Whole-rock SiO2 Research Articles

Geochronology and Geochemistry of Granodiorite Porphyry in the Baoshan Cu-Pb-Zn Deposit, South China: Insights into Petrogenesis and Metallogeny

The Baoshan Cu-Pb-Zn deposit is situated at the intersection of the Qin-Hang Cu polymetallic and Nanling W-Sn polymetallic metallogenic belts. The age, lithology, petrogenesis, and tectonic setting of granodiorite porphyry within the deposit remain subjects of debate. Additionally, there is a lack of comparative studies with the W-Sn-related granites in the region. This study conducted whole-rock major and trace element analysis, Sr-Nd isotope analysis, and zircon U-Pb dating on the Baoshan granodiorite porphyry. The zircon U-Pb age of the granodiorite porphyry is 162 ± 1 Ma. The whole-rock SiO2 and K2O contents range from 65.87 to 68.21 wt.% and 3.42 to 5.62 wt.%, respectively, indicating that the granodiorite porphyry belongs to high-potassium calc-alkaline I-type granite. The granodiorite porphyry is characterized by enrichment in LREE and depletion in HREE (LREE/HREE ratio = 6.2–21.2). The samples of granodiorite porphyry generally exhibit weak negative Eu anomalies or no Eu anomalies (δEu = 0.62–1.04, mean = 0.82). The (87Sr/86Sr)i and εNd(t) values are 0.707717–0.709506 and −7.54 to −4.87, respectively. The whole-rock geochemical composition and Sr-Nd isotopic values indicate that the magma originated from the partial melting of the Mesoproterozoic ancient crust and Neoproterozoic mafic juvenile lower crust, with the addition of high oxygen fugacity and water-rich lithospheric mantle melts. The source of the granodiorite porphyry in the Baoshan deposit is significantly different from the crust-derived metapelite source of the W-Sn-related granite in the area, indicating that different magma sources might be the main reason for the co-spatial and nearly contemporaneous development of Cu-Pb-Zn and W-Sn mineralization in the southern Hunan region.

Magma recharge in persistently active basaltic–andesite systems and its geohazards implications: the case of Villarrica volcano, Chile

We report whole-rock chemistry, mineral chemistry, and volatile content from Villarrica volcano’s major recent paroxysms and background activity. Composition of the volcanic products are basalt to basaltic andesite with whole-rock SiO2 content between 50 and 56 wt%, and a mineralogy dominated by olivine (Fo71-80), clinopyroxene (Mg# ~ 50) and plagioclase (An60–80). Volatile contents in melt inclusions are up to 1.5 wt% H2O, 500 ppm CO2, 1230 ppm sulfur and 580 ppm chlorine. Regardless of the type of activity, there are no substantial variations in whole-rock composition or the volatile content when the activity switches from background activity to a major paroxysm, strongly suggesting that this shift does not just depend on the arrival of new magma in the shallow magmatic system. Geothermobarometry constrains crystallization of the major mineral phases at various depths between 3 and 12.7 km, suggesting that degassing of a volatile-rich recharge magma occurs deeper than 12 km, producing efficient mixing throughout the whole system, and sustaining the lava lake activity in Villarrica’s summit crater. The occurrence of a permanent lava lake also suggests that the magma recharge must be close to continuous and therefore sudden changes between background and paroxysmal volcanic activity are likely controlled by relatively small changes in the rate of recharge and/or the volatile release rate in the magmatic system. This has important implications for the understanding of eruption triggers and the forecasting of volcanic eruptions.Graphical abstract

Phases in fine volcanic ash

Volcanic ash emissions impact atmospheric processes, depositional ecosystems, human health, and global climate. These effects are sensitive to the size and composition of the ash; however, datasets describing the constituent phases over size ranges relevant for atmospheric transport and widely distributed impacts are practically nonexistent. Here, we present results of X-ray diffraction measurements on size-separated fractions of 40 ash samples from VEI 2–6 eruptions. We characterize changes in phase fractions with grainsize, tectonic setting, and whole-rock SiO2. For grainsizes < 45 μm, average fractions of crystalline silica and surface salts increased while glass and iron oxides decreased with respect to the bulk sample. Samples from arc and intraplate settings are distinguished by feldspar and clinopyroxene fractions (determined by different crystallization sequences) which, together with glass, comprise 80–100% of most samples. We provide a dataset to approximate glass-free proportions of major crystalline phases; however, glass fractions are highly variable. To tackle this, we describe regressions between glass and major crystal phase fractions that help constrain the major phase proportions in volcanic ash with limited a priori information. Using our dataset, we find that pore-free ash density is well-estimated as a function of the clinopyroxene + Fe-oxide fraction, with median values of 2.67 ± 0.01 and 2.85 ± 0.03 g/cm3 for intraplate and arc samples, respectively. Finally, we discuss effects including atmospheric transport and alteration on modal composition and contextualize our proximal airfall ash samples with volcanic ash cloud properties. Our study helps constrain the atmospheric and environmental budget of the phases in fine volcanic ash and their effect on ash density, integral to refine our understanding of the impact of explosive volcanism on the Earth system from single eruptions to global modeling.

