Materials For Water Treatment Research Articles

Utilization of efficient Al2O3@g-C3N4 nano sorbent for eliminated Ni (II) ions from polluted water

Toxic metals in water systems pose a global health risk. Thus, multifunctional water monitoring and treatment materials are indispensable. Nickel ions, a frequent heavy metal pollutant, affect ecosystem function. However, developing affordable, functional materials for efficient heavy metal removal remains problematic. This study investigates the utilization of Al2O3@g-C3N4 (AlCN) nanosorbent for adsorbing Ni (II) ions from aqueous solutions. The physicochemical analyses verify the creation of an AlCN nanosorbent with a mean size of 31.25 nm crystals and a specific surface area of 58 m2/g. Batch adsorption experiments were conducted to examine the impact of pH, initial Ni (II) concentration, and adsorbent dose on the efficiency of Ni (II) removal using the synthesized (AlCN) nanosorbent. Adding Al2O3 to g-C3N4 nanosheets increased the adsorption capacity to a maximum of 410 mg/g under ideal conditions, as demonstrated by the results. Ni (II) ions adsorption kinetics on AlCN nanosorbents follow the pseudo-second-order kinetic model with an R2 value of 0.99, surpassing the Elovich pseudo-first model. The adsorption isotherm results show that the Langmuir model fits the experimental data better than the Freundlich and Temkin models, indicating a monolayer adsorption process for the AlCN nanosorbent. In addition, the AlCN exhibited multi-elemental adsorption ability and good recyclability. These findings can nominate the fabricated composite as a candidate for water treatment.

Insights of the La promotion in CoFe-LDH as particle electrodes on degradation process of N-nitrosopyrrolidine in electrocatalytic continuous-flow system

Layered double hydroxides (LDH), as a green, easy to prepare and modify material, has been widely concerned in the field of electrochemical catalytic degradation of difficult to remove pollutants in water. In our work, modified LDH material is synthesized by doping La into the lattice of CoFe-LDH based on its unique electronic structure and large ionic radius, which is used to build the particle electrode to degrade the N-nitrosopyrrolidine (NPYR) in a three-dimensional continuous flow aerated electrocatalytic reactor. The LaCoFe-LDH particle electrodes can generate more active free radicals under electric field, which are beneficial to the degradation of pollutants. The degradation effect of NPYR in the system is satisfactory, and the removal rate reached 83.3% within 90 min. According to the results of characterization analysis, radical quenching experiment, and EPR test, La doping improves the electron transfer ability of the catalyst, which effectively accelerates the redox cycle of Fe2+/Fe3+ and Co2+/Co3+ to achieve sustainable catalysis of particle electrodes to form free radicals, thus enhancing the degradation of NPYR. The DFT calculation results of CoFeLa-LDH show that the energy required for oxygen adsorption by CoFeLa-LDH (-6.79 eV) is lower than that of CoFe-LDH (-6.08 eV), illustrating the improved adsorption properties of the material after La doping. According to the detection results of GC-MS and LC-MS, the possible degradation path of NPYR is proposed. Moreover, the toxicity of the products after degradation of NPYR is generally reduced, indicating that the system is environmentally friendly. The study provides new insights into the design of electrocatalytic materials in water treatment.

Natural mineral raw materials as granular filtering materials in industrial and waste water treatment

Analysis of currently existing methods of natural and waste water treatment from heavy metals has shown that one of the most promising is the sorption method using natural inorganic materials as sorbents: zeolite, diatomite, and vermiculite. The relevance of the topic is dictated by the need to develop an original technology of wastewater treatment and water treatment, which allows constant monitoring of the level of pollution of natural waters by industrial wastewater from metallurgical enterprises. The proposed methods of sorbent modification create a basis for studying the structure, porosity, and sorption capabilities of the mentioned natural materials. All three minerals: zeolite, diatomite, and vermiculite belong to highly porous, structured materials, promising for use as stable sorption systems in water treatment and water purification. The influence of physical and chemical characteristics of natural sorbents and the application of new promising environmentally safe materials and reagents for water treatment are considered. The sorption of copper ions on natural zeolite material before and after its modification by hydrothermal method was investigated. The activity of sorbents was estimated by the value of sorption capacity, i.e. the amount of heavy metal ions absorbed by a unit mass of sorbent based on zeolite and its modified form.

