Wavelength Dispersive X-ray Fluorescence Research Articles

Determination of Rare Earth Elements in Cosmo-geological Samples Aided by Wavelength Dispersive X-ray Fluorescence Spectroscopy

Determination of Rare Earth Elements in Cosmo-geological Samples Aided by Wavelength Dispersive X-ray Fluorescence Spectroscopy

Mineralogical Characteristics and Their Usability as Gemstones of Jaspers in Altered Metavolcanics Belonging to the Topçam Formation, Tokat, Turkiye

The jaspers located in the Topçam Mountain, Tepeyurt region (Tokat, Turkey), were formed at green-colored metavolcanic levels within Permian–Triassic schists. The sizes of the jaspers generally vary from a few cm to 1.5 m, and their colors vary from grayish–reddish–brownish/blackish tones depending on the increase in the amount of Fe and Mn elements they contain. According to thin section and X-ray Diffraction (XRD) analysis examinations, it was determined that the composition of jaspers includes quartz, hematite, calcite, and pyrite. As stated by the Wavelength Dispersive X-ray Fluorescence (WDXRF) analysis results, it was observed that the amount of SiO2 in jaspers was 82.5%, and the amount of Fe2O3 was 15.5%. According to Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) analysis results, Fe and Mn impurities, which are thought to cause the color of jaspers, as well as the amount of Fe (6975.5 ppm–46,893.9 ppm–96,431.1 ppm) and the amount of Mn (935.9–3219.7–6040.4 ppm), caused a darkening in color tones (grayish–reddish–brownish/blackish). Cabochon cutting applications were made of jaspers taken from the study area. As a result of these applications, it has been determined that jaspers can be used as gemstones due to their properties, such as their workability, polish retention, and color and light reflection.

Effect of IR Laser Energy on Several Polymers Using LIBS Analysis

ABSTRACTThe focus of this research is to use the thermal ablation properties of a Nd:YAG infrared laser to highlight the thermal damage caused by the extinction of the plasma, which leads to the disappearance of the spectra of certain polymers as the laser energy increases. The study involved testing five commonly used polymers: polytetrafluoroethylene (PTFE) also known as Teflon, polyoxymethylene (POM), polyvinyl chloride (PVC), Bakelite, and polyamide. Laser induced breakdown spectroscopy (LIBS) analysis was used to qualitatively analyze the plasma generated from the polymer samples, identifying the excited species present in each of the five polymers. Wavelength dispersive X‐ray fluorescence (WDXRF) analysis of the polymer samples further confirmed the identification of these excited species. The results obtained from the spectra recorded at different laser energies in an air environment showed that the saturation observed in the plasma, induced by increasing laser energy, is not consistently observed for all polymers. This plasma extinction phenomenon in certain polymers is attributed to thermal effects when using an infrared (IR) laser as a heating source.

Iron removal from red clay using oxalic acid leaching for enhanced ceramic industry applications

This work focused on removing iron with oxalic acid from red clay samples collected from Kapasia Upazila, Gazipur District, Bangladesh. To characterize the red clay, the study employed several techniques: particle size analysis, WDXRF (wavelength-dispersive X-ray fluorescence), AAS (atomic absorption spectroscopy), XRD (X-ray diffraction), TGA (thermogravimetric analysis), and FESEM (field emission scanning electron microscopy). Additionally, leaching experiments were conducted with varying concentrations of oxalic acid, temperatures and times. After leaching, the red clay composition changed significantly: SiO₂ increased from 53.6 % to 63.13 %, Fe₂O₃ decreased from 17.1 % to 3.64 %, Al₂O₃ remained relatively stable at 18 %–18.22 %, and other oxides showed minor variations. 78.71 % of the iron was removed at optimal leaching conditions (1.0 M oxalic acid, 100 °C, 150 min, and 250 rpm). Mineralogically, the red clay samples are composed of illite, kaolinite, quartz, feldspar, hematite and chlorite. Thermal analysis showed significant weight loss at temperatures between 300 and 600 °C. Ceramic trials were conducted at firing temperatures of 900 °C and 1100 °C to evaluate the mechanical properties of tiles. The results obtained showed significant improvements in red clay quality for ceramics. Being a low-cost and eco-friendly process, this becomes a very prominent alternative to conventional iron removal techniques and helps produce high-quality ceramic tiles, contributing towards economic growth in Bangladesh.

