Water Vapor Pressure Research Articles

Analysis of the influence of thermal insulation parameters on the effectiveness of enclosing structures and building heating systems

The results of thermal engineering calculations of external multilayer enclosing structures of buildings and the thermal power of the heating system of residential buildings are presented, including calculations of temperature fields and partial pressures of water vapor at various parameters of structural layers and thermal insulation layers. Variants are considered and an assessment is given of the variation of parameters and the different location of thermal insulation in external multilayer fences for changes in temperature fields and partial pressures of water vapor in the fence, as well as for changes in the thermal power of the heating system of the building premises for two climatological design areas. The calculations were performed according to the methodology presented below using a specially developed computer program.

Spatio-temporal changes in atmospheric aridity over the arid region of Central Asia during 1979–2019

The arid region of Central Asia (CA) is the largest non-zonal arid region in the world. It has experienced significant changes in climate and hydrological cycle systems owing to global warming, which has posed serious impacts on the water resources and ecological environment in this region. Although the atmospheric water vapor pressure deficit (VPD) can directly reflect the atmospheric moisture condition, studies on the change of atmospheric moisture deficit in CA are scarce. Thus, we investigated the changes in VPD in the arid region of CA from the perspective of atmospheric aridity based on the CRU TS4.04 and ERA5 data. Our results showed that the VPD in more than 95 % of grids in the arid region had a significantly increasing trend during 1979–2019. Seasonally, VPD trends were increasing in spring, summer, and autumn but decreasing in winter. The changes in saturated water vapor pressure and actual water vapor pressure determined the VPD changes. The saturated water vapor pressure showed a clearly upward trend, whereas the actual water vapor pressure did not increase at the same rate, resulting in the increase of VPD. The first four leading modes revealed by empirical orthogonal function (EOF) analysis represented the patterns by explaining 81.4 % of the total variance. The positive phase of EOF1 was characterized by a monopole pattern, and this mode continued to increase. Contrastingly, EOF2 (and EOF3) showed dipole patterns over east–west CA (and north–south CA), with a mainly interannual variability. Due to the combined effect of increasing temperatures and decreasing relative humidity, the VPD has been intensifying since the mid-to-late 1990 s in CA, and the atmosphere has become significantly drier. These research results can deepen the scientific understanding of global warming impacts on atmospheric moisture and provides a reference for revealing the VPD changes and their impacts on the climate system and ecosystem in arid regions. Our results highlight that the impacts of VPD change should be adequately considered in environmental management and policy-making processes in Central Asia.

Detectability of biosignatures in warm, water-rich atmospheres

Warm rocky exoplanets within the habitable zone of Sun-like stars are favoured targets for current and future missions. Theory indicates these planets could be wet at formation and remain habitable long enough for life to develop. However, it is unclear to what extent an early ocean on such worlds could influence the response of potential biosignatures. In this work we test the climate-chemistry response, maintenance, and detectability of biosignatures in warm, water-rich atmospheres with Earth biomass fluxes within the framework of the planned LIFE mission. We used the coupled climate-chemistry column model 1D-TERRA to simulate the composition of planetary atmospheres at different distances from the Sun, assuming Earth's planetary parameters and evolution. We increased the incoming instellation by up to 50 percent in steps of 10 percent, corresponding to orbits of 1.00 to 0.82 AU. Simulations were performed with and without modern Earth’s biomass fluxes at the surface. Theoretical emission spectra of all simulations were produced using the GARLIC radiative transfer model. LIFEsim was then used to add noise to and simulate observations of these spectra to assess how biotic and abiotic atmospheres of Earth-like planets can be distinguished. Increasing instellation leads to surface water vapour pressures rising from 0.01 bar (1.31<!PCT!>, S = 1.0) to 0.61 bar (34.72<!PCT!>, S = 1.5). In the biotic scenarios, the ozone layer survives because hydrogen oxide reactions with nitrogen oxides prevent the net ozone chemical sink from increasing. Methane is strongly reduced for instellations that are 20<!PCT!> higher than that of the Earth due to the increased hydrogen oxide abundances and UV fluxes. Synthetic observations with LIFEsim, assuming a 2.0 m aperture and resolving power of a R = 50, show that ozone signatures at 9.6 mu m reliably point to Earth-like biosphere surface fluxes of O$_2$ only for systems within 10 parsecs. The differences in atmospheric temperature structures due to differing H$_2$O profiles also enable observations at 15.0 mu m to reliably identify planets with a CH$_4$ surface flux equal to that of Earth's biosphere. Increasing the aperture to 3.5 m and increasing instrument throughput to 15<!PCT!> increases this range to 22.5 pc.

