Vertical distributions of chemical components of particulate matter (PM) are essential for better understanding the climate, environmental and health effects. The steep slope from western SiChuan Basin (SCB) to eastern Tibetan Plateau (TP) provides a good platform for obtaining the gradient variations of PM chemical components. Daytime and nighttime PM1 (particulate matter smaller than 1 μm) samples were collected with the medium-volume sampler at six sites with elevation ranging from 500 m to 3500 m (Chengdu, Sanbacun, Wenchuan, Lixian, Maerkang and Hongyuan). The secondary inorganic ions and carbonaceous aerosols were the largest contributor to PM1 concentrations. The chemical components from the anthropogenic sources existed strong stratification with high concentrations inside the basin, while primary natural ions showed little discrepancy among the sites. The concentrations of primary inorganic ions from anthropogenic sources were much higher at nighttime than daytime, which was contrary to the diurnal cycle of secondary inorganic ions. Spatial heterogeneity of PM chemical components was large between basin and plateau sites, especially for NO3− and NH4+, large depending on season and daylight. The excess NH4+ concentrations existed in spring, summer and fall, while SO42− and NO3− cannot be completely neutralized by NH4+ in winter. The proportion of secondary formation in all sources significantly increased from about 10 % to 30 %–40 % with the increased elevation, while the contribution of motor vehicles declined from western SCB to eastern TP. This study will fill the scarce observations of PM chemical components at the sloped terrain and deepen the understanding of formation mechanism of heavy pollution inside the basin.
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