Mixed Water Research Articles

A single‐sided 1H NMR study of the self‐drying properties of a ternary self‐levelling underlayment

AbstractSelf‐leveling underlayments (SLU) are used for smoothing and levelling sub‐floors before any flexible flooring is applied. Though being comparatively simple in its requirements, commercial SLUs have become one of the most complex cementitious mixtures in dry‐mortar technology. By using ternary binders, most SLUs are designed to be self‐drying, binding most of the mixing water in crystalline cementitious phases, allowing a fast work progress. In this study, the simultaneous hydration and drying of a commercial SLU are monitored with single‐sided 1H nuclear magnetic resonance (NMR). This technique allows the quantification of chemically bound water and water in different pore environments with superior time and depth resolution. The technique is combined with conventional testing techniques enabling a more comprehensive view on the processes at hand. Results allow quantification of hydration and self‐drying, superimposed by physical drying effects over time. Additionally, the drying of a PVC adhesive through water absorption into a well‐dried SLU are visualized with this technique. The results are discussed in the context of moisture transport processes and floor‐laying readiness of the material.

Spatial and Temporal Characteristics of Winter Diel Vertical Migration of Zooplankton and Nekton in the East China Shelf Seas Based on Multi‐Frequency Echosounder

AbstractThe diel vertical migration (DVM) of plankton and nekton plays an important role in the energy flow and material cycling of marine ecosystems. Especially in shelf seas, seasonal environmental variations may distinguish DVM characteristics in winter mixed water from summer pattern. Therefore, to investigate the patterns and influencing factors of winter DVM in East China Shelf Seas (ECSS), we carried out comprehensive research based on high‐resolution multi‐frequency acoustic data during the winter of 2019/2020. The results showed that: (a) acoustic and zooplankton sampling data can effectively capture the widely existence of winter DVM of different biological community in ECSS and their spatio‐temporal variabilities. (b) In East China Sea, the migration was mainly dominated by the Gas‐bearing class (GB), which had fast migration speed, compared to the Yellow Sea where the migration was dominated by the Fluid‐like class (FL). In addition, GB descends earlier than FL. (c) For large scale factors, during the full moon, the GB will aggregate deeper and the FL shallower, compared to the new moon, and regional temperature is an important factor affecting the distribution of organisms at meridional direction; for small scale processes, cold and warm currents and ocean fronts can also affect migration behavior. In the muddy area with full moon and spring tide, GB and FL show different inconsistent migration compared to normal relatively consistent pattern. These results will help us to better understand the physiological, ecological and environmental elements that control winter DVM, facilitating the management of ecosystem‐based fisheries resources.

Rheological Investigation of a Set of PCE Superplasticizers in Cement

AbstractThe importance of polycarboxylate ethers (PCE) as concrete superplasticizers has significantly increased in recent decades, both technically and commercially. At the least, three descriptors describe the average PCE structure: the side chain length (P), the charge density (N), and the number of repeating units (n). The synthesis parameters determine the average composition of the PCEs and, consequently, their performance in cementitious materials. This study examines the rheological properties of 27 different PCE structures, which were synthesized using redox‐initiated free‐radical copolymerization. We independently varied the parameters P and N and produced three PCEs with different molar weights for each combination of P and N. Cement pastes with low PCE dosages of 0.035 wt% were tested in a rheometer using a plate‐plate geometry. It turns out that when the PCE is added directly to the mixing water, the PCE has a complex influence on the very early hydration. Consequently, the obtained rheology data is not entirely in line with available structure‐activity relationships. Additionally, we attempted to model the observed rheology data based on three structural PCE descriptors. While a multivariate linear regression model failed to accurately describe the relationship, a random forest model delivered a better model. In summary, we conclude that the impact of PCEs on early hydration significantly affects the rheology of the paste. The changed hydration pathway causes a deviation of our results from existing structure‐activity relationships and makes it challenging to statistically model the sparse rheology data with a minimal set of three structural descriptors.