Recovery of cellulose acetate bioplastic from cigarette butts: realization of a sustainable sorbent for water remediation

Cigarette butts, one of the most common forms of litter in the world, represent a source of chemical and plastic pollution releasing thousands of toxic compounds and microfibers of cellulose acetate (CA). Besides the correct waste management, the recovery of CA from cigarette filters is a way to cushion their negative effects on the environment. Thus far, recycling strategies have been limited to industrial applications, while not many solutions have designed for water remediation. This work describes a strategy to valorize this harmful waste and to reverse its environmental impact, proposing a simple and effective procedure of reclamation of CA and its reuse to prepare a composite sorbent for the treatment of polluted water. The first step entails the washing of filters with hot water (T = 90 °C) and hot ethanol (T = 58–68 °C) to remove the impurities produced during cigarette burning, as verified by means of UV and attenuated total reflection-Fourier-transform infrared (ATR-FTIR) spectroscopy, thermal gravimetric analysis (TGA), and differential scanning calorimetry (DSC). The second step involves the use of the regenerated CA to prepare porous cylinder-shaped cryogels (15 mm × 10 mm) whose sorption properties are enhanced by the combination with AC (15 % w/w). The synthesis takes advantage of the sol-gel transition of the polymer dispersion (5 % w/V) in a solution acetone/water 5 mM in NH3 (60/40, v/v). After characterization by dynamic mechanical analysis (DMA), TGA, FT-IR, and scanning electron microscopy (SEM), the adsorption capability of the physical cryogel was studied in terms of treated environmental water volume, contact time and concentration of the selected pollutants. The results have shown that the proposed strategy is a low-cost way to recycle CA from cigarette butts and that the designed sorbent is a promising material for water treatment, allowing quick removal times and yields >79.6 %.

Polyaniline doping induced abundant active sites in orange peel as an efficient adsorbent material for water treatment

Polyaniline doping induced abundant active sites in orange peel as an efficient adsorbent material for water treatment

Effect on the adsorption performance and mechanism of antibiotics tetracyclines by the magnetic biochar used peanut shells as raw materials

Widespread environmental pollution caused by the misuse of tetracyclines (TCs) has become a global issue, necessitating the development of water treatment materials for antibiotic removal. Magnetic biochar (MBC) possesses several advantages, including a wide range of raw material sources and low cost, making it a potential adsorbent that overcomes the limitations of biochar (BC) regarding solid–liquid separation. In this study, peanut shell-derived magnetic biochar loaded with Fe3O4 (Fe3O4/BC) was prepared to study its adsorption performance and environmental factors for TCs. The adsorption mechanism was revealed using adsorption isotherms, adsorption kinetics and thermodynamics. The results showed that the total pore volume was increased, and surface oxygen-containing functional groups were formed of that before BC modification. In a wide pH range, Fe3O4/BC showed high adsorption performance for TCs, with an adsorption rate of over 85%. Chemical adsorption was the main adsorption mechanism, including hydrogen bonding, as well as π-π interactions, electrostatic interactions, intrapore diffusion and hydrophobic interactions. Moreover, reusability and obtaining cost of the material were analyzed, demonstrating its promising application prospects. This study will promote the application of Fe3O4/BC in the removal of antibiotics pollutants from water.

From Nano Zero-Valent Iron to Nanocomposite Materials for Sustainable Water Treatment

Nano zero-valent iron (nZVI) is a well-known and effective remediation agent for various water contaminants. However, the challenges associated with its application, such as agglomeration and difficulty in recovery, have limited its effectiveness in large-scale treatment processes. In recent years, the development of nZVI nanocomposites has shown promise in addressing these challenges, as they offer improved stability, reactivity, and recoverability. This paper reviews the latest advancements in nZVI nanocomposites for water treatment and discusses their potential for the sustainable remediation of various contaminants, including heavy metals, organic contaminants, and emerging contaminants. The potential applications, limitations, and future prospects of nZVI nanocomposites in water treatment are discussed in detail. Overall, the findings suggest that nZVI nanocomposites have significant potential for sustainable water treatment and can contribute to the development of cost-effective and environmentally friendly water treatment solutions.

