Water Layer Research Articles

How Can Restoration Improve the Environmental Conditions of a Meromictic Urban Lake?

This study was conducted on Klasztorne Małe Lake located in the city of Kartuzy. For about 100 years, the lake served as a receiver of domestic, industrial, and rain sewage. The lake was completely degraded. In addition, excessive sewage inflow caused the accumulation of dense pollution in the area of the lake’s deepest part, which caused the formation of a monimolimnion layer. The bradymictic KML became a meromictic lake. After cutting off the inflow of pollutants, the lake was restored by the P inactivation method using coagulants PIX 111 and PAX 18. Before the restoration process of this lake, concentrations of nutrients in the bottom water layers achieved very high values of TN (total N) 65 mg/L and TP (total P) 30 mg/L. An average concentration of chlorophyll was 65 µg/L and visibility did not exceed 1 m. The method used brought very good results. In the entire volume of water, over 90% reduction in TP and a several-fold decrease in the content of TN were noted. The withdrawal of mineral P from the water limited the production processes in the lake, which was reflected in the reduction in chlorophyll amounts (19 µg/L) and the increase in water visibility (2 m). In addition, oxygen conditions in the lake improved. The application of coagulants caused a decrease in the density of the monimolimnion water, which was indicated by a significant decrease in water conductivity. However, the restoration method did not improve the water dynamics.

Simplification of solvation shell with water clusters in the simulation of electrochemical nitrogen reduction reaction.

Electrochemical methods for nitrogen reduction have received extensive attention due to the mild reaction conditions. In order to gain an insight into the mechanism of the electrochemical nitrogen reduction process, theoretical simulations are necessary. However, current simulation studies contain many imprecise approximations that may hinder the real recognition of the reaction process. Although solvation methods have recently been developed to provide efficient descriptions, their further applications are hindered by controversy over modeling of solvents and the enormous computational effort required. In this work, we simplify the solvation conditions by using water clusters and compare them with an accurate water layer model. The results demonstrate that the simplified water clusters can effectively capture protons, simulate the surface electric environment, and enable the calculation of the activation energy of the reaction. This method offers an affordable approach for simulating the surface potentials and solvents and provides a new reference for the theoretical study of the electrochemical nitrogen reduction reaction.

The first record of larval <i>Crassostrea gigas</i> (Thunberg 1793) (Bivalvia, Ostreidae) from the Black Sea

Larvae of the oyster, Crassostrea gigas (Thunberg 1793) are being found in the plankton of the Black Sea for the first time. The studies were carried out in 2014–2023 along the Sevastopol coast. Samples were taken monthly with a Jeddy plankton net (inlet diameter 36 cm, mill gas mesh 135 µm). A water layer of 10–0 m was investigated. Live material was processed by total counting the larvae in the Bogorov chamber, using MBS-9 and Mikmed-5 light microscopes. Oyster larvae were recorded in August 2020 and observed in the plankton from the end of August to the beginning of October. They were also found in the waters at Miskhor, southern coast of Crimea in August 2023. The density of larvae amounted to 1–3 ind./m3. Larvae were found at the following water temperatures: minimum, 19.7 °C (September 2021), maximum, 26.6 °C (August 2022). In August, the larvae of C. gigas were at the stage of veliconch, their sizes ranging 275–340 mkm. The sizes of oyster larvae in September and October were 380 mkm, being already in the late stages of development. In the coastal waters of the northern part of the Black Sea, C. gigas larvae can settle on substrates from late August to mid-October.

Evaluating the Influence of Thin Film of Water on the Frequency Dependences of Transmission Line S-Parameters at Positive and Negative Temperatures

