Weathering Crust Research Articles

Metagenomic inference of microbial community composition and function in the weathering crust aquifer of a temperate glacier

Bacterial, fungal, and algal communities that colonize aquatic systems on glacial ice surfaces mediate biogeochemical reactions that alter meltwater composition and affect meltwater production and storage. In this study, we sought to improve understanding of microbial communities inhabiting the shallow aquifer that forms seasonally within the ice surface of a glacier’s ablation zone (i.e., the weathering crust aquifer). Using a metagenomic approach, we compared gene contents of microbial assemblages in the weathering crust aquifer (WCA) of the Matanuska Glacier (Alaska, USA) to those recovered from supraglacial features and englacial ice. High abundances of Pseudomonadota, Cyanobacteriota, Actinomycetota, and Bacteroidota were observed across all samples, while taxa in class Gammaproteobacteria were found at significantly higher abundances in the weathering crust aquifer. The weathering crust aquifer samples also contained higher abundances of Dothideomycetes and Microbotryomyetes; fungal classes commonly observed in snow and other icy ecosystems. Phylogenetic analysis of 18S rRNA and rbcL gene sequences indicated high abundances of algae in the WCA that are closely related (> 98% and > 93% identity, respectively) to taxa of Ancylonema (Streptophyta) and Ochromonas (Ochrophyta) reported from glacial ice surfaces in Svalbard and Antarctic sea ice. Many functional gene categories (e.g., homeostasis, cellular regulation, and stress responses) were enriched in samples from the weathering crust aquifer compared to those from proximal englacial and supraglacial habitats, providing evidence for ecological specialization in the communities. The identification of phagotrophic phytoflagellate taxa and genes involved in mixotrophy implies that combined phototrophic and heterotrophic production may assist with persistence in the low light, low energy, and ephemeral conditions of the weathering crust environment. The compositional and functional differences we have documented indicate distinct microbial distributions and functional processes occur in the weathering crust aquifer environment, and we discuss how deciphering these nuances is essential for developing a more complete understanding of ecosystem biogeochemistry in supraglacial hydrological systems.

Geological Features and Ore Formation Pattern of Jinzhong Bauxite Mine, Shanxi Province, China

Bauxite is located in the lower part of the Benxi Formation, and the prospecting project shows that the distribution of bauxite ore bodies in the area is discontinuous, and there are differences in the thickness of the ore bodies. To have a clearer understanding of the bauxite ore bodies and metallogenic pattern in the census area, this study has made use of the prospecting project data, sample analysis results, etc., and combined with the geological and tectonic background of the area, the stratigraphic spreading characteristics of the bauxite ore body spatial spreading, ore characteristics and ore controlling factors in the area have been explored and researched. The bauxite ore bodies in the study area are stratified but the ore-bearing rock system is influenced by the Ordovician paleokarst geomorphology and intermittently distributed horizontally, which can be distinguished into three different ore bodies. The bauxite ore body and Shanxi-style iron ore are associated with hard clay ore, in which the ore minerals are mainly monohydrate duralumin. The natural ore type can be divided into dense bauxite and oolitic bauxite. Bauxite in this area mainly originated from the basal Ordovician carbonate rocks, with a combination of iron-rich and aluminum-rich layers, and is a typical carbonate rock sedimentary deposit of ancient weathering crust.

Characteristics of Effective Fractures in Deep Buried-Hill Basement Gas Reservoirs and Its Effects on Fluids: The Jianbei Slope, Qaidam Basin, China