The Mitigating Effects of Water Sound Attributes on Stress Responses to Traffic Noise

Traffic noise is a significant risk factor for adverse health outcomes. Despite burgeoning interest in reducing the harmful health effects of traffic noise, research on the influence of physical and psychoacoustic attributes has been sparse. Consequently, this study examines the impacts of various acoustic attributes on mitigating stress response to traffic noise using dependent variables derived from electrodermal activity. The results indicate that: (a) mixing water sound (noise) at a low signal-to-noise ratio effectively mitigated stress response to traffic noise (signal), whereas mixing white noise with high fractal complexity (noise) significantly induced stress; and (b) sound pressure and acoustic sharpness significantly reduced stress response to traffic noise. Conversely, attributes such as high fractal complexity, moderate and high signal-to-noise ratios, acoustic loudness, and mean frequency significantly increased stress. This research offers a viable blueprint for creating evidence-based noise mitigation strategies that focus on intervention sound attributes.

Linking Water Age, Nitrate Export Regime, and Nitrate Isotope Biogeochemistry in a Tile‐Drained Agricultural Field

AbstractAccurately quantifying and predicting the reactive transport of nitrate () in hydrologic systems continues to be a challenge, due to the complex hydrological and biogeochemical interactions that underlie this transport. Recent advances related to time‐variant water age have led to a new method that probes water mixing and selection behaviors using StorAge Selection (SAS) functions. In this study, SAS functions were applied to investigate storage, water selection behaviors, and export regimes in a tile‐drained corn‐soybean field. The natural abundance stable nitrogen and oxygen isotopes of tile drainage were also measured to provide constraints on biogeochemical transformations. The SAS functions, calibrated using chloride measurements at tile drain outlets, revealed a strong young water preference during tile discharge generation. The use of a time‐variant SAS function for tile discharge generated unique water age dynamics that reveal an inverse storage effect driven by the activation of preferential flow paths and mechanically explain the observed variations in isotopes. Combining the water age estimates with isotope fingerprinting shed new light on export dynamics at the tile‐drain scale, where a large mixing volume and the lack of a strong vertical contrast in concentration resulted in chemostatic export regimes. For the first time, isotopes were embedded into a water age‐based transport model to model reactive transport under transient conditions. The results of this modeling study provided a proof‐of‐concept for the potential of coupling water age modeling with isotope analysis to elucidate the mechanisms driving reactive transport.

Development of artificial leak-free phase change material (PCM) aggregates using emulsion technique, cementless binder, and cold-bonded pelletization

The present study developed new leak-free artificial PCM aggregates using an emulsion technique, cementless binder, and cold-bonded pelletization (hereafter, PCM-surfactant-aggregate) and significantly increased the PCM quantity in aggregates without PCM leakage, which was demonstrated from differential scanning calorimetric (DSC) and thermogravimetry (TG) results. The PCM-water-emulsion was produced by using a non-ionic surfactant, Pluronic P123, and used as mixing water to produce cementless artificial aggregates using Ca(OH)2-Na2CO3-activated fly ash and cold-bonded pelletization. The produced artificial PCM-surfactant-aggregates showed no material separation during preparation and no visual PCM leakage on the surface and were lightweight aggregates in terms of compressive strength (ASTM C330). In the concrete testing results, the 28-day compressive strength was 18.1 MPa when all fine and coarse aggregates were replaced with artificial PCM-surfactant-aggregates and the thermal conductivity decreased with increasing aggregate content. The testing on the heated concrete specimens having PCM-surfactant-aggregates indicated no PCM leakage, no dimensional change, and no strength reduction due to the PCM phase transition from solid to liquid. Overall, the concrete containing PCM-surfactant-aggregates showed an increase in the lowest temperature and a decrease in the highest temperature in the temperature profile of the indoor space in the dynamic heat flow test.

Preliminary Experimental Work on Concrete-Fly Ash Compressive Strength Blended with Seawater as Mixing Water

Fly ash is widely used in the construction sector, but application with seawater has not fully utilised. Seawater is used in construction to minimise the scarcity of drinking water. The concrete was strengthened by the application of fly ash. Seawater replacing 100% tapwater as mixing water. Meanwhile, fly ash was substituted with ordinary Portland cement at 10%, 20%, 30%, and 40%. To achive the objective, the 100 mm x 100 mm x 100 mm cube size with 0.33 water-cementitious ratio were prepared. All series of mixture were casted and cured in water for 7 and 28 days. The fly ash blended with seawater in concrete were investigate through its compressive strength. In addition, scanning electron miscroscope were carried out to capture surface image of the specimen. The experimental work result shows, with the existence of fly ash in concrete mixture, it decreases workability, density and compressive strength. Though the decreasing pattern was seen in every series, the structural strength was still deemed adequate.