Improving Liquid Desiccant Dehumidifiers through Square Baffle Plate Design and Nanofluid Innovation

Enhancing the performance of the liquid desiccant dehumidifier (LDDs) is pivotal, with mass transfer playing a significant role. Compared to the previous method, using a baffles plate improved liquid desiccant dehumidification performance. The study utilized an aqueous solution containing nanocarbon tubes (NCTs) in LiCl/H2O as the desiccant, cascading over baffles plate with a square profile. The performance of this system was determined using numerical methods. The concentrations of NCTs ranged from 0.03% to 0.5% by weight. Furthermore, this paper investigates the impact of nanoparticles and parameters, including flow rates, solution concentration, humidity, solution temperature, etc. on the analysis through Computational Fluid Dynamics (CFD) simulation. The study shows a 29% increase in moisture removal and humidity change, along with a 15.57% improvement in film thickness. These findings are underpinned by the principle of a reduced in contact angle from 57° to 29°, resulting in reduced partial pressure of water vapor from the solution, thereby enhancing the mass transfer mechanism. Consequently, the utilization of baffles plate demonstrates a significant improvement in the moisture removal performance of the LDDs.

Low‐temperature bubble formation in silica glass

AbstractPhase separation was observed in silica glass following low‐temperature heat treatment in high water vapor pressure through the formation of bubbles. Although the 6 day diffusion treatment in saturated water vapor pressure at 250°C does not normally cause phase separation, the reactive fracture surface and subsurface damage caused by polishing with cerium oxide (CeO2) allowed for an increase in water absorption during treatment and heterogeneous nucleation of the bubbles at damaged sites. The sub‐surface damage, characteristic of blunt contact damage, was only revealed when the polished sample was etched. The formation of bubbles and polishing damage were observed in two silica glasses—one containing chlorine impurities and the other containing OH impurities. Raman spectra collected after fracture or polishing and water diffusion treatment demonstrated an increase in the abundance of –OH species including silanol (SiOH) groups and an evolution in the glass structure in the bubble regions compared with the bubble‐free regions. These results indicate an increase in the reactivity between water and glass fracture surfaces relative to the bulk.

Synthesis and Characterization of Calcium Sulfoaluminate Hydrates-Ettringite (AFt) and Monosulfate (AFm).

The goal of the presented work was to find the most favorable conditions for the synthesis and stabilization of chemically pure ettringite and monosulfate. The reaction was carried out by mixing pure tricalcium aluminate (C3A) and gypsum (CS¯H2) in an excess amount of water. The impact of hydration time (2-7 days), C3A:CS¯ molar ratio (1:1-1:3) and water vapor pressure of the selected drying agents (anhydrite-III and supersaturated CaCl2 solution) on the phase composition of the products was evaluated. After 7 days of hydration, either ettringite or monosulfate was obtained as the main product, depending on the C3A:CS¯ molar ratio. The synthesis carried out at a C3A:CS¯ molar ratio of 1:3 produced pure ettringite. In the case of the sample characterized by the ratio of 1:1 (typical of monosulfate), a considerable portion of ettringite (27.9%) was present in the final products along the AFm phase. Therefore, a different synthesis method has to be selected in order to obtain pure monosulfate. The results showed that thermal analysis, X-ray diffractometry and FTIR spectroscopy can be used to distinguish the characteristic features of ettringite and monosulfate.