Summary Buried hills are basement uplifts beneath sediment layers that possess significant exploration potential. Using the Jianbei Slope of the Qaidam Basin in China as a case study, we systematically investigated the types and origins of fractures in deep buried-hill gas reservoirs. In our study, we synthesized various data, including experimental results, production dynamics, and both conventional and special logging with the aim of clarifying the sequence and effectiveness of fracture formation in these gas reservoirs; analyzing the impact of effective fractures on fluid migration, accumulation, and preservation; and proposing a development plan to enhance stable production. Research reveals that since the Late Paleozoic, the region has been influenced by multiple phases of tectonic stress, deep fluid dissolution, and surface weathering leaching. This has resulted in a fracture system dominated by east-west trending deep major faults, with accompanying tectonic fractures, alongside dissolution, diagenetic, and weathering-collapse fractures. Smaller fractures oriented at an angle to the maximum principal stress and fractures with normal stress lower than the compressive strength are conducive to maintaining fracture effectiveness. Fracture widths range from 0.1 μm to 343.36 μm, with effective fractures comprising 63.49% of the total. Based on aperture and permeability, effective fractures are categorized into three levels: Level I fractures (>100 μm) serve as primary migration pathways; Level II fractures (10–100 μm) are well configured with dissolution pores, forming a foundation for favorable reservoir development; and Level III fractures (micron scale) enhance reservoir storage capacity by connecting fractures. The gas-water interface in the reservoir rises rapidly and unevenly. In the I + II + III fracture combination model, fluid exhibits high-conductivity channeling, leading to rapid declines in formation pressure, quick water breakthroughs in single wells, and severe water sealing. Conversely, in the II + III fracture combination model, fluid invasion is characterized by weak-to-strong finger-like intrusion, leading to prolonged stable production. Vertically, the 20-m to 60-m interval above the bedrock weathering crust has a favorable pore-fracture configuration, making it a high-quality reservoir zone in buried hills. In addition, local thick layers of Level II microfractures within the bedrock represent potential exploration targets. Considering the differential distribution of reservoir fractures, the optimal development plan is expected to achieve a recovery rate of 28.35% by 2030.

INVESTIGATION OF RARE AND RARE-EARTH ELEMENTS LEACHING PROCESSES FROM THE WEATHERING CRUST ORES OF THE KUNDYBAY DEPOSIT

The weathering crust ore of the Kundybay deposit is a hard-enriched ore that contains such minerals as cherchite, bastnesite, kaolinite, etc., which are embedded in the matrix structure of other silicate rocks. These minerals contain rare earth (RE) and rare earth elements (REE). The multi-component structure and dense packing of minerals in the aluminosilicate matrix of the ore make it difficult to be blocking out. Determination of the optimal ore blocking method in order to extract RE and REE is an urgent task for today. The purpose of this work is to develop an effective method of leaching RE, REE and "white soot" from the weathering crust ores of the Kundybay deposit. Methods. Processing with soluble ammonium, magnesium and aluminium salts will allow estimation of the state of RE and REE in the ore. The indicator of RE and REE blocking out during leaching with sodium hydroxide is the transfer of silica into solution, due to which RE and REE form their own hydroxides, which can be subsequently transferred into solution by acid treatment. Acid leaching with sodium pyrosulfite, hydrofluoric acid and sulfuric acid will allow the RE and REE to be immediately transferred into solution. Results and Discussion. The main characteristics of the Kundybay deposit weathering crust ore were determined, such as: silica content, moisture content, base metals, RE and REE. Conclusion. The degree of extraction of RE and REE by soluble salts of ammonium, magnesium and aluminium did not exceed 2%, which indicates the existence of RE and REE in the form of their own minerals. Leaching with sodium hydroxide showed low recovery of silica, with RE and REE remaining in a difficult-torecover form. Leaching with a mixture of sodium pyrosulfite, hydrofluoric and sulfuric acids is a promising method for RE and REE recovery due to the complex effect of the components of this mixture.

Characteristics and Genesis of Carbonate Weathering Crust Reservoirs: A Case from the Ma5Member of Ordovician in Gaoqiao Area, Ordos Basin, China.

