielded wide U–Pb ages from 18 Ma to 2424 Ma, showing three significant age peaks at ∼246 Ma, 193 Ma, and the most intense one at 128 Ma, which represent three major magmatic processes that developed in the area. The earliest zircon dates suggest the age of volcanic eruption in the Coqen area was not earlier than 18 Ma. zircon xenocrysts trace elements data point to the central Lhasa subterrane continental crust origin. We provide evidence for evolutive magmatism of the Lhasa terrane by calculating ΔFMQ, and show that the oxygen fugacity goes from reduced to oxidized (Cambrian to Miocene). The very low εHf(t) indicate a long-term magmatic event sequence, with the Zenong Group having the most vigorous magmatic activity. The old U–Pb ages and TDMC confirmed that an ancient basement of the Precambrian exist in the middle Lhasa terrane. Our work also restores the tectonic and crustal thickness evolutionary process of Coqen area even entire Lhasa terrane. In the back of a series of thickening and thinning processes, the Tibetan crust drastically thickened at ∼54 Ma, and gradually created what is now believed to be the thickest crust in the world.