Wet Phases Research Articles

Deciphering Permian wetland deposits of the Parnaíba Basin through an integrated study of lithofacies and palynofacies in Western Gondwana

During the Permian, the northwestern portion of the supercontinent Gondwana experienced significant climate changes, among which the increasing aridity in the Parnaíba Basin, located between Brazil's northern and northeastern regions. The marine influence associated with the Panthalassa Ocean, evident in the Silurian and Devonian deposits, was progressively attenuated in the late Carboniferous, culminating in extensive continental deposits during the Permian and the Early Triassic in this region. In this paper, we present the first palynofacies analysis of the Permian Pedra de Fogo Formation, conducted concurrently with the description and association of sedimentary facies from outcrops located in the state of Maranhão, southwest of the Parnaíba Basin. A total of 15 m of sedimentary succession was described, and 28 samples were selected for palynofacies analysis. As a result, we identified six sedimentary facies, which were grouped into two distinct facies associations: Fa1 – Central Lake and Fa2 – Playa Lake. The palynofacies analysis considered the sedimentary organic matter, classifying it into amorphous organic matter, phytoclasts (subdivided into eight subgroups), and palynomorphs (with six subgroups). Integrating the results enabled an understanding of the depositional context, which is closely related to water dynamics and climate seasonality. The shallow lake system interpreted during the wet phases recorded interruptions in the normal sedimentation of the central lake due to turbidite deposits associated with ephemeral rivers. Conversely, during dry phases, salt precipitation occurred with subsequent substitution and aerial exposure of the surface when the water balance was negative. Eodiagenetic events were inferred and are considered throughout the article. The alternation of the hydrological regime allowed the deposition in proximal, transitional, and distal environments, creating a distinctive mosaic of wetland landscapes. The data presented indicate humid conditions within a context of increasing aridity in the studied location, particularly in the upper part of the Pedra de Fogo Formation.

Historical drivers and future streamflow variations of the Kura River in the Western Transcaucasia region of Georgia: Analysis of tree-ring chronologies from 1720 to 2021 CE

In this paper, we conduct a dendrochronological study in the Western Transcaucasia region of Georgia to elucidate the relationship between tree growth and climatic variables (temperature, precipitation, and streamflow) in order to reconstruct the paleohydrology of the Kura River and to assess the impacts of climate change on water resources. We analyzed tree-ring chronologies from 1720 to 2021 CE, and analysis of July–August streamflow revealed five wet phases (1739–1753, 1764–1807, 1811–1831, 1962–1988 and 2000–2019 CE ranging in duration from 11 to 49 years) when streamflow exceeded the long-term mean, and four dry phases (1720–1738, 1832–1881, 1936–1961 and 1989–1999 CE) when streamflow was below average. The most extreme wet and dry years were 1771 and 1851 CE, respectively. Spatial correlation patterns of Kura River reconstructed runoff against sea level pressure (SLP) are negative in the Arctic and positive in mid- to high-latitude Eurasia. The Arctic Oscillation (AO)/North Atlantic Oscillation (NAO), and solar activity are important drivers of hydroclimatic conditions in the Mediterranean region, by modifying the location of high-pressure areas and large-scale atmospheric circulations. Comparison of our Kura streamflow reconstructions and data in the Old World Drought Atlas (OWDA) reveals a moderately positive correlation (0.40) throughout the study period, being strongest over the Southern Caucasus and Eastern Turkey. This validates the drought signals and emphasizes the importance of using multi-proxy approaches, supported by spatially resolved data, to enhance understanding of regional hydroclimatic variability and drought patterns. We additionally conducted future streamflow scenarios, most notably under the high-emission SSP585 scenario, in line with global trends in CMIP6 projections. Our streamflow results indicate a trend towards increasing drought severity, which highlights the need for urgent adaptation and mitigation strategies in water resource management in this region. Ultimately, this study provides valuable information on historical hydroclimatic conditions in the Kura River Basin, which help to develop strategies to mitigate the hydrologic impacts of climate change in the Western Transcaucasia Caucasus region. We further highlight the importance of regional and global teleconnections for understanding regional hydrological dynamics.