Zircon U–Pb Dating and Geochemical Characteristics of Chahannuo Gabbros in the Northern Margin of Qaidam Basin, Northern Tibetan Plateau

Late Paleozoic–early Mesozoic intrusive rocks are distributed widely along the northern margin of the Qaidam Basin in the northern Tibetan Plateau. To constrain the tectonic evolution, we carried out petrological, chronological, and geochemical studies of the Chahannuo gabbros. LA-ICP-MS Zircon U–Pb dating yields an age of 255.0 ± 0.9 Ma for the gabbros, which confirms the existence of Indosinian tectono-magmatic activity on the northern margin of the Qaidam Basin. The Chahannuo gabbros have low whole-rock SiO2, Fe2O3 contents, and high Al2O3 contents, which suggests a calc-alkaline affinity. In addition, the gabbros have high MgO, Cr, and Ni contents and Mg#, similar to those predicted of the regional basaltic melts, and indicating that they were affected mainly by fluid from the subducted slab. The Chahannuo gabbros are characterized by arc-like trace element patterns, with enrichment in LREE and LILE, and depletion in HREE and HFSE. No obvious negative Eu anomalies also indicate that no significant magmatic differentiation has occurred. The low Nb/La ratio and Ti content in gabbros samples suggests that the Chahannuo gabbros were partially contaminated by the crust during their formation. The Chahannuo gabbros have high incompatible element ratios (Rb/Sr, Th/Nd, and Th/La), which are closer to the category of enriched mantle. Combing our data with previous data from contemporaneous magmatism in the region, we suggest that the Chahannuo gabbros formed in a continental arc environment related to the northward subduction of the Paleo-Tethyan oceanic plate.

The effect of crystal fractionation on the geochemical composition of syn-exhumation magmas: Implication for the formation of high δ56Fe granites in collisional orogens

Syn-exhumation magmatism in collisional orogens is an important process for crustal differentiation and crust-mantle interaction at convergent plate boundaries. It is intriguing to elucidate which factors control the geochemical composition of such magmatic products. To answer this question, a combined study of whole-rock major-trace elements and Nd-Fe isotopes, mineral O isotopes, and zircon U–Pb ages and trace elements was carried out for syn-exhumation granites from the Sulu ultrahigh-pressure (UHP) metamorphic belt in east-central China. Several granitic plutons of Triassic age were newly found in this typical collisional orogen, with a total exposure area of ∼10 km2, suggesting large-scale partial melting of the deeply subducted continental crust in the terminal stage of continental collision. Field observations indicate that the massive granites show little deformation. The granites are high-K calc-alkaline and exhibit enrichment in LILE and LREE but depletion in HFSE relative to HREE in trace element distribution patterns. Zircons in these granites contain relict magmatic cores characterized by steep HREE patterns with strong negative Eu anomalies. These cores show middle Neoproterozoic U-Pb ages of 724–779 Ma, consistent with the protolith age of UHP metaigneous rocks in the Dabie-Sulu orogenic belt. Zircon rims exhibit oscillatory zoning, and are characterized by Triassic U-Pb ages of 210–216 Ma, low LREE contents and steep HREE patterns with significant negative Eu anomalies, suggesting their growth from granitic magmas during exhumation of the deeply subducted continental crust. The granites have low δ18O values of 2.0–6.1‰ for quartz, 1.1–5.2‰ for whole-rock, and 0.9–3.2‰ for zircon cores. The low δ18O values and Neoproterozoic U-Pb ages of zircon cores in the granites are characteristic feature of the deeply subducted continental crust in the northern margin of the South China Block. One coesite inclusion was found in the anatectic zircon rim, pointing to the deep origin of anatectic melts at a subarc depth of >80 km. Whole-rock SiO2 contents are correlated with major and trace elements, which are ascribed to crystal fractionation of mainly biotite and plagioclase during magma evolution. In particular, these granites exhibit highly variable δ56Fe values from 0.05 to 0.30‰, which are correlated with Fe3+/ΣFe, SiO2, Al2O3, Nb/Ta and Eu/Eu*. This suggests that the crystal fractionation of biotite would have controlled the Fe isotope variation in the granites. Therefore, the syn-exhumation granites experienced significant geochemical differentiation mainly through the fractional crystallization during the magma evolution. A compilation of syn-exhumation granites in the typical collisional orogens of the world shows that such granites were mainly formed through dehydration melting of hydrous minerals during decompressional exhumation. They fall into the magnesian group with relatively low REE and HFSE (like Ti, Nb and Zr) contents, distinct from the geochemical compositions of A-type granites. Therefore, syn-exhumation granites record crustal differentiation in the terminal stage of continental collision.

Zinc isotope constraints on carbonated mantle sources for rejuvenated-stage lavas from Kauaʻi, Hawaiʻi