Durability Assessment for Mortar Containing LDH Additives

Abstract This study investigates the potential of Layered Double Hydroxides (LDH) as additives to improve the durability and physical properties of cement-based mortars, with a focus on freeze-thaw resistance. Three LDH types—MgAl-LDH, CaAl-LDH, and ZnAl-LDH—were synthesized and incorporated into mortar at a 1/1000 w/w ratio. X-ray diffraction (XRD) and wavelength dispersive X-ray fluorescence spectroscopy (WDXRF) were used to characterize the LDHs, and the effects of the additives on mortar density, water absorption, and durability under 30 freeze-thaw cycles were examined. Results revealed that MgAl-LDH provided the best freeze-thaw resistance, likely due to its smaller crystallite size and enhanced cement hydration. CaAl-LDH offered moderate improvements, while ZnAl-LDH negatively impacted the mortar’s mechanical integrity, leading to higher degradation. The study demonstrates the potential of LDH additives—particularly MgAl-LDH—in improving the durability of cementitious materials, although further optimization is required to enhance long-term performance and resistance to environmental stresses.

A Study of the Influence of Thermoactivated Natural Zeolite on the Hydration of White Cement Mortars.

One trend in the development of building materials is the partial or complete replacement of traditional materials that have a high carbon footprint with eco-friendly ecological raw materials and ingredients. In the present work, the influence of replacing cement with 10 wt% thermally activated natural zeolite on the structural and physical-mechanical characteristics of cured mortars based on white Portland cement and river sand was investigated. The phase compositions were determined by wavelength dispersive X-ray fluorescence (WD-XRF) analysis, X-ray powder diffraction (PXRD), diffuse reflectance infrared Fourier transformed spectroscopy (DRIFTS), and scanning electron microscopy (SEM), as well as thermogravimetric analysis simultaneously with differential scanning calorimetry (TG/DTG-DSC). The results show that the incorporation of zeolite increases the amount of pores accessible with mercury intrusion porosimetry by about 40%, but the measured strengths are also higher by over 13%. When these samples were aged in an aqueous environment from day 28 to day 120, the amount of pores decreased by about 10% and the compressive strength increased by nearly 15%, respectively. The microstructural analysis carried out proves that these results are due to hydration with a low content of crystal water and the realization of pozzolanic reactions that last over time. Replacing some of the white cement with thermally activated natural zeolite results in the formation of a greater variety of crystals, including new crystalline CSH and CSAH phases that allow better intergrowth and interlocking. The results of the investigations allow us to present a plausible reaction mechanism of pozzolanic reactions and of the formation of new crystal hydrate phases. This gives grounds to claim that the replacement of part of the cement with zeolite improves the corrosion resistance of the investigated building solutions against aggressive weathering.

Assessment, identifying, and presenting a plan for the stabilization of loessic soils exposed to scouring in the path of gas pipelines, case study: Maraveh-Tappeh city

