Wet Grinding Research Articles

Exploring the Link between HY Wet Ball Mill Work Index and Grinding Energy Consumption

Exploring the Link between HY Wet Ball Mill Work Index and Grinding Energy Consumption

Phytochemical properties and antioxidative activities of ginseng superfine powders prepared by wet grinding method with high-pressure homogenization

Phytochemical properties and antioxidative activities of ginseng superfine powders prepared by wet grinding method with high-pressure homogenization

A comparison of dry and wet grinding on gold-bearing sulphide ore flotation

This study investigates the hypothesis that dry grinding prior to flotation can mitigate the adverse effects of galvanic interactions, improve the selectivity of gold flotation compared to wet grinding, and offer additional benefits due to water scarcity concerns and high water treatment costs. The effects of dry and wet grinding on the flotation behavior of gold-bearing sulphide ore were studied comparatively in terms of flotation test results and pulp chemistry parameters (pH, Eh, and dissolved oxygen). In addition, flotation tests without conditioning were also conducted following dry grinding in an attempt to minimize water contact further. Results demonstrated that dry grinding increased pulp potentials and dissolved oxygen levels, implying more oxidative conditions. Despite a lower mass pull with dry grinding, flotation recoveries and grades of gold and chalcopyrite were comparable to wet grinding, while dry grinding enhanced pyrite flotation at the rougher stage. Notably, flotation without conditioning effectively rejected pyrite and achieved higher grades for gold and chalcopyrite, indicating selective flotation. Therefore, dry grinding before flotation emerges as a viable alternative for gold and chalcopyrite flotation due to its improved selectivity while carefully optimizing flotation strategies and reagents to maximize recoveries.

Oxidation anisotropy of 4H-SiC wafers during chemical-mechanical polishing

4H silicon carbide (4H-SiC) wafers are widely used in high-power, high-temperature, and high-frequency electronics owing to their excellent physical and electrical properties. In the processing of 4H-SiC wafers, chemical-mechanical polishing (CMP) is commonly employed to realize atomic-scale smoothness, damage-free surface, and global planarization. The CMP process is the synergy of wet oxidation and mechanical grinding, whose efficiency significantly relies on the oxidation process. Therefore, understanding the wet oxidation mechanism of Si face and C face of 4H-SiC wafers is critical to high-efficiency double-side CMP. In this work, the anisotropic CMP performance of Si face and C face of 4H-SiC wafers are investigated. It has been found that the material removal rate of the C face is 2–3 times that of the Si face. The thicknesses of the transient oxide layer on the C face and Si face are 8.71 nm and 3.50 nm, respectively. X-ray photoelectron spectroscopy analysis reveals that the oxygen content on the C face is higher than that on the Si face after wet KMnO4 oxidation. This indicates that the C face of 4H-SiC is easier to oxidize, which results in more oxides that that on the Si face of 4H-SiC. Our work shows that accelerating the oxidation of the Si face of 4H-SiC wafers during the simultaneous double-sided CMP process is crucial for the efficient polishing of 4H-SiC wafers.

Wet grinding effect on the release of phosphate grains and gangue mineral grains of phosphate ores from the Djebel Onk deposit

Wet grinding effect on the release of phosphate grains and gangue mineral grains of phosphate ores from the Djebel Onk deposit

Effect of Water Content in Semidry Grinding on the Quality of Glutinous Rice Flour.

The grinding process is one of the key factors affecting the quality of glutinous rice flour (GRF). As an emerging grinding method, semidry grinding aims to solve the problems of the high yield of wastewater in traditional wet grinding and the high content of damaged starch in dry grinding, in which the water content has a great influence on the quality of GRF. However, semidry grinding has not yet been formally put into production due to limitations such as the long time required to adjust the water content of rice grains. Therefore, this work was carried out to shorten the soaking time of glutinous rice (GR) by hot air pretreatment, and to conduct a systematic and in-depth study of the effect of water content on the quality of GRF, including water distribution, water hydration properties, thermal properties, rheological properties, and microstructure. The results showed that the GRF with higher water content had lower water solubility and higher enthalpy of pasting, which were due to the low content of damaged starch and the high degree of crystallization. The particle size of the GRF became smaller as the interaction between water and starch was enhanced and the GR was softened. In addition, the viscosity and elasticity of the GRF were also improved with an increase in water content. This work provides theoretical guidance for the improvement of semidry grinding to a certain extent.