Macroinvertebrate, algal and diatom assemblages respond differently to both drying and wetting transitions in non‐perennial streams

Abstract Biological assemblages in streams are influenced by hydrological dynamics, particularly in non‐perennial systems. Although there has been increasing attention on how drying impacts stream organisms, few studies have investigated how specific characteristics of drying and subsequent wetting transitions influence biotic responses via resistance and resilience traits. Here, we characterized how hydrologic metrics, including those quantifying drying and wetting transitions as well as dry and wet phases, alter diversity and composition of three aquatic assemblages in non‐perennial streams in southern California: benthic macroinvertebrates, soft‐bodied algae and diatoms. We found that flow duration prior to sampling was correlated with variation in macroinvertebrate and soft‐bodied algal assemblage composition. The composition and richness of diatom assemblages, however, were predominantly influenced by the drying start date prior to sampling. Contrary to other studies, the duration of the dry phase prior to sampling did not influence the composition or richness of any assemblage. Although our study was conducted within a region in which each assemblage experienced comparable environmental conditions, we found no single hydrologic metric that influenced all assemblages in the same way. The hot‐summer Mediterranean climate of southern California likely acts as a strong environmental filter, with taxa in this region relying on resistance and resilience adaptations to survive and recolonize non‐perennial streams following wetting. The different responses of algal and diatom assemblages to hydrologic metrics suggest greater resilience to drying and wetting events, particularly for primary producers. As drying and wetting patterns continue to change, understanding biodiversity responses to hydrologic metrics could inform management actions that enhance the ecological resilience of communities in non‐perennial streams. In particular, the creation and enhancement of flow regimes in which natural timing and duration of dry and wet phases sustain refuges that support community persistence in a changing environment.

Multi-proxy reconstruction of climate changes from the Medieval Climate Anomaly to the Little Ice Age in Southeast China

Exploring climate fluctuations across geological eras provides crucial historical context for addressing contemporary global climate challenges. This research leverages multi-proxies records analytical techniques, including pollen and charcoal analysis, X-ray fluorescence (XRF), and assessments of humification degree and loss on ignition (LOI), alongside paleoclimate simulations based on an alpine peat bog in Jiangxi Province, Southeast China. The study aims to provide a comprehensive review of vegetation evolution, climatic shifts, East Asian summer monsoon (EASM) intensity, and the potential drivers behind EASM behavior over the past two millennia. Our findings reveal a significant transition in precipitation and temperature patterns from the Medieval Climate Anomaly (MCA, 960–1420 CE) to the Little Ice Age (LIA, 1420–1850 CE). A distinct pattern emerges, highlighting particularly wet periods occurring between 960–1050 CE, 1190–1250 CE, and 1350–1400 CE, as well as significant droughts during 1430–1550 CE, 1590–1650 CE, 1680–1720 CE, and 1750–1800 CE. When compared to our temperature reconstruction series and precipitation data, a clear correlation emerges—wet phases align with warmer period characteristic of the MCA. Based on our simulation results, we suggest that ENSO oscillations and the Indo-Pacific warm pool played a substantial role in driving climate dynamics from the MCA to the LIA.

Climate variability in a 3.8 Ma old sedimentary record from the hyperarid Atacama Desert

The hyperarid Atacama Desert is one of the driest and oldest deserts on Earth, rendering it a valuable climate archive. However, unraveling its past climate is particularly challenging and the few studied paleoclimate records of the region reveal strong temporal and spatial variabilities. To enhance our understanding of these dynamics we investigated a sedimentary record in the Yungay valley located in the southern hyperarid Atacama Desert. We employed paleomagnetic and radiocarbon dating, and for the first time for Atacama Desert sediments, a meteoric 10Be/9Be based method for determining the depositional age. The respective 4.20 m deep profile comprises a lower alluvial fan deposit with a maximum age of 3.8 ± 0.8 Ma, and an upper 1.84 m thick clay pan deposit that has accumulated over the last 19 ka. Different proxies including grain size, salt concentration, and elemental composition indicate an aridity increase around 2.3 Ma ago and repeated dry and wet phases during the late Pleistocene and the Holocene. The latter climatic shifts can be assigned to variabilities of the South American Summer Monsoon and El Niño Southern Oscillation with moisture sources from the Atlantic and the Pacific Ocean, respectively. This study provides deeper insights into the heterogeneous climate of the hyperarid Atacama Desert and underlines the importance of interdisciplinary investigations to decipher climate systems and their effect on potential habitable regions in such an extreme environment.