Fluid evolution and genesis of the Zhuanghuhe Au–Sb mineralization in the Duobaoshan orefield, Northeast China: Evidence from fluid inclusions and H–O–C isotopes

The newly discovered Zhuanghuhe Au–Sb occurrence is located 20 km north of the famous Duobaoshan Cu–Mo deposit, it is the first gold–antimony deposit discovered in the Duobaoshan orefield. The hydrothermal quartz vein-type orebodies occur in the Middle Ordovician Duobaoshan Formation and are controlled by NNW and ENE compressional faults. Four mineralization stages are identified: stage I quartz + pyrite + arsenopyrite, stage II quartz + polymetallic sulfides, stage III quartz + stibnite, and stage IV quartz + calcite. Fluid inclusions (FIs) in quartz and calcite veins include six types: types I (two-phase aqueous), IIa (aqueous–carbonic; the volume of the carbon phase <50 %), IIb (aqueous–carbonic; the volume of the carbon phase >50 %, with more CO2 than CH4), IIc (aqueous–carbonic; the volume of the carbon phase >50 %, with more CH4 than CO2), IIIa (carbonic, with more CO2 than CH4) and IIIb (carbonic, with more CH4 than CO2). FIs of stage I are types I, IIa, IIb and IIIa, with homogenization temperatures of 279–311 °C and salinities of 4.87–11.84 wt%, indicating a medium-temperature low-salinity immiscible NaCl–H2O–CO2 fluid system. Stage II contains all FI types with final homogenization temperatures of 233–288 °C and salinities of 4.94–8.67 wt%, indicating a medium- to low-temperature low-salinity NaCl–H2O–CO2–CH4 system. FIs of stage III contain types I and IIa with homogenization temperatures of 193–240 °C and salinities of 3.85–6.63 wt%, belong to a low-temperature low-salinity NaCl–H2O–CO2 ± CH4 system. FIs of stage IV contain only type I with homogenization temperatures of 158–212 °C and salinities of 2.56–4.01 wt%, indicating a NaCl–H2O system. The H–O–C isotope data show that the NaCl–H2O–CO2 fluids of stage I (δD = −98 to −105.7 ‰, δOH2O = 5.7 to 6.9 ‰, δ13CCO2 = −11.9 to −11.1 ‰) were derived from a magmatic system, the fluids of stage II (δD = −85.7 ‰, δOH2O = 2.8 ‰, δ13CCO2 = −14.2 ‰, δ13CCH4 = −32.5 to −31.9 ‰) were characterized by the addition of CH4, which might have come from the reaction between the original ore-forming fluids and carbonaceous slate of the Duobaoshan Formation. The fluids in stage III (δD = −90.2 to −89.6 ‰, δOH2O = −9.1 to −6.1 ‰) and stage IV (δD = −110.6 to −96.3 ‰, δOH2O = −13.0 to −12.6 ‰) were characterized by mixing of meteoric water. According to the geology, fluid inclusion and H-O-C stable isotope evidences, the initial magma-derived NaCl-H2O-CO2 fluids were immiscible in stage I and then the process of mixing with CH4-bearing fluids in stage II, resulting in the gold precipitation; the precipitation of antimony was mainly related to the temperature drop and the mixing of meteoric water in stage III.