Relevance. Provision of reliable and uninterrupted radio communication is critically important under changing climatic conditions of its operation. The combined effect of temperature and humidity can lead to changes in the electrical characteristics of transceiving devices and thereby disrupt the communication channel. In difficult climatic conditions of operation, due to constant temperature changes on the surface of the printed circuit boards, which are part of them, condensation can form, affecting the performance of the entire device. In this regard, the electrical characteristics change, which must be taken into account when designing critical REE. When designing transmission lines on printed circuit boards, it is reasonable to evaluate climatic impacts on it in a wide frequency range, which requires the development of new models and methods that allow taking into account these impacts.Goal of the work: to evaluate the influence of the temperature of a thin film of water on the surface of a microstrip transmission line on its frequency dependences of S-parameters. Finite element methods and laboratory experiment were used.Results. A methodology to account for the effects of ambient temperature and humidity on the electrical characteristics of a microstrip transmission line (MTL) is presented, which allows evaluating the variation of the S-parameters of the line over wide ranges of frequencies, air temperature and humidity, as well as the chemical composition of the environment. The S-parameters of water in a container placed inside a coaxial chamber are measured over the frequency and temperature ranges of 10 MHz to 12 GHz and minus 50 to 100℃, respectively. Using the presented model, the frequency dependences of the electrical conductivity of water at different temperatures are calculated. It is shown that at positive temperature, the electrical conductivity can reach 6.5 Sm/m and at negative temperature it can reach 1.3 Sm/m. Using the developed methodology, the influence of different water electrical conductivity on the S-parameters of MTLs is evaluated. The influence of water and ice layer thickness on the S-parameters of MTLs was shown. It is found that models describing the electrical conductivity of water have an excellent influence on the electrical parameters of the transmission line. Novelty. A method of accounting for the influence of ambient temperature and humidity on the S-parameters of the transmission line is presented, which is characterized by the use of a model of water conductivity based on insertion losses calculated from the measured S-parameters of a coaxial chamber with water in the container when its temperature is changed. Practical significance: a model and a methodology for taking into account the impact of temperature and humidity of the environment on the MTL characteristics are presented, allowing estimating the S-parameters of the line in a wide range of frequencies, air temperature and humidity, as well as the chemical composition of the environment.

MINERALOGICAL, PETROGRAPHIC, AND LITHOCHEMICAL FEATURES OF THE UPPER JURASSIC–LOWER CRETACEOUS SECTION OF THE NORDVIK PENINSULA (NORTH OF EASTERN SIBERIA)

Some intervals of the Jurassic–Cretaceous strata of the Anabar-Lena sedimentary basin have a certain oil and gas production potential, which can be realized in the synchronous offshore horizons of the adjacent territories of the Arctic shelf. Among the most representative objects in this regard are the outcrops of Upper Jurassic and Lower Cretaceous formations of the Nordvik Peninsula. The main data on the composition and structure of this section were obtained mainly at the beginning of the second half of last century. The results of complex mineralogical, petrographic, and lithochemical studies of the Urdyuk-Khaya and Paksa formations of Cape Urdyuk-Khaya of the Nordvik Peninsula presented in here enabled us to identify 10 boundaries for changing of sedimentation regimes of the paleobasin. It was found that the Urdyuk-Khaya Formation was formed mainly in the conditions of the shelf transition zone (moderate deep water) with low rates of terrigenous material intake, some depletion of oxygen in bottom waters, and a trend towards an increase in the depths of the basin. The basal stratum of the Paksa Formation was formed in offshore conditions with periodically occurring dioxic conditions in bottom waters and extremely low rates of terrigenous material intake. The overlying part of the formation was formed in various parts of offshore transition conditions with a gradual decrease in the depths of the basin, an increase in the oxygen content in the bottom layer of water, and the rate of terrigenous material intake. The main provenance area was igneous rocks of mafic, possibly intermediate composition. There was some influence of felsic igneous rocks, or ancient sedimentary rocks rich in quartz. The parent strata were subjected to moderate and severe chemical weathering, in a warm humid climate. The revealed features of the studied strata are similar to the characteristics of the same-age sediments of the lower reaches of the Anabar River, which determines their high correlation potential and allows us to judge the evolution of the western part of the Anabar-Lena basin.