A molecular study of CO2 adsorption performance of functionalized Mg-MOF-74 at different water vapor concentrations and pressures

This study numerically evaluates the CO2 adsorption capability of functionalized Mg-MOF-74 at different water vapor concentrations and pressures. The −O-Li- and –NO2 display the most advantageous adsorption locations for CO2 and enhance the adsorption energy for H2O within the secondary building unit region. The enhancement of CO2 adsorption at 1 bar is achieved through the incorporation of Li-O and –NO2, whereas introducing –CH3 improves the selectivity of Mg-MOF-74 towards CO2/H2O. The absorption of CO2 at 10 bar is influenced by the available void space within the pores and altering the functional groups leads to a reduced porosity, thereby hindering the CO2 adsorption. However, –CH3 can effectively improve the CO2/H2O selectivity. The increased CO2 adsorption sites by the functionalization is more advantageous for enhancing CO2 adsorption capacity in gas/vapor mixtures at low pressures. Furthermore, enhancing absorbent hydrophobicity results in an enhanced selectivity for CO2/H2O, thereby facilitating CO2 adsorption at elevated pressures.

Impact of broader ecological and socio-environmental components on Aedes mosquito population dynamics: a spatial-temporal longitudinal study.

The increasing spread of mosquito-borne diseases is a significant problem globally, but mosquito management strategies are less efficient. Therefore, a comprehensive understanding of the population dynamics of Aedes mosquito is essential for improving mosquito management strategies. Constructing a model to understand Aedes mosquito development in response to environmental factors is crucial to addressing these challenges. An extensive data set on Aedes spp. mosquito populations was constructed, considering the environmental factors temperature, water vapor pressure, wind speed, daylength, and rainfall. This data set, compiled from mosquito collections over a period of four years across multiple locations in Alabama, USA, facilitated the prediction of mosquito dynamics. The random forest model was used to explain mosquito population changes in response to these factors. These findings indicated that temperature, daylength, and water vapor pressure had the most significant impacts on mosquito population dynamics. The model also allowed predictions of mosquito population changes over time and across different geographic regions, extending beyond Alabama to the southeastern USA. This study provided valuable insights into the impacts of environmental factors on mosquito populations. This novel approach using machine learning and the random forest model will enable researchers to predict future mosquito populations and contribute to developing more-effective strategies for mosquito management. © 2024 Society of Chemical Industry. Published by John Wiley & Sons Ltd.

The Synergistic Effect of the Same Climatic Factors on Water Use Efficiency Varies between Daily and Monthly Scales

The coupled processes of ecosystem carbon and water cycles are usually evaluated using the water use efficiency (WUE), and improving WUE is crucial for maintaining the sustainability of ecosystems. However, it remains unclear whether the WUE in different ecosystem responds synchronously to the synergistic effect of the same climate factors at daily and monthly scales. Therefore, we employed a machine learning-driven factor analysis method and a geographic detector model, and we quantitatively evaluated the individual effects and the synergistic effect of climate factors on the daily mean water use efficiency (WUED) and monthly mean water use efficiency (WUEM) in different ecosystems in China. Our results showed that (1) among the 10 carbon flux monitoring sites in China, WUED and WUEM exhibited the highest positive correlations with the near-surface air humidity and the highest negative correlation with solar radiation. The correlation between WUEM and climate factors was generally greater than that between WUED and climate factors. (2) There were significant differences in the order of importance and degree of impact of the same climate factors on WUED and WUEM in the different ecosystems. Among the 10 carbon flux monitoring sites in China, the near-surface air humidity imposed the greatest influence on the WUED and WUEM changes, followed by the near-surface water vapor pressure. (3) There were significant differences in the synergistic effects of the same climate factors on WUED and WUEM in the different ecosystems. Among the 10 carbon flux monitoring sites in China, the WUED variability was most sensitive to the synergistic effect of solar radiation and photosynthetically active radiation, while the WUEM variability was most sensitive to the synergistic effect of the near-surface air humidity and soil moisture. The research results indicated that synchronous responses of the WUE in very few ecosystems to the same climate factors and their synergistic effect occurred at daily and monthly scales. This finding enhances the understanding of sustainable water resource use and the impact of climate change on water use efficiency, providing crucial insights for improving climate-adaptive ecosystem management and sustainable water resource utilization across different ecosystems.