Seasonal Controls of Seawater CO2 Systems in Subtropical Coral Reefs: A Case Study from the Eastern Coast of Shenzhen, China

In situ field investigations coupled with coral culture experiments were carried out in the coral reef waters of the eastern coast of Shenzhen, Da’ao Bay (DAB), Dalu Bay (DLB), and Yangmeikeng Sea Area (YMKSA) to study the dynamics of the carbon dioxide (CO2) system in seawater and its controlling factors. The results indicated that the CO2 parameters were highly variable over a range of spatiotemporal scales, forced by various physical and biochemical processes. Comprehensively, DAB acted as a sink for atmospheric CO2 with exchange flux of –1.51 ± 0.31 to 0.27 ± 0.50 mmol C m−2 d−1, while DLB and YMKSA acted as a CO2 source with exchange fluxes of –0.42 ± 0.36 to 1.69 ± 0.74 mmol C m−2 d−1 and –0.58 ± 0.48 to 1.69 ± 0.41 mmol C m−2 d−1, respectively. The biological process and mixing effect could be the most important factor for the seasonal variation in total alkalinity (TA). In terms of dissolved inorganic carbon (DIC), in addition to biological process and mixing, its seasonal variation was affected by air–sea exchange and coral metabolism to some extent. Different from the former, the other CO2 parameters, total scale pH (pHT), partial pressure of CO2 (pCO2), and aragonite saturation state (ΩA), were mainly controlled by a combination of the temperature change, biochemical processes, air–sea exchange, and coral metabolism, while water mixing has little effect on them. In addition, our results indicated that coral communities could significantly increase the DIC/TA ratio by reducing the TA concentration and increasing the DIC in the reef waters, which may promote the acidification of local seawater and need attention.

Reflecting on changes in the drinking and irrigation water quality of rivers Beas, Satluj and confluence waters.

Prevention and control of water pollution for maintaining and restoring the wholesomeness of rivers are unavoidable. The current water quality approach of designated best use has some limitations such as it is non-integrative and inflexible with regard to the consideration of variables and does not provide a separate rating scale for a given designated use. We thus used water quality index approach proposed by the Canadian Council of Ministers of the Environment (CCME WQI) to evaluate and develop a separate rating system for drinking and irrigation purposes of rivers Beas, Satluj and their confluence water of the Indian Punjab using information collected over 4 years (2016 to 2019). River Beas exhibited better water quality compared to river Satluj for irrigation as well as for drinking. The overall drinking water quality index (DWQI) for Beas was marginal (45.5), whereas it was poor for Satluj (37.7) and confluence waters (40.1). The spatial variation in DWQI was greater for Satluj compared to Beas and confluence waters reflecting the effect of dumping of untreated industrial and domestic waste waters. Variables such as Total coliform (T. coli), dissolved oxygen (DO), turbidity and biological oxygen demand (BOD) contributed to the deterioration of DWQI. The irrigation water quality index (IWQI) was good for Beas (86), marginal for Satluj (60.1) and fair for confluence waters (71.2). Faecal coliform (F. coli), Kelly ratio (KR) and %Na contributed to the deterioration of IWQI. Calcium-magnesium-bicarbonate (Ca-Mg-HCO3) was the dominant water type in Beas and confluence waters, whereas for Satluj, in addition to Ca-Mg-HCO3, sodium-potassium-chloride-sulphate and mixed water types were also prevalent. The river waters witnessed salinity hazard but did not pose sodicity hazard except at a few locations of Satluj. The study indicates the need to take location specific measures for improving river water quality for drinking as well as irrigation purposes. The current status of water quality calls for an urgent need to formulate stringent policy regulations to maintain the surface water quality.

Relationship between the colours of the rivers in the Amazon and the incidence of malaria

BackgroundMalaria is transmitted by different Anopheles species. In Brazil, the disease is concentrated in the Amazon region. Rivers play an important role in the life cycle of malaria since the vector reproduces in aquatic environments. The waters of the rivers in the Amazon have distinct chemical characteristics, which affect the colour of the water and therefore, the study analysed whether the colour of the waters of the rivers have an on influence the distribution of malaria. The goal of the study was to correlate the different colourations of the water (black, white and mixed water) and the malaria incidence in 50 municipalities of the Amazonas state, Brazil, and then test hypotheses about the characteristics of the colour of the rivers and disease incidence.MethodsThis study was conducted for a period of seventeen years (2003–2019) in 50 municipalities in the state of Amazonas, Brazil. A conditionally Gaussian dynamic linear model was developed to analyse the association of malaria incidence and three types of river colour: white, black and mixed.ResultsThe analyses indicate that the distribution of malaria is related to the colouration of the rivers. The results showed that places located near black-water rivers have a higher malaria incidence when compared to places on the banks of white-water rivers.ConclusionsHistorically, the hydrological regime has played an important role in the dynamics of malaria in the Amazon, but little is known about the relationship between river colours and the incidence of the disease. This research was carried out in a region with hydrographic characteristics that were heterogeneous enough to allow an analysis that contrasted different colours of the rivers and covered almost the whole of the state of Amazonas. The results help to identify the places with the highest risk of malaria transmission and it is believed that they will be able to contribute to more precise planning of actions aimed at controlling the disease in the region.