Sedimentary carbonates could be transported into Earth's mantle by plate subduction, but the ultimate fate of these carbonates remains unclear. Zinc isotopes can allow the tracing of recycled isotopically heavy Zn-rich sedimentary carbonates (δ66Zn up to 0.91‰) within the mantle. This study presents new whole-rock major- and trace-element geochemical and Sr–Nd–Pb–Hf–Zn isotopic data for a complete series of rejuvenated-stage alkaline samples from Kauaʻi, Hawaiʻi. These samples have high MgO contents (MgO >8.6 wt%) and show a wide range of whole-rock geochemical compositions, with lower SiO2 contents, higher alkali element contents, higher CaO/Al2O3 values at a given MgO content, more depleted Sr–Nd–Hf isotopic compositions, and more radiogenic Pb isotopic compositions relative to shield tholeiites. The trace-element compositions of these samples have some similarities to carbonatites, including large ion lithophile element enrichments and K, Pb, and ZrHf depletions. These samples also have systematically higher δ66Zn values (0.34–0.43‰) than shield tholeiites from the Kauaʻi (0.27 ± 0.04‰) and Kīlauea Iki lava lake (0.26–0.30‰) and normal mantle (0.18 ± 0.05‰). Modeling the elemental and isotopic behavior of Zn indicates that the heavy Zn isotopic compositions of these samples reflect the nature of their mantle source rather than any processes associated with mantle melting and fractional crystallization. The low 87Sr/86Sr and heavy Zn isotopic compositions of these alkaline samples can be replicated by mixing depleted mantle with minor amounts of sedimentary Mg‑carbonates (<5%). A decrease in whole-rock SiO2 contents from the alkaline basalts to the melilitites in this region correlates with increases in the geochemical signature of sedimentary carbonate-bearing enriched components (e.g., high δ66Zn and low εNd and εHf values). The correlation between the δ66Zn and 206Pb/204Pb values of the samples is in concert with the role of recycled carbonates that could elevate the U/Pb ratio of mantle component caused by the carbonated melt. This implies that the studied samples formed from magmas derived from a mixed mantle source at least containing depleted peridotite and sedimentary carbonate-bearing components. The addition of recycled sedimentary carbonates may be a key factor for the high δ66Zn and 206Pb/204Pb values of the Kauaʻi rejuvenated-stage lavas. These findings suggest that the subducted sedimentary carbonates could accompany the whole circle of recycling of oceanic slab and experience a recycle deep-to-lower mantle in the Hawaiian mantle plume.

Evolution of the magma plumbing system of Miyakejima volcano with periodic recharge of basaltic magmas

Defining the variations in petrological characteristics of erupted magmas within a high-resolution chronostratigraphy provides a necessary framework for monitoring the long-term activity and eruption potential of an active volcano. Here, we investigate the evolution of the magmatic system of Miyakejima volcano, Japan, between the last two caldera-forming eruptions, at ~ 2.3 ka and AD 2000, based on new stratigraphic constraints, radiocarbon ages, and whole-rock geochemical data. The activity of Miyakejima during this interval can be divided into three magmatic periods based on cyclic whole-rock compositional trends. Period 1 spans the interval between ~ 2.3 ka and the 7th century, from the Hatchodaira eruption with caldera collapse to immediately before the Suoana–Kazahaya eruption. Period 2 spans the time period between the seventh century and the fourteenth century, from the Suoana–Kazahaya to the Sonei–bokujyo eruptions. Period 3 covers the period from the two major flank eruptions that occurred in the sixteenth century to the end of the twentieth century until the last caldera-collapse event in AD 2000. The eruption rate decreased from 0.5 km3 per 1000 years in Period 1 to ~ 0.2 km3 per 1000 years in Period 2 and 3. Recharge of primitive basaltic magmas into shallower crustal systems triggered extensive basaltic fissure eruptions at the beginning of each period. Progressively increasing whole-rock SiO2 contents of the hybrid magmas in subsequent eruptions indicates continuous fractional crystallization in small shallow magma chambers which formed at the start of each magmatic period. Intermittent injections of basaltic magma into shallow magma chambers induced magma mixing that caused eruption of hybrid basaltic andesite in each period. We suggest that some basaltic magmas formed isolated magma reservoirs at shallow depth, in which rapid fractionation was able to occur. Rupturing of these isolated magma storage regions filled with gas-rich evolved magma can lead to violent ejection of andesitic magmas, such as for the Suoana–Kazahaya eruption in the seventh century. Our results suggest two main scenarios of eruption for the basaltic magma system at Miyakejima and similar mafic volcanoes in the northern Izu–Bonin arc; (1) eruption of voluminous basaltic lavas after the recharge of primitive basaltic magmas into the shallow magmatic system, and (2) explosive fissure eruption by rupturing of isolated magma bodies filled with gas-rich evolved magmas.Graphical

Na/K Diversity of Primary Basaltic Magmas Induced by the Separation of Slab-derived Supercritical Liquid: Implications from Alkali Basaltic Lavas from Rishiri Volcano, Southern Kuril Arc

Abstract Primary basaltic magmas in subduction zones exhibit chemical diversity even in individual volcanoes. In this study, we aim to elucidate the dominant factors that determine the chemical composition, especially the Na/K, of primary basaltic magmas by conducting a comparative petrological study of the high-Na/K Horyosawa lava and low-Na/K Nozuka lava from Rishiri Volcano in the southern Kuril Arc. Both lava flows are basaltic and are suitable for estimating the magma generation conditions. The whole-rock SiO2 content of the high-Na/K Horyosawa lava, the main target of this study, ranges from 51·9 to 53·4 wt%. The petrological and geochemical features of this lava indicate that the effects of magma mixing and assimilation of crustal materials were limited, and the low-SiO2 magmas were essentially derived via olivine fractionation from the primary magma. The primary magma is estimated to have been generated by ~2·4 % partial melting of the source mantle with ~0·10 wt% water at ~1300 °C and ~2·4 GPa. By comparing the results of the high-Na/K Horyosawa lavas with those published for the low-Na/K basalts (Nozuka lava), we find that (1) the slab-derived fluids involved in their formation were supercritical liquids with similar compositions, including Na/K, when released from the subducting slab, and (2) the Horyosawa primary magma was generated at a shallower level in the mantle than the Nozuka primary magma. From these observations, it is inferred that the primary magma of the Horyosawa lava was formed by the influx melting of aqueous fluid separated from the supercritical liquid at depths shallower than the critical point, whereas the Nozuka lava was generated by supercritical liquid-fluxed melting at depths deeper than the critical point. These findings show that elemental partitioning during the separation of slab-derived supercritical liquid into aqueous fluid and hydrous melt can induce chemical diversity within the primary basaltic magmas of a single volcanic system.

