Western Mediterranean Deep Water Research Articles

The time series at the Strait of Gibraltar as a baseline for long-term assessment of vulnerability of calcifiers to ocean acidification

The assessment of the saturation state (Ω) for calcium carbonate minerals (aragonite and calcite) in the ocean is important to determine if calcifying organisms have favourable or unfavourable conditions to synthesize their carbonated structures. This parameter is largely affected by ocean acidification, as the decline in seawater pH causes a decrease in carbonate ion concentration, which in turn, lowers Ω. This work examines temporal trends of seawater pH, ΩAragonite and ΩCalcite in major Atlantic and Mediterranean water masses that exchange in the Strait of Gibraltar: North Atlantic Central Water (NACW), Levantine Intermediate Water (LIW) and Western Mediterranean Deep Water (WMDW) using accurate measurements of carbonate system parameters collected in the area from 2005-2021. Our analysis evidences a gradual reduction in pH in the three water mases during the monitoring period, which is accompanied by a decline in Ω for both minerals. The highest and lowest decreasing trends were found in the NACW and LIW, respectively. Projected long-term changes of Ω for future increases in atmospheric CO2 under the IPCC AR6 Shared Socio-economic Pathway "fossil-fuel-rich development" (SSP5-8.5) indicate that critical conditions for calcifiers with respect to aragonite availability will be reached in the entire water column of the region before the end of the current century, with a corrosive environment (undersaturation of carbonate) expected after 2100.

A Lagrangian Estimate of the Mediterranean Outflow's Origin

AbstractThe origin of the Mediterranean Outflow is investigated by deploying six millions virtual Lagrangian parcels at the Strait of Gibraltar, and tracing them backward in time using velocity estimates from an eddy‐permitting reanalysis. The Lagrangian parcels are followed until they intercept one of three sections. The hypothesis is that each section is associated with distinct water masses: the Gulf of Lions, related to Western Mediterranean Deep Water and Western Intermediate Water, carries 86% of the Outflow's transport; the Northern Tyrrhenian, related to Tyrrhenian Deep and Intermediate Waters, carries 1% of the transport; the Strait of Sicily, related to Levantine Intermediate Waters, carries 13% of the transport. The median transit times from the sections to the Strait of Gibraltar range from 5 years (Gulf of Lions) to 8 years (Strait of Sicily).

Water mass age and dissolved organic matter properties drive the diversity of pelagic prokaryotes in the Western Mediterranean Sea

The deep sea is among the largest, yet still poorly known, ecosystems on Earth. This knowledge gap is particularly evident for the bathypelagic layer (between 1000 and 4000 m) of the deep Mediterranean Sea (MS), characterized by peculiar environmental conditions at meso- and bathypelagic depths, such as the thermal signature of the deep waters, showing temperatures approximately 10 °C higher than any oceanic system at comparable depths. This sustains high rates of prokaryotic activities and fast dissolved organic matter (DOM) mineralization rates, and likely selects for unique microbial assemblages. We collected seawater samples in stations representative of different areas of the Western Mediterranean Sea (Algero-Provençal Basin, Alboran Sea and Gulf of Lion), from the surface to the bathypelagic layer (down to 2680 m) and in different water masses, and described the composition of pelagic prokaryotic communities, along with measurements of the main physical-chemical variables, concentration and optical properties (absorption and fluorescence) of DOM. Remarkable differences in DOM optical properties were observed among water masses, with highest dissolved organic carbon (DOC) values in surface waters and lowest in the oldest water masses represented by the Western Mediterranean Deep Water (WMDW) and the Levantine Intermediate Water (LIW), which were characterized by the highest concentration of recalcitrant DOM. The water mass had a significant partitioning effect on microbial community composition, which showed the highest richness in LIW. DOC, the marine humic-like component of DOM (C1mh) and oxygen were the main drivers of prokaryotic community structure. Changes in quality of DOM were reflected in shifts in community composition, supporting the existence of strong relationships between DOM quality and microbial community composition in the deep MS. Our data shed light on the community composition and diversity patterns of prokaryotic plankton in the deep western MS, helping to elucidate the major microbial players in the DOM cycling, and to progress towards a better comprehension of its future trends in light of changing conditions that are modifying the oceanography of the entire MS basin.

