Wide Current Range Research Articles

Facile self-assembled monolayer deposition on copper foil for high-performance lithium-metal batteries

Li metal is widely acknowledged as the optimal negative electrode material for high-energy-density Li rechargeable batteries. However, challenges arise owing to the formation of Li dendrites and poor surface stability, leading to reduced cycle life and energy efficiency, thereby limiting widespread application. In this study, we introduced a novel approach of a molecular single-layer surface modification onto a Cu foil using a self-assembled monolayer with hexamethyldisilane (HMDS) to enhance the performance of Li-metal electrodes. The deposition of a single molecular layer at the Å-level was achieved by a simple combination of precursor casting and heat treatment without greatly affecting the energy and power density. Furthermore, this process was both scalable and cost-effective, making it highly suitable for large-scale battery manufacturing. The molecular deposition of HMDS effectively mitigated electrolyte decomposition and promoted uniform Li deposition by enhancing the surface stability under repeated Li plating–stripping processes. Optical microscopy revealed the homogeneous Li plating even after extended cycling; the first cycle on the modified surface depicted uniform plating without blank spots owing to the reduced gas-phase by-products from electrolyte decomposition. Thus, HMDS modification greatly improved the cycle stability of Li-metal batteries by successfully mitigating polarization due to electrolyte decomposition. Such improvement improved the Coulombic efficiencies and enhanced the energy efficiency, especially over a wide current density range of 1–5 mA cm−2. Furthermore, full cells with LiFePO4 cathodes and HMDS-modified Cu foils exhibited extended cyclability with increased energy efficiencies.

Innovative feedback approach for high-performance low-voltage current mirror

The paper presents an approach to increase the performance in terms of input and output resistance of a low voltage flipped voltage follower (FVF) based current mirror. The proposed technique consists of substituting the main output transistor with a network of transistors in a feedback arrangement, designed to improve the output resistance. Furthermore, a low saturation onset transistor approach is used to improve the performance. Such an approach also helped in reducing the input resistance of the current mirror, which ranges in ohms. A wide current range of up to 1 mA is achieved at a minimal current transfer error of 0.38 %. This feedback mechanism-based current mirror exhibits an output resistance of 29.61 GΩ, an input resistance of 30.45 Ω, and a bandwidth of 1.464 GHz. The proposed current mirror runs on ±0.5 V supply voltage. The robustness of the proposed circuit is evaluated through process corner analysis, temperature mismatch assessment, and Monte-Carlo simulations. The performance characteristics of the proposed current mirror have been validated and simulated using Cadence Virtuoso and Spectre simulations on 0.18 μm UMC technology. The validation process included both pre-layout and post-layout simulation results.

Electrothermal Averaged Model of a Half-Bridge DC–DC Converter Containing a Power Module

This article proposes an electrothermal averaged model of a half-bridge DC–DC converter containing a power module. This kind of model enables the computation of characteristics of DC–DC converters using DC analysis. The form of the elaborated model is presented. Both the electrical and thermal properties of the analyzed DC–DC converter are included in this model. This is the first averaged electrothermal model of a DC–DC converter which makes it possible to compute the junction temperature of all the semiconductor devices and magnetic components. The accuracy of the model was experimentally verified in a wide range of switching frequencies and output currents. Particularly, the influence of mutual thermal couplings between the transistors contained in the considered module on the characteristics of the converter and the junction temperature of the transistors is analyzed.

Unconventional angular dependence of spin-orbit torque-induced harmonic Hall resistance in Pt/YIG bilayers

Spin-orbit torque (SOT), arising from spin-orbit coupling-induced spin currents, provides efficient control of magnetization. SOT characterization involving harmonic Hall resistances is typically done in low-current regimes, distinct from high-current regimes, where SOT-induced magnetization switching occurs. In this study, we investigate azimuthal angle (ϕ)-dependent harmonic Hall resistances of a Pt/yttrium iron garnet (YIG) layer across a wide range of measurement currents. Under low-current conditions, conventional ϕ-dependent Hall resistances are observed; the first harmonic Hall resistance exhibits sin 2ϕ behavior and the second harmonic Hall resistance comprises cos ϕ and cos 3ϕ terms. Interestingly, with increasing current, higher-order angular-dependent terms become non-negligible, referring to the sin 4ϕ and sin 6ϕ terms for the first harmonic and the cos 5ϕ and cos 7ϕ terms for the second harmonic Hall resistances. We attribute this unconventional angular dependence to the nonlinear response of magnetization direction to SOT, emphasizing its relevance to understanding the magnetization dynamics during SOT-induced switching under large currents.