Silver nanoparticles modified titanium carbide MXene composite for RSM-CCD optimised chloride removal from water

Unsafe levels of chloride in drinking water can make it unpalatable, susceptible to infrastructure corrosion and prone to heavy metals mobility. Conventional chloride mitigation strategies are subjected to inefficient performance and costly operation, necessitating innovations for more sustainable, affordable, and scalable technologies. In this study, silver nanoparticles-modified Ti3C2 MXene nanocomposite (AgMX) is synthesised via dry impregnation method for effective removal of chloride ion from water. The composite physicochemical properties were thoroughly characterised using various analytical techniques, including TEM, SEM, XRD, EDS, BET, zeta potential and pHpzc analysis. The experimental testing was optimised using CCD-RSM method in terms of adsorbent dosage (0.2–2 g/L), reaction time (1–17 min), and chloride concentration (10–90 mg/L). Under optimal conditions (adsorbent:1.55 g/L, time: 12.19 min, & concentration: 52.17 mg/L), a promising chloride removal of 91.8 % was achieved. Langmuir model showed the best fit to adsorption isotherm (R2: 0.9852) comparing to Freundlich and Dubinin-Kaganer-Radushkevich (DKR) isotherms, while pseudo-second-order kinetic model offered the closest data to the experimental results (R2: 9893) compared to the pseudo-first-order, Elovich and Intraparticle diffusion models R2: 0.2335,0.1212 and 0.2050, respectively. The composite reusability and regeneration potential after four repeated cycles were found practically efficient as ≥ 68 % and ≥ 84 %, respectively. The outcomes of this study can demonstrate the efficiency of the formulated composite as a promising material for the sustainable treatment of chloride-contaminated water.

Exploring recyclable alginate-enhanced GCN-LDO sponge for U(VI) and Cd(II) removal: Insights from batch and column studies

Developing effective water treatment materials, particularly through proven adsorption methods, is crucial for removing heavy metal contaminants. This study synthesizes a cost-effective three-dimensional material encapsulating graphitic carbon nitride-layered double oxide (GCN-LDO) in sodium alginate (SA) through the freeze-drying method. The material is applied to remove uranium (U(VI)) and cadmium (Cd(II)) in real water systems. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) analyses conclusively verified the elemental composition and successful encapsulation of GCN-LDO within the SA matrix. Removal effectiveness was tested under various conditions, including adsorbent dose, ionic strength, contact time, temperature, different initial pollutant concentrations, and the impact of co-existing ions. The adsorption of U(VI) and Cd(II) conformed to the pseudo-second-order (PSO) kinetic model, signifying a chemical interaction between the sodium alginate-graphitic carbon nitride-layered double oxide (SA-GCN-LDO) sponge and the metal ions. The Langmuir isotherm indicated monolayer, homogeneous adsorption for U(VI) and Cd(II) with capacities of 158.25 and 165.00 mg/g. SA-GCN-LDO recyclability was found in up to seven adsorption cycles with a removal efficacy of 70%. The temperature effect study depicts the exothermic nature of the U(VI) and Cd(II) ion removal process. Various mechanisms involved in U(VI) and Cd(II) removal were proposed. Further, continuous fixed bed column studies were performed, and Thomas and the Yoon-Nelson model were studied. These insights from this investigation contribute to advancing our knowledge of the material's performance within the context of U(VI) and Cd(II) adsorption, paving the way for optimized and sustainable water treatment solutions.

Adsorption of PO43−, Cd(II), Pb(II), Cu(II), As(III), and As(V) using the La-based and modified La-based metal–organic framework materials

Metal–organic framework (MOF) materials are novel adsorption materials for water treatment. In this study, La-MOF ({[La2(H2DHTPA)3(H2O)7]·4H2O}n, H4DHTPA denotes 2,5-dihydroxyterephthalic acid) was synthesized by a hydrothermal method. The material had a strong water stability, but its adsorption performance was weak and its processability was poor. K-La-MOF, with good processability, was obtained using a potassium permanganate oxidation modification method to modify the La-MOF. The results showed that the maximum adsorption capacity (qmax) of the La-MOF for PO43− was 72.19 mg/g, and the adsorption was monolayer chemical adsorption. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) showed that P was adsorbed on the surface of the La-MOF material in the form of HPO42−. The adsorption properties of the K-La-MOF were also investigated. The results showed that the maximum adsorption capacities of the K-La-MOF for PO43−, Cd(II), Pb(II), Cu(II), As(III), and As(V) were 87.56, 37.08, 992.99, 190.51, 42.20, and 131.66 mg/g, respectively. The adsorption of PO43−, Cd(II), Cu(II), and As(III) by the K-La-MOF was determined to be monolayer chemisorption by fitting adsorption isotherm and kinetics models. The adsorption process of Pb(II) by the K-La-MOF involved both single-molecular-layer and lateral-multi-molecular-layer chemisorption. In contrast, the adsorption of As(V) by the K-La-MOF occurred through both monolayer chemical adsorption and pore physical adsorption. XRD and XPS analyses showed that P, Cd(II), Pb(II), Cu(II), As(III), and As(V) were adsorbed on the K-La-MOF in the forms of PO43−, CdO, PbO and Pb(OH)2, CuO, K3AsO4, and K4As2O7, respectively.