Hyaluronan oligosaccharides form double-helical duplexes in water:1,4-dioxane mixed solvent

Hyaluronic acid (HA) is a hydrophilic natural polysaccharide consisting of alternating monosaccharide units of glucuronic acid and N-acetyl glucosamine. In aqueous solutions the electrostatic repulsion of the carboxylate groups hampers the formation of supermolecular structures that can be partially stabilized by the addition of salt. Increased permittivity of the mixed water:organic solvents causes better compensation of the negative charge of HA chains by dissolved cations which changes their interactions with other molecules. In this study we simulate interactions of two HA chains in water:1,4-dioxane and water:tert-butanol mixed solvents with varying NaCl concentrations using molecular dynamics (MD). Anti-parallel double-helix-like duplexes are formed in NaCl-containing water:1,4-dioxane mixture and remain stable even when NaCl is removed. Parallel duplexes separate after a short time. In water:tert-butanol analogous duplexes are unstable. Stability of HA duplexes is thus determined by the solvent composition and the ability of its components to separate in the solvation shell of HA molecules, as well as by the mutual orientation of the chains.

Effect of Water Magnetization Technique on the Properties of Metakaolin-Based Sustainable Concrete

Using metakaolin (MK) in concrete with magnetized water (MW) has a high possibility to enhance concrete suitability. In this study, the effect of using MK and MW on concrete characteristics was studied through testing twelve concrete mixes. Seven ratios of MK were used in this study, namely 0%, 5%, 10%, and 20%, as an alternative to cement and +5%, +10%, and +20% as a cement additive. In addition, five water magnetization methods were applied on MK concrete. In the first stage of this study, the impact of different MK ratios on the workability of concrete, compressive strength, flexural strength, and tensile strength was studied using traditional tap water (TW) as the concrete mixing water. In the second stage, the best mix (best MK ratio) from the first stage was chosen to study the effect of the water magnetization method on concrete properties and to determine the best method for water magnetization. Scanning electronic microscope (SEM) analysis was also carried out on selected mixes to closely investigate the effect of MK and MW on concrete microstructure. The results showed that the best ratio of MK in concrete was +10% (MK as a 10% cement addition), and the best water magnetization method was to pass the water through 1.6 tesla then through 1.4 tesla magnetic fields. The SEM analysis confirmed the absence of pores after using MW instead of regular TW by increasing the calcium silicate hydrate (CSH) gel and reducing calcium hydroxide (CH). Using MK and MW enhanced the compressive strength by up to 33%, 32%, and 27% at 7, 28, and 365 days, respectively, and MW enhanced the workability by up to 3% compared to that of the control mix.

Monitoring galactolipid digestion and simultaneous changes in lipid-bile salt micellar organization by real-time NMR spectroscopy

The use of Nuclear Magnetic Resonance spectroscopy for studying lipid digestion in vitro most often consists of quantifying lipolysis products after they have been extracted from the reaction medium using organic solvents. However, the current sensitivity level of NMR spectrometers makes possible to avoid the extraction step and continuously quantify the lipids directly in the reaction medium. We used real-time 1H NMR spectroscopy and guinea pig pancreatic lipase-related protein 2 (GPLRP2) as biocatalyst to monitor in situ the lipolysis of monogalactosyl diacylglycerol (MGDG) in the form of mixed micelles with the bile salt sodium taurodeoxycholate (NaTDC). Residual substrate and lipolysis products (monogalactosyl monoacylglycerol (MGMG); monogalactosylglycerol (MGG) and octanoic acid (OA) were simultaneously quantified throughout the reaction thanks to specific proton resonances. Lipolysis was complete with the release of all MGDG fatty acids. These results were confirmed by thin layer chromatography (TLC) and densitometry after lipid extraction at different reaction times. Using diffusion-ordered NMR spectroscopy (DOSY), we could also estimate the diffusion coefficients of all the reaction compounds and deduce the hydrodynamic radius of the lipid aggregates in which they were present. It was shown that MGDG-NaTDC mixed micelles with an initial hydrodynamic radius rH of 7.3 ± 0.5 nm were changed into smaller micelles of NaTDC-MGDG-MGMG of 2.3 ± 0.5 nm in the course of the lipolysis reaction, and finally into NaTDC-OA mixed micelles (rH of 2.9 ± 0.5 nm) and water soluble MGG. These results provide a better understanding of the digestion of galactolipids by PLRP2, a process that leads to the complete micellar solubilisation of their fatty acids and renders their intestinal absorption possible.