Revisiting past savanna environments: Pollen analysis of the Colbyn wetland on the southern African central plateau

A high-resolution, radiocarbon dated, pollen sequence of the ecotone between the Grassland and Savanna Biomes, was extracted from a 2.5 m peat core at the Colbyn wetland in South Africa. The lithology indicates transitions between organic sediment, clay, and well-preserved peat layers. The pollen and micro-charcoal records suggest interactions between the seasonal climate, burning and possible human and other disturbance. The vegetation development over the last 4000 cal yr BP is compared with chronologically parallel pollen sequences from the nearby Moreleta River and Rietvlei Dam sequences. The study, that can be correlated with wider regional isotopic records of the region, shows drier conditions c. 3800 to 3400 cal yr BP, and around 800 cal yr BP, and a wetter phase at Colbyn c. 3000–1500 cal yr BP.

Reconstruction of late Holocene palaeoenvironmental and palaeohydrological changes using multi-proxy analysis of Sattal lake sediments, Kumaun lesser Himalaya, India

The present study aims to investigate the palaeoenvironmental changes around Sattal Lake, Kumaun Lesser Himalaya spanning the last 1670 years. Based on multi proxy analysis (i.e., grain size, mineral magnetism, clay mineralogy, Total Organic Carbon (TOC) and carbon isotopes), supported by a robust radiocarbon chronology, three major environmental phases were identified. Warm, wet phases occurred between 1,150–650 cal yr BP and 260 cal yr BP to the present. These phases coincide closely with the Medieval Climatic Anomaly (MCA) and modern warming, respectively. These warm/wet events were due to elevated precipitation, resulting in high lake levels and an expansion of the lake margin, which were marked by lower δ13C values, comparatively higher sand concentration, TOC values and magnetic susceptibility (χlf). The inference of a modern warm phase is supported by high resolution instrumental data. The MCA, which is marked by elevated amounts of coarse grained (sand) detrital material, is inferred to be an interval of strengthened of monsoonal intensity, which correlates with available monsoon records from various continental paleoclimate archives. Following the MCA a cold and dry phase was observed to occur between 610 and 260 cal yr BP, corresponding to the Little Ice Age (LIA). The LIA, which was characterized by high silt and clay concentration, high δ13C, low TOC and reduced magnetic susceptibility (χlf), is inferred to represent an interval of low lake levels, likely reflecting an episode of weakened monsoonal intensity.

MIS 3 innovative behavior and highland occupation during a stable wet episode in the Lake Tana paleoclimate record, Ethiopia

Securely dated archaeological sites from key regions and periods are critical for understanding early modern human adaptive responses to past environmental change. Here, we report new radiocarbon dates of > 42,000 cal years BP for an intensive human occupation of Gorgora rockshelter in the Ethiopian Highlands. We also document the development of innovative technologies and symbolic behaviors starting around this time. The evidenced occupation and behavioral patterns coincide with the onset and persistence of a stable wet phase in the geographically proximate high-resolution core record of Lake Tana. Range expansion into montane habitats and the subsequent development of innovative technologies and behaviors are consistent with population dispersal waves within Africa and beyond during wetter phases ~ 60–40 thousand years ago (ka).

Wildfire-vegetation-climate-human interactions in the central Taiwan region during 17.3–2.0 cal kyr BP, inferred from sediments of Toushe Basin