Effect of CO2-assisted surfactant/polymer flooding on enhanced oil recovery and its mechanism

D oilfield is a typical heavy oil reservoir affected by bottom water and has the characteristics of high porosity, high permeability, and strong heterogeneity. However, water flooding leaves oil behind due to unfavorable mobility ratios and capillary forces. The layer (well section) with poor or no liquid entry ability originally has been improved in the process of surfactant/polymer flood. However, fluid entry distribution interlayers were not improved obviously in the middle and late stages. To further improve the recovery efficiency of surfactant/polymer flooding on bottom water reservoirs, the CO2-assisted surfactant/polymer flooding development method had been proposed. The optimal composition of the surfactant/polymer system was selected by evaluating the oil-water interfacial tension and viscosity. Three-dimensional cores with bottom water were used in CO2-assisted surfactant/polymer flooding experiments to improve oil recovery. On this foundation, the screening of oil displacement agents, optimization of oil production well location, and injection pressure were carried out. Based on the comprehensive analysis of the produced liquid, the CO2 assisted surfactant/polymer flooding to enhanced oil recovery mechanism was analyzed. The results showed that the surfactant named BS had a low oil-water interfacial tension of 3.79 × 10-3 mN/m. In addition, salinity decreases the viscosity of the surfactant/polymer solution. It was found that conducting CO2 huff and puff after chemical flooding can improve oil recovery. Among the four chemical agents, CO2-assisted the anionic nonionic surfactant and the salt-resistant polymer system flooding had the highest recovery. Moreover, the location of the oil production well, that is, the distance between it and the bottom water layer, has an impact on the recovery. During the experiment, 2.5 cm was the farthest distance between the oil production well and the bottom water layer, at which point the recovery was highest at 70.9%, and the bottom water breakthrough rate was 2.4%. These results provide theoretical and technical support for the development of CO2-assisted surfactant/polymer flooding and its application in wells.

The numerical analysis of complete and partial electrocoalescence in the droplet-layer system employing the sharp interface technique for multiphase-medium simulation

In this paper, the coalescence of a drop of water suspended in oil with a layer of water under the influence of a constant electric field is numerically investigated. Unlike most existing studies, the calculations are based on the application of the arbitrary Lagrangian-Eulerian method (ALEM), also called the moving mesh method, which belongs to the class of methods for modeling two-phase liquids with a sharp interface. Using this approach made it possible to avoid a false "escape" of the surface charge from the interface, which often occurs when using methods involving a diffuse interface. Despite the fact that ALEM does not allow describing topology changes by default, a numerical model was implemented in which the calculation is divided into three parts: the convergence of the drop and the layer before the moment of touch; the manual construction of the bridge at the moment of touch; the union of the drop and the layer. The developed model allowed us to obtain three possible modes of this process: complete coalescence, partial coalescence and a mode of stretching which has not practically been considered yet. The dependence of the volume of the separated secondary droplet on the size of the initial droplet and the average intensity of the applied electric field is obtained. The model showed good quantitative agreement with experimental studies. It has been shown that generally, the spots where the bridge and the neck are formed in case of partial coalescence do not coincide. A map of coalescence modes was obtained, i.e., the dependence of the transition threshold from coalescence to partial coalescence and from partial coalescence to stretching regime in a wide range of radii of initial droplets and electric field strengths. It has been shown that there is a maximum field strength at which droplets of any size merge with the layer. This map makes it possible to predict the coalescence regime in electrocoalescer. The proposed modeling technique can be used to calculate electrocoalescence modes at various values of the main parameters, which will help to optimize electrocoalescers at the design stage.

Influence of the stratification parameters on the wake field of an underwater vehicle in a two-layer stratified flow

Because the ocean exhibits different stratification states in different seasons and regions, the effect of different stratification parameters on a submarine wake must be studied. In particular, to investigate such effect in a two-layer stratified flow, this study established a computational fluid dynamics (CFD) model based on the URANS equations, shear-stress transport (SST) k-ω turbulence model, and Eulerian multiphase flow model. The volume of fluid (VOF) method was adopted to implement the free-surface capture method. The working conditions of the SUBOFF model under an infinite diving depth and near the free surface were compared with those of the experiments, and the convergence of the time step and grid number under stratified flow conditions was verified. These validation steps proved the feasibility of the CFD method. Finally, the effects of the stratification parameters on the free surface waves, internal waves, and turbulent kinetic energy behind the vehicle were observed by varying the stratification parameters to achieve different working conditions. The results show that when an underwater vehicle sails in a two-layer stratified flow, the interstratified density ratio and depth of the internal wave surface affect its wake field. When the underwater vehicle sails in the water layer, with an increase in the interstratified density ratio, the free-surface roughness increases and the turbulent kinetic energy decreases. When the underwater vehicle sails in the salt water layer, the result is just the opposite.