Controlling factors of different Late Cretaceous granitoid-related mineralization between western margin of the Yangtze Block and the neighbor Yidun arc

Late Cretaceous granitoid-related deposits with different ore-forming elements show regional discrepancies: Sn polymetallic deposits formed in the southwestern margin of the Yangtze Block, whereas Cu-Mo deposits occurred in the neighbor Yidun arc. In order to figure out the controlling factors of this different mineralization, this study presents a combination of new zircon and apatite data with previously published geochemical data of Sn-related granitoids from Gejiu and Dachang deposits and Cu-Mo-related granitoids from Tongchanggou, Hongshan, and Relin deposits. The Sn-related granitoids are S-type granitoids with ɛNd(t) values of −10 to −7.6 and two-stage Nd model ages of 1700–1501 Ma, which implies that they were formed by partial melting of Proterozoic crustal materials. The Cu-Mo-related granitoids are I-type granitoids with adakitic features and wide ranges of εNd(t) values (−7.7 to −4.2) and zircon εHf(t) values (−9.6 to −1.3), reflecting the contributions of crustal- and mantle-derived materials in the source. Compared with the Cu-Mo-related granitoids, higher whole-rock SiO2 contents and Rb/Sr ratios, lower Nb/Ta, Zr/Hf, and K/Rb ratios in the Sn-related granitoids together with variations in zircon and apatite trace element ratios affirm that they are more fractionated. The magmas of Cu-Mo-related granitoids however are more oxidized and hydrous. They show higher zircon EuN/EuN* (average = 0.70), Ce4+/Ce3+ (average = 671), Ce/√(Ui×Ti) ratios and apatite EuN/EuN*ratios, and lower Ti-in-zircon temperature (average = 675) and zircon (Ce/Nd)/Y ratios than those of the Sn-related granitoids (average zircon EuN/EuN* = 0.09, average Ce4+/Ce3+ ratios = 53, average Ti-in-zircon temperature = 749). The higher Cl content in apatite for the Cu-Mo-related granitoids reflects a Cl-richer magma for the Cu-Mo-related granitoids. Combined with the previous studies on regional contemporaneous magmatic activity and structures, the Sn- and Cu-Mo-related granitoids formed in the intraplate and post-collisional extension environments, respectively. Reduced and fractionated crustal-derived magmas facilitate Sn enrichment, while oxidized, hydrous, and Cl-rich magmas with mantle-derived materials promote Cu-Mo mineralization. Accordingly, magma source, fractionation, redox, and volatile conjunctively control the formation of granitoid-related deposits with different ore element assemblages.

Decoupled whole-rock and zircon Hf isotopes in young evolved post-collisional lavas from Dayingshan (SE Tibet): Evidence for open-system magmatic processes

Young zircons from volcanic rocks provide ideal samples for evaluating whole-rock and zircon Hf isotope equilibrium. We report zircon and whole-rock Hf isotopic compositions for Holocene post-collisional lavas (trachyandesites and trachytes) from Dayingshan volcano, SE Tibetan Plateau. Individual zircon εHf values differ from the host whole-rock value by up to 7.4ε units, and average zircon εHf values in individual samples are about 3ε units lower than the corresponding whole-rock εHf values, indicating discrepancy of zircon and whole-rock Hf isotopes. δ18O values for Dayingshan zircons vary from 6.1 to 7.8‰ and are negatively correlated with zircon εHf values. The decoupling of zircon/whole-rock Hf isotopic compositions is attributed to open-system magmatic processes rather than disequilibrium partial melting, as indicated by the negative correlation of zircon Hf-O isotopic compositions, as well as the correlations between whole-rock SiO2 content and Nd-Sr-Hf isotope ratios. The decoupling of zircon/whole-rock Hf isotopic compositions in Dayingshan lavas suggest that care must be taken when using individual zircon εHf values to study crust-mantle evolution. This Hf isotope decoupling might be more common than previously thought in continental post-collisional volcanic rocks where open-system magmatic processes are common.

The Origin of Rhyolitic Magmas at Krafla Central Volcano (Iceland)

