Strongly Dependent Research Articles

Аппроксимация экспериментальных коэффициентов гидродинамических сил крыльевого гидродинамического якоря

The article considers a full-scale comparative experiment conducted in 2020 in the water area of the Novosibirsk reservoir on the simultaneous drift of six marine life rafts with a capacity of 6 people each. Each raft was equipped with one of the developed hydrodynamic anchors (HDA); one raft had a standard parachute floating anchor; one raft had no means of preventing drift. The wing hydrodynamic armature showed good results in reducing the drift velocity. To develop design methods of this kind, hydrodynamic forces were determined in the direct experimental basin of the Siberian State University of Water Transport (SSUWT) by towing with different speeds and angles of attack. According to the tests conducted in the direct experimental pool of the police Department, HDA the coefficients of hydrodynamic forces were obtained. It is noted that the HDA is made in full size, which does not require recalculation according to similarity criteria; the values of the coefficients show an unstable dependence on the towing speed, which is explained by the influence of errors of the experimental method and required averaging of the results. To substantiate the possibility of using the averaging method, the results of numerical modeling of the work of HDA carried out in the Ansys Fluent program are used, which revealed a very weak dependence of the coefficients on the flow rate. On this basis, a decision was made on the possibility of averaging coefficients related to flow velocities v ≥ 0.2 m/s, at which the spread of coefficient values is relatively small. The averaged values of the coefficients obtained in the physical experiment are approximated in their ranges of angles of attack by quadratic polynomials to smooth out the results and facilitate their use in mathematical models of the device operation.

The electron density at the midpoint of the plasmapause

The high density plasmasphere in the magnetosphere is often separated from a lower density region outside of the plasmasphere, called the plasmatrough, by a sharp gradient in electron density called the plasmapause. Here we use plasmapause events identified from electron density data from the ISEE, CRRES, Polar, and IMAGE missions, and the nonlinear genetic algorithm TuringBot, to find models for the electron density at the midpoint of the plasmapause, ne,pp. A good model for ne,pp should include dependence on L, which is the strongest dependence. But models can be improved by including weaker dependencies on the magnetic local time, MLT, the solar EUV index F10.7, and geomagnetic activity as indicated by averages of Kp and AE. The most complicated model that we present predicts ne,pp within a factor of 1.64, and is within the range of observed plasmapause densities for about 96% of our events. These models can be useful for separating plasma populations into plasmasphere-like and plasmatrough-like populations. We also make available our database of electron density measurements categorized into various populations.

Production of sub-micron-sized high-entropy alloy particles and nanoparticles via pulsed laser ablation of CrMnFeCoNi targets in water

High-entropy alloys (HEAs) are a class of materials known for their unique properties, including high strength, excellent wear resistance, and good corrosion resistance. Sub-micron- and nanosized HEA particles were fabricated via pulsed laser ablation in liquid using a Cantor alloy target. The Cr20Mn20Fe20Co20Ni20 target was immersed in pure water and ablated using a focused nanosecond-pulsed Nd: YAG laser. A dark solution containing HEA particles was obtained which was stable for about one week before agglomeration and precipitation was observed. The diameters of the obtained particles ranged from several tens of nanometers to several hundred nanometers. Increasing the laser power resulted in higher particle concentration and an increase in the intensity of UV-vis absorption spectra. Electron diffraction was used to confirm that the composition of the particles was close to that of the Cantor alloy, although the concentrations of Cr and Mn were slightly deficient. There was also a weak dependence of the composition on laser power, and all the particles also contained oxygen. Selected area electron diffraction revealed that the composition varied spatially within some particles and that they are mainly polycrystalline. This work shows that HEA particles can be quickly, safely, and effectively manufactured using liquid-based laser ablation, opening the pathway for mass manufacture and disruptive applications in, e.g., catalysis or tribology.