Chloride binding mechanism and free chloride reduction method of alkali-activated slag/fly ash mixed with seawater

The chloride binding mechanism of alkali-activated materials (AAM) under various granulated blast furnace slag (GBFS)/fly ash (FA) ratios is investigated in this work. Two types of layered double hydroxides (LDH), i.e., MgAl-LDH and CaAl-LDH, and active magnesium oxide (MgO) were added to reduce the concentration of free chloride in AAM. The results demonstrate that the ratio of GBFS to FA has non-negligible influence on the AAM’s ability to bind chloride. The content of bound chloride increased by 3.78%-17.42% as the FA content in seawater-based alkali-activated materials (SAAM) raised. The chloride binding forms of SAAM were mainly chemical binding by the hydrated calcium aluminate (AFm) phase and physical adsorption by calcium (alumino) silicate hydration (C-(A)-S-H) gels when the FA dosage is less than 20% in SAAM. When the FA mass ratio in SAAM was larger than 20%, the chloride binding form of SAAM was mainly the physical adsorption by calcium (sodium)alumino-silicatehydrate ((C,N)-A-S-H) gels. Among the three additive materials, CaAl-LDH was the most effective in reducing the free chlorine content by 11.34%. While for MgAl-LDH, the chloride binding capacity was compromised by the less strength loss. In this work, seawater was used as the mixing water to introduce chloride ions, the results of which could provide a reference for the application of seawater in future projects.

PROPERTIES OF CONCRETE INCORPORATED WITH SELF-HEALING AND INTERNAL CURING AGENTS

In this study, effects of collective addition of self-healing and internal curing agents on the strength and permeation properties of concrete were determined. The internal curing agent Polyethylene Glycol (PEG 400) was added at 2% of cement based on weight and a mixture of Bentonite, Quick lime and Magnesium oxide were replaced for cement at 5% each as self-healing agent. Six mixes were investigated which includes a control mix (water curing), a mix with PEG 400 (with and without water curing), a mix with self-healing agents (water curing) and a mix integrated PEG 400 and self-healing agents. (With and without water curing) The density of concrete and strength parameters like compressive, flexural and tensile strengths were found by conducting experiments using the procedures given in testing standards. Permeation features were also studied by subjecting the concrete to water absorption and sorptivity tests. Density values lowered because of internal curing agents. The integration of internal curing and self-healing agents have adverse effects on density, strengths, water absorption and sorptivity co-efficients but there is an improvement in the mentioned properties when the specimens were cured in water.

Enhancing permeability reduction computation for water injection in Homogeneous Reservoirs

A critical challenge encountered in water injection processes is the formation of mineral scales due to the incompatibility between the injected water and the naturally occurring formation water. The traditional method for predicting damage ratios during injection involves a simplistic approach, where the pressure drop ratio during injection tests is compared to the stabilized pressure drop prior to the initiation of the injection test. However, this method overlooks a crucial aspect assuming equal viscosity between the mixed injection waters and the formation water, without accounting for the dynamic viscosity changes that occur throughout the injection process. To address this limitation, this study introduces an innovative approach for calculating the viscosity of mixed waters within porous media. The viscosity of mixed waters in both homogeneous sandstone and carbonate cores was determined by employing non-interacting and non-precipitating tracers. Experimental data were meticulously collected and subjected to mathematical modeling, enabling the prediction of mixed water concentrations at any given time during the injection process. Using the concentration of mixed water, the viscosity of mixture then is calculated which will be used in the accurate calculation of permeability reduction during the injection test. The results obtained reveal significant variations in viscosity ratios, reaching values as high as 27 percent. The model suggested here to predict mixture viscosity while injecting water in porous media underscores the critical importance of considering the viscosity of mixed waters within porous media when calculating damage ratios accurately. In this work, crucial factors for effectively determining the viscosity of mixed water include selecting suitable tracers, utilizing appropriate mathematical techniques, and accurately determining dispersion coefficients.