The hydrocarbon reserves in carbonate rocks account for about half of the global hydrocarbon reserves and are an important reservoir type. The Ordovician Majiagou Formation in the central Ordos Basin is a representative weathering crust reservoir. The Caledonian movement uplifted the stratum as a whole, and subsequently, 120 million years of exposed weathering, denudation, and leaching created this unique karst paleomorphology. Dolomite reservoirs have developed dissolved pores and microfractures, which are the best reserved spaces for natural gas and good hydrocarbon migration channels. This paper takes the Ma5Member (hereinafter referred to as Ma51+2) carbonate reservoir in Gaoqiao Gas Field as the research target, based on the core, thin section, cathodoluminescence, logging data, etc., and systematically study the effect of karstification on the reservoir and the genesis of the dolomite reservoir. The results show that the depositional period of the Ordovician Majiagou strata is a regression cycle and the depositional environment is a limited evaporative tidal flat. The reservoir lithology of Ma51+2 is mainly gypsiferous dolomite and micrite dolomite. The reservoir space types consist of intergranular pores, gypsum mold pore, intragranular dissolution pores, intercrystalline pores, and microfractures. The porosity has values from 0.3 to 11.2% (mostly less than 5.0%) with an average of 3.3%, and the permeability ranges from 0.003 to 13.2 mD (mostly less than 1 mD) with an average of 0.36 mD. Karstification is divided into three periods, including syngenetic karst, eogenetic karst, and burial karst. The sedimentary microfacies determine the material basis of the reservoir, and multistage karstification finally modifies the physical properties. By deeply exploring the formation mechanism and influencing factors of the carbonate reservoir in the Ordovician Majiagou Formation, it provides an important theoretical basis and practical guidance for oil and gas exploration and development. At the same time, it also has important reference value for understanding and predicting the development law and distribution characteristics of carbonate reservoirs under similar geological background.

Pre-Jurassic weathering crust of the Kalinovoe hydrocarbon deposit, Tomsk region: composition and structure characteristics

Abstract. The study of pre-Jurassic deposits in the southwestern part of Western Siberia is highly relevant due to their potential of increasing hydrocarbon resources. These deposits are considered prospective targets for the discovery of hydrocarbon accumulations. Weathering crusts developed on the upper part of the Paleozoic rocks in the Tomsk region exhibit a complex composition and structure, reflecting the interplay of various factors, including primary sedimentary processes and later alteration processes, including fracture-controlled fluid flow and metasomatism. Aim. To establish the characteristics of the mineralogical composition and structure of the Paleozoic weathering crust formations developed at the Kalinovoe oil-gas-condensate field. Methods. Optical microscopy, X-ray diffraction, scanning electron microscopy. Results and conclusions. The composition and structure of the deposits at the boundary zone between the Paleozoic and Mesozoic successions have been studied in detail in the section of one of the wells at the Kalinovoe oil-gas-condensate field. The factual material is represented by core and thin sections of weathering crust deposits. The primary rock-forming minerals are silica minerals (quartz, chalcedony and opal) and clay minerals, with a lesser amount of carbonate minerals (siderite). Different lithological units were identified based on the content of minerals and bioclast (radiolarians and sponge spicules), indicating their formation under marine conditions. The protoliths of the altered rocks were carbonate-siliceous rocks, argillaceous limestones, and radiolarian cherts, which as a result of multiple stages of hydrothermal alteration and metasomatic processes were transformed into argillaceous-silicified rocks. In these rocks, with intense post-alteration overprinting, good reservoir quality porosity can develop. This porosity includes biogenic voids, microcavities, micropores, and open fractures.

Study on seismic characterization and distribution characteristics of effective reservoirs of granite weathering crust in Dongying Sag, Bohai Bay Basin