Dealing with collapsible soils consistently presents a crucial challenge for geological and geotechnical engineers. Loess soil is among the most widely recognized types of collapsible soils, covering approximately 10 % of the Earth's land surface. Loessic soil is a sedimentary deposit primarily composed of silt-size grains, loosely bound together by calcium carbonate. In Iran, approximately 17 % of Golestan province is covered by silty, clayey, and sandy loesses, primarily composed of loessic soil. Additionally, several energy transmission lines in this province traverse these loess-covered areas. Based on the reports from Golestan Gas Company experts, the scouring of gas pipeline channels in various regions, such as Dashli-Alum in Maraveh-Tappeh city, causes significant risks in the traffic roads and is one of the most critical issues facing this company. This research assessed the dispersion and collapse potentials of loess soil using a range of field exploration and laboratory testing methods. These methods included atomic absorption spectroscopy, the double hydrometer, scanning electron microscope photography, wavelength-dispersive X-ray fluorescence spectrometry, and consolidation tests. The results indicate that soil collapsibility was acquired as one of the components of the scouring phenomenon occurrences. To achieve an optimal solution, the effectiveness of the chemical stabilization method involving cement, bentonite, micro-silica, and synthesized nano‑titanium additives was evaluated through an oedometer, Atterberg limits, uniaxial compression, and direct shear tests. Additives dry mixing of cement and nano‑titanium were obtained as the optimal stabilization solutions against scouring compared to other additives. However, considering the environmental impacts of cement production and use, nano‑titanium presents a more environmentally sustainable option due to CO2 absorption and reduced damage potential to vegetation.

Exploration geochemical evidence for the genesis of the Jiaodong gold deposits in eastern China: A case study of the Haiyu gold deposit

Jiaodong is the largest gold province in China and has great potential for further prospecting. It has been confirmed that the enrichment of Au is always accompanied by pyritization in Jiaodong gold deposits, so the genesis of pyritization in gold deposits and the mechanism of Au enrichment associated with pyritization has always been an issue of discussion to the researchers, the relationship between pyritization and Au enrichment is still unclear. In order to solve this problem, this paper studied the occurrence state and transformation characteristics of S in the ore-bearing geological bodies and discussed the mechanism of Au enrichment. 84 samples were collected from the drill hole ZK3006 of the Haiyu gold deposit, the average sampling interval was 15m, and 7 specific elements/analytical indexes were measured (Total sulfur, Reduced sulfur, Na2O,CaO, Sr, Ba, and Au), Burning-iodine quantity method was used to measure the content of Total sulfur, Combustion neutralization method was used to measure the content of Reduced sulfur Inductively coupled plasma-atomic emission spectrometry was used to measure the content of Na2O and CaO, Wavelength dispersive X-Ray fluorescence spectrometry was used to measure the content of Sr and Ba, and Foamed plastic enrichment-inductively coupled plasma-mass spectrometry was used to measure the content of Au.

Evaluation of iron speciation reference materials by wavelength-dispersive X-ray fluorescence, inductively coupled plasma optical emission spectroscopy, and flame/graphite furnace atomic absorption spectrometry for palaeoredox analysis

Fe speciation is crucial for distinguishing various redox conditions and thus offers valuable insights into the evolution of life and the environment throughout geological history. Monitoring experimental processes using reference materials is essential to ensure the consistency and reliability of Fe speciation analyses across laboratories. In this study, we evaluate the extraction processes and analytical methods used in the analysis of Fe speciation in four marine shale reference materials (WHIT, KL133, KL134, and BHW). A simple and feasible extraction process to extract Fecarb, Feox, and Femag that enables the simultaneous horizontal shaking of multiple samples by securing centrifuge tubes in foam racks is evaluated. Additionally, we compare the effects of the heating method on the extraction of FeR by heating the solution with a boiling water bath and a Bunsen burner. A new droplet method is devised for the instrumental analysis of Fe speciation using samples with high concentrations of total dissolved solids and organic matter matrices using wavelength-dispersive X-ray fluorescence spectrometry. A specialized PTFE support holder is designed to dry the filter paper in situ during sample preparation. We also compare figures of merits of wavelength-dispersive X-ray fluorescence spectrometry (WD-XRF), inductively coupled plasma-optical emission spectroscopy, and flame/graphite furnace atomic absorption spectrometry, including sample preparation, accuracy, precision, method limit of quantification, and linear range. The proposed WD-XRF droplet method will greatly simplify the sample preparation process and improve the efficiency of Fe speciation analysis.