Boron-Doped Ti3C2Tx MXene for Effective and Durable High-Current-Density Ammonia Synthesis.

Ammonia (NH3) synthesis via the nitrate reduction reaction (NO3RR) offers a competitive strategy for nitrogen cycling and carbon neutrality; however, this is hindered by the poor NO3RR performance under high current density. Herein, it is shown that boron-doped Ti3C2Tx MXene nanosheets can highly efficiently catalyze the conversion of NO3RR-to-NH3 at ambient conditions, showing a maximal NH3 Faradic efficiency of 91% with a peak yield rate of 26.2mgh-1mgcat. -1, and robust durability over ten consecutive cycles, all of them are comparable to the best-reported results and exceed those of pristine Ti3C2Tx MXene. More importantly, when tested in a flow cell, the designed catalyst delivers a current density of ‒1000mAcm-2 at a low potential of ‒1.18V versus the reversible hydrogen electrode and maintains a high NH3 selectivity over a wide current density range. Besides, a Zn-nitrate battery with the catalyst as the cathode is assembled, which achieves a power density of 5.24mWcm-2 and a yield rate of 1.15mgh-1mgcat. -1. Theoretical simulations further demonstrate that the boron dopants can optimize the adsorption and activation of NO3RR intermediates, and reduce the potential-determining step barrier, thus leading to an enhanced NH3 selectivity.

A transient-enhanced output-capacitorless LDO regulator with non-inverting pull–push gain stage

A novel non-inverting pull–push gain stage output-capacitorless low-dropout regulator (OCL-LDO) is introduced, designed specifically for power management of system-on-chip (SoC). The incorporation of an innovative non-inverting gain stage (NIGS) serves to shift the non-dominant parasitic poles to higher frequencies, thereby enhancing the overall stability of the system. The proposed pull-push configuration markedly improves the slew rate limitation at the gate of the power transistor. Post-layout simulation outcomes, corroborated through a 180-nm CMOS fabrication process, indicate that the proposed LDO regulator maintains stability across a wide range of loading currents, from 0 mA to 100 mA, with a Miller compensation capacitance of only 3.5 pF. The circuit operates with a quiescent current of 143 μA when powered by a 1.5 V single supply. The LDO regulator boasts a dropout voltage of 300 mV, enabling it to deliver up to 100 mA of load current. Simulation results show that the undershoot voltage is only 63.7 mV when the load current jumps from 0 to 100 mA with edge of 100 ns, while employing a 100 pF capacitance load. The recovery time to return to equilibrium post this abrupt change is approximately 0.15 μs. The proposed OCL-LDO regulator exhibits a substantial enhancement in transient response compared to its predecessors, alongside a harmonized balance between line regulation and load regulation performance parameters.

High‐power mode‐hop‐free tunable DFB laser at 780 nm

AbstractA distributed feedback laser with integrated quarter‐wave phase shift and more than 100 mW optical output power at an emission wavelength of 780 nm is presented. The laser provides mode‐hop‐free tuning over a wide range of injections currents and operating temperatures by design and can serve as an enabling component for more complex systems such as chips with additional monolithically integrated amplifiers, chip arrays and sources for hybrid integrated photonic circuits.

Development and validation of a noise insertion algorithm for photon-counting-detector CT.