To solve the problem of low resolution of seismic data from granite weathering crust and difficulty in predicting effective reservoir distribution. Based on the research idea of combining geology and seismology, seismic facies characteristics and effective reservoir distribution of granite weathering crust are studied by means of frequency division reconstruction processing, seismic facies analysis and sensitive attributes interpretation. This method consists of the following four main processes: (1) Using improved Morlet wavelet function for frequency division and reconstruction processing of seismic data; (2) From the perspective of geological evolution, analyzing the geological origin of seismic facies; (3) Based on the results of well- seismic combination, clarifying the types of effective reservoirs and predicting their distribution; (4) Comprehensive research indicating favorable reservoirs distribution. The results indicate that (1) a considerably improved resolution of seismic data processed by frequency division reconstruction is obtained based on the improved Morlet wavelet function. Thus, granite reservoirs then have clearer internal reflection characteristics. (2) Affected by differences in weathering, the seismic facies in granite weathering crusts can be classified as follows: Strong-amplitude facies with amplitudes of 23,700 − 32,800, corresponding to eluvium, represents the late stage of weathering crust evolution with high-intensity weathering. Medium-amplitude facies with amplitudes of 5,250 − 24,000, corresponding to dissolution layer, represents a middle stage of weathering crust evolution with moderate weathering. And weak-amplitude-blank facies with amplitudes of 0–5,330, corresponding to disintegration layer, represents an early stage of weathering crust evolution with weak weathering. (3) Effective reservoirs can be classified according to well-seismic calibrations and combined with reservoir spaces, porosities and permeabilities, and the logging and oil-bearing characteristics of the reservoirs. Type I effective reservoir comprises medium-amplitude facies, with favorable reservoir conditions and high-yield oil-bearing properties; this type is distributed in the western slopes, with an elevation of 1,300-2,500 m. Type II effective reservoir comprises strong-amplitude facies, with poor oil-bearing properties; this type is mainly distributed in the southeast and north slopes of the study area, with a relatively limited range, and the elevation is mostly below 1,500 m. Type III effective reservoir comprises weak-amplitude-blank facies, with poor reservoir conditions and poor oil-bearing properties; this type is widely distributed at various elevations. (4) The areas where medium-amplitude facies have developed are the most favorable reservoir exploration zones for granite in Dongying Sag, Bohai Bay Basin.

Characteristics and Genetic Mechanism of Granite Weathering Crust of Songnan Low Uplift, Qiongdongnan Basin, South China Sea

Characteristics and Genetic Mechanism of Granite Weathering Crust of Songnan Low Uplift, Qiongdongnan Basin, South China Sea

Recovery of Rare Earth Elements from Ion-Adsorption Deposits Using Electrokinetic Technology: The Soil Conductivity Mechanism Study

Rare earth elements (REEs) are essential raw materials for modern industries but mining them has caused severe environmental issues, particularly the recovery of heavy REEs (HREEs) from ion-adsorption deposits (IADs). Very recently, an emerging technology, electrokinetic mining (EKM), has been proposed for the green and efficient recovery of REEs from IADs. However, the conduction mechanism of the weathering crust soil, which is also a prerequisite for EKM, remains unclear, making the EKM process unpredictable. Here, we systematically investigated the conductivity of weathering crust soil in the presence of light REEs (LREEs, i.e., La3+ and Sm3+) and HREEs (Er3+ and Y3+), respectively. Results suggested that the voltage was dynamically and spatially redistributed by the movement of REEs and water during EKM, and the conventional assumption of the linear distribution of voltage leads to an inaccurate description of soil voltage. We proposed an improved Archie’s equation by coupling the mechanisms of liquid phase and solid-liquid interface conduction, which can predict soil conductivity more precisely. Moreover, the extended Archie’s equation is able to recalculate the voltage distribution at distinct times and spaces well during EKM. More importantly, the water content in field-scale weathered-crust soils can be retrieved by the newly proposed Archie’s equation, which helps optimize the leaching wells and improve the recovery rate of REE. This study focuses on the conduction mechanism of weathering crust soil, which provides a theoretical basis for better use of the EKM technology and promotes mining efficiency fundamentally.

Transport dynamics of rare earth elements in weathering crust soils

In modern industries, rare earth elements (REEs) are considered as essential metals and invaluable natural resources. Ion-adsorption deposits (IADs) are repositories of REE in the weathering crust soils, in which REEs are adsorbed on clay minerals. In the last few decades, the mining of REEs from IADs has caused substantial environmental damage owing to the overuse of leaching agents for the desorption and transport of REEs in weathering crust soils. These environmental issues have sparked extensive research interest in modeling REE transport dynamics in weathering crust soils. Nevertheless, because current models treat REE adsorption and transport independently, they do not accurately describe REE transport dynamics. Therefore, in this study, a unified workflow that synergizes adsorption and transport dynamics is proposed to predict REE transport. The adsorption of REEs on IADs was found to follow the Freundlich isotherm with the coefficient of determination exceeding 0.9826. The adsorption capacities of La3+, Sm3+, Er3+, and Y3+ reach 1.3127, 1.4423, 1.5793, and 1.1061 mg g−1 at 300 ppm, respectively. For the breakthrough curve, an advection–dispersion–adsorption–equation (ADAE) model was developed and utilized to accurately and reliably predict REE transport dynamics in soil columns. It was found the saturation time of REEs in soils is 39.22, 44.15, 50.64, and 32.17 h, respectively at 2 mL min−1 and decreased with the increase of flow velocity. The upper and lower limits of REE transport are ADAE-Freundlich and ADAE-Toth. More importantly, the model was applied to simulate REEs transport in field-scale weathering crusts over 100 years and predict REE accumulation in the highly weathered layered, which is found in natural weathering crusts. The qualitative prediction of REE transport dynamics in weathering crusts may help fundamentally lower the usage of leaching agents and mitigate concomitant the environmental impacts of mining.