Application of X-ray Spectroscopic Techniques to Determine the Inorganic Composition and Sulfur Chemical Speciation of the Amazonian Plant Bixa orellana

Bixa orellana is a plant that has a variety of uses, such as applications in the food and cosmetic industries, as well as culinary uses, and body painting for Indigenous people. Despite its versatility, few studies have explored its inorganic composition, and its sulfur chemical speciation has only been assessed from the point of view of sulfurous amino acids. Here, we report on the inorganic composition of Bixa orellana fruits, pericarps, and seeds obtained using Wavelength Dispersive X-ray Fluorescence (WD-XRF) and sulfur chemical speciation using X-ray Absorption Near-Edge Structure (XANES). Our results show that the seed is a source of potassium, calcium, magnesium, and phosphorous. But also, the pericarp, which is considered waste, contains a high amount of nutrients. From the XANES measurements, the distribution of the oxidation state of the sulfur atom was obtained, and it was shown that although several oxidation states of sulfur are present, oxidized sulfur (sulfate) is the dominant form of sulfur in all samples.

Micro PIXE mapping proves a differential distribution and concentration of trace elements in fungal structures of Rhizophagus intraradices

Arbuscular mycorrhizal (AM) fungi can sequester different potentially toxic elements, such as trace elements (TEs), within their structures to alleviate the toxicity for its host plant and themselves. To elucidate the role of AM fungi in TEs immobilization in the rhizosphere of host plants, it is important to know the TEs distribution in AM fungal structures. In the present study, we investigated the distribution and concentration of TEs within extraradical spores and mycelium of the AM fungus Rhizophagus intraradices, collected from the rhizosphere of Senecio bonariensis plants grown in a soil polluted with multiple TEs, by using Particle-Induced X-ray Emission with a micro-focused beam (micro PIXE). This technique enabled the simultaneous micrometric mapping of elements in a sample. The calculated values were compared with those in the polluted substrate, measured by the Wavelength Dispersive X-ray Fluorescence technique. The highest concentrations of Fe, P, Ti, Mn, Cr, Cu and Zn were found in AM fungal spores, where they were accumulated, while extraradical mycelium was enriched in Cu. Finally, we demonstrated that AM fungi can simultaneously accumulate high amounts of different TEs in their structures, thus reducing the toxicity of these elements to its host plant.

Transformation of Graphite Recovered from Batteries into Functionalized Graphene-Based Sorbents and Application to Gas Desulfurization.

The recycling and recovery of value-added secondary raw materials such as spent Zn/C batteries is crucial to reduce the environmental impact of wastes and to achieve cost-effective and sustainable processing technologies. The aim of this work is to fabricate reduced graphene oxide (rGO)-based sorbents with a desulfurization capability using recycled graphite from spent Zn/C batteries as raw material. Recycled graphite was obtained from a black mass recovered from the dismantling of spent batteries by a hydrometallurgical process. Graphene oxide (GO) obtained by the Tour's method was comparable to that obtained from pure graphite. rGO-based sorbents were prepared by doping obtained GO with NiO and ZnO precursors by a hydrothermal route with a final annealing step. Recycled graphite along with the obtained GO, intermediate (rGO-NiO-ZnO) and final composites (rGO-NiO-ZnO-400) were characterized by Wavelength Dispersive X-ray Fluorescence (WDXRF) and X-ray diffraction (XRD) that corroborated the removal of metal impurities from the starting material as well as the presence of NiO- and ZnO-doped reduced graphene oxide. The performance of the prepared composites was evaluated by sulfidation tests under different conditions. The results revealed that the proposed rGO-NiO-ZnO composite present a desulfurization capability similar to that of commercial sorbents which constitutes a competitive alternative to syngas cleaning.