Inserting noise into existing patient projection data to simulate lower-radiation-dose exams has been frequently used in traditional energy-integrating-detector (EID)-CT to optimize radiation dose in clinical protocols and to generate paired images for training deep-learning-based reconstruction and noise reduction methods. Recent introduction of photon counting detector CT (PCD-CT) also requires such a method to accomplish these tasks. However, clinical PCD-CT scanners often restrict the users access to the raw count data, exporting only the preprocessed, log-normalized sinogram. Therefore, it remains a challenge to employ projection domain noise insertion algorithms on PCD-CT. To develop and validate a projection domain noise insertion algorithm for PCD-CT that does not require access to the raw count data. A projection-domain noise model developed originally for EID-CT was adapted for PCD-CT. This model requires, as input, a map of the incident number of photons at each detector pixel when no object is in the beam. To obtain the map of incident number of photons, air scans were acquired on a PCD-CT scanner, then the noise equivalent photon number (NEPN) was calculated from the variance in the log normalized projection data of each scan. Additional air scans were acquired at various mA settings to investigate the impact of pulse pileup on the linearity of NEPN measurement. To validate the noise insertion algorithm, Noise Power Spectra (NPS) were generated from a 30cm water tank scan and used to compare the noise texture and noise level of measured and simulated half dose and quarter dose images. An anthropomorphic thorax phantom was scanned with automatic exposure control, and noise levels at different slice locations were compared between simulated and measured half dose and quarter dose images. Spectral correlation between energy thresholds T1 and T2, and energy bins, B1 and B2, was compared between simulated and measured data across a wide range of tube current. Additionally, noise insertion was performed on a clinical patient case for qualitative assessment. The NPS generated from simulated low dose water tank images showed similar shape and amplitude to that generated from the measured low dose images, differing by a maximum of 5.0% for half dose (HD) T1 images, 6.3% for HD T2 images, 4.1% for quarter dose (QD) T1 images, and 6.1% for QD T2 images. Noise versus slice measurements of the lung phantom showed comparable results between measured and simulated low dose images, with root mean square percent errors of 5.9%, 5.4%, 5.0%, and 4.6% for QD T1, HD T1, QD T2, and HD T2, respectively. NEPN measurements in air were linear up until 112mA, after which pulse pileup effects significantly distort the air scan NEPN profile. Spectral correlation between T1 and T2 in simulation agreed well with that in the measured data in typical dose ranges. A projection-domain noise insertion algorithm was developed and validated for PCD-CT to synthesize low-dose images from existing scans. It can be used for optimizing scanning protocols and generating paired images for training deep-learning-based methods.

Universal Formation of Single Atoms from Molten Salt for Facilitating Selective CO2 Reduction.

Clarifying the formation mechanism of single-atom sites guides the design of emerging single-atom catalysts (SACs) and facilitates the identification of the active sites at atomic scale. Herein, a molten-salt atomization strategy is developed for synthesizing zinc (Zn) SACs with temperature universality from 400 to 1000/1100°C and an evolved coordination from Zn-N2Cl2 to Zn-N4. The electrochemical tests and in situ attenuated total reflectance-surface-enhanced infrared absorption spectroscopy confirm that the Zn-N4 atomic sites are active for electrochemical carbon dioxide (CO2) conversion to carbon monoxide (CO). In a strongly acidic medium (0.2m K2SO4, pH = 1), the Zn SAC formed at 1000°C (Zn1NC) containing Zn-N4 sites enables highly selective CO2 electroreduction to CO, with nearly 100% selectivity toward CO product in a wide current density range of 100-600mAcm-2. During a 50 h continuous electrolysis at the industrial current density of 200mAcm-2, Zn1NC achieves Faradaic efficiencies greater than 95% for CO product. The work presents a temperature-universal formation of single-atom sites, which provides a novel platform for unraveling the active sites in Zn SACs for CO2 electroreduction and extends the synthesis of SACs with controllable coordination sites.

Dual-wavelength distributed feedback laser array based on four-phase-shifted sampled Bragg grating for terahertz generation.