In this study, a long-term relationship amongst wildfire, vegetation, climate, and human in the central Taiwan region, spanning from 17.3 to 2.0 cal kyr BP, is explored. To investigate this relationship, multiple proxy approaches were employed, including charcoal (CHAR and fire frequency), pollen data (Liew et al., 2006), magnetic susceptibility, and the carbon isotopic composition of organic carbon, along with the elemental ratio of total organic carbon to total nitrogen in the core sediments of the Toushe Basin, central Taiwan. From 17.3 to 14.5 cal kyr BP, the Toushe Basin experienced drier climate conditions, leading to high-intensity fires and reduced area of wetland. Between 14.5 and 11.5 cal kyr BP, a wetter climate corresponded with low-intensity fires and an increase in tree prevalence. From 11.5 to 5.0 cal kyr BP, the climate remained relatively stable with peaks of extreme wet phases, with frequent low-intensity fires promoting herbaceous plant growth. During the period from 5.0 to 2.0 cal kyr BP, wetter conditions persisted, but increased human activities likely intensified high-intensity fires, resulting in reduced tree and herbaceous plant populations and an expansion of wetlands, leading to complex impacts on the region's ecological dynamics. The pollen diversity index (PDI) and pollen richness index (PRI) showed that ecological diversity in the Toushe Basin decreased with high-intensity fires and increased with low-intensity fires, highlighting the complex interactions between natural and human factors during 17.3–2.0 cal kyr BP. In addition, this study showed a strong link between El-Niño events and increased wildfire activity in the Toushe Basin. El-Niño conditions, with reduced rainfall and increased dryness, likely heightened wildfire frequencies and intensity by lowering moisture levels and ignition thresholds. Increased lightning during these periods further exacerbated wildfires. This connection highlights El-Niño ‘s role in driving high-intensity fires, impacting the region's vegetation and ecological dynamics.

Carbon and nitrogen biogeochemistry of a high-altitude Himalayan lake sediment: Inferences for the late Holocene climate

A study was conducted to decipher changes in paleoenvironmental conditions of the Kashmir Valley (India) using stable isotopic compositions and elemental concentrations of total organic carbon (TOC) and total nitrogen (TN) in a sediment core from the Wular Lake. The Chronology of the core established through radiocarbon dating estimated the age of the core bottom to be 3752 Cal years BP, covering the late Holocene. Using carbon isotopic compositions of TOC (δ13C), nitrogen isotopic compositions of TN (δ15N), and TOC - TN contents, the study identified changes in biology and associated biogeochemical processes in the Wular Lake during the late Holocene. Changes in C and N biogeochemistry of the lake through the last 3752 Cal years BP suggested overall drier condition during 3752–1500 Cal years BP that transitioned into a wetter condition at around 1500 Cal years BP until at least 295 Cal years BP. Evidence for relatively intense drier events were observed within the dry and wet phases at around 2500 and 500 Cal years BP. Changes in δ13C and TOC contents in the sediment core revealed that the inorganic C dynamics and productivity (along with organic C contents) in the lake were largely regulated by variations in respired CO2 and HCO3− availability along with terrestrial matter supply through the Jhelum River. Similarly, variations in δ15N and TN contents showed changes in N dynamics of the lake with varying nitrification and decomposition throughout the studied period. Observed dry and wet phases in the region might be due to the weakening and strengthening of the precipitation, which was linked to negative and positive phases of the North Atlantic Oscillation, respectively.

Northeastern Caribbean Rainfall Variability Linked to Solar and Volcanic Forcing

AbstractWe present a 500‐year precipitation‐sensitive record based on co‐varying speleothem δ18O values and Mg/Ca ratios from Larga cave in Puerto Rico. This multi‐proxy record shows that the evolution of rainfall in the northeastern Caribbean was characterized by alternating centennial dry and wet phases corresponding to reduced versus enhanced convective activity. These phases occurred synchronous with relatively cool and warm tropical Atlantic sea‐surface temperatures (SSTs), respectively. While the observed pattern suggests a close link of northeastern Caribbean rainfall to the Atlantic Multidecadal Variability, a regional comparison reveals intermittent regional heterogeneity especially on decadal timescales, which may be related to a superimposing influence of the Pacific and Atlantic basins. Furthermore, the speleothem‐based hydroclimate reconstruction indicates a significant volcanic impact during the past two centuries, and further reveals a potential solar signal in the preceding three centuries. We posit that the forcing likely shifted from solar to volcanic during the eighteenth century in being an important source of multidecadal to centennial Caribbean rainfall variability. The link between convective rainfall and natural forcing may be explained through a modulation of SST variations in the tropical Atlantic and Pacific oceans.