Interfacial assembly of polyamide nanofilm membranes regulated by surfactants with different structural characteristics

Polyamide (PA) nanofilm membranes are key materials for water treatment and desalination. Although surfactants are widely used to tune the interfacial polymerization (IP) process for PA nanofilm formation, their regulatory mechanisms remain incompletely understood. Herein, we synthesized PA nanofilm membranes at a support-free interface in the presence of anionic surfactants with different tail lengths and counterions and comprehensively characterized them to identify the IP mechanism regulated by the surfactant structure. The use of the surfactant with a longer alkyl tail or a smaller/weaker-bound counterion resulted in greater alterations in the structural and physicochemical properties and separation performance of the PA nanofilm membranes. Collaborated with computational simulations, this phenomenon could be attributed to solutal Marangoni instability triggered by the interfacial migration (via binding to PA) of the surfactant complexed with amine monomers during IP. A longer alkyl chain or smaller/weaker-bound counterion of the surfactant intensified Marangoni instability by promoting the interfacial formation of surfactant–amine complexes and/or facilitating their binding to PA, leading to greater PA deformations. Our work provides new insights into the surfactant-regulated IP mechanism as well as a facile means to rationally tailor the properties and performance of IP-assembled nanofilm membranes for various environmental applications.

Insights into kinetics, thermodynamics, and mechanisms of chemically activated sunflower stem biochar for removal of phenol and bisphenol-A from wastewater

This study synthesized a highly efficient KOH-treated sunflower stem activated carbon (KOH-SSAC) using a two-step pyrolysis process and chemical activation using KOH. The resulting material exhibited exceptional properties, such as a high specific surface area (452 m2/g) and excellent adsorption capacities for phenol (333.03 mg/g) and bisphenol A (BPA) (365.81 mg/g). The adsorption process was spontaneous and exothermic, benefiting from the synergistic effects of hydrogen bonding, electrostatic attraction, and stacking interactions. Comparative analysis also showed that KOH-SSAC performed approximately twice as well as sunflower stem biochar (SSB), indicating its potential for water treatment and pollutant removal applications. The study suggests the exploration of optimization strategies to further enhance the efficiency of KOH-SSAC in large-scale scenarios. These findings contribute to the development of improved materials for efficient water treatment and pollution control.

Green, Low-carbon Silk-based Materials in Water Treatment: Current State and Future Trends.

The improper and inadequate treatment of industrial, agricultural, and household wastewater exerts substantial pressure on the existing ecosystem and poses a serious threat to the health of both humans and animals. To address these issues, different types of materials have been employed to eradicate detrimental pollutants from wastewater and facilitate the reuse of water resources. Nevertheless, owing to the challenges associated with the degradation of these traditional materials post-use and their incompatibility with the environment, natural biopolymers have garnered considerable interest. Silk protein, as a biomacromolecule, exhibits advantageous characteristics including environmental friendliness, low carbon emissions, biodegradability, sustainability, and biocompatibility. Considering recent research findings, this comprehensive review outlines the structure and properties of silk proteins and offers a detailed overview of the manufacturing techniques employed in the production of silk-based materials (SBMs) spanning different forms. Furthermore, it conducts an in-depth analysis of the state-of-the-art SBMs for water treatment purposes, encompassing adsorption, catalysis, water disinfection, desalination, and biosensing. The review highlights the potential of SBMs in addressing the challenges of wastewater treatment and provides valuable insights into prospective avenues for further research.