Toward Water-Resistant, Tunable Perovskite Absorbers Using Peptide Hydrogel Additives.

In recent years, hydrogels have been demonstrated as simple and cheap additives to improve the optical properties and material stability of organometal halide perovskites (OHPs), with most research centered on the use of hydrophilic, petrochemical-derived polymers. Here, we investigate the role of a peptide hydrogel in passivating defect sites and improving the stability of methylammonium lead iodide (MAPI, CH3NH3PbI3) using closely controlled, in situ X-ray photoelectron spectroscopy (XPS) techniques under realistic pressures. Optical measurements reveal that a reduction in the density of defect sites is achieved by incorporating peptide into the precursor solution during the conventional one-step MAPI fabrication approach. Increasing the concentration of peptide is shown to reduce the MAPI crystallite size, attributed to a reduction in hydrogel pore size, and a concomitant increase in the optical bandgap is shown to be consistent with that expected due to quantum size effects. Encapsulation of MAPI crystallites is further evidenced by XPS quantification, which demonstrates that the surface stoichiometry differs little from the expected nominal values for a homogeneously mixed system. In situ XPS demonstrates that thermally induced degradation in a vacuum is reduced by the inclusion of peptide, and near-ambient pressure XPS (NAP-XPS) reveals that this enhancement is partially retained at 9 mbar water vapor pressure, with a reduced loss of methylammonium (MA+) from the surface following heating achieved using 3 wt % peptide loading. A maximum power conversion efficiency (PCE) of 16.6% was achieved with a peptide loading of 3 wt %, compared with 15.9% from a 0 wt % device, the former maintaining 81% of its best efficiency over 480 h storage at 35% relative humidity (RH), compared with 48% maintained by a 0 wt % device.

Augmentation strategy toward superior water absorption performance: An attempt utilizing [EMIm]Ac ionic liquid/water pair

Ionic liquids (ILs) offer significant advantages as alternative absorbents in absorption refrigeration cycles due to their superior physicochemical properties. Assessing the performance of new IL-based working pairs in absorption systems is essential for their rapid application in industrial applications. This study evaluates the water absorption performance of an aqueous solution of 1-ethyl-3-methylimidazolium acetate ([EMIM]Ac) under both saturated atmospheric and vacuum conditions. Additionally, the performance of an absorption chiller utilizing the [EMIM]Ac/H2O working pair was analysed using the Aspen Plus process simulator. A discrepancy was observed between the water vapor pressure in the air and the saturated vapor pressure of the aqueous solution at equilibrium. A theoretical criterion for the minimum relative humidity required for effective water vapor absorption by this absorbent at a given mass fraction is proposed. Under vacuum conditions, lower absolute pressure or higher mass fraction enhances absorption. Surfactants significantly improve absorption performance, with 2-octanol and 1-octanol demonstrating approximately double the absorption capacity compared to [EMIM]Ac. Higher mass fractions of the aqueous solution enhance the absorption rate but reduce the desorption rate. The coefficient of performance (COP) of the system decreases with increasing pressure and mass fraction, reaching a peak of 0.9 at a mass fraction of 20 % and a pressure of 3 kPa. Lower pressure and mass fraction enhance exergy efficiency.