Geochemistry of Liquid Hydrocarbons and Natural Gases Combined with 1D Basin Modeling of the Oligocene Shale Source Rock System in the Offshore Nile Delta, Egypt.

The current study aims to integrate the geochemical characteristics of the Oligocene shale source rock system, oil, condensate, and natural gas samples in the Oligocene sandstone reservoirs from three exploration wells located in the offshore Nile Delta, East Mediterranean Sea, using organic geochemistry and a 1D basin modeling scheme. The Tineh shales exhibit total organic carbon values ranging between 0.90 and 1.89 wt %, along with hydrogen index values in the range of 54-240 mg hydrocarbon/g rock. The geochemical characterization suggests that the shale intervals of the Oligocene Tineh Formation contain type II-III and type III kerogens and, thereby, could be regarded as promising oil- and gas-prone source rocks with high contributions of gas generation potential. The study also reconstructs the 1D thermal and burial history models, showing that the Oligocene Tineh source rock system is in the main oil and wet gas generation phases from the late Miocene to the present time. The simulated basin models reveal the transformation (TR) of 10-50% kerogen to oil during the late Miocene-early Pliocene period and that the Oligocene Tineh source rock system has larger oil generation and expulsion competency, with a TR value of up to 65% during the early Pliocene-Pleistocene time period. The thermogenic gas was also formed during this time and continued to the present day. This study also investigated the presence of oil and condensate in the Oligocene sandstone reservoir samples and revealed that they were generated from mature source rock, ranging from moderately to highly mature stages. This source rock unit was deposited in fluvial to fluvial-deltaic environments under oxic mixed organic conditions and accumulated during the Tertiary time, as evidenced by the presence of the oleanane biomarker dating indicator. The molecular and isotope compositions of natural gases revealed that most of the natural gases in the Oligocene sandstone reservoir are mainly thermogenic methane gases that were generated from mainly mixed organic matter. The thermogenic methane gases were formed mainly from secondary cracking of oil and gas, with small contributions of primary kerogen cracking. The properties of natural gases together with oil and condensate in the Oligocene reservoir rocks suggest that most of the thermogenic methane gases and associated liquid hydrocarbons are derived primarily from the Oligocene shale source rock system and formed by primary kerogen cracking and secondary oil and oil/gas cracking in different thermal maturity stages. Therefore, the Oligocene Tineh Formation can be regarded as self-source generation and self-reservoir rock; hence, an intensive oil exploration and production program can be recommended whenever the Tineh source rock system is is well developed and deeply buried.

Salinity-induced succession of phototrophic communities in a southwestern Siberian soda lake during the solar activity cycle

A variety of lakes located in the dry steppe area of southwestern Siberia are exposed to rapid climatic changes, including intra-century cycles with alternating dry and wet phases driven by solar activity. As a result, the salt lakes of that region experience significant fluctuations in water level and salinity, which have an essential impact on the indigenous microbial communities. But there are few microbiological studies that have analyzed this impact, despite its importance for understanding the functioning of regional water ecosystems. This work is a retrospective study aimed at analyzing how solar activity-related changes in hydrological regime affect phototrophic microbial communities using the example of the shallow soda lake Tanatar VI, located in the Kulunda steppe (Altai Region, Russia, southwestern Siberia). The main approach used in this study was the comparison of hydrochemical and microscopic data obtained during annual field work with satellite and solar activity data for the 12-year observation period (2011–2022). The occurrence of 33 morphotypes of cyanobacteria, two key morphotypes of chlorophytes, and four morphotypes of anoxygenic phototrophic bacteria was analyzed due to their easily recognizable morphology. During the study period, the lake surface changed threefold and the salinity changed by more than an order of magnitude, which strongly correlated with the phases of the solar activity cycles. The periods of high (2011–2014; 100–250 g/L), medium (2015–2016; 60 g/L), extremely low (2017–2020; 13–16 g/L), and low (2021–2022; 23–34 g/L) salinity with unique biodiversity of phototrophic communities were distinguished. This study shows that solar activity cycles determine the dynamics of the total salinity of a southwestern Siberian soda lake, which in turn determines the communities and microorganisms that will occur in the lake, ultimately leading to cyclical changes in alternative states of the ecosystem (dynamic stability).

