Water Isotope Data Research Articles

The first firn core from Peter I Island – capturing climate variability across the Bellingshausen Sea

Abstract. Peter I Island is situated in the Bellingshausen Sea, a region that has experienced considerable climate change in recent decades. Warming sea surface temperatures and reduced sea ice cover have been accompanied by warming surface air temperature, increased snowfall, and accelerated mass loss over the adjacent ice sheet. Here we present data from the first firn core drilled on Peter I Island, spanning the period 2001–2017 CE. The stable water isotope data capture regional changes in surface air temperature and precipitation (snow accumulation) at the site, which are highly correlated with the surrounding Amundsen–Bellingshausen seas and the adjacent Antarctic Peninsula (r > 0.6, p < 0.05). The firn core data, together with the unique in situ data from an automatic weather station, confirm the high skill of the ERA5 reanalysis in capturing daily mean temperature and inter-annual precipitation variability, even over a small sub-Antarctic island. This study demonstrates the suitability of Peter I Island for future deep-ice-core drilling, with the potential to provide a valuable archive to explore ice–ocean–atmosphere interactions over decadal to centennial timescales for this dynamic region.

Effects of Short‐Term Climate Variations on Young Water Fraction in a Small Pre‐Alpine Catchment

AbstractContinuous and extended observations of hydrometeorological parameters, alongside the analysis of the isotopic composition across diverse waters within catchments, can significantly enhance our understanding of the potential ramifications of climate change on the hydrological response. In this study, a comprehensive analysis of hydrometeorological and isotopic data was conducted over 10 hydrological years (October 2012–September 2022) within a small, forested catchment in the Italian pre‐Alps, aiming to investigate the impacts of short‐term climatic changes on the isotopic composition of waters and the young water fraction (Fyw). The results showed that the catchment experienced climate conditions with rapid warming and drying trends. Significant isotopic enrichments were observed in all sampled water sources, driven primarily by air temperature. Fyw was estimated to be 0.64 ± 0.06, 0.45 ± 0.07, and 0.16 ± 0.03 for stream water, soil water, and shallow groundwater based on the whole‐period sinusoidal fittings, respectively. Comparative analyses comprising different approaches for the estimation of Fyw showed that time‐windows scenarios and detrending corrections yielded smaller Fyw than approaches based on the whole‐period fitting and discharge‐sensitivity modeling. Such differences can be attributed to an uneven temporal distribution of stream water isotopic data, the difficulties in capturing high flows in a humid catchment characterized by a fast runoff response during rainfall‐runoff events, and the presence of isotopic trends. Our findings underscore the imperative of integrating interannual isotopic trends and adopting appropriate sampling strategy and methodological approaches to ensure a robust Fyw estimation.

Potential Amplifiers of Hydrological Drought: A Deep Dive into the Seasonal Variations of New, Young, and Old Water Fractions in the Stream Discharge of a Pre-Alpine Catchment

This study examines runoff generation processes by focusing on new, young, and old water fractions in the stream discharge within the Swiss pre-Alpine Alp catchment and its smaller tributaries, Erlenbach and Vogelbach. Young water represents a contribution from the three most recent rainfall-runoff events. This research utilises a four-year time series of daily stable water isotope data from stream water and precipitation to investigate seasonal variations. An extended two-component hydrograph separation method is applied to analyse the catchment water and tracer mass balance across both the event and pre-event time axes. The calculated new, young and old water components in stream discharge help estimate time-varying backward travel time distributions. Factors such as air temperature, snow depth, and evapotranspiration data are considered to understand isotope fractionation because of phase changes. The results suggest that discharge generated in autumn and winter may have longer backward travel times compared with spring or summer discharge. Additionally, forest cover influences water fractions older than 40 days. The study identifies a nivo-pluvial runoff regime, with new water fractions peaking in August (Erlenbach, Vogelbach) and January (Alp). Young water fractions reach their highest levels at the start of winter and during snowmelt, while old water fractions peak towards the end of snowmelt and in mid-autumn. The Alp catchment and its tributaries exhibit higher new and young water components than old water following a month of low precipitation and high evapotranspiration in July. These findings are significant in light of the projected drier summers in Central Europe.

