X-ray Detector Research Articles

X-Ray Detector With Internal Gain Based on a SiC npn Structure

X-Ray Detector With Internal Gain Based on a SiC npn Structure

Exploring Aqueous Solution-Processed Pseudohalide Rare-Earth Double Perovskite Ferroelectrics toward X-Ray Detection with High Sensitivity.

Three-dimensional (3D) pseudohalide rare-earth double perovskites (PREDPs) have garnered significant attention for their versatile physical properties, including ferroelectricity, ferroelasticity, large piezoelectric responses, and circularly polarized luminescence. However, their potential for X-ray detection remains unexplored, and the low Curie temperature (TC) limits the performance window for PREDP ferroelectrics. Here, by applying the chemical regulation strategies involving halogen substitution on the organic cation and Rb/Cs substitution to the PREDP [(R)-M3HQ]2RbEu(NO3)6 [(R)-M3HQ=(R)-N-methyl-3-hydroxylquinuclidinium] with a low TC of 285 K, a novel 3D PREDP ferroelectric [(R)-CM3HQ]2CsEu(NO3)6 [(R)-CM3HQ=(R)-N-chloromethyl-3-hydroxylquinuclidinium] are successfully synthesized, for which the TC reaches 344 K. More importantly, such a strategy endowed [(R)-CM3HQ]2CsEu(NO3)6 with notable X-ray detection capabilities. Centimeter-sized [(R)-CM3HQ]2CsEu(NO3)6 single crystals fabricated from aqueous solutions demonstrated a sensitivity of 1307 μC Gyair -1 cm-2 and a low detectable dose rate of 152 nGyair s-1, the highest sensitivity reported for hybrid double perovskite ferroelectric detectors. This work positions PREDPs as promising candidates for the next generation of eco-friendly optoelectronic materials and also offers substantial insights into the interaction between structure, composition, and functionality in ferroelectric materials.

Design and technology review of the solar X-ray detector onboard the Macao Science Satellite-1B

Design and technology review of the solar X-ray detector onboard the Macao Science Satellite-1B

Nonstoichiometry Promoted Solventless Recrystallization of a Thick and Compact CsPbBr3 Film for Real-Time Dynamic X-Ray Imaging.

Inorganic CsPbBr3 perovskite emerges as a promising material for the development of next-generation X-ray detectors. However, the formation of a high-quality thick film of CsPbBr3 has been challenging due to the low solubility of its precursor and its high melting point. To address this limitation, a nonstoichiometry approach is taken that allows lower-temperature crystallization of the target perovskite under the solventless condition. This approach capitalizes on the presence of excess volatile PbBr2 within the CsPbBr3 film, which induces melting point depression and promotes recrystallization of CsPbBr3 at a temperature much lower than its melting point concomitant with the escape of PbBr2. Consequently, thick and compact films of CsPbBr3 are formed with grains ten times larger than those in the pristine films. The resulting X-ray detector exhibits a remarkable sensitivity of 4.2 × 104 µC Gyair -1 cm-2 and a low detection limit of 136 nGyair s-1, along with exceptional operational stability. Notably, the CsPbBr3-based flat-panel detector achieves a high resolution of 0.65 lp pix-1 and the first demonstration of real-time dynamic X-ray imaging for perovskite-based devices.

Spontaneous Cooling Enables High-Quality Perovskite Wafers for High-Sensitivity X-Ray Detectors with a Low-Detection Limit.

Developing high-quality perovskite wafers is essential for integrating perovskite technology throughout the chip industry chain. In this article, a spontaneous cooling strategy with a hot-pressing technique is presented to develop high-purity, wafer-scale, pinhole-free perovskite wafers with a reflective surface. This method can be extended to a variety of perovskite wafers, including organic-inorganic, 2D, and lead-free perovskites. Besides, the size of the wafer with diameters of 10, 15, and 20 mm can be tailored by changing the mold. Furthermore, the mechanism of spontaneous cooling for improving the quality of perovskite wafers is revealed. Finally, the high-quality lead-free Cs3Cu2I5 perovskite wafers demonstrate excellent X-ray detection performances with a high sensitivity of 3433.6 µC Gyair -1 cm-2 and a low detection limit of 33.17 nGyair s-1. Moreover, the Cs3Cu2I5 wafers exhibit outstanding environmental and operational stability even without encapsulation. These research presents a spontaneous cooling strategy to achieve wafer-scale, high-quality perovskites with mirror-like surfaces for X-ray detection, paving the way for integrating perovskites into electronic and optoelectronic devices and promoting the practical application of perovskite X-ray detectors.