AbstractWe present a detailed petrologic study of rhyolites from seven eruptions spanning the full (∼190 ky) history of rhyolitic volcanism at Krafla volcano, northeast Iceland. The eruptions vary widely in size and style, but all rhyolites are crystal-poor (&amp;lt;6 modal%: plagioclase + augite ± pigeonite ± orthopyroxene ± titanomagnetite ± fayalite) and have similar evolved compositions (73.7–75.8 wt% normalized whole-rock SiO2) and trace element patterns. Macrocryst rim compositions from each eruption cluster within a narrow range and are appropriate for equilibrium with their carrier melt. Crystal cores and interiors display complex growth patterns and commonly host resorption surfaces, but compositional variations are slight (e.g. typically &amp;lt;10 mol% An for plagioclase, Mg# &amp;lt;10 for pyroxene), and consistent with an overall trend of cooling and differentiation by crystal fractionation. Although most crystal core and interior compositions are broadly appropriate for equilibrium with melts similar to their host whole-rock, variable growth histories, juxtaposition of grains with distinct trace element compositions, and scatter in melt inclusion compositions indicate mixing of antecrysts from compositionally similar evolved melts and/or assimilated felsic mush or intrusions before final rim growth. Evidence for mafic recharge (e.g. coupled increases in An and Fe in plagioclase) is absent in most crystals; rhyolite storage and fractionation thus occurred largely in isolation from the underlying mafic system. Comparison of observed matrix glass compositions with published experimental work on melting of altered (meta)basalts casts doubt on previous models favouring rhyolite generation by partial melting of hydrothermally altered basalts, instead supporting recent isotopic and modelling arguments for a crystallization-driven process [Hampton, R. L. et al. (2021). Journal of Volcanology and Geothermal Research 414, 107229]. MELTS fractional crystallization and assimilation-fractional crystallization (AFC) models at 1 kbar predict liquid major and trace element compositions similar to Krafla rhyolites after ∼60–70 vol% crystallization of a quartz tholeiite melt representative of the evolved crystal-poor basalts commonly erupted within Krafla caldera. We thus suggest that stalling and crystallization of these evolved basalts at shallow depth forms crystal mushes from which evolved (broadly dacitic to rhyolitic) melts are extracted. These melts ascend and mix with other compositionally similar melt bodies and/or assimilate felsic intrusive material in the uppermost crust. The Daly gap between ∼57 and 71 wt% SiO2 at Krafla is consistent with preferential extraction of evolved melts from quartz tholeiite mushes in the ∼50–70% crystallinity window. Residual solid (cumulate) compositions predicted by MELTS are exclusively mafic, hence efficient silicic melt extraction from quartz tholeiite mushes may also explain the apparent compositional bimodality in some Icelandic plutonic suites.

Geochronology and petrogenesis of Eocene gabbros and granitic rocks of the eastern Gangdese belt, southern Tibet: Implications for the timing of India-Asia collision

The Palaeocene-Eocene (66–41 Ma) hosts the most intense stage of extensive magmatism in the Gangdese belt of southern Tibet. However, the magma sources and tectonic setting of this magmatic belt have been a matter of discussion for decades. In this study, we conducted zircon geochronological and geochemical studies on Eocene gabbroic rocks and granitic rocks from the Jiacha area in the eastern Gangdese belt. Laser ablation-ICP-MS zircon U–Pb dating suggests almost synchronous crystallization ages of 50–47 Ma for both rock types. Geochemically, the gabbroic rocks have low total rare earth elements and high positive zircon εHf(t) values (from +8.4 to +15.0), indicating that the parental magma was derived from an isotopically depleted mantle. The granitic rocks are magnesian calc-alkalic to calcic granites that are characterized by variable zircon εHf(t) values (from +3.0 to +10.8), indicating that the magmas were generated by differentiation of a mantle-derived magma with variable contributions from ancient crustal materials. Furthermore, an enlarged database of 66–41 Ma plutonic rocks and coexisting Linzizong volcanic rocks reveals an evolutionary trend from mafic to silicic rocks. The zircon Hf and Nd isotopic compositions become more evolved with increasing whole-rock SiO2. The whole-rock and isotope geochemistry of the 66–41 Ma plutonic rocks and the Linzizong volcanic rocks indicate an origin and evolution of these rocks in an active continental margin setting. Therefore, we argue that the Gangdese belt was associated with the subduction of the Neo-Tethyan Oceanic plate throughout the Early Eocene, thereby implying that the initial India-Asia collision occurred after ~ 41 Ma.

Origin of Mesozoic Porphyritic Rocks and Regional Magmatic Evolution in the Zijinshan Ore Field of Fujian Province, China: Hf-O Isotope Characteristics of Magmatic Zircons

Mesozoic porphyritic rocks from the Zijinshan area, southwestern Fujian Province, China, are andesitic to rhyolitic in composition. The whole-rock SiO2 contents of these rocks are between 62.5% and 78.1%. Magmatic zircon from the Mesozoic porphyritic rocks was determined via secondary-ionization mass spectrometry (SIMS) for the U-Pb age and Hf and O isotopes. The zircon U-Pb ages could be mainly divided into three age groups: Group 1: ~138.8 Ma; Group 2: 109.2~107.4 Ma; and Group 3: 99.7~98.2 Ma. The εHf(t) and δ18O values of the porphyritic zircons showed that the porphyritic rocks in Group 2 were more affected by mantle-derived magma. Combined with previous research results, the medium-acidic magmatism in the southwestern Fujian Province can be divided into eight periods: Paleoproterozoic, Mesoproterozoic, Middle Neoproterozoic, Silurian to Lower Devonian, Permian to Triassic, Middle Jurassic to early Lower Cretaceous, late Lower Cretaceous, and late Lower Cretaceous to early Upper Cretaceous. The Paleoproterozoic crust was the predominant magmatic source for the subsequent Mesoproterozoic to Jurassic magmatism, but the only melts that were closely related to mineralization were derived from partial melting of the Mesoproterozoic crust and a more depleted upper mantle.