Biomass conversion and radiocaesium (Rad-Cs) leaching behaviors of radioactive grass in anaerobic wet fermentation systems: Effects of pre-treatments

Persistent concerns regarding environmental hazards arise from the difficulty in disposing of radioactive plant-based wastes originating from the nuclear accident at the Fukushima Daiichi Nuclear Power Plant (FNPP) in Japan in 2011. In this study, three anaerobic digestion (AD) strategies were proposed: Sole anaerobic wet fermentation, and wet fermentations with either alkaline-heat or ultrasonic pre-treatment, which were employed for long-term anaerobic treatment of a genuine radioactive grass stemming from the FNPP accident. The objectives of this work are to investigate the effects of pre-treatments on biomass conversion efficiency and to gain insight into the leaching behavior of radiocaesium (Rad-Cs) within AD processes. Experimental results indicate that by introducing alkaline-heat and ultrasonic pre-treatments to AD systems, the removal efficiencies of total solids (TS) from the raw grass increased by 60.8 % and 42.5 %, respectively, compared to sole wet fermentation. Pre-treatments have been shown to enhance the stability of AD systems, both in terms of enhancing methane production and mitigating pH fluctuations triggered by the accumulation of organic acids. Remarkably, even though the Rad-Cs leaching rate was highest when the AD system was fed with the alkaline-heat pre-treated grass, it remained unsatisfactory at only 5.77 %. We inadvertently isolated a soil-like component from the raw grass, and analyzed both its proportion in the raw grass and the radioactivity intensity. The results indicate that although the soil constituted only 9.51 % TS of the raw grass, it accounted for a significant 81.35 % of the total radioactivity. The soil, which has a pronounced affinity for ionic Cs, being mixed into the raw grass, was identified as the primary factor limiting the leaching efficiency of Rad-Cs throughout both the pre-treatment and wet fermentation phases.

Depression wetland formation by redox-driven iron and silica cycling

This paper investigates the origin and geomorphic evolution of Shadow Vlei, a depression wetland located approximately 30 km northwest of Gqeberha, South Africa. The wetland is on sandstone on the African Erosion Surface. The depression wetland has a rim of high-lying ground surrounding a central depression. Fluctuations between wet and dry periods create both highly reducing conditions in soils during wet phases in the depression, and highly oxidising conditions in the depression margin. Under reducing conditions, iron(III) oxides that are insoluble, are reduced to soluble iron(II), which is transported to and trapped in the margins of the depression under oxidising conditions when the water table declines and iron(II) is oxidised to iron(III). There is also a moderate flux of silica from the surface in the centre of the depression to the margins, which is suggested to be associated with maximum alkalinity associated with iron(III) reduction, and decreased alkalinity in the margins associated with iron(II) oxidation. However, the main flux of silica is from the surface in the centre of the depression to depth of greater than 1.5 m, again associated with variations in pH linked to iron-cycling. These reactions have thus caused a net volume loss in the centre of the depression, causing sagging, and a net volume gain at the margins of the depression, causing swelling. Wetland formation associated with alteration of landform morphology as a consequence of alternating redox conditions represents a novel mechanism that has not yet been described.

Characterization of climatic drought in the Souss-Massa watershed (Morocco) using the Standardized Precipitation Index (SPI)

In recent decades, drought has become a significant phenomenon attributed to climate change variability. Its long-term repercussions can lead to substantial agricultural, hydrological, social, and economic consequences. This study uses the Standardized Precipitation Index (SPI) to assess drought in Morocco’s SoussMassa watershed, revealing a significant decline in annual precipitation and highlighting the region’s increased drought susceptibility. Specifically, we analyzed data from five weather stations: Amaghouz (1978-2016), Amsoul (1979-2016), Immerguen (1971-2016), Lamded (1982-2016), and Taroudant (1967-2016) using statistical methods recommended by the World Meteorological Organization (WMO) for annual rainfall records. Additionally, we applied the SPI over a 12-month period to identify dry and wet years. Our analysis reveals alternating dry and wet phases, characterized by an overall decline in annual precipitation.