We propose and experimentally demonstrate a dual-wavelength distributed feedback (DFB) laser array utilizing a four-phase-shifted sampled Bragg grating. By using this grating, the coupling coefficient is enhanced by approximately 2.83 times compared to conventional sampled Bragg gratings. The devices exhibit a stable dual-mode lasing achieved by introducing further π-phase shifts at 1/3 and 2/3 positions along the cavity. These devices require only one stage of lithography to define both the ridge waveguide and the gratings, mitigating issues related to misalignment between them. A dual-wavelength laser array has been fabricated with frequency spacings of 320 GHz, 500 GHz, 640 GHz, 800 GHz, and 1 THz. When integrated with semiconductor optical amplifiers, the output power of the device can reach 23.6 mW. Furthermore, the dual-wavelength lasing is maintained across a wide range of injection currents, with a power difference of <3 dB between the two primary modes. A terahertz (THz) signal has been generated through photomixing in a photoconductive antenna, with the measured power reaching 12.8 µW.

60‐4: Minimal Efficiency Degradation and Elevated Radiometric Power Density of Ultraviolet‐A Micro‐LED with Homoepitaxial Structure

As display technology continues to advance, UVA micro‐LEDs are becoming increasingly important in a variety of display and beyond‐display applications. In this study, we investigate the optoelectronic characteristics of UVA micro‐LEDs based on a homogeneously epitaxial structure on freestanding gallium nitride (GaN) substrates. The device exhibits a central wavelength of 390 nm, positioned at the overlap of UVA and visible light spectra. It demonstrates an impressively low ideality factor of 1.49 at 2.86 V and a series resistance of 9.88 O beyond 3 V. Optically, our device shows virtually no wavelength shift across a wide current density range of 0.1‐1000 A/cm2, indicating exceptional optical stability and color accuracy. The emitted light is typical purple, reaching an expansive color gamut of 115.3% of Rec.2020. Furthermore, the GaN‐on‐GaN structure, with its superior crystal structure and heat dissipation properties, results in a very low droop ratio in EQE. This ensures sustained highpower output at high current densities, showcasing great potential in applications such as 3D printing, maskless photolithography, and fluorescence tagging.

Hybrid and Asymmetric Supercapacitors: Achieving Balanced Stored Charge across Electrode Materials.

An electrochemical capacitor configuration extends its operational potential window by leveraging diverse charge storage mechanisms on the positive and negative electrodes. Beyond harnessing capacitive, pseudocapacitive, or Faradaic energy storage mechanisms and enhancing electrochemical performance at high rates, achieving a balance of stored charge across electrodes poses a significant challenge over a wide range of charge-discharge currents or sweep rates. Consequently, fabricating hybrid and asymmetric supercapacitors demands precise electrochemical evaluations of electrode materials and the development of a reliable methodology. This work provides an overview of fundamental aspects related to charge-storage mechanisms and electrochemical methods, aiming to discern the contribution of each process. Subsequently, the electrochemical properties, including the working potential windows, rate capability profiles, and stabilities, of various families of electrode materials are explored. It is then demonstrated, how charge balancing between electrodes falters across a broad range of charge-discharge currents or sweep rates. Finally, a methodology for achieving charge balance in hybrid and asymmetric supercapacitors is proposed, outlining multiple conditions dependent on loaded mass and charge-discharge current. Two step-by-step tutorials and model examples for applying this methodology are also provided. The proposed methodology is anticipated to stimulate continued dialogue among researchers, fostering advancements in achieving stable and high-performance supercapacitor devices.

Organic package substrate embedded coupled magnetic core inductors using lithographic via technology for power supply in package

In this work, a cost-effective organic package substrate embedded coupled magnetic core inductor technology is proposed and demonstrated for power supply in package applications. Based on a novel lithographic via process, it involves a solid copper pillar electroplating step for creating a groove and integration of the vertical interconnects of the inductor. The primary and secondary windings of the coupled inductor are interleaved on the rectangular magnetic composite core which is accommodated within the groove. The coupled inductor combines solid vertical interconnecting with low loss magnetic composite core, therefore bringing together tight process tolerances and superior current capability. Experimental results show that the 2.9-mm2 coupled inductor achieves a high inductance to resistance ratio of 0.28 nH/mΩ, and a coupling factor of 0.57. In addition, the proposed inductor achieves an ultra-high saturation current of 16.52 A that is the highest reported value for a high-frequency integrated magnetic core inductor to the best of our knowledge. The performance of the coupled inductor has been calculated for a standard 1.8 to 1 V interleaved converter. Notably, it demonstrated a remarkable efficiency exceeding 95% across a wide range of phase currents between 0.11 and 2.32 A.