Investigation of cyclopentene + OH and cyclopentene thermal decomposition reactions

This study presents the first high-temperature measurements of cyclopentene+OH→k1Products reaction over 856 – 1258 K and 1.03 – 4.33 bar. The determined rate coefficients of k1 exhibited Arrhenius temperature dependence with an activation energy ∼ 3.3 kcal mol−1 and negligible pressure dependence. Rate coefficients of OH + cyclopentene are faster than OH + 1-pentene but comparable to OH + 2-pentene, highlighting the significance of allylic CH bonds in these reactions. At 1258 K, our rate coefficient is ∼ 30 % slower than the average room-temperature measurement, indicating the role of OH-addition pathways at low temperatures. Site-specific rate coefficients and branching ratios are determined, with H-abstraction at the allylic CH site accounting for ∼68 % of the reaction and alkylic CH bond contributing ∼22 %. Our measured k1 may be given as (unit: cm3molecule−1s−1):k1=1.64×10−10e(−1660T)Cyclopentene decomposition reaction (cyclopentene→k2cyclopentadiene+H2) is studied over 1186–1472 K and 1.17 – 1.38 bar. Time-resolved yields of the product, cyclopentadiene, are monitored using a sensitive UV laser diagnostic near 220 nm. Absorption cross-sections of cyclopentadiene, measured in two separate mixtures, showed weak positive temperature dependence (8.7 – 9.8 × 10−18 cm2molecule−1) over 961 – 1326 K. Our rate coefficients of k2 exhibited a positive Arrhenius temperature dependence with an activation energy of ∼ 54.7 kcal mol−1. At 1300 K, the decomposition of cyclopentene proceeds 5.5 and 28 times faster than that of cyclopentadiene and cyclopentane, respectively. Our measured k2 may be expressed as (unit: s−1):k2=2.55×1012e(−27,527.6T)The pentagonal structure of cyclopentene influences its H-abstraction and decomposition reactions distinctively. While H-abstraction by OH follows a mechanism akin to cyclohexene and linear alkenes, with comparable rate coefficients at allylic CH bonds, the penta-ring structure significantly impacts the decomposition mechanism. Cyclopentene decomposition predominantly produces cyclopentadiene and H2 in a ring-conserving manner, differing from the cleavage of allylic-alkylic CC bonds in the decompositions of 1-alkenes and cyclohexene.

Deviation inequalities for dependent sequences with applications to strong approximations

In this paper, we give precise rates of convergence in the strong invariance principle for stationary sequences of bounded real-valued random variables satisfying weak dependence conditions. One of the main ingredients is a new Fuk-Nagaev type inequality for a class of weakly dependent sequences. We describe also several classes of processes to which our results apply.

Analysis of a detailed multi-stage model of stochastic gene expression using queueing theory and model reduction

We introduce a biologically detailed, stochastic model of gene expression describing the multiple rate-limiting steps of transcription, nuclear pre-mRNA processing, nuclear mRNA export, cytoplasmic mRNA degradation and translation of mRNA into protein. The processes in sub-cellular compartments are described by an arbitrary number of processing stages, thus accounting for a significantly finer molecular description of gene expression than conventional models such as the telegraph, two-stage and three-stage models of gene expression. We use two distinct tools, queueing theory and model reduction using the slow-scale linear-noise approximation, to derive exact or approximate analytic expressions for the moments or distributions of nuclear mRNA, cytoplasmic mRNA and protein fluctuations, as well as lower bounds for their Fano factors in steady-state conditions. We use these to study the phase diagram of the stochastic model; in particular we derive parametric conditions determining three types of transitions in the properties of mRNA fluctuations: from sub-Poissonian to super-Poissonian noise, from high noise in the nucleus to high noise in the cytoplasm, and from a monotonic increase to a monotonic decrease of the Fano factor with the number of processing stages. In contrast, protein fluctuations are always super-Poissonian and show weak dependence on the number of mRNA processing stages. Our results delineate the region of parameter space where conventional models give qualitatively incorrect results and provide insight into how the number of processing stages, e.g. the number of rate-limiting steps in initiation, splicing and mRNA degradation, shape stochastic gene expression by modulation of molecular memory.

The impact of left-behind experience on urban identity of new-generation migrant workers.