Novel approach to estimate the water isotope diffusion length in deep ice cores with an application to Marine Isotope Stage 19 in the Dome C ice core

Abstract. Accurate estimates of water isotope diffusion lengths are crucial when reconstructing and interpreting water isotope records from ice cores. This is especially true in the deepest, oldest sections of deep ice cores, where thermally enhanced diffusive processes have acted over millennia on extremely thinned ice. Previous statistical estimation methods, used with great success in shallower, younger ice cores, falter when applied to these deep sections, as they fail to account for the statistics of the climate on millennial timescales. Here, we present a new method to estimate the diffusion length from water isotope data and apply it to the Marine Isotope Stage 19 (MIS 19) interglacial at the bottom of the EPICA Dome C (EDC, Dome Concordia) ice core. In contrast to the conventional estimator, our method uses other interglacial periods taken from further up in the ice core to estimate the structure of the variability before diffusion. Through use of a Bayesian framework, we are able to constrain our fit while propagating the uncertainty in our assumptions. We estimate a diffusion length of 31±5 cm for the MIS 19 period, which is significantly smaller than previously estimated (40–60 cm). Similar results were obtained for each interglacial used to represent the undiffused climate signal, demonstrating the robustness of our estimate. Our result suggests better preservation of the climate signal at the bottom of EDC and likely other deep ice cores, offering greater potentially recoverable temporal resolution and improved reconstructions through deconvolution.

Hydrogeologic and hydrochemical inputs to emerging wetlands on the shores of the receding Salton Sea, California

AbstractThe Salton Sea has experienced significant recession over the past two decades due to changes in the diversion of Colorado River water to the Salton Trough for agricultural irrigation. As a result, wetlands have emerged in some exposed playa areas along the Salton Sea, primarily in regions with extensive agricultural return flows and agricultural drainage. One notable wetland system, known as the Bombay Beach Wetlands, has formed on the north shore of the Salton Sea, in an area devoid of agriculture. In many other areas with limited or no agriculture, wetlands have failed to develop, leaving exposed playa surfaces as the Salton Sea recedes. These dry playa surfaces pose a significant threat to the health of local residents due to the presence of toxins contained in windblown dust associated with playa deposits. In this study, stable water isotope data, combined with other hydrological information, led to identification of two potential water sources for the Bombay Beach Wetlands. The first possibility proposes that thermal artesian waters alone contribute to the wetlands' water source, while the second hypothesis involves a combination of drainage from Salton Sea bank storage water mixing with the thermal artesian water. The thermal artesian water discharges into drainage channels that flow towards the Bombay Beach Wetlands, initially devoid of possible groundwater baseflow until reaching the wetlands. Studies were subsequently done along the full reach of the drainage channels receiving thermal artesian water. Dissolved solids content, P and N nutrients, arsenic, and stable water isotopes were tested synoptically along the drainage channels. Channel investigations led to the development of a novel model of salinization, which is linked to channel discharge, channel morphometrics, and channel incision.

Summer Hydrography Conditions at Proglacial Fjord Entrances Along East Greenland

AbstractClimate change is causing widespread melting of land and sea ice in the Arctic, leading to an increase in freshwater input to the ocean. This may have an impact on ocean circulation, marine ecosystems, and biodiversity in the region. Our findings provide new insights into the summer hydrography conditions at proglacial fjord entrances along large parts of the east coast of Greenland. As most freshwater exits the Arctic Ocean through Fram Strait this study focuses on understanding the origin of spatial distribution of temperature and freshwater in the coastal waters in East Greenland. We find that Polar Water and the Atlantic Water variants (Eurasian Basin Atlantic Water/Subpolar Mode Water) dominate coastal waters north and south of Denmark Strait, respectively, and that coastal waters are influenced by advected meltwater from the Arctic Ocean, glacier meltwater and local precipitation. Combining hydrographic observations, water isotope data, and water source fraction analysis, we show that glacier meltwaters can be detected at fjord entrances and down to approximately 200 m. Integrated over the upper 200 m of the water column, glacial meltwater account for approximately 9%, precipitation for around 8% and Polar Water (including sea ice melt) for approximately 83% of the freshwater observed along the East Greenland coast. Below 200 m, Atlantic Water variants dominate the entire coastal section. The freshwater along East Greenland stays close to the coast and we could not detect any glacier meltwater at the slope.

Technical note: Two-component electrical-conductivity-based hydrograph separation employing an exponential mixing model (EXPECT) provides reliable high-temporal-resolution young water fraction estimates in three small Swiss catchments