Enrichment and fractionation of rare earth elements (REEs) in ion-adsorption-type REE deposits: Constraints of an iron (hydr)oxide–clay mineral composite

Abstract Ion-adsorption-type rare earth element (REE) deposits are the source of more than 90% of global heavy REEs (HREEs). Thus, understanding the ore genesis of REEs, particularly the distribution characteristics and enrichment mechanisms of HREEs, is vital for efficient exploration and mining of ion-adsorption-type REE deposits worldwide. The characteristics and petrogenesis of bedrock, and the aqueous mobility of REEs, are known to be important factors controlling REE accumulation and fractionation in the weathering crust of REE deposits. However, the effect of REE adsorption on secondary minerals, which is a crucial step in deposit formation, remains poorly understood. This problem was addressed by the study described herein, which involved a systematic analysis of the complete weathering profile (78 m) of the Renju ion-adsorption-type REE deposit in South China and a simulated adsorption experiment. Clay minerals and iron (Fe) (hydr)oxides are the dominant REE adsorbents in the weathering crust and most are micro-to-nanosized particles. Thus, the fine particle fraction (< 2 μm) was separated from field samples, to better disclose their effects on the concentration and redistribution of REEs. Phase compositions and morphologies were characterized by X-ray diffraction, Mössbauer spectrometry, and scanning/transmission electron microscopy (SEM/TEM), which revealed that various clay minerals and Fe (hydr)oxides form composites along the profile of the deposit. Composites of ferrihydrite–kaolinite, goethite–kaolinite/halloysite, and hematite–kaolinite/halloysite were found to be distributed in the semi-weathered, completely weathered, and topsoil layers, respectively, with different sizes and shapes. The concentrations and partition patterns of REEs in different occurrence states were distinguished after sequential extraction. Ion-exchangeable-REEs were the major state and enriched in the upper completely weathered layer. These species were found to be adsorbed onto kaolinite and halloysite via electrostatic attraction, without obvious fractionation. Fe (hydr)oxides were determined to comprise ca. 20% of REEs at most depths and over 50% of REEs in the topsoil and semi-weathered layer. It was found that Fe (hydr)oxides scavenge REEs through complexation and oxidation, resulting in HREE enrichment and a positive cerium (Ce) anomaly, respectively. In addition, compared with crystalline Fe (hydr)oxides, amorphous Fe (hydr)oxides immobilize more REEs but exhibit weaker preferential adsorption of HREEs. The above-described findings are consistent with the results of simulated experiments for REE adsorption onto a clay mineral–Fe (hydr)oxide composite (Bt-60), which was obtained from hydrothermal processing of biotite. Furthermore, the distributions and stabilities of LREEs and HREEs were distinguished by TEM–energy–dispersive spectroscopy (EDS) of Bt-60 before and after REE extraction by ammonium sulfate. The phase transformation pathways of clay minerals and Fe (hydr)oxides, and their different enrichment and fractionation characteristics in REEs, were also discussed in terms of the structure and surface properties of minerals, adsorption mechanisms, and variations in chemical properties across the REE group. The results shed new light on how clay minerals and Fe (hydr)oxides affect the enrichment and fractionation of REEs in ion-adsorption-type deposits.

The distinctive weathering crust habitat of a High Arctic glacier comprises discrete microbial micro-habitats.