We investigate the impact of left-behind experiences on the urban identity of new-generation migrant workers using data from the 2017 China Migrants Dynamic Survey. The results show the following: (1) The left-behind experience is an important factor undermining the urban identity of new-generation migrant workers, and the conclusion remains consistent after robustness checks, such as propensity score matching. (2) Left-behind experiences of both parents away from home had the most significant negative impact on urban identity. (3) The results of the mechanism tests indicate that the left-behind experience exerts an adverse impact on urban identity through the pathways of poorer physical health, more frequent migration, more challenging job search, and stronger dependence on preexisting social networks. The findings of this study also offer policy suggestions for promoting the urban identity of new-generation migrant workers.

A novel eco-friendly and economical approach of bamboo colorization through biomimetic polymerization of dopamine melanin inspired by photonic microstructure of bird plumage

Bamboo is a low-carbon, sustainable, and versatile substitute for many synthetic materials, but limited variety of color restricts bamboo's decoration performance and added value. Traditional chemical colorization suffers poor generality, massive resource consumption, low colorfastness, high pollution, and remarkable damage to bamboo. This research pioneered an eco-friendly, economical approach to tailor bamboo color while keeping natural texture. Through a facile, mild modification by dopamine (a tyrosine derivative), its biomimetic polymerization endowed bamboo surface with a double-layered polydopamine melanin system mimicking morphology and composition of (keratin layer)/(melanin granules) microstructure of colorful bird plumage. Chromatic-optical and microstructural characterizations showed that polydopamine system's upper layer was nanoscale ∼ submicronscale (thickness 55∼215 nm) film bestowing on bamboo structural colors through thin-film interference. All colors at visible wavelength could be formed through controlling film thickness by adjusting dopamine concentration. Thicker film was more continuous and smoother, while thinner film was stabler. Polydopamine system's lower layer was micronscale (thickness 1.2∼4.4 μm) aggregate of particles enhancing color saturation through suppressing light scattering. Amorphous arrangement of polydopamine system made structural colors on bamboo display weak angle dependence. Physicochemical characterizations proved that bamboo featured non-covalent interaction with deposited polydopamine, which never destroyed bamboo's crystalline structure. Structural colors on bamboo exhibited satisfactory stability in long-term exposure and mechanical washing tests. Overall, proposed colorization was confirmed eco-friendly, convenient, and effective, thus contributing novel ideas to cleaner production in bamboo utilization.

Topological semimetal interface resistivity scaling for vertical interconnect applications

In this work, we explore the electron scattering characteristics at interfaces between normal metals and topological semimetals in bulk as well as in thin film structures. We consider Cu/Ta and CoSi/Ta as representative metal/metal and topological semimetal/metal interface structures, respectively. For bulk interface structures, we find that metal/topological semimetal interfaces have roughly 20× higher interfacial resistivity than normal metal/metal interfaces primarily due to the low electronic density of states, the Fermi level in bulk topological semimetals. For thin films, we find that normal metal/metal interfacial resistivity shows a weak dependence on film thickness and is generally close to the corresponding bulk value. Interfaces between surface-conduction dominated topological semimetals, such as CoSi and normal metals in thin films, however, show decreasing interfacial resistivity with decreasing film thickness. This apparent reduction in interface resistivity originates from the surface-dominated transport, where the total transmission across the interface varies little with reduced film thickness, yielding an effective increase in interface conductivity at smaller dimensions. These results suggest that topological semimetals may be attractive candidates for next-generation interconnect materials with critically small dimensions where interfaces with other metals are ubiquitous.

Study on Water Splitting of the 214-Type Perovskite Oxides LnSrCoO4 (Ln = La, Pr, Sm, Eu, and Ga).

We present a study on the electrocatalysis of 214-type perovskite oxides LnSrCoO4 (Ln = La, Pr, Sm, Eu, and Ga) with semiconducting-like behavior synthesized using the sol-gel method. Among these five catalysts, PrSrCoO4 exhibits the optimal electrochemical performance in both the oxygen evolution reaction and the hydrogen evolution reaction, mainly due to its larger electrical conductivity, mass activity, and turnover frequency. Importantly, the weak dependency of LSV curves in a KOH solution with different pH values, revealing the adsorbate evolving mechanism in PrSrCoO4, and the density functional theory (DFT) calculations indicate that PrSrCoO4 has a smaller Gibbs free energy and a higher density of states near the Fermi level, which accelerates the electrochemical water splitting. The mutual substitution of different rare-earth elements will change the unit-cell parameters, regulate the electronic states of catalytic active site Co ions, and further affect their catalytic performance. Furthermore, the magnetic results indicate strong spin-orbit coupling in the electroactive sites of Co ions in SmSrCoO4 and EuSrCoO4, whereas the magnetic moments of Co ions in the other three catalysts mainly arise from the spin itself. Our experimental results expand the electrochemical applications of 214-type perovskite oxides and provide a good platform for a deeper understanding of their catalytic mechanisms.