Effects of C-S-H Seed Prepared by Wet Grinding on the Properties of Cement Containing Large Amounts of Silica Fume

This study aimed to utilize the hydration characteristics of cement through wet grinding techniques to efficiently and conveniently prepare a stable C-S-H seed suspension, providing key parameters and a scientific basis for their large-scale production, which ensures the stability of the C-S-H suspension during production, transportation, and application. This preparation aimed to mitigate the adverse effects of high-volume silica fume on the early mechanical properties of high-performance cement concrete. The properties of C-S-H seed were characterized in detail by SEM, XRD, and TD. In the concrete performance test, silica fume was used to replace part of the cement, and different contents of C-S-H seed were added to test its effect on the compressive strength of concrete, with XRD and SEM used to analyze the performance differences. The results show that the particle size and hydration degree of cement no longer developed after 90 min of wet grinding. Polycarboxylate ether (PCE) superplasticizer can increase the fluidity of the crystal C-S-H seed suspension when the content exceeds 1.5%. When the content of PCE exceeded 2%, the C-S-H seed suspension precipitated. Adding 5% C-S-H seed can increase the compressive strength of cement concrete by 10% under the condition of reducing the amount of cement and increasing the amount of silica fume. And Ca(OH)2 (CH) was produced by cement hydration consumed by silica fumes to generate C-S-H gel, by which the concrete became denser with more strength. However, when the amount of C-S-H seed exceeded 7%, the compressive strength of the concrete decreased.

Surface roughness and fracture cracks of Al2O3/TiO2 composite coating by wet chemical mechanical grinding with structured abrasives pad

In the fields of wind power, and other industries, the Al2O3/TiO2 coating is prepared and ground on the bearing ring, in order to obtain the insulation resisting the electrical erosion for the motors at high voltage. A novel wet chemical mechanical grinding (WCMG) method is proposed to finish this hard-brittle composite material, utilizing the structured diamond abrasives pad and the NaOH solution. The softened workpiece's surface under the chemical reaction was demonstrated by means of Raman spectrum, indentation and scratching tests. The analytical model of surface roughness and fracture cracks is established based on the synthesis of geometry and kinematics, contact mechanics, material removal and indentation fracture mechanics. The surface roughness of coating was reduced from initial Sa 3.293 μm down to final Sa 0.049 μm in the WCMG process with grain size 3 μm and pH 12.01, mostly attributed to the ductile removal of chemically softened coating surface.

Activation technology of steel slag for concrete exposed to plateau climate: a state-of-the-art review.

As a byproduct of steelmaking, steel slag occupies significant land resources and poses potential environmental and safety challenges due to its extensive accumulation. Recently, steel slag has shown promising applications in the field of concrete. However, considering the complexity of the plateau environment, the utilization of steel slag is relatively lacking, and its low reactivity and poor volume stability remain the main factors restricting its application in plateau concrete. This paper reviews the research status of steel slag activation techniques for concrete, including wet grinding, chemi-excitation, high-temperature activation, and carbonation treatment. The effects of different treatment techniques on the mechanical and durability properties of concrete and the potential issues are discussed. Although different modification methods can improve the activity and volume stability of steel slag to varying degrees, a single modification technology is difficult to achieve the high-quality utilization of steel slag in concrete on the plateau. Based on this, a steel slag grading grinding-magnetic separation utilization technique suitable for high-altitude areas is proposed, which is beneficial for improving the added value and utilization rate of steel slag in concrete.

Preparation of diatomite-based porous ceramics and their adsorption properties for Cu2+

Diatomite-based porous ceramics were prepared by wet grinding and high temperature calcination with diatomite as the main raw material. The structure and properties of the ceramics were characterized by SEM, XRD, and FI-TR detection techniques. The results show that the diatomite-based porous ceramics are mainly quartz crystal phase and contain a large amount of Si-OH. Their pore size distribution is 500∼3500 nm, the specific surface area is 6.14 m2/g, and the porosity is 47.8%. The static adsorption process of Cu2+ in water by ceramic particles conforms to the quasi-second-order kinetic model, and the adsorption equilibrium is reached after 6 h with the maximum adsorption capacity of 4.5 mg/g. The Thomas model can be applied to represent the dynamic adsorption of Cu2+ in water. In the adsorption of Cu2+, pH exerts a strong influence. In solution, Cu2+ forms a ligand with hydroxyl surface functional groups on the surface of ceramics and pores through electrostatic interaction, and the hydrogen on the hydroxyl group exchanges with Cu2+, so that Cu2+ can be removed.