Sunlight penetrates the ice surfaces of glaciers and ice sheets, forming a water-bearing porous ice matrix known as the weathering crust. This crust is home to a significant microbial community. Despite the potential implications of microbial processes in the weathering crust for glacial melting, biogeochemical cycles, and downstream ecosystems, there have been few explorations of its microbial communities. In our study, we used 16S rRNA gene sequencing and shotgun metagenomics of a Svalbard glacier surface catchment to characterise the microbial communities within the weathering crust, their origins and destinies, and the functional potential of the weathering crust metagenome. Our findings reveal that the bacterial community in the weathering crust is distinct from those in upstream and downstream habitats. However, it comprises two separate micro-habitats, each with different taxa and functional categories. The interstitial porewater is dominated by Polaromonas, influenced by the transfer of snowmelt, and exported via meltwater channels. In contrast, the ice matrix is dominated by Hymenobacter, and its metagenome exhibits a diverse range of functional adaptations. Given that the global weathering crust area and the subsequent release of microbes from it are strongly responsive to climate projections for the rest of the century, our results underscore the pressing need to integrate the microbiome of the weathering crust with other communities and processes in glacial ecosystems.

Typomorphism of native gold as a criterion for typization of gold mineralization in weathering crusts of the Eravninsky ore district (Republic of Buryatia)

The features of native gold from weathering crust are considered. It is demonstrated how the features obtained in combination with studying the weathering crust composition make it possible to identify the type of the primary gold mineralization and to facilitate effective interpretation of the prospecting results.

Optimization of a Rare Earth and Aluminum Leaching Process from Weathered Crust Elution-Deposited Rare Earth Ore with Surfactant CTAB

Ammonium sulfate is typically employed as a leaching agent in the in situ leaching of weathered crust elution-deposited rare earth ore. However, it is associated with challenges such as low efficiency in mass transfer for rare earth (RE) leaching, high usage of the leaching agent, and prolonged leaching duration. To address the issues mentioned above, the surfactant cetyltrimethyl ammonium bromide (CTAB) was compounded with 2% ammonium sulfate to form a leaching agent in this paper. The effects of CTAB concentration, temperature, pH, and leaching agent flow rate on the rare earth (RE) and aluminum (Al) leaching mass transfer process from RE ore were investigated using chromatographic plate theory. The results revealed that CTAB addition improved the RE mass transfer process while moderately inhibiting the Al mass transfer efficiency. Increasing the temperature and pH of the leaching solution led to higher theoretical plate numbers for RE and Al leaching, lowered theoretical plate height (HETP), and enhanced leaching mass transfer efficiency. However, under high temperature and alkaline conditions, the mass transfer efficiency begins to decrease, indicating that high temperature and alkaline conditions are not conducive to the synergistic enhancement of RE and Al leaching by CTAB. Considering that clay minerals have good pH buffering properties, adjusting the pH of the leaching solution during rare earth ore leaching operations was deemed unnecessary. The optimal mass transfer conditions for leaching RE and Al were identified as 2% ammonium sulfate concentration, 0.00103 mol/L CTAB concentration, pH range of 5.2–5.5 for the leaching solution, 0.6 mL/min leaching solution flow rate, and room temperature. The rare earth leaching mass transfer effect could be enhanced during summer operations.

Characteristics of Weathering Reservoirs and Differences in Fracture Formation in the Weathering Crust of the Pre-Cenozoic Basement of Lishui Sag, East China Sea Basin, China

Characteristics of Weathering Reservoirs and Differences in Fracture Formation in the Weathering Crust of the Pre-Cenozoic Basement of Lishui Sag, East China Sea Basin, China

Detection of subsurface cavities in the structurally bounded Labe prefecture area, Republic of Guinea using two-dimensional electrical resistivity tomography (ERT)