Characterization of the Atlantic Water and Levantine Intermediate Water in the Mediterranean Sea using 20 years of Argo data

Abstract. Atlantic Water (AW) and Levantine Intermediate Water (LIW) are important water masses that play a crucial role in the internal variability of the Mediterranean thermohaline circulation. To be more specific, their variability and interaction, along with other water masses that characterize the Mediterranean basin, such as the Western Mediterranean Deep Water (WMDW), contribute to modify the Mediterranean Outflow through the Strait of Gibraltar, and hence they may influence the stability of the global thermohaline circulation. This work aims to characterize AW and LIW in the Mediterranean Sea, taking advantage of the large observational dataset (freely available on https://argo.ucsd.edu, https://www.ocean-ops.org, last access: 17 January 2022; Wong et al., 2020) provided by Argo floats from 2001 to 2019. AW and LIW were identified using different diagnostic methods, highlighting the inter-basin variability and the strong zonal gradient that both denote the two water masses in this marginal sea. Their temporal variability was also investigated over the last 2 decades, providing a more robust view of AW and LIW characteristics, which have only been investigated using very short periods in previous studies due to a lack of data. A clear salinification and warming trend characterize AW and LIW over the last 2 decades (∼ 0.007 ± 0.140 and 0.006 ± 0.038 yr−1; 0.026 ± 0.715 and 0.022 ± 0.232 ∘C yr−1, respectively). The salinity and temperature trends found at sub-basin scale are in good agreement with previous results. The strongest trends are found in the Adriatic basin in the properties of both AW and LIW.

Paleoceanographic and paleoclimatic variability in the Western Mediterranean during the last 25 cal. kyr BP. New insights from contourite drifts

The Western Mediterranean Deep Water (WMDW), on its way out toward the Atlantic Ocean, has favored the formation of contourite drifts in the Alboran Sea (SW Mediterranean) since the opening of the Strait of Gibraltar. Resolving the nature of these deposits is crucial for reconstructing the WMDW variability at a millennial scale, deciphering its bottom current paleo-velocity, and establishing paleoclimatic implications over the last 25 cal. kyr BP. Two sediment cores retrieved from elongated separated and plastered contourite drifts formed along its path are investigated by means of multi-sedimentological data (terrigenous grain-size, sortable silt, terrigenous and carbonate sediment fluxes, bioturbation and ichnofabric changes), geochemical data (Zr/Al and Si/(Si + Al) ratios), chronostratigraphic data (δ18O, and 14C data) as well as statistical analyses (grain-size end-member modelling and spectral analysis). Integration of these data confirms the contouritic nature of Alboran drift deposits. The high-resolution paleocurrent records of the WMDW inferred from the sortable silt of contourite sequences led us to define two regimes in terms of WMDW flow energy. Regime 1 (weak to moderate velocity) defined by paleo-velocities of ⁓4 to 23 cm s−1 is dominant during the last 24 cal kyr BP. Regime 2 (strong velocity) is characterized by estimated paleo-velocities of about ⁓36 cm s−1 during Heinrich Stadial 2. The spectral analysis of bottom current proxies (sortable silt and Zr/Al ratio) matches four cyclic climatic signals (1900 yr, 2300 yr, 4000 ye and 6100 yr), corroborating the occurrence of millennial-scale cyclicity. These cycles are related to atmospheric climate variability, in turn linked to variations in solar activity. Our results, when combined with published data from a neighboring NW Mediterranean contourite drift, provide for a better regional understanding of the WMDW millennial-scale dynamics.