Nanocellulose separation from barley straw via ultrasound-assisted choline chloride – Formic acid deep eutectic solvent pretreatment and high-intensity ultrasonication

The present study aims at investigating the application of ultrasound assisted choline chloride (ChCl) – formic acid (FA) deep eutectic solvent (DES) pretreatment of Barley straw. In addition, the efficiency of a wet grinding followed by high intensity ultrasound (HIUS) treatment for production of cellulose nanofibers (CNF) has been evaluated. The DES (using ChCl: FA at 1:9 M ratio) treatment at 45 kHz ultrasound frequency and 3 h of treatment duration resulted in 84.68 ± 1.02 % and 82.96 ± 0.79 % of lignin and hemicellulose solubilisation, respectively. The purification of DES treated solid residue resulted in cellulose with more than 90 % purity. Further, 10 min of wet grinding followed by 40 min of HIUS treatment resulted in more than 80 % nano-fibrillation efficiency. The produced CNF had diameters less than 100 nm in number size distribution and type I cellulose structure. This study confirmed that the developed process offers a sustainable method for producing nanocellulose from agricultural waste.

The effects of processing parameters on the shape of particle size distribution and grinding rate in a stirred mill

The study of particle size distribution (PSD) of materials is a crucial aspect of mineral processing. It not only determines the appropriate beneficiation process and equipment but also has a significant impact on the grade and recovery of concentrate. This study utilizes a pin-stirred mill for the wet fine grinding of limonite to examine four different widths of PSD functions and compares their quantitative descriptions of the PSD. Skewness is a parameter introduced to quantitatively describe the asymmetry of the PSD. This study aims to investigate the effect of the stirrer speed, the density and the size of the grinding media on the shape of the PSD and on the grinding rate. The results show that a lower stirrer speed and a lower density of the grinding media result in a narrower and a more symmetrical PSD of the grinding products. Moreover, the time-dependent approach succeeds in simulating and proving the evolution behavior of the median particle size. It was found that the optimum mixing ratio of the grinding media can effectively adjust the shape of the PSD and improve the grinding efficiency.

Effect of wet grinding carbonation of sintering red mud on the performance of carbon sequestered mortar

The use of alkaline solid waste to CO2 capture is a potential way to upgrade the recycling of solid waste and reduce CO2 emission. In previous work, we proposed a novel wet grinding carbonation technique to achieve rapid carbonation of sintering red mud (SRM). Herein, the effect of wet grinding carbonation of SRM (WGCS) replacement rate (0 %, 5 %, 10 %, 15 %, 20 % and 25 %) on the hydration and hardening of Portland cement was further explored, such as rheology, compressive strength, hydration products and water transfer properties. The plastic viscosity and yield stress of carbon sequestered paste rose together with the WGCS replacement rate, which was due to the decreased D50 of SRM after wet grinding carbonation. When the WGCS replacement rate was 15 %, the 56 d compressive strength of carbon sequestered mortar was increased by 14.1 %. The microscopic characterization showed that the nucleation of calcite crystals and the pozzolanic reaction of silica-rich gels clearly improved the microstructure compactness. The electric flux and porosity of cement mortar was decreased by 25.7 % and 11.4 %, respectively. In terms of environmental and economic benefits, the CO2 sequestration of carbon sequestered mortar reached as high as 24.7 kg/m3 and the CO2 emission was reduced by 30.9 %.