In Situ Crystal Growth and Fusing-Confined Engineering of Quasi-Monocrystalline Perovskite Thick Junctions for X-ray Detection and Imaging.

Metal halide perovskites exhibit great promise for utilization in X-ray detection owing to their excellent optoelectronic properties and high X-ray attenuation capabilities. However, fabricating large-area thick films for high-performance perovskite X-ray detection remains challenging. This study develops an in situ crystal growth and fusing-confined approach to prepare high-quality, large-scale perovskite quasi-monocrystalline thick junctions. The perovskite crystals are grown in situ using a highly concentrated perovskite colloidal solution in 2-methoxyethanol. Introducing methylammonium chloride enhances grain reorganization during in situ growth and fusing-confined processes, effectively reducing grain boundaries and surface defects. This allows for the preparation of quasi-monocrystalline thick junctions of large grains (>100 μm) with high crystallinity, uniform orientation, and vertical penetration across the film thickness. Additionally, the carrier mobility and lifetime of the thick junctions are significantly enhanced. The optimized MAPbI3 detectors demonstrate an X-ray sensitivity of 2.6 × 104 μC Gyair-1 cm-2 and an exceptionally low detection limit of 1 nGyair s-1. Furthermore, inspired by a honeycomb structure, these detectors realize X-ray imaging in 64 × 64 pixels through a pixelated separation design, effectively reducing the charge-sharing effect. This study offers valuable insights into the preparation of large-scale perovskite quasi-monocrystalline thick junctions for highly sensitive X-ray detection and imaging applications.

Tailoring efficient manganese bromide-based scintillator films with ethyl acetate assistance

Metal halide scintillators serve as a compelling substitute for traditional scintillators in X-ray detection and imaging due to their low-temperature fabrication process, high light yield and mechanical flexibility. Nevertheless, the spatial resolution and photoluminescence quantum yield (PLQY) of these films are hindered by the agglomeration and uneven distribution of metal halides crystal particles during the fabrication process. We introduce a modified fabrication approach for metal halide scintillator films involving an additional step of ethyl acetate (EA) treatment, resulting in the preparation of a smooth EA-treated (Ph4P)2MnBr4/Polydimethylsiloxane film. The carbonyl groups within EA interact with elements of the (Ph4P)2MnBr4 microcrystals powder, ensuring uniform dispersion and preventing agglomeration. The EA-treated composite film demonstrates a remarkable PLQY of approximately 95% and an impressive spatial resolution of 14 lp/mm, with enhanced stability under harsh environments. These characteristics ensure its suitability as a high-performance X-ray imaging scintillator.&#xD.

Unveiling the origin of XMM-Newton soft proton flare. II. Systematics in the proton spectral analysis

Low-energy ($<$ 300 keV) protons entering the field of view of the XMM-Newton telescope scatter with the X-ray mirror surface and might reach the X-ray detectors on the focal plane. They manifest in the form of a sudden increase in the rates, usually referred to as soft proton flares. By knowing the conversion factor between the soft proton energy and the deposited charge on the detector, it is possible to derive the incoming flux and to study the environment of the Earth magnetosphere at different distances, given the wide and elliptical XMM-Newton orbit. Thanks to detailed Geant4 simulations, we were able to build specific soft proton response matrices for MOS and PN. In this second paper, we present the results of testing these matrices with real data for the first time, while also exploring the seasonal and solar activity effect on the proton environment. The selected spectra are relative to 55 simultaneous MOS and PN observations with flares raised in four different temporal windows: December-January and July-August of 2001-2002 (solar maximum) and 2019-2020 (solar minimum). We selected and extracted the flare mean spectra and count rates in the 2 -- 11.5 keV energy range for the four epochs. After investigating the rate variations among the MOS1, MOS2, and PN instruments, we fit the X-ray spectra using XSPEC and the proton response matrices. The best-fitting parameters derived for the three instruments were compared in order to obtain the systematic errors. There is no seasonal or solar activity effect on the soft proton mean count rates, but we find large discrepancies in the instrument cross-correlations across the 20 years of satellite operations. In 2001-2002, after a few years of operation, the MOS1 and MOS2 rates are similar, and about 20<!PCT!> with regard to the PN ones. After 20 years, PN does not present any variation in its response, while MOS1 suffers a reduction of sim 30<!PCT!>, in addition to the 30<!PCT!> loss due to the damage of two CCDs, and MOS2 is affected by an even worse degradation (70<!PCT!>). The main result of the spectral analysis is that the physical model representative of the proton spectra at the input of the telescope is a power law. However, a second and phenomenological component is necessary to take into account imprecision in the generation of the matrices at softer ($<$5keV) energies. This component contributes for 21<!PCT!> for the MOS and 5<!PCT!> for the PN to the total flux in the 2–5 keV energy range. This study, which is the first application of the soft proton response matrices to real data, shows coherent results between detectors and allows us to estimate systematic uncertainties in the measured spectra of 3<!PCT!> between the two MOS detectors and of 24<!PCT!> between MOS and PN, together with a systematic in the input flux of about a factor of two. They are all likely due to uncertainties in the proton transmission models, with the presence of additional passive material in front of the front-illuminated MOS, and element deposition on its electrode structure across the mission life. Dedicated studies and laboratory measurements are required for improving the accuracy of the proton response files.