Multiproxy record of suborbital-scale climate changes in the Algero-Balearic Basin during late MIS 20 - Termination IX

High-resolution quantitative analyses have been carried out in samples from the Ocean Drilling Program (ODP) Site 975 in the Algero-Balearic basin through late Marine Isotope Stage (MIS 20)-Termination IX (800–784 ka). The multi-proxy study combines data of planktonic δ18O, δ13C, calcareous plankton (coccolithophores, foraminifera), palynomorphs, alkenone-based sea surface temperature (SST), % alkenone tetraunsatured (% C37:4), and terrigenous biomarkers (C23–C31n-alkanes, C22–C30n-alkanols) with the aim to reconstruct climate-induced paleoenvironmental changes at orbital-submillennial scale, in a crucial time interval of the Early-Midde Pleistocene transition. The surface water δ18Osw has been reconstructed from δ18OG.bulloides and alkenone-based SST as a proxy for salinity changes. The late MIS 20 has been subdivided in several phases based on evidence of (i) meltwater events of polar origin or from surrounding mountain glaciers, (ii) changes in the production rate of Western Mediterranean Deep Water (WMDW) and in deep water ventilation, (iii) variation in terrestrial input and river discharge, and iv) variations in the strength of the north westerlies, and polar front shift. Following a glacial stadial (lasting ca 3 kyr) marked by the strongest WMDW production, coeval with a boreal summer insolation minimum and a marked low sea level, the latest MIS 20 is characterized by a terminal stadial event (lasting ca 3.5 kyr), which is traced by the occurrence of cold-low salinity water, pointing to meltwater advection at the site location. Short-term warm and cool events occurred through Termination IX during sea level rise and insolation increase, preceding the onset of full MIS 19c, characterized by an organic rich layer (ORL) associated with insolation cycle 74. The succession of these climate and oceanographic events has been compared to evidences from other Mediterranean sites, highlighting similar basin-wide patterns, which recall the climate evolution of Termination I. The comparison of our results with the climate proxies from the Integrated Ocean Drilling Program (IODP) Site U1385 located west of Iberian margin made it possible to point at the connection between Mediterranean oceanographic and atmospheric dynamics and the northern hemisphere ice-sheet instability, providing insight on the relationship with the Atlantic meridional overturning circulation and thermal front migration.

Hotter and Weaker Mediterranean Outflow as a Response to Basin-Wide Alterations

Time series collected from 2004 to 2020 at an oceanographic station located at the westernmost sill of the Strait of Gibraltar to monitor the Mediterranean outflow into the North Atlantic have been used to give some insights on changes that have been taking place in the Mediterranean basin. Velocity data indicate that the exchange through the Strait is submaximal (that is, greater values of the exchanged flows are possible) with a mean value of −0.847 ± 0.129 Sv and a slight trend to decrease in magnitude (+0.017 ± 0.003 Sv decade−1). Submaximal exchange promotes footprints in the Mediterranean outflow with little or no-time delay with regards to changes occurring in the basin. An astonishing warming trend of 0.339 ± 0.008°C decade−1 in the deepest layer of the outflow from 2013 onwards stands out among these changes, a trend that is an order of magnitude greater than any other reported so far in the water masses of the Mediterranean Sea. Biogeochemical (pH) data display a negative trend indicating a gradual acidification of the outflow in the monitoring station. Data analysis suggests that these trends are compatible with a progressively larger participation of Levantine Intermediate Water (slightly warmer and characterized by a pH lower than that of Western Mediterranean Deep Water) in the outflow. Such interpretation is supported by climatic data analysis that indicate diminished buoyancy fluxes to the atmosphere during the seven last years of the analyzed series, which in turn would have reduced the rate of formation of Western Mediterranean Deep Water. The flow through the Strait has echoed this fact in a situation of submaximal exchange and, ultimately, reflects it in the shocking temperature trend recorded at the monitoring station.

Ichnological analysis as a tool for assessing deep-sea circulation in the westernmost Mediterranean over the last Glacial Cycle