Determination of macro‐ and microelements concentrations by wavelength‐dispersive X‐ray fluorescence spectrometry in the objects of the technogenic ecosystem

AbstractThe wavelength‐dispersive X‐ray fluorescence (WDXRF) spectrometry was applied to determine Na, Mg, Al, P, S, K, Ca, Cr, Mn, Fe, Ni, Cu, Zn, Sr, Ba, and Pb concentrations in the needles of dwarfish spruce Picea canadensis conica and the blue prickly spruce Picea pungens glauca, as well in technogenic soil of Irkutsk city, in which these spruce species grow. All measurements were performed in vacuum using WDXRF spectrometer S8 TIGER produced by Bruker AXS, Germany. The calculated values of instrumental limit of detection (ILD) ranged from 0.5 for Ni to 67 mg/kg for Al for soil certified reference materials (CRMs) such as OOKO151 (light chestnut soil) and from 0.2 for Cu and Ni to 18–24 mg/kg for Na for the plant CRMs such as LB‐1 (birch leaf) and EC‐1 (Canadian waterweed). The repeatability is satisfactory. The values of relative standard deviations (RSDs) do not exceed 15% for soils and available plant material. With calculated T‐statistics, it was found that the WDXRF data do not contain systematic errors. The values of relative discrepancy for WDXRF, total reflection X‐ray fluorescence (TXRF) spectrometry, and atomic emission spectrometry with arc discharge (d.c. arc‐AES) results do not exceed 30% for studied elements.

Quantitative determination of sulfate sulfur in soils and sediments using the S-Kα and S-Kβ X-ray spectra and PLS regression

A new approach to the quantitative determination of sulfate sulfur in soils and sediments by wavelength-dispersive X-ray fluorescence spectrometry in combination with partial least squares (PLS) regression has been investigated. The quantitative analysis of sulfate sulfur was carried out by analyzing the spectra in the S-Kα and S-Kβ regions of sulfur spectral lines. The study shows that the differences in the spectra in both regions can be used for quantitative analysis of sulfate sulfur in the presence of sulfur in other forms. The obtained information can be used for quantitative express analysis of sulfur forms in objects of various nature.

Compositional and Microstructural Investigations of Prehistoric Ceramics from Southern Romania (Middle Neolithic Pottery)

In this paper, based on our previous expertise on ceramic artifacts, several archaeometric methods applied to some samples collected from the Dudești archaeological site (Oltenia region, Romania) are reported for the first time in the literature. The chemical composition, and microstructural and morphological characterization of these samples offer important conclusions about the processing conditions. Some specific techniques such as X-ray diffraction (XRD), wavelength-dispersive X-ray fluorescence (WDXRF), optical microscopy (OM), stereomicroscopy, environmental scanning electron microscopy (ESEM), Fourier-transform infrared spectroscopy (FTIR), and Raman spectroscopy provide compositional information about composition and the decay processes. Additionally, the Brunauer–Emmett–Teller (BET) method helps to estimate pore sizes and specific surface areas. A thermogravimetric analysis (TGA/TDG) was used to establish details regarding the production technology and also the raw materials source used to make the ceramics. The obtained results indicated that the ceramics are based on a paste of muscovite and feldspar, with high plasticity, together with quartz and hematite/goethite and calcite, the latter in very low concentrations. According to the obtained results, we could assume that clays from the investigated samples had a low concentration of calcium. Gypsum is present as paste in a very low concentration, identified by the presence of a sulphate group in WDXRF. In the same context, iron oxides have a significant impact on the firing atmosphere of iron-rich clay, resulting in blackening under reducing conditions and a reddish coloration under oxidative conditions. The use of hematite and gypsum as pigments further contributes to the color variations in the pottery. The consistent firing temperature range of 200–600 °C in Dudești pottery implies a standardized production process, the variation in color being dependent on the specific reducing/oxidative regime conditions (reducing atmosphere followed by rapid oxidation). This relationship between clay composition and local sources suggests a connection to Neolithic pottery production in the region and their color depending on the reducing/oxidative regime conditions.