Fundamental investigation on a new methodology to fabricate thin ion gel membranes for CO2 separation

A new method for fabricating thin ion gel membranes is proposed in this study. A precursor solution of a hydrophobic tough ion gel composed of an interpenetrating polymer network (IPN) and 80 wt% ionic liquid (IL) was spin coated onto a water-soluble sacrificial layer (poly(sodium 4-styrenesulfonate) (PSS-Na)) and a thin ion gel membrane was obtained after dissolving the sacrificial layer in IL-saturated water. Subsequently, the thin ion gel membrane was transferred onto a porous support membrane for obtaining a thin-film composite (TFC) membrane. The TFC membranes showed the same CO2 permeability as the thick ion gel membrane prepared using the same ion gel precursor solution, which indicates that the thin ion gel layer on the TFC membrane was defect free and contained the desired amount of IL. The TFC membrane with 9.3-μm-thick ion gel layer displayed the CO2 permeance of 98.2 GPU and CO2/N2 permselectivity of 31. This CO2 permeation performance was maintained for at least 200 h, indicating the good long-term stability of the prepared thin ion gel layer. The proposed method for forming a thin ion gel layer can be applied to other ion gels with different ILs.

An Empirical Algorithm for Estimating the Absorption of Colored Dissolved Organic Matter from Sentinel-2 (MSI) and Landsat-8 (OLI) Observations of Coastal Waters

Sentinel-2/MSI and Landsat-8/OLI sensors enable the mapping of ocean color-related bio-optical parameters of surface coastal and inland waters. While many algorithms have been developed to estimate the Chlorophyll-a concentration, Chl-a, and the suspended particulate matter, SPM, from OLI and MSI data, the absorption by colored dissolved organic matter, acdom, a key parameter to monitor the concentration of dissolved organic matter, has received less attention. Herein we present an inverse model (hereafter referred to as AquaCDOM) for estimating acdom at the wavelength 412 nm (acdom (412)), within the surface layer of coastal waters, from measurements of ocean remote sensing reflectance, Rrs (λ), for these two high spatial resolution (around 20 m) sensors. Combined with a water class-based approach, several empirical algorithms were tested on a mixed dataset of synthetic and in situ data collected from global coastal waters. The selection of the final algorithms was performed with an independent validation dataset, using in situ, synthetic, and satellite Rrs (λ) measurements, but also by testing their respective sensitivity to typical noise introduced by atmospheric correction algorithms. It was found that the proposed algorithms could estimate acdom (412) with a median absolute percentage difference of ~30% and a median bias of 0.002 m−1 from the in situ and synthetic datasets. While similar performances have been shown with two other algorithms based on different methodological developments, we have shown that AquaCDOM is much less sensitive to atmospheric correction uncertainties, mainly due to the use of band ratios in its formulation. After the application of the top-of-atmosphere gains and of the same atmospheric correction algorithm, excellent agreement has been found between the OLI- and MSI-derived acdom (412) values for various coastal areas, enabling the application of these algorithms for time series analysis. An example application of our algorithms for the time series analysis of acdom (412) is provided for a coastal transect in the south of Vietnam.

Macroscopic observation of a first order one-dimensional swelling-deswelling transition in a nanolayered material

AbstractThe high purity and superior quality of the synthetic clay mineral fluorohectorite allows for studies of phenomena that are masked by imperfections and the inhomogeneous charge distribution in the case of natural clay minerals. We have exploited this opportunity offered by synthetic fluorohectorite and report here digital optical microscopy observations of salinity controlled macroscopic swelling and deswelling behavior of extra-large nanolamellar clay mineral particle accordions of various sizes. We find that clay particle accordions, immersed in a saline solution, at sufficiently high salinity, are in their crystalline swelling region, with only a few water layers hydrating the accordion interlayer nano-spaces, corresponding to an interlayer spacing of about 1.5 nm. Using a micropipette as a micro-tweezer and thereby transferring accordions carefully back and forth between high and low salinity solutions, we observe well defined macroscopic accordion transitions between the crystalline swelling regime and an osmotic swelling regime where the interlayer spacings reach tens of nanometers, calculated from accordion thicknesses measured by digital imaging. The transitions display a clear first order character as evidenced by threshold salinity levels for their abrupt onsets as well as clear hysteresis with retention of crystalline or osmotic state memory, as salinity is increased or lowered. The experimental observations are supported by a theoretical model of the accordion interlayer spacing based on a Donnan equilibrium originating from the salinity gradient between the embedding saline solution and the ionic strength in the clay interlayers in the osmotic swelling regime.