High Durability of Pemion® Proton Exchange Membranes in Cross-Pressure Accelerated Mechanical Stress Tests

Polymer electrolyte membrane fuel cells (PEMFC) are the dominant technology for hydrogen-powered fuel cell electric vehicles in clean transportation systems. To be suitable for commercialization and applicability in real-world use-cases, light and heavy-duty fuel cell vehicles require lifetimes of over 8,000 and 30,000 hours, respectively [1]. Hence, enhancing the durability of all fuel cell components, particularly the proton exchange membrane (PEM), is of great importance.Recently, fuel cell membranes based on hydrocarbon (HC) chemistries have become increasingly common in the literature [2]. Materials with polyaromatic backbones, tunable electrochemical properties, and low reactant permeability are increasingly seen as potential alternatives to incumbent perfluorosulfonic acid (PFSA) materials [2]. Additionally, as restrictions on the use of fluorinated materials in various industries continue to grow, the importance of HC chemistries will as well. Sulfo-phenylated polyphenylenes (sPPPs) are a particular class of HC materials that show promise [3]. However, the phase separation between hydrophilic and hydrophobic domains within sPPPs may not be as discrete as in PFSAs [3], requiring higher ion exchange capacity (IEC) values than PFSAs to achieve similar protonic conductivity. High IEC typically results in greater material hydrophilicity, which can render membranes dimensionally unstable in a fuel cell [4].State-of-the-art commercial PEMs are now manufactured as thin films (≤ 18 µm), offering small ohmic loss and therefore high fuel cell performance. To improve dimensional stability and eliminate the risks of electrical shorting, PEMs are commonly mechanically reinforced using a porous, inert, and non-ionic substrate, such as expanded polytetrafluoroethylene (ePTFE). In a work by Miyake et al. [5], sulfonated polyphenylene-based ionomer membranes with flexible polyethylene mechanical reinforcement were prepared and the results indicated promising mechanical properties and improved longevity in RH cycling tests. However, there is still a lack of data about the fatigue durability of HC membranes in the literature, and evaluating and comparing the mechanical durability of numerous PEMs with a mechanical reinforcement layer in a traditional wet-dry cycling accelerated stress test would be a time-consuming and thus costly process [6].In our previous work, [7] we combined constant pressure differential across an ePTFE-reinforced perfluorosulfonic acid (PFSA) ionomer membrane with in-situ RH cycles (ΔP-AMST) to simulate the actual mechanical stresses in the fuel cell environment, while accelerating the durability testing for reinforced PEMs. In this study, ΔP-AMST is used to benchmark the fatigue lifetime curves for Pemion® membranes and compare it with a commercial reinforced PFSA-based PEM. The test temperature was set to 90 °C, and dry and wet (90% RH) phases were 60s and 30s, respectively. The hardware and semi-MEA specifications used for the test are shown in Figure 1a-c. A semitransparent polycarbonate spacer plate with 20 mm thickness and a circular aperture (25.4 mm) in the middle was used to allow free expansion of the membrane (Figure 1d). The cathode side was pressurized to create a cross pressure between the two sides and intensify the stress on the membrane during the RH cycling process. The ultimate failure of the membrane is shown in Figure 1e. The radial stress at the center of the deformed membrane is estimated by Hencky’s solution, as reported in our previous work [7]. Figure 1f demonstrates the estimated nominal stress on the membranes as a function of their lifetimes in terms of RH cycles. According to the fatigue S-N curves, reinforced Pemion® membranes afford longer lifetime than incumbent PFSA materials if the membrane edges are well protected. In addition, the impact of IEC on the fatigue durability of Pemion® membranes is investigated and the results are evaluated against stress of dehydration and dynamic mechanical analysis measurements. Acknowledgements This project was financially supported by Natural Sciences and Engineering Research Council of Canada (NSERC), Ionomr Innovations Inc, Canada Foundation for Innovation (CFI), British Columbia Knowledge Development Fund (BCKDF), Western Economic Diversification Canada (WD), and Canada Research Chairs (CRC).