A Critical Review of Two-Dimensional Nanomaterial MXenes and their Applications in Water Treatment

: Environmental pollution has accelerated and intensified because of the acceleration of industrialization, therefore fabricating excellent materials to remove hazardous pollutants has become inevitable. MXenes as emerging transition metal nitrides, carbides, or carbonitrides with high conductivity, hydrophilicity, excellent structural stability, and versatile surface chemistry, become ideal candidates for water treatment. This review summarizes recent advances in the synthesis and applications of MXenes as adsorbents, photocatalysts, and separation membranes for water purification. Extensive information related to the synthesis and applications of MXenes for water treatment and their associated patents were collected. This review has given a comprehensive survey of the recently reported 2D nanomaterial (NM) MXenes which are used in various water treatment applications. The effects of structure control, surface modification and composite of MXene on the adsorption performance of MXene and the formation of effective heterojunction, photocatalysts separation membrane were discussed in detail. The existing problems in the water treatment applications of MXene were summarized and analyzed. The overview also features discussions on the computational attempts, biocompatibility, and environmental impact in the exploration of MXenes for applications of water treatment, highlighting the challenges and opportunities of these advanced 2D NMs. The prospects of designing MXene based water treatment materials with excellent performance were put forward.

Mechanochemical synthesis of microscale zero-valent iron/N-doped graphene-like biochar composite for degradation of tetracycline via molecular O2 activation

In this study, we prepared a micron zero-valent iron/N-doped graphene-like biochar (mZVI/NGB) composite using a mechanochemical method for tetracycline (TC) degradation through O2 activation. The mZVI and NGB components formed a strong coupling catalytic system, with mZVI acting as an electron pool and NGB as a catalyst for H2O2 generation. Under circumneutral pH (5.0–6.8), the mZVI/NGB composite exhibited exceptional TC removal efficiency, reaching nearly 100 % under optimal conditions. It also showed good tolerance to co-existing anions, such as Cl-, SO42-, and humic acid. Further studies found that the TC degradation mechanism was mainly ascribed to the non-radical pathway (1O2 and electron transfer), and the Fe2+/Fe3+ redox cycle on the composite's surface also played a crucial role in maintaining catalytic activity. This research contributes to the development of advanced materials for sustainable and effective water treatment, addressing pharmaceutical pollutant contamination in water sources.

Spicing up membrane distillation: Enhancing PVDF membrane performance with cinnamic acid

The increasing demand for freshwater is driving the rapid development of new water treatment materials. Furthermore, there is significant pressure to replace the toxic substances often used in membrane production with environmentally friendly, biocompatible, and natural compounds. In this work, poly(vinylidene fluoride) (PVDF) membranes were modified for the first time with a naturally occurring, non-toxic, biodegradable substance – cinnamic acid. The application of its molecules for membrane modification allows for diminishing the problem of bioaccumulation and toxicity in the environment. The procedure was selected with the accordance of green chemistry principles (green modifier – cinnamic acid, and green solvent – ethanol), and employed to chemically bind the modifier to the membrane surface. The modified membranes exhibited an increase in the hydrophobicity of the surface. The water contact angle increased from 124.7° for the pristine membrane to 139.3° for the membrane modified with a 10 % concentrated solution of cinnamic acid (PVDF-Cin10). All membranes possessed an excellent salt rejection coefficient. Membrane antiwetting features have been determined under challenging conditions of salt (3 M NaCl) and low surface tension liquid (sodium dodecyl sulfate). The dynamic goniometric studies were implemented to evolve membranes' wetting stability.