Determination of S, Ni, Cu in copper-nickel sulfide ores by total reflection X-ray fluorescence analysis: experience of participation in the interlaboratory comparisons

The quality of the determination of S, Ni, Cu in copper-nickel sulfide ores was assessed in the framework of the program for interlaboratory comparative tests (ICT) using total reflection X-ray fluorescence analysis (TXRF) taking into account the criteria for methods for determining the chemical composition of mineral raw materials. Certified TXRF techniques for the analysis of mineral materials are absent, so the interlaboratory comparison test was used to control and improve the accuracy of measurements by TXRF. Powdered ore samples were prepared as suspensions by wet grinding: 100 mg of the powder, 4 ml of ultra-pure water and 250 μl of the Ga standard solution were milled using 20 g of ZrO2 balls 1 mm in diameter in the mixing mill for 10 minutes at a frequency of 20 Hz. The ratio of the intensities of the characteristic lines of the analyzed elements and the Ga internal standard was chosen as an analytical signal. To plot calibration curves, a set of ore reference samples was analyzed using certified procedures (atomic absorption spectrometry for Cu, Ni, gravimetry for S). The quality of the TXRF analysis was assessed by the value of Z-criterion. The measurement error did not exceed 5 rel. %. The relative percentage differences between the TXRF results and the results obtained in the interlaboratory study was less than 10%. The described method can be used for rapid analysis of copper-nickel sulfide ores.

Physicochemical characteristics of jack bean (Canavalia ensiformis (L.) DC.) milk, a non-dairy milk alternative developed using various pretreatment methods

The endeavor to turn jack bean (Canavalia ensiformis (L.) DC.) into jack bean milk faced a challenge regarding its hard skin, which makes pretreatment of the jack bean before processing essential to soften and ease the dehulling of beans, as well as aid the grinding process. However, different pretreatment methods influence the characteristics of treated jack beans and jack bean milk as the final product. This study, thus, aimed to investigate the effect of different jack bean pretreatment methods such as soaking in NaHCO3 solution (P1), soaking in hot water (95℃) (P2), and a combination of boiling and soaking in water (P3), on the physicochemical properties of jack bean milk. Jack bean milk was prepared by subjecting jack beans to pretreatment, dehulling, wet grinding, filtering, and heating before proceeding with analyses based on proximate composition, phase behavior, color and viscosity. The results demonstrated that P2 produced the highest protein (7.01±0.11%), fat (0.10±0.00%), and ash contents (0.11±0.00%) of jack bean milk. P1 yielded higher protein and ash contents of jack bean milk than that of P3, while no significant differences in fat contents were discovered in both P1 and P3. Besides, a slight difference in carbohydrate contents was found among all treatments, ranging from 1.17 to 1.20%. The phase behavior and color analyses showed P1 and P2 to significantly generate higher colloidal stability and whiteness index value of jack bean milk than P3. In addition, jack bean milk from P2 possessed the highest viscosity value of 48.1±1.4 cP, followed by P1 (28.6±0.6 cP) and P3 (12.6±0.5 cP). Accordingly, the recent study proposes the pretreatment of soaking in hot water (95℃) to be applied in jack bean milk processing and provides new insights into how pretreatment methods affect the characteristics of plantbased milk products.

Efficient modelling of thermo-hydrodynamic properties in lubricated technical systems using NURBS-based isogeometric analysis

Wet grinding is a process that involves many different subprocesses. In order to model this highly complex process, efficient models of the individual subprocesses are required that are robust enough to be used in multiphysics analyses. To approach the modelling of the macroscopic hydrodynamic effects of the grinding wheel as one component of the analysis, this paper is dedicated to the thermo-hydrodynamic problem and its modelling by expanding the isogeometric analysis (IGA) from hydrodynamic analysis to the thermal consideration. Extended by a consideration of flow effects in areas with high surface gradients and particular attention paid to the necessary stabilization of the governing equations, thermo-hydrodynamic systems with temperature- and pressure-dependent fluid properties are considered. Selected benchmarks feasible for computational fluid dynamics (CFD) simulations are used to demonstrate the good suitability of this modelling strategy. The presented modelling strategies can also be applied to lubricated technical systems in general, beyond wet grinding systems.

Effect of Wet Grinding Concrete Slurry Waste on Hydration and Hardening Properties of Cement: Micro-Nano-Scale Modification.

The concrete slurry waste (CSW) produced by concrete mixing plants is a type of hazardous waste that is difficult to handle. To better recycle the CSW separated from the aggregates, this study uses a variety of wet-grinding processes to refine the solid in it, replaces some of the cement with the solid particles in wet grinding concrete slurry waste (WCSW), and investigates the properties of WCSW and its effect on the hydration and hardening properties of cement. The results show that a suitable wet-grinding process can ensure that the particle size in WCSW is less than 10 μm, the particle morphology is more flat, and the degree of hydration is higher. The WCSW particles can promote early cement hydration; after adding WCSW, the heat release peak of cement hydration appears earlier and more early hydration products are produced, and with the increase in the substitution amount, the promoting effect on early cement hydration will be more significant. The WCSW particles have a great effect on improving the strength of mortar, especially in the early stage. At 1 d, when the substitution amount is 7.5 wt.%, the compressive and flexural strength is increased by 43.67% and 45.04%; this is related to the filling of matrix pores and the improvement of the interface transition zone by micro- and nanoparticles. After the wet grinding of CSW, fine WCSW particles are obtained, which can improve the performance of cement-based materials by replacing cement.