Automated assessment of task-based performance of digital mammography and tomosynthesis systems using an anthropomorphic breast phantom and deep learning-based scoring.

Conventional metrics used for assessing digital mammography (DM) and digital breast tomosynthesis (DBT) image quality, including noise, spatial resolution, and detective quantum efficiency, do not necessarily predict how well the system will perform in a clinical task. A number of existing phantom-based methods have their own limitations, such as unrealistic uniform backgrounds, subjective scoring using humans, and regular signal patterns unrepresentative of common clinical findings. We attempted to address this problem with a realistic breast phantom with random hydroxyapatite microcalcifications and semi-automated deep learning-based image scoring. Our goal was to develop a methodology for objective task-based assessment of image quality for tomosynthesis and DM systems, which includes an anthropomorphic phantom, a detection task (microcalcification clusters), and automated performance evaluation using a convolutional neural network. Experimental 2D and pseudo-3D mammograms of an anthropomorphic inkjet-printed breast phantom with inserted microcalcification clusters were collected on clinical mammography systems to train a signal-present/signal-absent image classifier based on Resnet-18 architecture. In a separate validation study using simulations, this Resnet-18 classifier was shown to approach the performance of an ideal observer. Microcalcification detection performance was evaluated as a function of four dose levels using receiver operating characteristic (ROC) analysis [i.e., area under the ROC curve (AUC)]. To demonstrate the use of this evaluation approach for assessing different technologies, the method was applied to two different mammography systems, as well as to mammograms with re-binned pixels emulating a lower-resolution X-ray detector. Microcalcification detectability, as assessed by the deep learning classifier, was observed to vary with the exposure incident on the breast phantom for both DM and tomosynthesis. At full dose, experimental AUC was 0.96 (for DM) and 0.95 (for DBT), whereas at half dose, it dropped to 0.85 and 0.71, respectively. AUC performance on DM was significantly decreased with an effective larger pixel size obtained with re-binning. The task-based assessment approach also showed the superiority of a newer mammography system compared with an older system. An objective task-based methodology for assessing the image quality of mammography and tomosynthesis systems is proposed. Possible uses for this tool could be quality control, acceptance, and constancy testing, assessing the safety and effectiveness of new technology for regulatory submissions, and system optimization. The results from this study showed that the proposed evaluation method using a deep learning model observer can track differences in microcalcification signal detectability with varied exposure conditions.

Development of Dy-doped CaHfO3 single crystal scintillator for X-ray detectors

Dy:CaHfO3 single crystals were synthesized by the floating zone technique and examined for their photoluminescence and scintillation properties. Under excitation at 350 nm, the 3.0 % Dy:CaHfO3 showed the highest quantum yield of 72.5 % among all the samples. Under X-ray irradiation, all the samples showed multiple emission peaks at 480, 575, and 670 nm associated with the 4f–4f transitions of Dy3+. Pulse height spectra of 137Cs as a γ-ray source revealed 3.0 % Dy:CaHfO3 showed the highest light yield of 20,000 photons/MeV among the samples.

Intercalation Electrode and Grain Reconstruction Induce Significant Sensitivity Enhancement for Perovskite X-ray Detectors.