Geochronology and petrogenesis of paleoproterozoic post-collisional quartz monzodiorites from the Helanshan Complex, North China Craton: Implications for crust–mantle interaction

Insights into crust–mantle interaction in continental collisional orogens is key to understanding high- and ultrahigh-temperature (HT–UHT) metamorphism, continental crustal growth, and the tectonic evolution of such orogens. Here, we present whole-rock major- and trace-element and Nd isotope geochemistry, as well as zircon U–Pb geochronology and Hf isotope data, for quartz monzodiorites from the Helanshan Complex to constrain their petrogenesis and draw implications regarding crust–mantle interaction during formation of the Khondalite Belt in the North China Craton. LA–ICP–MS zircon U–Pb dating yields crystallization ages of 1938–1931 Ma for three samples, contemporaneous with spinel-bearing UHT pelitic granulites from the Helanshan Complex. The quartz monzodiorite samples have variable whole-rock compositions, with relatively low SiO2 (low to 51.41 wt.%) but high MgO (up to 5.05 wt.%) and Cr (up to 80.9 ppm) contents, as well as high Mg# values (up to 0.50), which suggest their derivation from the mantle. These samples exhibit a narrow range of εNd(t) values of −0.3 to + 1.0, with no decrease as decreasing whole-rock MgO content, and variable zircon εHf(t) values of −2.4 to + 5.8. In addition, Mg# values of hornblende and biotite, and Xan values of plagioclase decrease gradually with increasing whole-rock SiO2 content. All of these geochemical data indicate that the studied quartz monzodiorites were produced by fractional crystallization of mantle-derived magma, with assimilation of crustal material. On the basis of previously published data in the Khondalite Belt, the Helanshan quartz monzodiorites formed in the post-collisional setting, and record a tectonic transition from compression to extension during the period ca. 1.95–1.93 Ga. The emplacement of mantle-derived magma that formed the quartz monzodiorites through differentiation at ca. 1.93 Ga, was possibly responsible for the formation of ca. 1.93 Ga UHT rocks in the Helanshan Complex.

Early Paleozoic intracontinental granites in the Guangzhou region of South China: Partial melting of a metasediment-dominated crustal source

Whether the formation of early Paleozoic granites in the South China Block was related to intracontinental orogenic processes or oceanic subduction continues to be debated. Here, we present whole-rock major element, trace element, and SrNd isotopic data, as well as secondary ion mass spectrometry and laser ablation–inductively coupled plasma–mass spectrometry zircon UPb geochronological and HfO isotopic data, from biotite, two-mica, and muscovite granites in the Baiyunshan and Maofengshan areas of Guangzhou City, South China. Zircon UPb ages reveal that these rocks were formed during the early Paleozoic (446–438 Ma). These muscovite- and biotite-bearing granites have high SiO2 (69.0–80.4 wt%) and K2O (3.19–5.32 wt%) contents, and low MgO (0.46–1.17 wt%) contents. The granites are enriched in Rb, Th, U, and Pb, and depleted in Ba, Sr, Nb, and Ti. The Baiyunshan muscovite granites and Maofengshan biotite granites are slightly to moderately enriched in light rare-earth elements [LREEs; (La/Yb)CN = 2.27–15.1] with slight to pronounced negative Eu anomalies (Eu/Eu* = 0.27–0.72), whereas the Baiyunshan two-mica granites are significantly enriched in LREEs [(La/Yb)CN = 19.6–32.1] with moderate negative Eu anomalies (Eu/Eu* = 0.42–0.58). These muscovite- and biotite-bearing granites have enriched whole-rock Nd and zircon Hf isotopic compositions (εNd(t) = −12.1 to −7.6; εHf(t) = −11.4 to −0.8), and high zircon δ18O values (8.5‰–10.0‰). We suggest that the Baiyunshan granites were formed by partial melting of metasedimentary rocks, as they contain primary muscovite and have high zircon δ18O values. The Maofengshan granites were formed by partial melting of a hybridized crustal source containing metasedimentary rocks with subordinate amphibolites, as they have high zircon δ18O values, variable whole-rock SiO2 contents, and biotite compositions similar to those crystallized in I- and S-type magmas. These granites, along with the widespread early Paleozoic S-type granites in the Wuyi–Yunkai orogen, are distributed across a broad area rather than in a narrow belt. In addition, early Paleozoic S-type granites in the South China Block generally do not show younging trends from east to west or south to north. Moreover, the Baiyunshan–Maofengshan granites show geochemical characteristics similar to syn- or post-collisional granites and different from volcanic arc granites. We therefore propose that these muscovite- and biotite-bearing granites were formed in an intracontinental orogenic setting.

Generation of calc-alkaline andesite magma through crustal melting induced by emplacement of mantle-derived water-rich primary magma: Evidence from Rishiri Volcano, southern Kuril Arc

Calc-alkaline andesite is a typical rock series in many island and continental arcs, and it commonly coexists with tholeiitic series rocks in individual volcanoes. In this study, the main controlling factors on the occurrence of calc-alkaline magmatism are examined for andesitic lavas from Rishiri Volcano, northern Japan. The whole-rock SiO2 contents of lavas range from 57.9 wt% to 61.9 wt%, and they are classified as calc-alkaline series. The lavas have petrographical and mineralogical features that show evidence of magma mixing. The whole-rock compositional variations of the lavas indicate that three end-member magmas were involved in their generation, a primitive mafic end-member magma, an evolved mafic end-member magma, and a felsic end-member magma. We suggest that the primitive mafic end-member magma represents a near primary magma generated in the upper mantle, the evolved mafic end-member magma was derived from the primitive magma by olivine fractionation, and the felsic end-member magma was produced primarily by partial melting of the crust. The primitive end-member magma is estimated to contain ~5 wt% water, which is much higher than those of the primary basaltic magmas of other volcanic stages of Rishiri that do not include calc-alkaline magmas. Based on this observation, we suggest that the water content of the primary magma was the main factor controlling the genesis of calc-alkaline magmatism at Rishiri. The more hydrous the primary magma and its derivative magma, the more extensive the melting of the crust due to the higher water flux from the solidifying magma chamber.