Effect of plasticizer composition on the properties of injection molded cassava starch-based bioplastics

Sustainability has led to an exponential increase in the interest for using renewable resources. The abundance of starch in nature has promoted the production of starch-based bioplastics through widespread industrial techniques employed for conventional polymers, such as injection molding (IM). This research specifically aims to assess the effect of different plasticizers (i.e., glycerol, glycerol/water) on the properties of cassava (Manihot esculenta) starch bioplastics obtained through IM. Through dynamic mechanical analysis (DMA) and tensile tests, viscoelastic and mechanical properties of the bioplastics at different plasticizer to starch ratios (30–40 %, w/w) were analyzed. Other properties, such as water uptake capacity (WUC) or soluble matter loss were studied and related to the structure of the materials analyzed via scanning electron microscopy and X-ray diffraction. The effect of relative humidity (RH) on dynamic mechanical response of bioplastics was explored. Mixed plasticizer fractions, including glycerol and water, gave rise to hardened materials with rougher surfaces that were dramatically softened at both low and high RH. The low WUC and uniform structure displayed by materials produced from cassava starch and 30 % of glycerol might be of interest for its application in food packaging due to their optimal performance with temperature at high RH (80 %).

Local hydrodynamic in coastal system affects the coccolithophore community at a short spatial scale

Coccolithophores are an ecologically and biogeochemically important group of calcifying marine plankton, contributing globally to both the organic carbon pump and the carbonate counter pump. Understanding their distribution in today's ecosystems is crucial for both paleoenvironmental reconstruction and for predicting their fate under climate change and environmental pollution. Traditionally regarded as open ocean dwellers, more recent studies have highlighted their importance in coastal systems.Here we describe the coccolithophore community in the Catalan Sea (Northwestern Mediterranean), off the Ebro River Delta, based on an oceanographic survey conducted in autumn 2019. We identify three environmentally distinct regimes: mixed (mostly shallow), transition (upper photic layers offshore), and stratified deep waters (below 75 m). Total coccolithophore density is driven by E. huxleyi and peaks in the mixed zone where nutrient concentrations are low, but nitrite concentrations are high. We propose that peak cell densities are partly explained by a switch from nitrate to nitrite usage similarly to diatoms behavior. Species diversity peaks in deeper offshore waters due to vertical stratification. Helicosphaera carteri and Algirosphaera robusta benefit from Emiliania huxleyi decrease both in coastal and offshore environment.

Numerical Study on the Influence of Different Operating Conditions on Mixing Uniformity of the Helical Gear Pump Mixer

The uniformity of the gelatin solution and water mixing process is a critical factor in the performance of helical gear pump mixers that affects pump efficiency. In this study, we investigate the impact of water inlet velocity and rotational speed on the helical gear pump mixer. A numerical model of the helical gear pump mixer is established using Simerics MP+ 5.2.15 software. By varying the water inlet velocity from 0.159 m/s to 1.272 m/s and the rotational speed from 8 rpm to 50 rpm, we obtained volume fraction distributions of water in different sections of the helical gear pump mixer. The simulation results show that the high water inlet velocity causes the water and gelatin solution in the mixing tank to not mix fully. When the inlet speed is 0.318 m/s, the mixing uniformity of the gelatin solution and water in the mixing tank is effectively promoted, and the maximum volume fraction of water in the water-rich region is reduced by 70.24%. In poor water regions, the maximum volume fraction of water increased by 9.25 times. Furthermore, within a certain range, increasing the rotational speed of the helical gear pump promotes the faster transport of water to the back of the mixing tank, leading to reduced non-uniformity in the gelatin solution and water mixing process. These findings provide valuable insights for enhancing mixing uniformity in helical gear pump mixers.