Different States of water in α-Cyclodextrin hydrates

The pressure of saturated and unsaturated water vapor over α-CD·nH2O hydrates has been measured by static method with membrane-gauge manometer under conditions of complete loss of water. The temperature dependences of water vapor pressure have been obtained in the wide range of temperatures (287–469 K), pressures (0.04–34.95 kPa) and water content (0.17 ≤ n ≤ 6.0).The data obtained indicate the presence of water molecules with different volatility in α-CD·nH2O hydrates. Water molecules with lower volatility can be considered “external”, included in the network of intermolecular hydrogen bonds, while water molecules with higher volatility, discovered in our previous study, are considered “internal”, presumably located in the α-CD cavity. For each composition, the amount of “external” and “internal” water has been determined and the equations described the dependence of the content of each type of water on n in α-CD·nH2O have been obtained. The analytical expressions for the lnp – 1/T dependences as well as the values of enthalpy and entropy of processes studied have been calculated. Experimental data were used to obtain the Gibbs energy changes when “external” water molecules bind to the α-CD framework. The values obtained are differed from the values for “internal” water given in our previous study. The phase transition in α-CD·nH2O revealed in our previous study is also observed in this work and its thermodynamic characteristics are in good agreement with the results obtained earlier. The findings have been confirmed by 1H NMR studies.

Multiple-Win Effects and Beneficial Implications from Analyzing Long-Term Variations of Carbon Exchange in a Subtropical Coniferous Plantation in China

To improve our understanding of the carbon balance, it is significant to study long-term variations of all components of carbon exchange and their driving factors. Gross primary production (GPP), respiration (Re), and net ecosystem productivity (NEP) from the hourly to the annual sums in a subtropical coniferous forest in China during 2003–2017 were calculated using empirical models developed previously in terms of PAR (photosynthetically active radiation), and meteorological parameters, GPP, Re, and NEP were calculated. The calculated GPP, Re, and NEP were in reasonable agreement with the observations, and their seasonal and interannual variations were well reproduced. The model-estimated annual sums of GPP and Re over 2003–2017 were larger than the observations of 11.38% and 5.52%, respectively, and the model-simulated NEP was lower by 34.99%. The GPP, Re, and NEP showed clear interannual variations, and both the calculated and the observed annual sums of GPPs increased on average by 1.04% and 0.93%, respectively, while the Re values increased by 4.57% and 1.06% between 2003 and 2017. The calculated and the observed annual sums of NEPs/NEEs (net ecosystem exchange) decreased/increased by 1.04%/0.93%, respectively, which exhibited an increase of the carbon sink at the experimental site. During the period 2003–2017, the annual averages of PAR and the air temperature decreased by 0.28% and 0.02%, respectively, while the annual average water vapor pressure increased by 0.87%. The increase in water vapor contributed to the increases of GPP, Re, and NEE in 2003–2017. Good linear and non-linear relationships were found between the monthly calculated GPP and the satellite solar-induced fluorescence (SIF) and then applied to compute GPP with relative biases of annual sums of GPP of 5.20% and 4.88%, respectively. Large amounts of CO2 were produced in a clean atmosphere, indicating a clean atmospheric environment will enhance CO2 storage in plants, i.e., clean atmosphere is beneficial to human health and carbon sink, as well as slowing down climate warming.

The Usability of Metallurgical Production Waste as a Siliceous Component in Autoclaved Aerated Concrete Technology

The reconstruction of buildings is a complex process that often requires the consideration of the construction load when selecting correct building materials. Autoclaved aerated concrete (AAC)—which has a lower bulk density (compared to traditional masonry materials)—is very beneficial in such applications. A current trend in AAC development is the utilization of secondary raw materials in high-performance AAC, characterized by higher bulk density and compressive strength than regular AAC. The increase in bulk density is achieved by increasing the content of quartz sand in the mixing water. In this study, part of the siliceous component was replaced by ladle slag, foundry sand, furnace lining, and chamotte block powder. These materials are generated as by-products in metallurgy. The substitution rates were 10% and 30%. The samples were autoclaved in a laboratory autoclave for 8 h of isothermal duration at 190 °C with a saturated water vapor pressure of 1.4 MPa. The physical–mechanical parameters were determined, and the microstructure was described by XRD and SEM analyses. The results were compared with traditional AAC, with silica sand being used as the siliceous component. The measurement results show that sand substitution by the secondary raw material is possible, and it does not have a significant impact on the properties of AAC, and in a proper dosage, it can be beneficial for AAC production.