During the Last Glacial Cycle (last ~130 kyr) climatically induced changes in the ocean dynamics affected the tracemaker habitat in the Alboran Sea Basin (westernmost Mediterranean), as observed in sediment records from ODP Leg 161 Sites 976 and 977. The trace fossil assemblage present is assigned to the Zoophycos ichnofacies and is of low/moderate diversity and comprises common Planolites, Chondrites and Thalassinoides, with occasional Scolicia and Zoophycos. Ichnodiversity, size of biogenic structures and percentage of bioturbational sedimentary structures clearly correlate. Fluctuations in ichnological features evidence a well-developed short-term cyclic pattern that could be related to environmental changes such as export production and oxygenation at the seafloor. The percentage of bioturbational sedimentary structures correlates well with sea-surface temperature (SST) records obtained for the Alboran Sea and Gulf of Lions, as well as with the δ18O profiles of Greenland ice cores. Correlation is seen for both the long-term (over the Last Glacial Cycle) and short-term changes, the latter comprising climate oscillations such as Heinrich Events, Younger Dryas, and periods of organic-rich layer deposition. Ichnological data also allow for a reconstruction of climatically induced changes in the ocean dynamics, which have a major incidence in the Western Mediterranean Deep Water that, in turn, affects deep-sea environmental conditions.

The Postglacial Isotopic Record of Intermediate Water Connects Mediterranean Sapropels and Organic‐Rich Layers

AbstractCarbon‐rich layers exist at both sides of the Mediterranean Sea sedimentary record and are called sapropels and organic rich layers (ORLs), respectively, in the eastern and western basins. They have different levels of organic carbon accumulation and seafloor oxygen deprivation. The most recent sapropel and ORL depositions have a different timing, approximately 10.8–6.1 and 14.5–9.0 ka, respectively. Here we investigate oxygen isotopic records of three foraminifera species that occupy different habitats within the Sicily Channel water column since ~12.0 ka, thus in the sill between the eastern and western Mediterranean basins. These data are ice volume corrected, to get information on water masses density variability, and are accompanied by benthic foraminifera δ13C measurements to establish Sicily Channel seafloor ventilation. Our results, and the comparison with other chronologically well‐constrained Mediterranean records, highlight the connection of the two subbasins due to monsoon activity. The end of the maximum Nile River flooding at ~9.2 ka, and eastern Mediterranean seafloor reventilation above 1,800–1,500 m depth at ~ 8.2 and 7.2 ka, left a clear signature in the intermediate water isotopic record of the Sicily Channel. Concurrently, the western Mediterranean deep water circulation experienced a significant recovery after a long period of slowdown. We argue that African monsoon weakening was transmitted into the western Mediterranean, through the intermediate layer of circulation, where deep water formation took place and brought oxygen to the seafloor.

Climatological Hydrographic Properties and Water Mass Transports in the Balearic Channels From Repeated Observations Over 1996–2019

The longest time series of CTD transects available in the Mallorca and Ibiza Channels (1996-2019) are presented. These hydrographic sections have a three-monthly periodicity and allow to resolve the seasonal cycle of water mass properties. Hydrographic sectionsThey are organized in two closed boxes also allowing the use of inverse models for the calculation of absolute geostrophic transports through the Channels. These use of long time series allows to establish the climatological distributions of potential temperature and salinity for each season of the year as well asand other relevant statistical properties such as the variance and covariance functions. TheOur results indicate that these distributions depart from normality makingand the median asis a better statistic than the mean value for the description of climatological fields. The salinity field shows a seasonal cycle in the upper layer indicating a higher influence of the Atlantic Water during summer, decreasing through the rest of the year. The Western Intermediate Water, which is mainlygenerally formed in the North-Western Mediterranean and the Balearic Sea, is observed preferentially in the Ibiza Channel during winter and spring. This water mass is better detected using a geometry-based method instead of the traditional criterion based on predefined temperature and salinity ranges. TheseBoth water masses flow preferentially southwards through the Ibiza Channel, and northwards through the Mallorca Channel, although intrusions in the opposite directions are observed. Below, tThe Levantine Intermediate Water shows a similar behaviour, but the mass transport analyses suggest that most of this water mass recirculates with the Balearic Current along the northern slope of the Islands with the Balearic Current. Although the depth of both Channels prevents the circulation of deep waters, a small fraction of the Western Mediterranean Deep Water could overflow the sills.