Electrical Resistivity and Phase Evolution of Fe–N Binary System at High Pressure and High Temperature

Partitioning experiments and the chemistry of iron meteorites indicate that the light element nitrogen could be sequestered into the metallic core of rocky planets during core–mantle differentiation. The thermal conductivity and the mineralogy of the Fe–N system under core conditions could therefore influence the planetary cooling, core crystallization, and evolution of the intrinsic magnetic field of rocky planets. Limited experiments have been conducted to study the thermal properties and phase relations of Fe–N components under planetary core conditions, such as those found in the Moon, Mercury, and Ganymede. In this study, we report results from high-pressure experiments involving electrical resistivity measurements of Fe–N phases at a pressure of 5 GPa and temperatures up to 1400 K. Four Fe–N compositions, including Fe–10%N, Fe–6.4%N, Fe–2%N, and Fe–1%N (by weight percent), were prepared and subjected to recovery experiments at 5 GPa and 1273 K. These experiments show that Fe–10%N and Fe–6.4%N form a single hexagonal close-packed phase (ɛ-nitrides), while Fe–2%N and Fe–1%N exhibit a face-centered cubic structure (γ-Fe). In separate experiments, the resistivity data were collected during the cooling after compressing the starting materials to 5 GPa and heating to ~1400 K. The resistivity of all compositions, similar to the pure γ-Fe, exhibits weak temperature dependence. We found that N has a strong effect on the resistivity of metallic Fe under rocky planetary core conditions compared to other potential light elements such as Si. The temperature-dependence of the resistivity also revealed high-pressure phase transition points in the Fe–N system. A congruent reaction, ε ⇌ γ’, occurs at ~673 K in Fe–6.4%N, which is ~280 K lower than that at ambient pressure. Furthermore, the resistivity data provided constraints on the high-pressure phase boundary of the polymorphic transition, γ ⇌ α, and an eutectoid equilibrium of γ’ ⇌ α + ε. The data, along with the recently reported phase equilibrium experiments at high pressures, enable construction of a phase diagram of the Fe–N binary system at 5 GPa.

Asymptotic normality of spectral means of Hilbert space valued random processes

A variety of statistics for functional time series allows for a representation as weighted average of corresponding periodogram operators over the frequency domain. We study consistency and asymptotic normality of such spectral mean estimators under mild assumptions. We show that weak convergence of these estimators can be deduced from the (joint) weak convergence of the sample autocovariance operators. The latter is established for a large class of weakly dependent functional time series, which admit expansions as Bernoulli shifts and the weak dependence is quantified by the condition of L4-m-approximability.

Probing Turbulent Scattering Effects on Suprathermal Electrons in the Solar Wind: Modeling, Observations, and Implications

This study explores the impact of a turbulent scattering mechanism, akin to those influencing solar and galactic cosmic rays propagating in the interplanetary medium, on the population of suprathermal electrons in the solar wind. We employ a Fokker–Planck equation to model the radial evolution of electron pitch angle distributions under the action of magnetic focusing, which moves the electrons away from isotropy, and of a diffusion process that tends to bring them back to it. We compare the steady-state solutions of this Fokker–Planck equation with data obtained from the Solar Orbiter and Parker Solar Probe missions and find a remarkable agreement, varying the turbulent mean free path as the sole free parameter in our model. The obtained mean free paths are of the order of the astronomical unit, and display weak dependence on electron energy within the 100 eV–1 keV range. This value is notably lower than Coulomb collision estimates but aligns well with observed mean free paths of low-rigidity solar energetic particle events. The strong agreement between our model and observations leads us to conclude that the hypothesis of turbulent scattering at work on electrons at all heliospheric distances is justified. We discuss several implications, notably the existence of a low Knudsen number region at large distances from the Sun, which offers a natural explanation for the presence of an isotropic “halo” component at all distances from the Sun—electrons being isotropized in this distant region before traveling back into the inner part of the interplanetary medium.