Mineral inclusion assemblage and detrital zircon provenance

Mineral inclusions are common in magmatic zircon and a potentially rich source of petrologic information. Controls on the relative proportions of inclusion phases, specifically early-crystallizing minerals such as apatite and late-crystallizing phases such as quartz, K-feldspar, and muscovite, have not been systematically studied. For instance, apatite dominates many magmatic zircon inclusion suites, and selective replacement of apatite over other phases has been proposed as a mechanism for generating apatite-poor inclusion assemblages in detrital zircons. However, the extent to which apatite inclusion abundance is influenced by source rock composition has not been established. The preservation of characteristic minerals in granite series, such as differences in magnetite and ilmenite abundances due to varying redox, have also not been systematically explored as inclusion phases in zircon. We surveyed zircon inclusion assemblages in Phanerozoic granitoids of a range of compositions and found a broadly inverse relationship between the presence of apatite in the inclusion suite and whole-rock SiO2 content. Selective loss of apatite is evident from deficits in apatite content among inclusions in contact with cracks in both detrital zircons and some granitoid zircons with independent evidence for fluid ingress (i.e., secondary phases filling open cracks). In cases where microstructural observations can identify primary inclusion assemblages (versus those impacted by fluid ingress), the relative occurrence of apatite can be used to broadly predict source rock SiO2 content. There is little relationship between whole-rock chemistry and the abundance of late-crystallizing phases or the relative proportions of quartz, plagioclase, and alkali feldspar. The presence of ilmenite not in contact with cracks in the host zircon likely points to origins in ilmenite-series (i.e., reduced) magmas, but the presence of magnetite is less diagnostic. Using the apatite abundance metric, detrital Hadean zircons from Jack Hills (Western Australia), appear to derive from felsic rather than intermediate or mafic granitoids and detrital Eoarchean zircons from Nuvvuagittuq Supracrustal Belt (Quebec) may derive from intermediate to felsic granitoids. No Fe-Ti oxides have been identified in Nuvvuagittuq zircons, but rare ilmenite in Jack Hills zircons points to origins of at least some part of the population in ilmenite-series magmas.

Post-collisional ultrapotassic rocks and mantle xenoliths in the Sailipu volcanic field of Lhasa terrane, south Tibet: Petrological and geochemical constraints on mantle source and geodynamic setting

Post-collisional ultrapotassic magmatic rocks (15.2–18.8Ma), containing mantle xenoliths, are extensively distributed in the Sailipu volcanic field of the Lhasa terrane in south Tibet. They could be subdivided into high-MgO and low-MgO subgroups based on their petrological and geochemical characteristics. The high-MgO subgroup has olivine-I (Fo87–92), phlogopite and clinopyroxene as phenocryst phases, while the low-MgO subgroup consists mainly of phlogopite, clinopyroxene and olivine-II (Fo77–89). These ultrapotassic magmatic rocks have high MgO (4.6–14.5wt%), Ni (145–346ppm), Cr (289–610ppm) contents, and display enrichment in light rare earth element (REE) over heavy REE and enriched large ion lithophile elements (LILE) relative to high field strength elements (HFSE) with strongly negative Nb-Ta-Ti anomalies in primitive mantle-normalized trace element diagrams. They have extremely radiogenic (87Sr/86Sr)i (0.7167–0.7274) and unradiogenic (143Nd/144Nd)i (0.5118–0.5120), high (207Pb/204Pb)i (15.740–15.816) and (208Pb/204Pb)i (39.661–39.827) at a given (206Pb/204Pb)i (18.363–18.790) with high δ18O values (7.3–9.7‰). Strongly linear correlations between depleted mid-ocean ridge basalt-source mantle (DMM) and the Indian continental crust (HHCS) in Sr-Nd-Pb-O isotopic diagrams indicate that the geochemical features could result from reaction between mantle peridotite and enriched components (fluids and melts) released by the eclogitized Indian continental crust (HHCS) in the mantle wedge. The high-MgO (13.7–14.5wt%) subgroup displays higher (143Nd/144Nd)i, lower (87Sr/86Sr)i and (206Pb/204Pb)i ratios and lower δ18O values compared with the low-MgO (4.6–8.8wt%) subgroup. High Ni (850–4862ppm) contents of olivine phenocrysts and high whole-rock SiO2, NiO, low CaO contents indicate that the low-MgO ultrapotassic magmatic rocks are derived from partial melting of olivine-poor mantle pyroxenite. However, lower Ni concentrations of olivine phenocryst and lower whole-rock SiO2, NiO, higher CaO contents of the high-MgO ultrapotassic rocks may indicate their peridotite mantle source. This could be attributed to different amounts of silicate-rich components added into the mantle sources of the parental magmas in the mantle wedge caused by the northward subduction of the Indian continental lithosphere. The reaction-formed websterite xenoliths, reported for the first time in this study, are made up of anhedral and interlocking clinopyroxene (45–65vol%) and orthopyroxene (30–50vol%) with minor phlogopite (<3vol%) and quartz (<2vol%) and are suggested to be formed by silicate metasomatism of the mantle peridotite. The harzburgites, another major type of mantle xenolith in south Tibet, have a mineral assemblage of olivine (60–75vol%), orthopyroxene (20–35vol%), clinopyroxene (<3vol%), phlogopite (<2vol%) and spinel (<2vol%) and may have experienced subduction-related metasomatism. Combined with two types of ultrapotassic magmas, we propose that compositions of mantle wedge beneath south Tibet may gradually evolve from harzburgite through lherzolite to websterite with strong metasomatism of silicate-rich components in their mantle source region. Partial melting of the enriched mantle sources could be triggered by rollback of Indian continental slab during 25–8Ma in south Tibet.