Recent Changes in Deep Ventilation of the Mediterranean Sea; Evidence From Long-Term Transient Tracer Observations

The Mediterranean Sea is a small region of the global ocean but with a very active overturning circulation that allows surface perturbations to be transported to the interior ocean. Understanding of ventilation is important for understanding and predicting climate change and its impact on ocean ecosystems. To quantify changes of deep ventilation, we investigated the spatiotemporal variability of transient tracers (i.e. CFC-12 and SF6) observations combined with temporal evolution of hydrographic and oxygen observations in the Mediterranean Sea from 13 cruises conducted during 1987-2018, with emphasize on the update from 2011 to 2018. Spatially, both the Eastern and Western Mediterranean Deep Water (EMDW and WMDW) show a general west-to-east gradient of increasing salinity and potential temperature but decreasing oxygen and transient tracer concentrations. Temporally, stagnant and weak ventilation is found in most areas of the EMDW during the last decade despite the prevailing ventilation in the Adriatic Deep Water between 2011 and 2016, which could be a result of the weakened Adriatic source intensity. The EMDW has been a mixture of the older Southern Aegean Sea dense waters formed during the Eastern Mediterranean Transient (EMT) event, and the more recent ventilated deep-water of the Adriatic origin. In the western Mediterranean basin, we found uplifting of old WMDW being replaced by the new deep-water from the Western Mediterranean Transition (WMT) event and uplifting of the new WMDW toward the Alboran Sea. The temporal variability revealed enhanced ventilation after the WMT event but slightly weakened ventilation after 2016, which could be a result of combined influences from the eastern (for the weakened Adriatic source intensity) and western (for the weakened influence from the WMT event) Mediterranean Sea. Additionally, the Mediterranean Sea is characterized by a Tracer Minimum Zone (TMZ) at mid-depth of the water column attributed to the rapid deep ventilation so that the TMZ is the slowest ventilated layer. This zone of weak ventilation stretches across the whole Mediterranean Sea from the Levantine basin into the western basin.

Muted cooling and drying of NW Mediterranean in response to the strongest last glacial North American ice surges

Abstract The massive North Atlantic iceberg discharges of the last glacial period, the so-called Heinrich events (HE), resulted in atmospheric and oceanic responses of the Mediterranean region that remain poorly documented and understood. This paper focuses on the climatic phases termed Heinrich stadials (HS) 4 and 5 generated by the HE 4 and 5 that occurred during a period of similar intermediate global ice volume and greenhouse gas concentrations but with different iceberg discharges and orbital boundary conditions. Our comparison of sea surface temperature and salinity changes with deep water conditions in the Gulf of Lions (planktonic and benthic foraminifera δ18O and δ13C records) and regional pollen-based temperature and precipitation reconstructions in NW Mediterranean for these Heinrich stadials reveal a paradoxical situation. A lower North American iceberg discharge during HS 5 compared to HS 4 is associated with colder and drier conditions in the NW Mediterranean borderlands. During the moderate iceberg discharge of HS 5 a relatively high salinity in the Gulf of Lions lead to stronger Western Mediterranean Deep Water formation and mixing of the surface with the deeper layers. By contrast during HS 4, we suggest that the massive North Atlantic iceberg break-up decreased the salinity of the Gulf of Lions and reduced the wind stress in the Mediterranean, leading to the stratification of the Mediterranean water column and inducing limited upward mixing of cold water, resulting in regional atmospheric warming and wetting compared to HS 5. This work highlights the potential crucial role of local processes in modulating the regional response to a global climate change related with ice-sheet instabilities.

Oceanic mercury concentrations on both sides of the Strait of Gibraltar decreased between 1989 and 2012

Mercury (Hg) is a toxic metal that threatens the health of aquatic ecosystems and fish consumers. Its natural cycle has been deeply perturbed by Anthropogenic Hg emissions have deeply perturbed its natural cycle, especially since the start of the Industrial Revolution circa 1850 CE. Anthropogenic Hg emissions from North America and Europe have decreased by a factor of two in the last decades following the implementation of strict regulations. The response of North Atlantic Ocean and Mediterranean waters to this decrease remains poorly documented by field observations. A comparison of results obtained between 1989 and 2012 shows a significant decrease of Hg concentrations in waters on both sides of the Strait of Gibraltar. West of Gibraltar, the Hg decrease ranges from ∼35 % in the upper North East Atlantic Deep Water to ∼50 % in the North East Atlantic Central Water. East of Gibraltar, the observed decrease is ∼30 % in the Western Mediterranean Deep Water. No decrease is observed in the deep Atlantic Ocean layer that formed before the industrial era. These results strongly substantiate the effectiveness of global anti-pollution policies on Hg contamination in oceanic waters. A consequent decline of Hg bioaccumulation in Northeastern Atlantic and Western Mediterranean pelagic ecosystems still requires verification.