Solvation of molecules from the family of "domain of unknown function" 3494 and their ability to bind to ice.

In 2012, the molecular structure of a new, broad class of ice-binding proteins, classified as "domain of unknown function" (DUF) 3494, was described for the first time. These proteins have a common tertiary structure and are characterized by a very wide spectrum of antifreeze activity (from weakly active to hyperactive). The ice-binding surface (IBS) region of these molecules differs significantly in its structure from the IBS of previously known antifreeze proteins (AFPs), showing a complete lack of regularity and high hydrophilicity. The presence of a regular, repeating structural motif in the IBS region of hitherto known AFP molecules, combined with the hydrophobic nature of this surface, promotes the formation of an ice-like ordering of the solvation water layer and, as a result, facilitates the process of transformation of this water layer into ice. It is, therefore, surprising that the newly discovered DUF3494 class of proteins clearly breaks out of this characteristic. In this paper, using molecular dynamics simulations, we analyze the solvation water structure of the IBS region of both DUF3494 family molecules and AFPs. As we show, although the IBS of DUF3494 molecules does not form an ice-like water structure in the solvation layer, this is compensated by the formation of the equivalent of "anchored clathrate water," in the form of a relatively large number of water molecules bound to the surface of the protein molecule and providing potential binding sites for it to the ice surface.

Exploring Spatial Dynamics of Water Quality in a Tropical Lake Affected by Aquaculture

Lake Maninjau, like many surface water bodies worldwide, faces significant water pollution challenges due to extensive aquaculture activities, making it an ideal site to study the impact of fish farming on water quality, which has contributed to eutrophication and declining water quality. This study investigates the physicochemical parameters and pollution levels in the lake, aiming to provide insights into its environmental health. In August 2022, a comprehensive sampling campaign was undertaken at nine stations within the upper layers of open water and littoral zones of Lake Maninjau. In situ measurements, including temperature, dissolved oxygen, and pH, were conducted, accompanied by water sample collection for laboratory analysis of trace elements and heavy metals. Our study revealed notable variability in water parameters across different sites, with surface water layers exhibiting the greatest differences. While certain parameters such as temperature and conductivity remain relatively stable, pH levels show a decreasing trend with increasing water depth. Dissolved oxygen levels vary widely, while oxidation–reduction potential indicates water pollution, particularly in littoral zones. Potassium dominance within cations likely suggests anthropogenic influences, notably from aquaculture activities, that may also contribute to nutrient enrichment and heavy metal pollution. Elevated levels of total nitrogen and ammonia underscore the lake’s moderate pollution levels, with heavy metals such as mercury exceeding permissible limits, posing risks to aquatic life and human health.

Geoacoustic Digital Model for the Sea of Japan Shelf (Peter the Great Bay)

In this paper, the authors present and analyze the geoacoustic digital seabed model they developed, which is a digital description of the water column characteristics, seabed topography, and information about sediments and rocks (their composition and elastic properties) for Peter the Great Bay, the Sea of Japan. The model consists of four relief layers, a foundation and three layers of bottom sediments, and also contains the velocities of longitudinal waves in rocks and statistical characteristics of the sound velocity distribution in the water layer for three seasons. Acoustic characteristics of geological structures are based on seismoacoustic studies, sediment lithology, and laboratory measurements of rock samples collected onshore. The velocities of longitudinal and transversal waves and also the density of the sediments were calculated from their empirical dependencies on the granulometric composition of bottom sediment samples over an area of about 800 km2. In a limited area of the shelf (approximately 130 km2), high-frequency acoustic studies were carried out using echo sounders, and the longitudinal wave velocities of the top sedimentary layer were determined. Porosity, density, longitudinal, and transverse wave velocities in bottom sediments were calculated using empirical models with a normal coefficient of reflection from the seabed. A comparison was made of the results of calculating the elastic properties of the seabed using various methods.

