There is a great need for versatile biomass additives sourced from renewable materials to enhance the performance of polylactic acid (PLA) composites. This study introduces a furan-based polyester elastomer called PNF-PBC that is designed to improve the mechanical and water vapor barrier characteristics of PLA. By incorporating PNF-PBC into PLA, the toughness of the PLA/PNF-PBC biocomposites was considerably enhanced through various intermolecular interactions. A 15 wt% PNF-PBC blend with PLA exhibited a 13.6-fold increase in elongation at break, while having a negligible impact on tensile strength. Furthermore, the water vapor barrier performance of PLA/PNF-PBC biocomposites was greatly boosted by a factor of 10 compared to pure PLA, making them highly suitable for food packaging materials. With its versatile properties, we anticipate that this bio-based PLA/PNF-PBC material will significantly expand the range of applications for PLA composites.
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