수처리용 섬유여과기 성능평가인자 도출 및 평가방법개발에 관한 연구

This study investigated the performance evaluation factors for the fiber filtration process in water treatment and researched the performance evaluation items and methods for assessing these factors. South Korea's water supply and sewage policies focus on modernizing civil structures and networks and introducing advanced treatment facilities. Reflecting these policies, the Waterworks Act describes the minimum requirements that water supply facilities must meet to ensure a consistent quality (water quality) of drinking water. Therefore, the Waterworks Act has introduced usage standards for water treatment processes and materials for water supply to manage the quality of drinking water. Firstly, the Ministry of Environment has issued water supply facility standards, which explain the minimum standards for water supply facilities. Secondly, there are hygiene and safety standards (suitability certification) and group standard certification. Standards and certifications are established to evaluate materials and products suitable for water supply facilities. Thus, two criteria are required to apply them to water supply facilities.
 In Republic of Korea, a new concept of water treatment process has been developed that can replace traditional water treatment processes. This involves a fiber filtration process that contracts and relaxes fiber strands, removing turbidity and suspended solids. There is a movement to adopt this process. Such fiber filters can provide better treatment efficiency, use smaller sites, and have faster processing speeds. However, the use of different evaluation methods by manufacturers has prevented consumers from accurately understanding the performance and raised doubts about the reliability of the technology.
 The result of this study is the development of a standardized performance evaluation method, and the derivation of performance evaluation factors for fiber filters. Through standardized performance evaluation factors and methods, an objective performance evaluation of the fiber filtration process can be conducted.

Bio-Based Aerogels for the Removal of Heavy Metal Ions and Oils from Water: Novel Solutions for Environmental Remediation.

Contamination of the aqueous environment caused by the presence of heavy metal ions and oils is a growing concern that must be addressed to reduce their detrimental impact on living organisms and safeguard the environment. Recent efficient and environmentally friendly remediation methods for the treatment of water are based on third-generation bioaerogels as emerging applications for the removal of heavy metal ions and oils from aqueous systems. The peculiarities of these materials are various, considering their high specific surface area and low density, together with a highly porous three-dimensional structure and tunable surface chemistry. This review illustrates the recent progress in aerogels developed from cellulose and chitosan as emerging materials in water treatment. The potential of aerogel-based adsorbents for wastewater treatment is reported in terms of adsorption efficacy and reusability. Despite various gaps affecting the manufacturing and production costs of aerogels that actually limit their successful implementation in the market, the research progress suggests that bio-based aerogels are ready to be used in water-treatment applications in the near future.

Structure Evolution of Iron (Hydr)oxides under Nanoconfinement and Its Implication for Water Treatment.

In the development of nanoenabled technologies for large-scale water treatment, immobilizing nanosized functional materials into the confined space of suitable substrates is one of the most effective strategies. However, the intrinsic effects of nanoconfinement on the decontamination performance of nanomaterials, particularly in terms of structural modulation, are rarely unveiled. Herein, we investigate the structure evolution and decontamination performance of iron (hydr)oxide nanoparticles, a widely used material for water treatment, when confined in track-etched (TE) membranes with channel sizes varying from 200 to 20 nm. Nanoconfinement drives phase transformation from ferrihydrite to goethite, rather than to hematite occurring in bulk systems, and the increase in the nanoconfinement degree from 200 to 20 nm leads to a significant drop in the fraction of the goethite phase within the aged products (from 41% to 0%). The nanoconfinement configuration is believed to greatly slow down the phase transformation kinetics, thereby preserving the specific adsorption of ferrihydrite toward As(V) even after 20-day aging at 343 K. This study unravels the structure evolution of confined iron hydroxide nanoparticles and provides new insights into the temporospatial effects of nanoconfinement on improving the water decontamination performance.

Vertical porous aerogel based on polypyrrole and bimetallic modified β-cyclodextrin polymer-chitosan for efficient solar evaporation

Solar-driven interfacial evaporation (SDIE) stands out as a prospective technology for freshwater production, playing a significant role in mitigating global water scarcity. Herein, a cyclodextrin polymer/chitosan composite aerogel (PPy-La/Al@CDP-CS) with vertically aligned channels was prepared as a solar evaporator for efficient solar steam generation. The vertically aligned pore structure, achieved through directional freezing assisted by liquid nitrogen, not only improves water transport during evaporation but also enhances light absorption through multiple reflections of sunlight within the pores. The polypyrrole particles sprayed on the surface of the aerogel acted as a light-absorbing layer, resulting in an impressive absorbance of 98.15 % under wetting conditions. The aerogel has an evaporation rate of 1.85 kg m−2 h−1 under 1 kW m−2 irradiation. Notably, the vertical pore structure of the aerogel allows it to exhibit excellent evaporation performance and salt resistance even in highly concentrated salt solutions. Furthermore, this aerogel is an excellent solar-driven interfacial evaporator for purifying seawater and fluoride-containing wastewater. This photothermal aerogel has the advantages of excellent performance, low cost, and environmental friendliness, and thus this work provides a new approach to the design and fabrication of solar photothermal materials for water treatment.