Organic-inorganic hybrid perovskites have been recognized as potential candidates in direct X-ray detectors and have triggered tremendous interest in the past years. The blade coating method meets the requirements of large area and low cost for perovskite X-ray detectors, while the low compactness resulting from solvent evaporation limits the charge collection efficiency (CCE) and device sensitivity. Most of the reports are focused on the melioration of perovskite films to increase device sensitivity; there are still problems of low CCE. Herein, we introduce an intercalation-electrode device structure and achieve a ∼20-fold sensitivity enhancement. Carrier distribution throughout the thick films is simulated, and the electrode intercalating site can be optimized according to the mobility-lifetime factor to achieve the highest CCE. A methylamine thiocyanate (MASCN) additive-assisted coating strategy is developed, and pinhole free thick films with regrown particles are obtained without frequently used hot/soft pressing. A sensitivity level of ∼105 μC Gyair-1 cm-2 as well as a detection limit of 77 nGyair s-1 is achieved under low bias, which is among the best performance for polycrystalline perovskite direct X-ray detectors. This work provides a universal device structure design to overcome carrier loss through a long transport distance and enhances the CCE for ultrahigh sensitivity.

Wafer-Sized CsPbBr3/CsPbCl3 Heterojunction: Breaking the Trade-Off between Sensitivity and Dark Current for Efficient X-ray Detector.

Polycrystalline lead halide perovskite finds promising use in fabricating X-ray detectors with a large lateral size, adjustable thickness, and diverse synthesis processes. However, a large dark current hinders its development for weak signal detection. Herein, we propose a multistep pressing strategy for manufacturing a CsPbBr3/CsPbCl3 heterojunction wafer for a reduced dark current X-ray detector, and the device keeps a high sensitivity value after the insertion of a barrier by heterojunction; thus, the trade-off between sensitivity and dark current can be broken. The X-ray detector with a metal-semiconductor-metal structure yields a sensitivity of 6.32 × 104 μC Gyair-1 cm-2 at a bias of 12 V, a 1/f noise of 1.02 × 10-13 A/Hz-1/2, and a detection limit of 66.58 nGy s-1. These performance parameters are considerably better than those of a similar X-ray detector based on the single-structure wafer. The improved device performance of the heterostructure X-ray detector is ascribed to the suppressed carrier recombination, enhanced carrier transportation of the heterojunction, and strong X-ray attenuation of the CsPbCl3 layer. The pixel array device is further used in imaging applications. Hence, this study provides an efficient strategy for fabricating heterostructure polycrystalline lead halide perovskite wafers for use in high-performance wafer-based X-ray detectors.

Imaging performance of a LaBr3:Ce scintillation detector for photon counting x-ray computed tomography: Simulation study.

Photon counting detectors (PCDs) for x-ray computed tomography (CT) are the future of CT imaging. At present, semiconductor-based PCDs such as cadmium telluride (CdTe), cadmium zinc telluride, and silicon have been either used or investigated for clinical PCD CT. Unfortunately, all of them have the same major challenges, namely high cost and limited spectral signal-to-noise ratio (SNR). Recent studies showed that some high-quality scintillators, such as lanthanum bromide doped with cerium (LaBr3:Ce), are less expensive and almost as fast as CdTe. The objective of this study is to assess the performance of a LaBr3:Ce PCD for clinical x-ray CT. We performed Monte Carlo simulations and compared the performance of 3 mm thick LaBr3:Ce and 2 mm thick CdTe for PCD CT with x-rays at 120 kVp and 20-1000mA. The two PCDs were operated with either a threshold-subtract (TS) counting scheme or a direct energy binning (DB) counting scheme. The performance was assessed in terms of the accuracy of registered spectra, counting capability, and count-rate-dependent spectral imaging-task performance, for conventional CT imaging, water-bone material decomposition, and K-edge imaging with tungsten as the K-edge material. The performance for these imaging-tasks was quantified by nCRLB, that is, the Cramér-Rao lower bound on the variance of basis line-integral estimation, normalized by the corresponding value of CdTe at 20mA. The spectrum recorded by CdTe was distorted significantly due to charge sharing, whereas the spectra recorded by LaBr3:Ce better matched the incident spectrum. The dead time, estimated by fitting a paralyzable detector model to the count-rate curves, was 20.7, 15.0, 37.2, and 13.0ns for CdTe with TS, CdTe with DB, LaBr3:Ce with TS, and LaBr3:Ce with DB, respectively. Conventional CT imaging showed an adverse effect of reduced geometrical efficiency due to optical reflectors in LaBr3:Ce PCD. The nCRLBs (a lower value indicates a better SNR) for CdTe with TS, CdTe with DB, LaBr3:Ce with TS, LaBr3:Ce with DB, and the ideal PCD, were 1.00±0.01, 1.00±0.01, 1.18±0.02, 1.18±0.02, and 0.79±0.01, respectively, at 20mA. The nCRLBs for water-bone material decomposition, in the same order, were 1.00±0.02, 1.00±0.02, 0.85±0.02, 0.85±0.02, and 0.24±0.02, respectively, at 20mA; and 0.98±0.02, 0.98±0.02, 1.09±0.02, 0.83±0.02, and 0.24±0.02, respectively, at 1000mA. Finally, the nCRLBs for K-edge imaging, the most demanding task among the five, were 1.00±0.02, 1.00±0.02, 0.55±0.02, 0.55±0.02, and 0.13±0.02, respectively, at 20mA; and 2.45±0.02, 2.29±0.02, 3.12±0.02, 2.11±0.02, and 0.13±0.02, respectively, at 1,000mA. The Monte Carlo simulations showed that, compared to CdTe with either TS or DB, LaBr3:Ce with DB provided more accurate spectra, comparable or better counting capability, and superior spectral imaging-task performances, that is, water-bone material decomposition and K-edge imaging. CdTe had a better performance than LaBr3:Ce for the conventional CT imaging task due to its higher geometrical efficiency. LaBr3:Ce PCD with DB scheme may be an excellent alternative option for CdTe PCD.