Decadal acidification in Atlantic and Mediterranean water masses exchanging at the Strait of Gibraltar

Seawater pH is undergoing a decreasing trend due to the absorption of atmospheric CO2, a phenomenon known as ocean acidification (OA). Biogeochemical processes occurring naturally in the ocean also change pH and hence, for an accurate assessment of OA, the contribution of the natural component to the total pH variation must be quantified. In this work, we used 11 years (2005–2015) of biogeochemical measurements collected at the Strait of Gibraltar to estimate decadal trends of pH in two major Mediterranean water masses, the Western Mediterranean Deep Water (WMDW) and the Levantine Intermediate Water (LIW) and assess the magnitude of natural and anthropogenic components on the total pH change. The assessment was also performed in the North Atlantic Central Water (NACW) feeding the Mediterranean Sea. Our analysis revealed a significant human impact on all water masses in terms of accumulation of anthropogenic CO2. However, the decadal pH decline found in the WMDW and the NACW was markedly affected by natural processes, which accounted for by nearly 60% and 40% of the total pH decrease, respectively. The LIW did not exhibit a significant pH temporal trend although data indicated natural and anthropogenic perturbations on its biogeochemical signatures.

Deep-water formation variability in the north-western Mediterranean Sea during the last 2500 yr: A proxy validation with present-day data

Abstract Here we investigate the sensitivity of deep-water formation in the north-western Mediterranean Sea to climate variability during the last 2500 yr. With this purpose, the grain-size parameter UP10 (fraction > 10 μm) is used as a proxy for intensity of deep-water circulation. Such a proxy is first validated through the analysis of oceanographic data collected from October 2012 to October 2014 by means of two deep-water mooring lines equipped with sediment traps and currentmeters in the Gulf of Lion and north of Minorca Island. Enhancements of deep current speed resulted from dense shelf water cascading and open-sea deep convection in February 2013 leading to dense-water formation. The grain-size distribution of settling particles from sediment traps collected during 2012–2013 shows a distinctive particle mode and high UP10 values correlated to deep-water formation. These data are consistent with grain-size values in sediment cores from the north of Minorca, thus supporting the validity of the UP10 parameter to reconstruct changes of intensity in deep-water formation and associated near-bottom currents. The deep-water sediment record of the north of Minorca for the last 2.5 kyr shows that the strongest deep-water formation events occurred during relatively warm intervals, such as the Roman Period (123 BCE-470 CE 2 ), the end of the Medieval Climate Anomaly (900–1275 CE) and the first part of the Little Ice Age (1275–1850 CE). By contrast, our data indicate a progressive reduction in the overturning conditions during the Early Middle Ages (470–900 CE) resulting in weaker deep-water formation events during most of the Medieval Climate Anomaly. Intense deep-water formation events appear to be mostly associated with periods of enhanced Evaporation-Precipitation balance rather than to buoyancy loss due to winter cooling only. Our results suggest that warm sea surface temperature during spring months could have played an important role by increasing the Evaporation–Precipitation balance and favouring buoyany loss by increased of salinity. The comparison our data with other oceanographic and climatic records indicates a change in the proxy relation before and after the Early Middle Ages. Western Mediterranean Deep Water and Levantine Intermediate Water behave in opposite way after the Early Middle Ages, thus indicating that the previously proposed Mediterranean see-saw pattern in the Evaporation-Precipitation balance also influenced convection patterns in the basins during the last 1500 yr. These changes are discussed in the frame of different configurations of the North Atlantic Oscillation and East Atlantic/ West Russian modes of atmospheric variation.