Modern River-Sand Geochemical Mapping in the Manufahi Municipality and Its Surroundings, Timor-Leste: Implications for Provenance

A geochemical mapping of regional modern river-sand is performed to clarify geological information in the study area of Timor-Leste. Several areas of Timor-Leste including the study area in particular have limited geological information due to limited accessibility and dense vegetation coverage, and deformed, weathered, and erosion-covered materials. A total of 53 modern river sand samples were collected and analyzed. Ten major elements were determined by using wavelength-dispersive X-ray fluorescence. Areas characterized by clastic sedimentary rocks are recognized clearly by elevated concentrations of SiO2, Al2O3, and K2O. Meanwhile, areas covered by carbonate sedimentary rocks are detected by significant concentrations of CaO and MnO. The occurrences of the altered clastic and carbonate sedimentary rocks of the Wailuli and Aitutu Formations due to metamorphic, silicification and other alteration processes were responsible for the elevated concentrations and positive correlation between SiO2, CaO, K2O, and MnO, and CaO, TiO2, and MnO in the midstream and near the downstream areas of the Clerec and Sahe River catchments. The positive correlation observed between TiO2, CaO and MnO may be ascribed to the presence of carbonate components associated with secondary Ti-bearing minerals, which are potentially formed through hydrothermal alteration processes.

Application of some calibration strategies in comparison to determine Cr, Ni, Cu, Zn, As, and Pb in contaminated plants by wavelength dispersive x‐ray fluorescence

AbstractThe study of nonstandard samples wherein their element compositions differ from those of routine samples motivates analysts to look for new methodological approaches. To determine the high concentrations of Cr, Ni, Cu, Zn, As, and Pb in polluted plants, the authors applied wavelength dispersive x‐ray fluorescence (WDXRF), using three calibration strategies in comparison. The following sets of calibration samples were tested: available plant and biological CRMs; synthetic samples; and “house reference materials” (HRMs). The synthetic samples were prepared, adding small portions of the loose sediment CRMs to a plant CRM. The polluted plant samples, analyzed by atomic absorption spectrometry and inductively coupled plasma mass spectrometry, were used as HRMs to construct the calibration curves and validate XRF results. It was ascertained that all three calibration strategies can be used to quantify above elements in contaminated plants, providing different precision of WDXRF results. The calibration procedure with HRMs has provided the least errors in the element determinations. Calibration with synthetic samples causes larger errors due to some differences in chemical compositions between calibration and analyzed samples as well as due to probable errors in the synthetic sample preparation. The calibration with plant and biological samples is of limited applicability in XRF of contaminated plants by reason of narrow content ranges of some elements.

Elemental geochemistry insights into source inputs, paleo-productivity, and paleo-depositional conditions of the Montney Formation

The analysis of the elemental composition of sediments provides valuable information about input sources, paleoredox conditions, or paleoproductivity. In this study, 1498 rock samples from six wells within the Triassic Montney Formation in Central Alberta, Western Canada, were analyzed using energy-dispersive X-ray fluorescence (ED-XRF). Wavelength dispersive X-ray fluorescence measurements were used to build and validate a Montney-specific calibration to interpret elemental concentrations from the ED-XRF dataset. The calibration accounted for heterogeneities, matrix variations and unique elemental associations that may be present within the Montney Formation. Sediment input sources are interpreted based on cross-plots of proxy elements to be terrigenous, carbonates and biogenic in origins. Analysis of multiple paleoredox proxies indicated the environment of deposition to be mainly oxic. The ratios of potassium (K) to rubidium (Rb) were used as a paleoclimate proxy. Results suggest the predominance of low chemical weathering attributed to a hot and arid paleoclimate during deposition of Montney Formation sediments. Phosphorous concentrations were determined to be strongly associated with Ca, as such it was interpreted to be inorganically sourced, thereby precluding it from being used to assess paleoproductivity. Excess Si interpreted to be biogenically sourced was used in interpreting moderate and high paleoproductivity for the Montney formation. This work demonstrates the versality of matrix-specific calibrated ED-XRF measurements as a valuable, cost efficient, standalone technique in geochemical analysis for characterizing geological formations.