Optimized substrate temperature for high-quality CdZnTe epitaxial film in X-ray flat panel detectors

Cadmium zinc telluride (CdZnTe or CZT) materials, favored for their physical superiority in optoelectronic applications, can be efficiently produced as large-area epitaxial film via close space sublimation (CSS), enhancing potential in flat-panel detector imaging. However, the application of CdZnTe epitaxial film in medical imaging equipment is limited by their lower resistivity, prolonged response times, and diminished sensitivity. By elevating the substrate temperature, we enhanced the number and depth of reverse sublimation pits on the surface of the CdZnTe epitaxial film, established an approximately 100 nm Zn-rich layer, broadened the bandwidth, and minimized electrode injection. Additionally, we observed an aggregation of dislocations at the edges of the reverse sublimation pits, which promoted surface recombination and reduced leakage current. These modifications significantly increased the film's resistivity to 1011 Ω cm. Further, they notably decreased the rise and drop times to 2 m s and 4 m s, respectively. Integrated with thin-film transistors (TFTs), the optimized CdZnTe epitaxial film now distinctly differentiate between air, plastics, and metals under X-ray examination. This improved performance of X-ray flat panel detectors (FPDs) based on CdZnTe epitaxial film is promising for the development of next-generation X-ray detection systems.

Flexible Single Microwire X-Ray Detector with Ultrahigh Sensitivity for Portable Radiation Detection System.

Sensitive, flexible, and low false alarm rate X-ray detector is crucial for medical diagnosis, industrial inspection, and scientific research. However, most semiconductors for X-ray detectors are susceptible to interference from ambient light, and their high thickness hinders their application in wearable electronics. Herein, a flexible visible-blind and ultraviolet-blind X-ray detector based on Indium-doped Gallium oxide (Ga2O3:In) single microwire is prepared. Joint experiment-theory characterizations reveal that the Ga2O3:In microwire possess a high crystal quality, large band gap, and satisfactory stability, and reliability. On this basis, an extraordinary sensitivity of 5.9×105µCGyair -1cm-2 and a low detection limit of 67.4nGyairs-1 are achieved based on the prepared Ag/Ga2O3:In/Ag device, which has outstanding operation stability and excellent high temperature stability. Taking advantage of the flexible properties of the single microwire, a portable X-ray detection system is demonstrated that shows the potential to adapt to flexible and lightweight formats. The proposed X-ray detection system enables real-time monitor for X-rays, which can be displayed on the user interface. More importantly, it has excellent resistance to natural light interference, showing a low false alarm rate. This work provides a feasible method for exploring high-performance flexible integrated micro/nano X-ray detection devices.

SN 2021adxl: A luminous nearby interacting supernova in an extremely low-metallicity environment