Sparse-penalized deep neural networks estimator under weak dependence

Sparse-penalized deep neural networks estimator under weak dependence

How Long Will the Quasar UV/Optical Flickering Be Damped?

The UV/optical light curves of Active Galactic Nuclei (AGNs) are commonly described by the Damped Random Walk (DRW) model. However, the physical interpretation of the damping timescale, a key parameter in the DRW model, remains unclear. Particularly, recent observations indicate a weak dependence of the damping timescale upon both wavelength and accretion rate, clearly being inconsistent with the accretion-disk theory. In this study, we investigate the damping timescale in the framework of the Corona Heated Accretion disk Reprocessing (CHAR) model, a physical model that describes AGN variability. We find that while the CHAR model can reproduce the observed power spectral densities of the 20 yr light curves for 190 sources from Stone et al., the observed damping timescale, as well as its weak dependence on wavelength, can also be well recovered through fitting the mock light curves with DRW. We further demonstrate that such weak dependence is artificial due to the effect of inadequate durations of light curves, which leads to best-fitting damping timescales lower than the intrinsic ones. After eliminating this effect, the CHAR model indeed yields a strong dependence of the intrinsic damping timescale on the bolometric luminosity and rest-frame wavelength. Our results highlight the demand for sufficiently long light curves in AGN variability studies and important applications of the CHAR model in such studies.

Anomalous thermal transport and high thermoelectric performance of Cu-based vanadate CuVO3

Thermoelectric (TE) conversion technology, capable of transforming heat into electricity, is critical for sustainable energy solutions. Many promising TE materials contain rare or toxic elements, so the development of cost-effective and eco-friendly high-performance TE materials is highly urgent. Herein, we explore the thermal transport and TE properties of transition metal vanadate CuVO3 by using first-principles calculation. On the basis of the unified theory of heat conduction, we uncover the hierarchical thermal transport feature in CuVO3, where wave-like tunneling makes a significant contribution to the lattice thermal conductivity (κl) and results in the anomalously weak temperature dependence of κl. This is primarily attributable to the complex phononic band structure caused by the heterogeneity of Cu–O and V–O bonds. Simultaneously, we report a high power factor of 5.45 mW·K−2·m−1 realized in hole-doped CuVO3, which arises from a high electrical conductivity and a large Seebeck coefficient enabled by the multiple valleys and large electronic density of states near the valence band edge. Impressively, the low κl and the high power factor make p-typed CuVO3 have ZT of up to 1.39, with the excellent average ZT above 1.0 from 300 to 600 K, which is superior to most reported Cu-based TE materials. Our findings suggest that the CuVO3 compound is a promising candidate for energy conversion applications in innovative TE devices.

First investigation on the isomeric ratio in multinucleon transfer reactions: Entrance channel effects on the spin distribution

The multinucleon transfer (MNT) reaction approach was successfully employed for the first time to measure the isomeric ratios (IRs) of 211Po isomer (25/2+) and its ground state (9/2+) at the IGISOL facility using a 945 MeV 136Xe beam impinged on 209Bi and natPb targets. The dominant production of isomers compared to the corresponding ground states was consistently revealed in the α-decay spectra. Deduced IR of 211Po populated through the 136Xe+natPb reaction was found to have an enhancement of ≈1.8-times than that observed for the 136Xe+209Bi. State-of-the-art Langevin-type model calculations have been utilized to estimate the spin distribution of an MNT residue. The computations qualitatively corroborate with the considerable increase in the IRs of 211Po produced from 136Xe+natPb compared to 136Xe+209Bi. Theoretical investigations indicate a weak dependence of target spin on the IRs. The enhancement of the 211Po isomer in the 136Xe+natPb over 136Xe+209Bi can be attributed to the different proton (p)-transfer production routes. Estimations demonstrate an increment in the angular momentum transfer, favorable for isomer production, with increasing projectile energy. Comparative analysis reveals the two entrance channel parameters, projectile mass and p-transfer channels, strongly influencing the population of the high-spin isomer of 211Po (25/2+). This letter reports the first experimental and theoretical study on the IRs of nuclei formed from two different p-transfer channels via two independent MNT reactions.