ABSTRACT This study is conducted within the Gambia River Basin Development Organization Energy Project (OMVG) framework. The construction of a high voltage interconnection network fed by a hydropower station to supply electricity to OMVG Member States was done on stable ground. During the installation pits for the pylons in Labé Prefecture, Republic of Guinea, cavities were discovered in the geological formations during the initial planned route. Structurally, the study area is bounded by two major faults to the east and west of northeast direction. The geomorphology is made up of a central plateau, intermountain depressions, piedmont plains, talwegs, and glacis. Geological investigations were obtained by a geophysical Two-dimensional Electrical Resistivity Tomography (ERT) method. The results show that the synthetic lithological profile from top to base was sandy-clayey soil, hard cuirass, and a layer of gravel followed by a mottled zone comprising an indurated part and an imbibed part just before the source rock. The cavities were observed probably because of the dissolution of certain minerals constituting the weathering crust due to the infiltration, underground waters, and the seasonal variation in the level of the surface watercourses. Geophysical results showed a very good agreement with the visual observations.

Ilmenite Content of Different Genesis of Productive Sediments of the Trostyanytsky Deposit

The article presents information on the geological structure and ore content of the Trostyanytsky ilmenite deposit located in the northern part of the Volodarsk-Volynskyi massif of the Korostensky pluton bedrock. The deposit is localized in the weathering crust of the basement crystalline rocks and continental deluvial-alluvial and alluvial sediments of the Middle Jurassic-Lower Cretaceous, which were formed by erosion and redeposition of eluvium. Weathering crust together with deluvial-alluvial and alluvial sediments formed the productive deposits of the Trostyanytsky deposit. On the basis of the created target database containing conditional coordinates of wells, their description and testing results, mapping constructions (isohypses of the roof, sole, isopachites of the thickness of the weathering crust of crystalline rocks of the basement, alluvial sands and redeposited kaolins of the Middle Jurassic-Lower Cretaceous) were carried out; lateral distribution of the average ilmenite content in the weathering crust, in the Middle Jurassic-Lower Cretaceous fluvial deposits and in productive sediments, distribution of ilmenite content in the vertical section of wells). These mapping constructions were created based on the results of preliminary (1999) and detailed (2008) geological exploration. The direction and strength of correlations between the topography of the sole and the surface, topography of the sole and the thickness of ilmenite-bearing formations, sole relief and ilmenite content, sediment thickness and ilmenite content in the weathering crust, alluvial deposits of the Middle Jurassic-Lower Cretaceous and in productive deposits. The obtained results made it possible to clarify the structural and material parameters of the ore-bearing rocks, the lateral and vertical distribution of ore bearing in different genetic and different age's formations.

Ultrahigh-Pressure Orange Garnets from the Sedimentary Deposits of the Upper Bug Area (Ukrainian Shield)

The article is dedicated to the investigation of orange garnets from Miocene-Pliocene deposits of the Balta suite and the Sarmatian stage in the Vinnytsia area. The Vinnytsia area is located on the southwestern slope of the Ukrainian Shield. The crystalline basement on most of the area is represented by granitoids of the Berdychiv complex of Paleoproterozoic age, and to a lesser extent by enderbites and charnockites of the Lityn complex of Neoarchean age. Among these, there are mafic and ultramafic bodies ranging from 0.5 to 2 meters in thickness. The sedimentary cover with a total thickness of up to 20 m is represented by sands and clays of the middle Sarmatian, Balta and Quaternary sediments. These deposits are enriched with mantle minerals, predominantly pyrope, and four diamond crystals have also been discovered. We studied the chemical composition (253 crystals) and morphology (278 crystals) of the orange garnets. The studied samples are mostly represented by garnets of pyrope and pyrope-almandine composition, a small part is represented by grossulars. Most of the garnets are unrounded crystal fragments ranging in size from 0.2 to 0.6 mm, exhibiting signs of intense hypergene changes. These are evident in the development of positive (block) and negative relief features, appearing as drop-shaped, cone-shaped, small hilly microrelief and various forms of etching channels. The morphological features suggest that these garnets were probably relocated a short distance from their primary sources and had been present in the weathering crust for an extended period. The original sources of garnets are most likely Precambrian and located on active tectonic zones, which led to their destruction. According to chemical composition data, among orange garnets low-chromium websterite and low-calcium eclogite varieties, as well as garnets of high-iron mantle pyroxenites are dominated. The presence of titanium impurities in many garnets indicates the possible diamond-bearing nature of some primary sources.