Semitransparent Cu2O Films Based on CuO Back Layer for Photoelectrochemical Water Splitting and Photovoltaic Applications.

Cuprous oxide (Cu2O) as an intrinsic p-type semiconductor is promising for solar energy conversion. The major challenge in fabricating Cu2O lies in achieving both high transparency and high performance in a tandem device. The Cu2O photocathodes often employ gold as the back contact layer. However, it is not an optimal choice in tandem device due to its poor transmission, scarcity, and electron-hole recombination at the interface of Au and Cu2O. Here, we presented a facile method that utilizes the earth-abundant material copper oxide (CuO) to fabricate highly transparent Cu2O devices. The maximum transmittance of the Cu2O film on CuO (FTO/CuO/Cu2O) increased from 42 % to 58 % compared with Cu2O film on Au (FTO/Au (3 nm)/Cu2O) in 550-800 nm. After coating atomic layer deposition (ALD) layers and hydrogen evolution reaction (HER) catalyst, the photocurrent density at 0 V (versus RHE) of the semitransparent Cu2O photocathode with CuO as the back layer for photoelectrochemical (PEC) water splitting reached -4.9 mA cm-2, which showed a 24.5 % improvement compared with FTO/Au/Cu2O photocathode. Moreover, expanding the CuO layer strategy to the field of solar cells enables Cu2O solar cells to achieve a PCE of 2.37 %.

Dynamic Water Microskin Induced by Photothermally Responsive Interpenetrating Hydrogel Networks for High‐Performance Light‐Tracking Water Evaporation

AbstractSolar‐driven interfacial water evaporation is attracting increasing attention as a promising environmentally‐friendly solution to freshwater scarcity. It has been proven that a thin water layer on photothermal materials can prevent solar energy from invalidly heating the excess water to enhance the evaporation rate. However, the current water layers are usually formed on inelastic materials via confined capillarity, which are static and uncontrollable. Herein, we propose a flexible hydrogel‐based photothermal conversion material with thermal responsiveness by facile frontal polymerization, which can generate a unique dynamic water microskin (DWMS) during the solar evaporation process. The copolymerized hydrogel, introduced by the second polymeric poly(vinyl alcohol) network and thermally responsive poly(N‐isopropylacrylamide) (PNIPAM), exhibits reinforced mechanical strength and photothermally triggers reversible shrinking/swelling cycles that enable a thin water layer (≈32 µm) to balance the feedwater supply and photothermic energy input dynamically. As a result, a stable superior vaporization rate of 8.7 kg m−2 h−1 is achieved based on a cylindrical hydrogel with 6 cm height under 1 sun. Moreover, the simultaneous responsive bending allows efficient omnidirectional solar evaporation by light‐tracking to ensure maximum perpendicular solar absorption, which provides an alternative strategy for durable high‐efficiency solar evaporators for effective thermal management and solar utilization.

Study on Quantitative Assessment of CO2 Leakage Risk Along the Wellbore Under the Geological Storage of the Salt Water Layer

In the process of CO2 geological storage in the salt water layer, CO2 leakage along the wellbore will seriously affect the effective storage of CO2 in the target geological area. To solve this problem, based on the investigation of a large number of failure cases of CO2 storage along the wellbore and failure cases of gas storage wells in the injection stage of the wellbore, the influencing factors of CO2 leakage risk along the wellbore were investigated in detail. Based on the analytic hierarchy process (AHP) and extension theory, 17 basic evaluation indexes were selected from 6 perspectives to establish the evaluation index system of CO2 leakage risk along the wellbore. The established evaluation system was used to evaluate the leakage risk of a CO2 storage well in the X gas field of BZ Block. The results showed that the influencing factors of tubing had the smallest weight, followed by cement sheath, and the influencing factors of casing–cement sheath interface and cement sheath–formation interface had the largest weight, accounting for 23.73% and 34.32%, respectively. The CO2 storage well leakage risk evaluation grade was Ι, with minimal leakage risk. The CO2 storage effect was excellent. The evaluation system comprehensively considers the tubing string, cement sheath, and micro-annulus interface, which can provide a scientific basis for the risk assessment of CO2 leakage along the wellbore under the CO2 geological storage of the salt water layer.