Preface to the Special Section: Dense Water Formations in the Northwestern Mediterranean: From the Physical Forcings to the Biogeochemical Consequences

AbstractThe northwestern Mediterranean Sea is one of the few sites of open‐sea deep convection and dense water formation. The area is characterized by intense air‐sea exchanges favored by the succession of strong northerly and northwesterly winds during autumn and winter that eventually induce deep convection episodes and the formation of the Western Mediterranean Deep Water. This region exhibits a significant spring phytoplankton bloom, which appears to be largely influenced in intensity and diversity by the winter mixing. To understand and resolve the interplay between the atmosphere and ocean, and the impact of ocean circulation and mixing on biogeochemistry, we carried out an unprecedented observational effort during a large experiment between July 2012 and July 2013. A multiplatform approach—combining aircraft, balloons, ships, moorings, floats, and gliders ‐ aimed both at characterizing the dynamics of the atmosphere and at quantifying the physical, biogeochemical, and biological properties of the water masses. Beyond a better understanding of the wind dynamics, the interannual variability of the deep convection, and the seasonal variability of the nutrient distribution and plankton structure in the pelagic ecosystem, the experiment provided a reference data set that was used as a benchmark for advancing the modeling of the surface fluxes, convective processes, dense water formation rates, and physical‐biogeochemical coupling processes. It also represented an opportunity for complementary investigations such as evaluating model parameterizations or studying the role of submesoscale eddies in dense water spreading and biogeochemistry.

Influence of deep water formation by open-sea convection on the transport of low hydrophobicity organic pollutants in the NW Mediterranean Sea

The significance of the offshore vertical convection currents in the transport and sinking of water-soluble organic pollutants into marine deep basins has been evaluated. For this purpose, sediment cores were collected in the Gulf of Lion (GoL) at sites between 26 and 2330 m water depth. The top core layers were analyzed for aromatic and aliphatic hydrocarbons and organochlorine compounds. Organic compounds with logKAW (air water partition coefficient) between −2 and −4, e.g. lindane, PCB 28, PCB 52, phenanthrene, methylphenanthrenes, dimethylphenanthrenes, C14–C23n-alkanes, are found in higher concentrations or exhibit relative concentration increases in the sediments deposited in the continental rise as consequence of the open-sea convection processes associated with the formation of Western Mediterranean Deep Water (WMDW). In contrast, the organic pollutants with intermediate air-water distribution coefficients, logKAW between −2 and 0, and high octanol water distribution coefficients (logKow > 6), e.g. highly chlorinated PCBs, DDTs, DDEs, DDDs, C25–C35n-alkanes, and polycyclic aromatic hydrocarbons with molecular weight higher than 200, occur in association to sediment particles, which are mainly transported by the Northern current along the continental shelf forming the mud belt. The Rhône prodelta is therefore the area of the GoL showing the highest concentrations of this group of organic compounds, which are preferentially associated with water particles. Overall, the results show that vertical open-sea convection processes related with offshore formation of WMDW may have an important role in the transport and accumulation of water soluble pollutants to deep marine environments of the GoL (>2000 m water depth).

Direct Observations Reveal the Deep Circulation of the Western Mediterranean Sea

AbstractDirect observations of the deep water circulation in the western Mediterranean Sea are presented, based on the analysis of autonomous profiling floats drifting at 1,200 and 1,900 m depth during the 1997–2002 period. The amount of water circulating in the basin is quantified, revealing several distinct gyres and boundary currents. It was also possible to follow the spreading of the newly formed Western Mediterranean Deep Water (nWMDW) and Tyrrhenian Deep Water (TDW), two main components of the deep water in the western Mediterranean, from their origin, based on their temperature and salinity signature. Both boundary currents and isolated eddies carrying the water into the interior are important for this.