НОВЫЕ ДАННЫЕ О МИНЕРАЛОГИИ, ГЕОХИМИИ И ГЕНЕТИЧЕСКИХ ОСОБЕННОСТЯХ БЕЛОГОРСКОГО МАГНЕТИТОВОГО МЕСТОРОЖДЕНИЯ (СИХОТЭ-АЛИНЬ)

New data are in favor of the view previously substantiated by geological, geochemical and isotopic data that orebodies of the Belogorskoe deposit are metamorphosed and partially regenerated in the Late Cretaceous-Paleogene products of erosion (in the Triassic) of laterite weathering crust of gabbroids. The source for the formation of the Belogorskoe deposit was shown to be products of exogenous destruction of rocks, which by their isotopic and geochemical characteristics are close to the Cambrian gabbroids of the Vladimiro-Alexandrovsky massif (the southern part of the Okrainsko-Sergeevsky terrane). It has been found that the Belogorskoe deposit is composed of rocks and ores, the primary (magmatic) distribution of REE in which was changed to varying degrees as a result of interaction between sediments (protoliths) and seawater (presumably during the Late Jurassic-Early Cretaceous accretion), as well as their metamorphosed analogues and hydrothermal solutions (in the Late Cretaceous-Paleogene). The influence of gabbroids (as a source of matter) on the chemical and mineral composition of the Belogorskoe deposit is consistent with the data reported in the article concerning the enrichment of orebodies in such elements as Fe and Mn that are characteristic of ultrabasic rocks and the presence of Au-Ag-Pd-Pt, Ni-Co and Bi mineralization in them. The orebodies of the Belogorskoe deposit contain accessory minerals and mineral varieties that are rarity in nature and little-studied. These include an unusually rich Th variety of zircon, baddeleyite, gudmundite, a large group of bismuth compounds, including Bi2Te, (Ag,Pb)BiS2, as well as coloradoite, lafossaite, sanbornite, perovskite, and the compound InPO4. There is also a large group of rare and unusual compounds of noble metals: copper gold, platinum gold, jonassonite, disordered solid solutions of Cu, Ag and Au (Au-based), Pt-Pd, Pt-Ag intermetallics, and other rare minerals and mineral varieties.

LATERAL AND VERTICAL DISTRIBUTION OF TITANIUM-ZIRCONIUM MINERALS WITHIN OF THE ANDRIIVSKYI AND LIKARIVSKYI DEPOSITS (SOUTH-WESTERN PART OF THE NOVOMYRHOROD MASSIF)

General information on the geological structure and ore-bearing capacity of the Likarivske and Andriivske deposits, which are located in the southwestern part of the Korsun-Novomyrhorod pluton within the Novomyrhorod massif (South-Western part), is provided. The productive deposits of the Likarivske and Andriivske deposits are represented by the weathering crust formation and the continental alluvial sand-kaolin formation of the Lower Cretaceous (Aptian-Lower Albian). On the basis of the coordinates, description and results of testing wells, a target database was created. On the basis of this database, cartographic constructions were carried out. The structural (relief of the bottom and of the top surfaces of ore-bearing deposits and their thickness) and material (lithological composition of productive deposits; lateral distribution of the average content of ilmenite, zircon, rutile and apatite in productive deposits) parameters of different ages and different genetic formations of the Likarivske and Andriivske deposits were studied. The direction and strength of correlations between ilmenite, rutile, zircon, and apatite in the weathered crust and continental sediments (sands and redeposited kaolins) of the Lower Cretaceous were studied. It was established that within the limits of the Likarivske and Andriivske deposits, during the geological development of the territory, a zircon-apatite-ilmenite ore-bearing system of different time and different genetics was formed, which is represented by a spatial-paragenetic series: crystalline rocks of the foundation; weathering crusts of crystalline rocks of the foundation; fluvial formations formed due to erosion and redeposition of eluvium; fluvial formations that were formed due to erosion and redeposition of eluvium and Mesozoic-Cenozoic placers of different ages. The results of the research are an information base for supporting mining operations within the studied deposits.