Ultralow Glassy Thermal Conductivity and Controllable, Promising Thermoelectric Properties in Crystalline o-CsCu5S3.

We thoroughly investigated the anharmonic lattice dynamics and microscopic mechanisms of the thermal and electronic transport characteristics in orthorhombic o-CsCu5S3 at the atomic level. Taking into account the phonon energy shifts and the wave-like tunneling phonon channel, we predict an ultralow κL of 0.42 w/mK at 300 K with an extremely weak temperature dependence following ∼T-0.33. These findings agree well with experimental values along with the parallel to the Bridgman growth direction. The κL in o-CsCu5S3 is suppressed down to the amorphous limit, primarily due to the unconventional Cu-S bonding induced by the p-d hybridization antibonding state coupled with the stochastic oscillation of Cs atoms. The nonstandard temperature dependence of κL can be traced back to the critical or dominant role of wave-like tunneling of phonon contributions in thermal transport. Moreover, the p-d hybridization of Cu(3)-S bonding results in the formation of a valence band with "pudding-mold" and high-degeneracy valleys, ensuring highly efficient electron transport characteristics. By properly adjusting the carrier concentration, excellent thermoelectric performance is achieved with a maximum thermoelectric conversion efficiency of 18.4% observed at 800 K in p-type o-CsCu5S3. Our work not only elucidates the anomalous electronic and thermal transport behavior in the copper-based chalcogenide o-CsCu5S3 but also provides insights for manipulating its thermal and electronic properties for potential thermoelectric applications.

Extraordinary Polarization and Thickness Dependences of Photocarrier Dynamics in PdSe2 Ribbons.

Pentagonal palladium diselenide (PdSe2) stands out for its exceptional optoelectronic properties, including high carrier mobility, tunable bandgap, and anisotropic electronic and optical responses. Herein, we systematically investigate photocarrier dynamics in PdSe2 ribbons using polarization-resolved optical pump-probe spectroscopy. In thin PdSe2 ribbons with a semiconductor phase, the photocarrier dynamics are found to be dominated by intraband hot-carrier cooling, interband recombination, and the exciton effect, showing weak crystalline orientation dependences. Conversely, in thick semimetal-phase PdSe2 ribbons, the photocarrier relaxations governed by the electron-optical/acoustic phonon scattering strongly depend on the sample orientation, albeit with a degradation in in-plane anisotropy following hot-carrier cooling. Furthermore, we analyze the correlations between photocarrier dynamics and anisotropic energy dispersions of electronic structures across a wide range in k space, as well as the contributions from the anisotropic electron-phonon couplings. Our study provides crucial insights for developing polarization-sensitive photoelectronic devices based on PdSe2.

A novel approach to detect salbutamol as a doping agent in athletes: A nanoparticle-modified electrode

This study successfully demonstrated a novel approach for the detection of salbutamol (SBM), a common doping drug in sports, using Tb4O7 nanoparticles and a reduced graphene oxide (Tb4O7/RGO) nanocomposite. The electrode modified with the Tb4O7/RGO nanocomposite exhibited remarkable selectivity, stability, and reproducibility, indicating its potential as a useful instrument for real-world uses. When used to detect salbutamol in serum samples, the sensor demonstrated a recovery rate of more than 96.50% and a relative standard deviation (RSD) of less than 4.17% (n=5). This work provides new insights into the electrochemical behavior of salbutamol and creates avenues for the development of very effective doping detection techniques. The sensor set a detection limit of 21 nM and functioned within a linear range of 1 µM to 710 µM. These results illustrate the accuracy and precision of the sensor and highlight its strong performance and dependability in a clinical context. As a result, the proposed sensor could be successfully used to determine the clinical levels of salbutamol in serum samples, giving medical personnel an invaluable tool for tracking and controlling patient health. With potential uses beyond sports doping detection, this work constitutes a noteworthy advancement in the field of electrochemical sensors.