Recent changes (2004–2016) of temperature and salinity in the Mediterranean outflow

AbstractTemperature and salinity series near the seafloor at Espartel Sill (Strait of Gibraltar) have been used to analyze the thermohaline variability of the Mediterranean outflow. The series shows temperature drops by the end of most winters/early springs, which are the remote response to Western Mediterranean Deep Water (WMDW) formation events in the Gulf of Lion that uplift old WMDW nearby the strait. This process distorts the seasonal cycle of colder/warmer water flowing out in summer/winter likely linked to the seasonality of the Western Alborán Gyre. The series shows positive trends in agreement with previous values, which are largely increased after 2013. It is tentatively interpreted as the Western Mediterranean Transition (WMT) signature that started with the very cold winters of 2005 and 2006. It was only after the large new WMDW production of 2012 and 2013 harsh winters that WMT waters were made available to flow out of the Mediterranean Sea.

Long-term climatic influences on the physiological condition of the red shrimp Aristeus antennatus in the Western Mediterranean Sea

CR Climate Research Contact the journal Facebook Twitter RSS Mailing List Subscribe to our mailing list via Mailchimp HomeLatest VolumeAbout the JournalEditorsSpecials CR 72:111-127 (2017) - DOI: https://doi.org/10.3354/cr01453 Long-term climatic influences on the physiological condition of the red shrimp Aristeus antennatus in the Western Mediterranean Sea Ana Carbonell1,*, Pere Joan Llompart2, Magdalena Gaza1, Arnau Mir2, Alberto Aparicio-González1, Diego Álvarez-Barastegui3, Rosa Balbín1, Joan Enric Cartes4 1Instituto Español de Oceanografía, Centro Oceanográfico de Baleares, Muelle de Poniente s/n, 07015 Palma de Mallorca, Islas Baleares, Spain 2Universitat de les Illes Balears, Carretera de Valldemossa, km 7.5. 07122 Palma de Mallorca, Islas Baleares, Spain 3SOCIB, Balearic Islands Coastal Observing and Forecasting System, Parc Bit, Norte, Bloc A 2op., pta. 3, 07121 Palma de Mallorca, Islas Baleares, Spain 4Institut de Cièncias del Mar (CMIMA_CSIC), Psg. Marítim de la Barceloneta 37-49, 08003 Barcelona, Spain *Corresponding author: ana.carbonell@ba.ieo.es ABSTRACT: Changes in the physiological condition (represented by Kn = body weight/length-predicted weight) of the deep-sea shrimp Aristeus antennatus associated with the warming and rising salinity trends in the western Mediterranean were analyzed to explore how deep-sea populations can reconfigure their biology to match the changes in ocean conditions. Two slope areas around the Balearic Islands (Western Mediterranean Sea) were analyzed using sampling data and generalized additive models. The 23 yr time series of monthly Kn estimates shows 2 different aspects of the life history of A. antennatus, corresponding to 2 different seasonal periods. The Kn series from June through September reflects the shrimps’ reproductive condition to the north of the Islands, while samples from October through May represent a period of low gonad weight and high hepatosomatic indices to the south of the Islands. Oceanographic variables used to construct models and seek relationships with changes in Kn were salinity, temperature, and dissolved oxygen in the Levantine Intermediate Water and Western Mediterranean Deep Water layers, and chlorophyll a satellite imagery data. The North Atlantic Oscillation and the Eastern Atlantic index were used as climatic indicators. Physiologic condition during the winter fattening periods decreased over the time series and was negatively correlated with increasing salinity. During the summer reproductive periods, the best-fitting models show a year-on-year effect and a significant probability of effects on condition from oligotrophication. These results suggest that increasing salinity at depth, which ultimately increases oligotrophy, may cause changes in physiological condition. KEY WORDS: Aristeus antennatus · Physiological condition · Time series · Fisheries · Climate change · Western Mediterranean Full text in pdf format PreviousNextCite this article as: Carbonell A, Llompart PJ, Gaza M, Mir A and others (2017) Long-term climatic influences on the physiological condition of the red shrimp Aristeus antennatus in the Western Mediterranean Sea. Clim Res 72:111-127. https://doi.org/10.3354/cr01453 Export citation RSS - Facebook - Tweet - linkedIn Cited by Published in CR Vol. 72, No. 2. Online publication date: May 18, 2017 Print ISSN: 0936-577X; Online ISSN: 1616-1572 Copyright © 2017 Inter-Research.