Millennial and suborbital-scale El Niño/Southern Oscillation control of climate variability in southern China over the past 70 ka

Hydroclimatic changes in East Asia on suborbital and millennial time scales have been shown to be highly uncertain. The El Niño-Southern Oscillation (ENSO) activity plays a key role in precipitation in low-latitude East Asia on interannual and interdecadal time scales. However, there remained some ambiguity about their connection on millennial and suborbital time scales. This study comprehensively explored the multifaceted relationships between ENSO activities, suborbital and millennial-scale drought events, and hydroclimatic variations within the Huguangyan Maar Lake (HML) region during the past 70 ka. Four suborbital-scale dry and wet hydroclimatic phases interspersed with ten millennial-scale extreme dry intervals were revealed by the ratio of hematite and goethite (Hem/Goe). These stages and intervals unexpectedly coupled with the zonal sea surface temperature (ΔSST) of the tropical Pacific Ocean, underscored the complex spatial and temporal dynamics of ENSO impacts. We propose the “glacial-El Niño-arid” and “interglacial-La Niña-humid” hydroclimate patterns on the suborbital scale. While on the millennial-scale, La Niña-like fluctuations during the persistent cold period (16–40 ka) increased the frequency and intensity of droughts in low-latitude East Asia, which was in stark contrast to the wet climate in northern China. The dynamic relationship underpins a millennia-spanning La Niña-drought pattern, elucidating the intertwined nature of ENSO dynamics and hydroclimatic variability on both sub-orbital and millennial scales. The above findings can be attributed to changes in the location and intensity of the Western Pacific subtropical high (WPSH) over southern China induced by persistent mean ENSO-like states in the tropical Pacific. This also indicates that the hydroclimate in low-latitude East Asia is more sensitive to variations in tropical ENSO compared to northern China.

Near-field exposures and human health impacts for organic chemicals in interior paints: A high-throughput screening

Interior paints contain organic chemicals that might be harmful to painters and building residents. This study aims to develop a high-throughput approach to screen near-field human exposures and health impacts related to organic chemicals in interior paints. We developed mass balance models for both water- and solvent-based paints, predicting emissions during wet and dry phases. We then screened exposures and risks, focusing on Sri Lanka where residential houses are frequently repainted. These models accurately predict paint drying time and indoor air concentrations of organic chemicals. Exposures of both painter and household resident were estimated for 65 organic chemicals in water-based and 26 in solvent-based paints, considering 12 solvents. Chemicals of concerns (CoCs) were identified, and maximum acceptable chemical contents (MACs) were calculated. Water-based paints generally pose lower health risks than solvent-based paints but might contain biocides of high concern. The total human health impact of one painting event on all household adults ranges from 1.5 × 10-3 to 2.1 × 10-2 DALYs for solvent-based paints, and from 4.1 × 10-4 to 9.5 × 10-3 DALYs for water-based paints. The present approach is a promising way to support the formulation of safer paint, and is integrated in the USEtox scientific consensus model for use in life cycle assessment, chemical substitution and risk screening.

Increase in optimal configuration of 25–60-day atmospheric circulations for Yangtze heavy rainfall under global warming background

In summer, the middle and lower reaches of the Yangtze River (MLYR) often suffers from severe floods as a result of a dominant intraseasonal oscillation (ISO) of rainfall with the quasi-period of 25–60 days. 75% of flooding events during summers of 1961–2022 are found to occur following wet phases of the 25−60-day ISO in rainfall. This study objectively extracts the optimal configuration (OC) of 25−60-day atmospheric ISOs for the wet phase of MLYR rainfall. The OC is characterized by the quadruple pattern of tropical convection configuring with the 25−60-day Silk Road Pattern (SRP) in the mid−high latitudes. The 25−60-day SRP in cooperation with tropical ISO over the western Pacific induces dipolar vertical cells over eastern China, with ascending branch between the vertical cells providing the vitally dynamical condition for MLYR rainfall. With topographic blocking of the Tibetan Plateau, the northward-propagating tropical ISO over the Indian Ocean enhances maintenance of the 25−60-day SRP via upper-tropospheric divergent flows, thus anchoring anomalous ascents to the MLYR. Numerical experiments further verify the remarkable tropical-extratropical interaction around the Tibetan Plateau in this OC. Under the global warming background, the tropical 25−60-day ISO tends to strengthen, leading to an increase in the occurrence frequency of strong OC through tropical-extratropical interaction, and thus the severe flood events doubled in summers of 1991–2020.