A Paleozoic fore-arc complex in the eastern Central Asian Orogenic Belt: Petrology, geochemistry and zircon U-Pb-Hf isotopic composition of paragneisses from the Xilingol Complex in Inner Mongolia, China

The Central Asian Orogenic Belt (CAOB) is one of the largest and most complex accretionary collages and responsible for considerable Phanerozoic juvenile crustal growth. The Xilingol Complex is a key tectonic unit within the eastern CAOB and consists of strongly deformed quartz-feldspathic gneisses with lenticular or quasi-lamellar amphibolites. Whether the complex in the belt represents Precambrian basement is controversial and here a combined analysis of petrology, geochemistry and geochronology of quartz-feldspathic gneisses from the complex is reported. The rocks belong to upper amphibolite facies and three stages of metamorphism are recognized based on mineral assemblages: prograde metamorphism (Bt-I+Ms-I+Pl+Qz+Mag), peak metamorphism (Alm+Sil+Kfs), and retrograde metamorphism (appearance of Bt-II+Ms-II). Both Precambrian and Paleozoic age populations are identified from each sample. The Precambrian zircons are sourced from magmatic rocks and the crystals display a wide range of 207Pb/206Pb ages from 3141±17Ma to 837±24Ma, and significant variation in εHf(t) values from −17.84 to +10.57 with TDM2 model ages from 3209 to 1389Ma. The Paleozoic zircons have 206Pb/238U ages from 494±14Ma to 402±10Ma, variation in εHf(t) values from −12.82 to +7.72 and TDM2 model ages from 2252 to 960Ma. The biotite 40Ar-39Ar dating yields a plateau age of 301.2±1.9Ma with a low temperature step age 288.1±1.7Ma. The samples have a wide range of whole-rock SiO2 (63.7–89.3%) and Al2O3 contents (5.66–16.3%), with Fe2O3T varying from 0.60% to 6.06%. All of them have trace element compositions consistent with those of the upper continental crust. The protoliths of paragneisses in the Xilingol Complex are wackes and litharenites, representing a part of fore-arc sedimentary sequence (>319Ma) with a major phase of diagenesis age between ca. 387 and 382 Ma in an active continental margin of the South Mongolian microcontinent. The Precambrian zircons from the complex are proposed to have been originally derived from the South Mongolian or those similar microcontinents in the CAOB. These microcontinents have been originally derived from the Tarim craton, instead of the Siberia or North China cratons or Gondwanaland. The prograde biotites from the paragneisses with ages of ca. 312–301Ma recorded the beginning of the accretionary wedge-continent collage during the northward subduction of the Paleo-Asian Ocean, which may last to ca. 282Ma recorded by the retrograde biotites. Detrital materials from the South Mongolian microcontinent and the Baolidao arc instead of the North China craton were deposited in the fore-arc basin indicating the presence of the Solonker zone separating the northern subduction zone from the southern subduction zone in the CAOB. The CAOB is formed as the model of multiple subduction zones with different subduction polarities.

Genesis of late carboniferous granitoid intrusions in the Dayinsu area, West Junggar, Northwest China: evidence of an arc setting for the western CAOB

ABSTRACTThe Dayinsu area is located in the northern part of the West Junggar district near the border between China and Kazakhstan and is an important component of the Central Asian Orogenic Belt (CAOB). The Dayinsu area hosts numerous granitoid plutons in Devonian–Carboniferous volcano–sedimentary strata. The older Laodayinsu and Kubei (345–330 Ma) plutons are located in the west with the younger Bayimuzha and Qianfeng (330–325 Ma) plutons in the east. The whole-rock SiO2 contents of the four granitoid plutons range from 52.22 to 68.42 wt.% and total alkaline contents (K2O + Na2O) range from 4.94 to 9.16 wt.%. The granites are enriched in large ion lithophile elements and light rare earth elements with depletions in Nb, Ta, Ce, Pr, P, and Ti. The plutons are metaluminous with I-type signatures. The geochemistry of the intrusions suggests that they formed in a subduction zone setting, and subsequently underwent fractional crystallization during emplacement, with higher degrees of fractionation in the eastern sector than in the west. Similarities in the geochronology and geochemical characteristics of the granitoid plutons in Dayinsu to those in the Tabei district (west to Dayinsu area) suggest that both districts are part of the Carboniferous Tarbagatay Mountain intrusive event. The early Carboniferous (345–324 Ma) granitoid intrusions in the Tarbagatay Mountain likely formed in an island arc subduction setting during the evolution of the CAOB.