Flux transfer circuits breaking conventional limit in transfer coefficient based on a negative inductance of a π-junction

We have demonstrated transfer coefficients breaking the conventional limit in flux transfer circuits (FTCs) by introducing a π-phase-shifted Josephson junction (π-junction), where the FTCs include an input/output inductor. According to the current-phase relationship of a π-junction, the π-junction behaves as an inductor with intrinsically negative kinetic inductance. When a single-π-junction superconducting quantum interference device (π-SQUID) in which a geometric inductor is placed in parallel with the π-junction is formed, a current flowing on the inductor, that is, the internal flux is increased against an input current or an input flux supplied externally to the π-SQUID in case that the π-SQUID shows no hysteresis in characteristics of internal-external flux. The FTC under investigation (π-FTC) is composed of two identical π-SQUIDs sharing a π-junction. The magnitude of the internal flux exceeds that of the external flux in the π-SQUID near zero external flux. Using this effect, the transfer coefficients are expected to be increased in the π-FTCs. Numerical analysis for π-FTCs reveals that the transfer coefficients exceed the conventional limit in a wide range of input currents corresponding to the input flux, although the negative kinetic inductance depends on the magnitude of the input. We made several π-FTCs for critical currents of the π-junctions of 50 πA and 60 πA. The output flux was measured by constructing a flux-locked loop. The experimentally obtained ratios of the transfer coefficients of the π-FTCs to the coefficient of the conventional FTC made on the same chip agree with the numerical results, which supports the negative kinetic inductances cause the increased coefficients breaking the conventional limit. Because the transfer coefficient is almost independent of input currents, we believe that the π-FTCs are applicable for strengthening not only couplings used in quantum annealers or SQUID sensors but also couplings used in superconductor digital circuits.

New Z copy- current differencing transconductance amplifier active filter using FinFET transistor based current Mode Universal Filter

This research paper presents the design of an active current mode device named Z-copy- Current Differencing Transconductance Amplifier (ZC-CDTA) in conjunction with FinFET (Fin Field-Effect Transistor) transistors. An input bias current can be used to adjust its parasitic resistances at its two current input ports. It is ideal for use in current-mode signal processing, which is steadily more common than voltage-style signal processing, because it operates in current mode on all terminals. The suggested component was implemented using Finfet technology, and its performances were assessed using simulations using cadence tools and linear technology SPICE. They demonstrate the new active element's usage, with a maximum bandwidth of 300MHz. The highest power consumption is 1.01 mW, and the supply voltages can be as low as ±0.1 V. The low-power consumption and wide current range tuning of the suggested Zc-CDTA are achieved.

Dynamically Reconstructed Triple-Copper-Vacancy Associates Confined in Cu Nanowires Enabling High-Rate and Selective CO2 Electroreduction to C2+ Products.

Electrochemically reconstructed Cu-based catalysts always exhibit enhanced CO2 electroreduction performance; however, it still remains ambiguous whether the reconstructed Cu vacancies have a substantial impact on CO2 -to-C2+ reactivity. Herein, Cu vacancies are first constructed through electrochemical reduction of Cu-based nanowires, in which high-angle annular dark-field scanning transmission electron microscopy image manifests the formation of triple-copper-vacancy associates with different concentrations, confirmed by positron annihilation lifetime spectroscopy. In situ attenuated total reflection-surface enhanced infrared absorption spectroscopy discloses the triple-copper-vacancy associates favor *CO adsorption and fast *CO dimerization. Moreover, density-functional-theory calculations unravel the triple-copper-vacancy associates endow the nearby Cu sites with enriched and disparate local charge density, which enhances the *CO adsorption and reduces the CO-CO coupling barrier, affirmed by the decreased *CO dimerization energy barrier by 0.4eV. As a result, the triple-copper-vacancy associates confined in Cu nanowires achieve a high Faradaic efficiency of over 80% for C2+ products in a wide current density range of 400-800mA cm-2 , outperforming most reported Cu-based electrocatalysts.