A novel model for the estimation of water vapor pressure and temperature considering diurnal variations in China

Water vapor pressure (e) and temperature (T) are essential tropospheric parameters in the Global Navigation Satellite System (GNSS) high-precision positioning navigation and GNSS meteorology. Current models for water vapor pressure and temperature exhibit insufficiently detailed vertical profiling and fail to effectively capture diurnal variations. For two tropospheric parameters, e and T, the empirical models of meteorological parameters in China, CET-H models, were established based on the fifth-generation European Center for Medium-Range Weather Forecasts Reanalysis (ERA5) reanalysis data and the elaborate diurnal variation from 2017 to 2019. The 2020 ERA5 atmospheric reanalysis data and radiosonde data are used as reference values and compared with the current GPT3 model with higher accuracy. The results show that: (1) The BIAS and Root Mean Square Error (RMSE) of e obtained by the CET-H model at the ERA5 surface are 0.18 hPa and 2.65 hPa, respectively, higher by 42.4 % compared to the GPT3 model. The BIAS and RMSE of T obtained by the CET-H model at the ERA5 surface are −0.90 K and 3.63 K, respectively, higher by 21 % compared to the GPT3 model. The atmospheric layer mean values of both models are superior to the GPT3 model in all seasons across different latitude bands. (2) The BIAS and RMSE of e obtained by the CET-H model at the radiosonde station are −0.05 hPa and 3.17 hPa, higher by 43 % compared to the GPT3 model. The BIAS and RMSE of T obtained by the CET-H model at the radiosonde station are 4.49 hPa and 6.80 hPa, higher by 15 % compared to the GPT3 model. The atmospheric layer mean values of both models are superior to the GPT3 model in all seasons across different latitude bands. Therefore, the new model will provide a new reference for GNSS meteorology.

Thermoelectric and electrical transport properties of mixed-conducting multicomponent oxides based on Ba(Zr,Ce)O3-δ

In this work, the chosen physicochemical properties of single-phase multicomponent oxides BaTi1/8Fe1/8Co1/8Y1/8Zr1/8Sn1/8Ce1/8Hf1/8O3-δ and BaTi1/9Fe1/9Co1/9Y1/9Zr1/9Sn1/9Ce1/9Hf1/9Bi1/9O3-δ were studied. The microstructure of the compounds strongly depended on the presence of bismuth in the structure. The electrical transport studies showed a level of electrical conductivity of ∼10-3 - 10-2 S/cm in the temperature range 673 – 1073 K. Electrical conductivity was thermally activated and the dominant conduction mechanism was the hopping of small polarons. Moreover, total electrical conductivity changes in the dry and humidified atmosphere at lower temperatures due to the presence of protonic defects in the structure. Thermoelectric measurements showed a relatively high value of the Seebeck coefficient for studied ceramics. Its values ranged between 50 and 250 μV/K depending on the sample and temperature. The Seebeck coefficient sign was positive, meaning that electron holes and/or oxygen vacancies were predominant charge carriers in oxidising atmospheres. Additionally, the Seebeck coefficient was found to be different in the humidified atmosphere which indicates an influence of protonic defects on thermoelectric transport. The obtained power factor Pf turned out to be low and dependent on the presence of protonic defects in the structure. This indicates, that the efficiency of the MOs-based operating thermoelectric generators can be controlled by changing the partial pressure of water vapor.