SN 2021adxl is a slowly evolving, luminous, Type IIn supernova with asymmetric emission line profiles, similar to the well-studied SN 2010jl. We present extensive optical, near-ultraviolet, and near-infrared photometry and spectroscopy covering ∼1.5 years post discovery. SN 2021adxl occurred in an unusual environment, atop a vigorously star-forming region that is offset from its host galaxy core. The appearance of Lyα and O II, as well as the compact core, would classify the host of SN 2021adxl as a “Blueberry” galaxy, analogous to higher redshift, low-metallicity, star-forming dwarf “Green Pea” galaxies. Using several abundance indicators, we find a metallicity of the explosion environment of only ∼0.1 Z⊙, the lowest reported metallicity for a Type IIn SN environment. SN 2021adxl reaches a peak magnitude of Mr ≈ −20.2 mag and since discovery, SN 2021adxl has faded by only ∼4 magnitudes in the r band with a cumulative radiated energy of ∼1.5 × 1050 erg over 18 months. SN 2021adxl shows strong signs of interaction with a complex circumstellar medium, seen by the detection of X-rays, revealed by the detection of coronal emission lines, and through multi-component hydrogen and helium profiles. In order to further understand this interaction, we model the Hα profile using a Monte Carlo electron scattering code. The blueshifted high-velocity component is consistent with emission from a radially thin spherical shell resulting in the broad emission components due to electron scattering. Using the velocity evolution of this emitting shell, we find that the SN ejecta collide with circumstellar material of at least ∼5 M⊙ assuming a steady-state mass-loss rate of ∼4 − 6 × 10−3 M⊙ yr−1 for the first ∼200 days of evolution. SN 2021adxl was last observed to be slowly declining at ∼0.01 mag d−1, and if this trend continues, SN 2021adxl will remain observable after its current solar conjunction. Continuing the observations of SN 2021adxl may reveal signatures of dust formation or an infrared excess, similar to that seen for SN 2010jl.

Active Galactic Nucleus Jet-inflated Bubbles as Possible Origin of Odd Radio Circles

Odd radio circles (ORCs) are newly discovered extragalactic radio objects with an unknown origin. In this work, we carry out three-dimensional cosmic-ray (CR) magnetohydrodynamic simulations using the FLASH code and predict the radio morphology of end-on active galactic nucleus (AGN) jet-inflated bubbles considering hadronic emission. We consider CR proton (CRp)-dominated jets as they tend to inflate oblate bubbles, promising to reproduce the large inferred sizes of the ORCs when viewed end-on. We find that powerful and long-duration CRp-dominated jets can create bubbles with similar sizes (∼300–600 kpc) and radio morphology (circular and edge-brightened) to the observed ORCs in low-mass (M vir ∼ 8 × 1012 − 8 × 1013 M ⊙) halos. Given the same amount of input jet energy, longer-duration (thus lower-power) jets tend to create larger bubbles since high-power jets generate strong shocks that carry away a significant portion of the jet energy. The edge-brightened feature of the observed ORCs is naturally reproduced due to efficient hadronic collisions at the interface between the bubbles and the ambient medium. We further discuss the radio luminosity, X-ray detectability, and the possible origin of such strong AGN jets in the context of galaxy evolution. We conclude that end-on CR-dominated AGN bubbles could be a plausible scenario for the formation of ORCs.

An X-ray fluorescence experimental method for photon-counting detector in computed tomography system

The X-ray fluorescence (XRF) spectrum of specific elements can be utilized in energy calibration, energy resolution measurement, and analysis of energy response functions for photon-counting detectors (PCDs). The applications can be beneficial for PCD threshold accuracy, performance verification, and optimizing image quality. In previous literature, the experimental configuration for the XRF spectrum typically employed a vertical configuration to avoid the influence of the primary X-ray beam. However, such an experimental configuration is constrained by the fixed position of the X-ray source and detector in the computed tomography (CT) system. Hence, the purpose of this study is to investigate a horizontal configuration for XRF measurements and compare the differences in XRF spectrum with vertical configuration. The results indicate that the spectral characteristics of the horizontal and vertical configurations are similar, suggesting that the horizontal configuration could be applied for energy calibration and spectral analysis in PCD-CT systems.

Data quality in laboratory convergent-beam X-ray total scattering

Measurement of laboratory atomic pair distribution function data has improved with contemporary X-ray sources, optics and detectors, with acquisition times of the order of minutes for ideal samples. This paper examines resolution effects in pair distribution function data obtained using a convergent-beam configuration and an Ag X-ray tube from standard silicon powder and from 10 nm BaTiO3 nanocubes. The elliptical multilayer X-ray mirror reflects a non-trivial X-ray spectrum and introduces resolution effects not commonly treated in ordinary parafocusing divergent-beam laboratory diffraction. These resolution effects are modeled using the fundamental parameters approach, and the influence this has on interpretation and modeling of the resulting reduced atomic pair distribution function data is demonstrated.

Effects of Electrode Size Mismatch on the Apparent Sensitivity of Perovskite X-Ray Detectors

Effects of Electrode Size Mismatch on the Apparent Sensitivity of Perovskite X-Ray Detectors