Bay Laurel of Northern Morocco: A Comprehensive Analysis of Its Phytochemical Profile, Mineralogical Composition, and Antioxidant Potential

Laurus nobilis, sometimes referred to as laurel, has been used for medicinal and culinary purposes for a very long time. The main subjects of this study are the phytochemical composition, mineralogical profile, and potential antioxidant properties of Laurus nobilis in Tangier, Northern Morocco. For phytochemical analysis of methanolic extracts, high-performance liquid chromatography (HPLC-UV-MS) was used, and Fourier transformation infrared spectroscopy (FT-IR) was used to identify each individual component. Minerals were studied by inductively coupled plasma atomic emission spectroscopy (ICP-AES) and wavelength dispersive X-ray fluorescence (WD-XRF). Total tannin, flavonoid, and phenolic amounts were quantified using aqueous and methanolic extracts. The antioxidant properties were assessed using 2,2-diphenyl-1-picrylhydrazyl (DPPH), 2,2′-azino-bis (3ethylbenzothiazoline-6-sulfonic acid) (ABTS), ferric reducing antioxidant power (FRAP), and oxygen radical absorbance capacity (ORAC) assays. Research has revealed a complex array of phytochemicals, including tannins, flavonoids, and phenolic acids. Mineral analysis has revealed the existence of vital components that are beneficial to health. Comparing the methanolic extract to the water extract, it demonstrated higher levels of phenols, flavonoids, and tannins as well as stronger antioxidant activity, indicating greater health benefits. This comprehensive study highlights the importance of Laurus nobilis from Northern Morocco as a reliable botanic resource with potential pharmaceutical, nutritional, and cosmetic uses.

Evaluation of Physico-Chemical Characteristics of Cement Superplasticizer Based on Polymelamine Sulphonate.

Cementitious materials are used to construct an engineered barrier in repositories for radioactive waste. The cement matrix may contain a variety of organic compounds, some of which are polymeric admixtures used as plasticizers. Superplasticizers (SPs) are highly effective organic cement additives for reducing water amount, increasing workability, homogeneity, plasticity and the non-segregation of mortars and grouts, improving mechanical properties and resistance to destructive environments. SPs in cement could have an impact on the long-term safety of the disposals of radioactive waste. These organic agents can leach from the cementitious matrix into groundwater and may affect the migration behaviour of radionuclides. The detailed chemical composition and other characteristics of the cement (CEM I 42.5 R, Sweden) used for the leaching experiments were evaluated. It contained mainly CaO (52.51 ± 1.37, %), and the surface area of the cement particles was 13.2 ± 1.3 m2/g. An insignificant increase in pH (from 12.6 ± 0.1 to 12.8 ± 0.1) was observed for the leachates over 10 days. A commercially available cement superplasticizer based on polymelamine sulphonate (PMS) Peramin SMF10 (Peramin AB, Sweden) was chosen for the research. The product's chemical composition was analysed using wavelength-dispersive X-ray fluorescence (WD-XRF) spectroscopy, while other physico-chemical properties of the PMS superplasticizer were assessed by Raman spectroscopy and thermo-gravimetric analysis. In aqueous solutions and powders of PMS, the same most intensive features were observed at 774 cm-1 (ring out-of-plane deformation), 977 cm-1 (C-N-C bending, SO stretching) and 1055 cm-1 (C-N=C bending) in the Raman spectra. At up to 270 °C, the polymer was thermally stable. Raman and UV/Vis spectroscopies were used to assess the rate of the alkaline degradation of PMS superplasticizer in different aqueous solutions. No changes were observed in the hydrolytic solutions with any of the above analytical methods over a period of 3 years. The results obtained revealed a good thermal and chemical stability (in highly alkaline media, pH = 9.9-12.9) of the PMS polymer.