Selective pharmaceutical sensitization design based on amino acid metabolism: 5-fluorouracil-sarcosine cocrystal prepared by wet powder grinding method

Pharmaceutical cocrystal is an emerging strategy not only to improve physicochemical properties, but also to generate synergistic effects. In this work, a novel cocrystal composed by 5-fluorouracil (5-FU) and sarcosine (SAR) was successfully assembled by wet powder grinding method. The cocrystal was characterized by single crystal X-ray diffraction (SCXRD), powder X-ray diffraction (PXRD), differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR) and Raman spectra. The differences of 1H NMR spectroscopy between 5-FU/SAR physical mixture (PM) and cocrystal hinted the existence of supramolecular interactions between 5-FU and SAR in solid and solution. Bioavailability of cocrystal was increased than 5-FU. Most importantly, the weak interactions between 5-FU and SAR in cocrystal solution induced the superior cellar inhibition activity on 4T1 and BEL-7402 cells compared than 5-FU and PM. Cocrystal can interfere with the stability of methionine cycle and tetrahydrofolate (FH4) level through the SAR-Gly-Met pathway, enhance the inhibition of thymidylate synthase (TS) compared to 5-FU, thereby interfering with cell cycle and inducing cell apoptosis. The results provided the novel strategy to develop the cocrystal drugs using bioactive amino acids as precursors to enhance the efficacy.

Wet mechanochemical surface modification of calcite employing an integration of conventional design and analytical hierarchy process

The demand for ultra-fine mineral powders from various industries requires the applications of wet grinding and surface modification. In this study, wet mechanochemical surface modification of micronized calcite (d50 = 4.92 μm) with stearic acid [CH3(CH2)16COOH] was carried out in a planetary ball mill. The seven parameters were specified: ball filling ratio (%), ball size distribution ratio (10 and 15 mm, %), micronized calcite filling ratio (%), pulp solid ratio (wt%), mill speed (rpm), stearic acid dosage (% of micronized calcite) and modification time (min). Then, these parameters were optimized using a conventional experimental design when maximizing the active ratio (%) as a significant value for coated calcite. Besides, the analytical hierarchy process was applied to observe the importance of each parameter. Stearic acid dosage, mill speed, and micronized calcite filling ratio are the top three parameters affecting the active ratio. Next, size distribution, XRF, XRD, SEM, FTIR, TGA-DTA, contact angle, and whiteness measurements were performed on the micronized calcite (MC) and coated micronized calcite (CMC) samples. The final CMC product had a 99.90% active ratio, 2.49 μm mean (d50) particle size, and 101.66o contact angle. Finally, CMC obtained by the surface modification can be used as a filler mineral.

High cyclic stability and low plateau of Ti2V2Zr/NaH/Al hydrogen storage composite system prepared by ultrasound-assisted ball milling

NaH/Al doped with Ti2V2Zr with the aim of lowering the rehydrogenation pressure, lowering the dehydrogenation temperature, and improving the hydrogenation/dehydrogenation kinetics of NaAlH4. It was found that moderate ultrasonic-assisted wet grinding was beneficial to fine particles efficiently, improved uniformity of particle size, and reduced lattice distortion because its crystalline phase can converge more active hydrogen atoms and reduce the energy barrier of H exchange between the alloy and the matrix, thus improving the comprehensive hydrogen storage performance of the composite systems. It could reversibly store 4.81 wt% of hydrogen and completely hydrogenation under a low hydrogen pressure of 55 atm, its starting and ending dehydrogenation temperatures decrease by 81 and 89 °C, respectively, and the activation energies of the two-step dehydrogenation decrease by 26.7 and 52.7 kJ mol−1 respectively, with a dehydrogenation capacity retention of up to 99.58% over five cycles.