A preliminary derived concentration guideline level (DCGL) was calculated for the soil of the Wolsong nuclear power plant (NPP) (the first commercial pressurized heavy water reactor in South Korea) site using the RESRAD-ONSITE computational code. In total, fourteen selected radionuclides were analyzed after considering the preliminary evaluation information of radionuclides observed in the pressure tube specimen in the Wolsong Unit 1 heavy water reactor and previous NPP decommissioning cases. Furthermore, a geological structure model of the Wolsong NPP site was established according to the safety analysis report of the Wolsong NPP. In addition, the distribution coefficients (Kd) of various radionuclides were derived using the JAEA-SDB and the pH information of the groundwater around the Wolsong NPP site. The DCGL for surface soil of the Wolsong NPP site was derived via the application of criteria for the site release to facilitate unrestricted reuse. Moreover, preliminary dose evaluation and relevant analysis were performed according to the Wolsong NPP site resident scenario. The novelty of this study lies in the first calculation of the preliminary DCGL values for the case of the pressurized heavy water reactor (Wolsong NPP) site. It is expected that further reliable DCGL results might be achievable if more precise radionuclide information and site-specific parameters with respect to the Wolsong NPP site are secured and applied in the future.