Drying model and drying characteristic analysis of multiphase porous medium for flake materials

The main purpose of this paper is to optimize the drying process and gain a fundamental understanding of the movement of different phases during the drying process of cigarette flakes. Therefore, the drying model of a multiphase porous medium for cigarette flakes has been established in this paper. Binary diffusion of water vapor and gas pressure transport, as well as capillary diffusion of liquid water and gas pressure transport, are considered in this model. The non-equilibrium equations are used to calculate the evaporation rate, and the fluxes of water vapor and liquid water are also obtained. The results indicated that the stochastic stacking model is suitable for studying cigarette flake drying. Because water evaporation absorbs more heat than hot air, the temperature of the cigarette flakes decreases during the drying process. The water activity, vapor density, and vapor mole fraction of the medium layer of cigarette flakes were significantly higher than those of the upper and lower layers. The highest water vapor and liquid water fluxes occur in the medium of the drying process. Additionally, it was observed that the saturated vapor pressure was higher than the equilibrium vapor pressure and steam pressure, non-equilibrium evaporation occurs in the medium of drying. The correlation between the evaporation rate and the drying temperature and humidity of the cigarette flakes was found to be positive.

Effect of moisture (2 mol%) on CO2 enhanced desorption from nano-dispersed Na2O/Al2O3 for direct air capture

This study demonstrates enhanced CO2 desorption from nano-dispersed “Na2O”/γ-Al2O3 using a low moisture content purge gas. As little as 2 mol% moisture (generated at the vapor pressure of water at 20 °C) present in an inert purge gas enhances the amount and rate of CO2 desorbed over a series of temperatures relative to a dry purge. Multi-cycle aging tests of 317 h, at various desorption conditions, confirmed the stability of system efficiency with the potential for energy savings in avoiding steam production commonly used for CO2 desorption.

Observations of Water Frost on Mars With THEMIS: Application to the Presence of Brines and the Stability of (Sub)Surface Water Ice

AbstractCharacterizing the exchange of water between the Martian atmosphere and the (sub)surface is a major challenge for understanding the mechanisms that regulate the water cycle. Here we present a new data set of water ice detected on the Martian surface with the Thermal Emission Imaging System (THEMIS). The detection is based on the correlation between bright blue‐white patterns in visible images and a temperature measured in the infrared that is too warm to be associated with ice and interpreted instead as water ice. Using this method, we detect ice down to 21.4°S, 48.4°N, on pole‐facing slopes at mid‐latitudes, and on any surface orientation poleward of 45° latitude. Water ice observed with THEMIS is most likely seasonal rather than diurnal. Our data set is consistent with near‐infrared frost detections and predictions by the Mars Planetary Climate Model. Water frost average temperature is 170 K, and the maximum temperature measured is 243 K, lower than the water ice melting point. Melting of pure water ice on the surface is unlikely due to cooling by latent heat during its sublimation. However, 243 THEMIS images show frosts that are hot enough to form brines if salts are present on the surface. The water vapor pressure at the surface, calculated from the ice temperature, indicates a dry atmosphere in early spring, during the recession of the ice cap. The large amount of water vapor released by the sublimation of warm frost cannot stabilize subsurface ice at mid‐latitudes.

Synthesis pathways of (HfZrTiCe/La/Y)O2-x nanoparticles via benzyl alcohol route at critical temperature

The controllable synthesis of high-entropy fluorite oxide (HEO) having large ionic radius mismatch remains a challenging due to poor understanding on nucleation. The (HfZrTiLn)-5HEO nanoparticles with 15 % ionic radius mismatch were synthesized via benzyl alcohol route at 220 °C-5 min in presence of PtCl4 and Fe(acac)3, exhibiting novel optical, electrical and magnetic properties. Nucleation pathways of the 5HEO at the critical temperature were elucidated by using a comparison study of conventional heating and microwave irradiation heating. Consistency of XRD patterns and STEM-EDX observation indicate that the resultant Hf-OBn monomers acted as the nucleation center of the 5HEO, determined by diffusion kinetics. The nucleation rate depended on the metal monomers assembly and esterification reaction, which was accelerated by water vapor pressure produced in-situ by 0.5×10−4mol/l PtCl4 catalyst. The Fe-metal organic cages derived from 1.5×10−4mol/l Fe(acac)3 additive served as the structure stabilizer of Zr/Ti monomers, and prevented early hydrothermal reaction route.