Hydrophilic Chain Length for Octylphenol Polyoxyethylene Ether Adsorption at the n-Hexadecane-Water Interface: Theoretical and Experimental Study.

With the advancement of technologies for developing tight and shale reservoirs, nonionic surfactants have garnered significant attention due to their remarkable properties. The structure of these surfactants plays a crucial role in determining the characteristics of the oil-water interface, particularly influencing emulsification behavior and crude oil recovery. This study investigates the effect of varying the number of hydrophilic polar groups (n = 10, 20, 30, 50) in octylphenol polyoxyethylene ether (OP-n) on its adsorption behavior at the n-hexadecane-water interface using molecular dynamics simulation. The impact of these variations on interfacial properties was further analyzed through measurements of interfacial tension and observations of emulsion droplet morphology. The study results indicate that variations in the number of hydrophilic polar groups significantly affect interfacial properties. Increasing the number of hydrophilic polar groups led to a notable increase in the thickness of the n-hexadecane or water phase, as well as the thickness of the water or oil layer and the surfactant layer. Moreover, when the number of hydrophilic polar groups reached 20, the OP-n molecules exhibited a more curled conformation at the interface, enhancing their ability to encapsulate water and resulting in a decrease in the diffusion coefficient of the molecules in each phase. Additionally, interfacial tension was found to be positively correlated with the number of hydrophilic polar groups and remained unchanged beyond a certain emulsion diameter. This study provides a theoretical basis and reference data for optimizing surfactant structures to improve crude oil recovery.

A temperature tipping point in hypoxic zone size

AbstractTemperature increases will have ubiquitous effects on aquatic food webs, from microbes to consumers, and affect the quality and quantity of carbon flows within and between water layers. A decline in the biological pump moving carbon from surface to lower layers is anticipated. We reviewed 37 years of data on hypoxic zone size and water quality in the northern Gulf of Mexico to determine if air and bottom water temperature increases (0.5°C decade−1) are significantly related to variations in its areal size. There was no significant decline in important river water quality in the 24 years since the national Hypoxia Action Plan was developed to reduce its size. Changes in the ratio of km2 hypoxia per 1000 mt nitrate loading from the Mississippi River from 2000 to 2023 reveals a tipping point in the hypoxic zone size that is driven by ocean warming. Biological factors varying with temperature such as ectotherm growth rates, zooplankton grazing, cell sinking rates, and diatom sequestration of Si or N are apparently more important influences on recent hypoxic zone size than variations in physical factors. This tipping point may be common to similarly warmed and eutrophic coastal waters where warming will likely result in diminished oxygen deficiency (< 2 mgO2 L−1). Hypoxia and food web models assuming a stationary equipoise of nutrient loadings, ratios and food webs will be deficient as coastal waters warm further, coastal storm and hurricane frequency increase and land uses in the watershed are altered with climate change.

Strong, Spontaneous, and Self-Healing Poly(Ionic Liquid) Elastomer Underwater Adhesive with Borate Ester Dynamic Crosslinking.

Adhesion in aqueous environments is often hindered by the water layer on the surface of the substrate due to the water sensitivity of the adhesive, greatly limiting the application environment. Here, a borate ester dynamically crosslinked poly(ionic liquid) elastomer adhesive (PIEA) with high strength, toughness, self-healing abilities, and ionic conductivity is synthesized by copolymerizing hydrophobic ionic liquid monomer ([HPVIm][TFSI]) and 2-methoxyethyl acrylate (MEA). The adhesion strength of PIEA can increase spontaneously from almost no adhesion to 314 kPa after 12 h without any external preloading due to the dissociation of the borate ester in water, leading to noncovalent interactions between the hydroxyl groups of PIEA and the substrate. Additionally, PIEA can be developed for soft sensors or ion electrodes to enable underwater detection and communication. This strategy offers broad application potential for the development of novel underwater smart adhesives.