Nonlinear Magnetic Model of IPMSM Based on the Frozen Permeability Technique Utilized in Improved MTPA Control

In this paper, the enhanced nonlinear magnetic model of the low voltage interior permanent magnet synchronous machine (IPMSM) is developed using the frozen permeability (FP) technique in finite element analysis (FEA) FEMM 4.2 software. The magnetic model is derived by obtaining flux saturation maps for a wide range of dq stator currents. Furthermore, the FEA FP technique accounts for the corresponding offset in the flux maps due to the excitation of the permanent magnets, and well as for fitting the coefficients for the curve-fitting procedure. In order to demonstrate the usefulness of the proposed magnetic model, a nonlinear control strategy based on the maximum torque per ampere (MTPA) optimal algorithm for IPMSM is employed. The magnetic model and the MTPA control strategy are validated through a variety of computer simulations based on FEMM 4.2 and MATLAB R2023a software, as well as on a real IPMSM electric vehicle (EV) traction drive experimental setup.

Submesoscale Variability and Basal Melting in Ice Shelf Cavities of the Amundsen Sea

AbstractMelting of ice shelves can energize a wide range of ocean currents, from three‐dimensional turbulence to relatively large‐scale boundary currents. Here, we conduct high‐resolution simulations of the western Amundsen Sea to show that submesoscale eddies are prevalent inside ice shelf cavities. The simulations indicate energetic submesoscale eddies at the top and bottom ocean boundary layers, regions with sharp topographic slopes and strong lateral buoyancy gradients. These eddies play a substantial role in the vertical and lateral (along‐isopycnal) heat advection toward the ice shelf base, enhancing the basal melting in all simulated cavities. In turn, the meltwater provides strong buoyancy gradients that energize the submesoscale variability, forming a positive loop that could affect the overall efficiency of heat exchange between the ocean and the ice shelf cavity. Our study implies that submesoscale‐induced enhancement of basal melting may be a ubiquitous process that needs to be parameterized in coarse‐resolution climate models.

A high-efficiency and wide-load current range LDO with dynamic loop gain control technique

The design proposes a low-dropout regulator incorporating dynamic loop gain control to accommodate a wide load current range. It introduces a multi-phase error detection mechanism, a tri-state damping selector, and a dynamic integration shift register. These elements predict load variations and dynamically increase loop gain when the load variation is significant, all without increasing the input clock. This approach achieves a fast response and low power consumption simultaneously. The chip was implemented in 0.18 μm CMOS, with an input operating voltage of 1.2 V and an output voltage of 1 V. The measured results revealed that it could provide output currents from 0.5 to 150 mA, indicating that it had a 300 times wider current range. The maximum current efficiency was 99.93%, and the core area was 0.198 mm2.

High PSR external capacitor‐less LDO with adaptive supply‐ripple cancellation technique

AbstractThis work presents an external capacitor‐less low‐dropout regulator (CL‐LDO) with high power supply rejection (PSR) over a wide frequency and load current ( ) range. The high PSR is implemented with an adaptive supply‐ripple cancellation (ASRC) technique. The proposed ASRC circuit consists of a buffer with diode‐connected structure and an adjusting unit. The novel buffer introduces the supply ripple through the diode‐connected transistor to the gate of the pass transistor, enhancing the PSR in the range of 1 MHz. Additionally, the adjusting unit trims the current of the buffer continuously according to the magnitude of to optimize the PSR adaptively. Designed in a 55 nm CMOS process with an input voltage of 1.4 V, the proposed LDO achieves −69 dB and −55 dB PSR at 100 KHz and 1 MHz for 50 mA of , respectively. Moreover, the maximum current efficiency of the LDO is 99.8% at a full of 50 mA.