Abstract. The young water fraction represents the portion of water molecules in a stream that have entered the catchment relatively recently, typically within 2–3 months. It can be reliably estimated in spatially heterogeneous and nonstationary catchments from the amplitude ratio of seasonal isotope (δ18O or δ2H) cycles of stream water and precipitation, respectively. Past studies have found that young water fractions increase with discharge (Q), thus reflecting the higher direct runoff under wetter catchment conditions. The rate of increase in the young water fraction with increasing Q, defined as the discharge sensitivity of the young water fraction (Sd*), can be useful for describing and comparing catchments' hydrological behaviour. However, the existing method for estimating Sd*, which only uses biweekly isotope data, can return highly uncertain and unreliable Sd* when stream water isotope data are sparse and do not capture the entire flow regime. Indeed, the information provided by isotope data depends on when the respective sample was taken. Accordingly, the low sampling frequency results in information gaps that could potentially be filled by using additional tracers sampled at a higher temporal resolution. By utilizing high-temporal-resolution and cost-effective electrical conductivity (EC) measurements, along with information obtainable from seasonal isotope cycles in stream water and precipitation, we develop a new method that can estimate the young water fraction at the same resolution as EC and Q measurements. These high-resolution estimates allow for improvements in the estimates of the Sd*. Our so-called EXPECT (Electrical-Conductivity-based hydrograph separaTion employing an EXPonential mixing model) method is built upon the following three key assumptions: We construct a mixing relationship consisting of an exponential decay of stream water EC with increasing young water fraction. This has been obtained based on the relationship between flow-specific young water fractions and EC. We assume that the two-component EC-based hydrograph separation technique, using the above-mentioned exponential mixing model, can be used for a time-source partitioning of stream water into young (transit times < 2–3 months) and old (transit times > 2–3 months) water. We assume that the EC value of the young water endmember (ECyw) is lower than that of the old water endmember (ECow). Selecting reliable values from measurements of ECyw and ECow to perform this unconventional EC-based hydrograph separation is challenging, but the combination of information derived from the two tracers allows for the estimation of endmembers' values. The two endmembers have been calibrated by constraining the unweighted and flow-weighted average young water fractions obtained with the EC-based hydrograph separation to be equal to the corresponding quantities derived from the seasonal isotope cycles. We test the EXPECT method in three small experimental catchments in the Swiss Alptal Valley using two different temporal resolutions of Q and EC data: sampling resolution (i.e. we only consider Q and EC measurements during dates of isotope sampling) and daily resolution. The EXPECT method has provided reliable young water fraction estimates at both temporal resolutions, from which a more accurate discharge sensitivity of the young water fraction (SdEXP) could be determined compared with the existing approach. Also, the method provided new information on ECyw and ECow, yielding calibrated values that fall outside the range of measured EC values. This suggests that stream water is always a mixture of young and old water, even under very high or very low wetness conditions. The calibrated endmembers revealed a good agreement with both endmembers obtained from an independent method and EC measurements from groundwater wells. For proper use of the EXPECT method, we have highlighted the limitations of EC as a tracer, identified certain catchment characteristics that may constrain the reliability of the current method and provided recommendations about its adaptation for future applications in catchments other than those investigated in this study.

The value of instream stable water isotope and nitrate concentration data for calibrating a travel time‐based water quality model

AbstractTransit time‐based water quality models using StorAge Selection (SAS) functions are crucial for nitrate (NO3−) management. However, relying solely on instream NO3− concentration for model calibration can result in poor parameter identifiability. This is due to the interaction, or correlation, between transport parameters, such as SAS function parameters, and denitrification rate, which challenges accurate parameters identification and description of catchment‐scale hydrological processes. To tackle this issue, we conducted three Monte‐Carlo experiments for a German mesoscale catchment by calibrating a SAS‐based model with daily instream NO3− concentrations (Experiment 1), monthly instream stable water isotopes (e.g. δ18O) (Experiment 2) and both datasets (Experiment 3). Our findings revealed comparable ranges of SAS transport parameters and median water transit times (TT50) across the experiments. This suggests that, despite their distinct reactive or conservative nature, and sampling strategies, the NO3− and δ18O time series offer similar information for calibration. However, the absolute values of transport parameters and TT50 time series, as well as the degree of parameter interaction differed. Experiment 1 showed greater interaction between certain transport parameters and denitrification rate, leading to greater equifinality. Conversely, Experiment 3 yielded reduced parameters interaction, which enhanced transport parameters identifiability and decreased uncertainty in TT50 time series. Hence, even a modest effort to incorporate only monthly δ18O values in model calibration for highly frequent NO3−, improved the description of hydrological transport. This study showcased the value of combining NO3− and δ18O model results to improve transport parameter identifiability and model robustness, which ultimately enhances NO3− management strategies.

Multi-year time series of daily solute and isotope measurements from three Swiss pre-Alpine catchments

Time series analyses of solute concentrations in streamwater and precipitation are powerful tools for unraveling the interplay of hydrological and biogeochemical processes at the catchment scale. While such datasets are available for many sites around the world, they often lack the necessary temporal resolution or are limited in the number of solutes they encompass. Here we present a multi-year dataset encompassing daily records of major ions and a range of trace metals in both streamwater and precipitation in three catchments in the northern Swiss Pre-Alps. These time series capture the temporal variability observed in solute concentrations in response to storm events, snow melt, and dry summer conditions. This dataset additionally includes stable water isotope data as an extension of a publicly available isotope dataset collected concurrently at the same locations, and together these data can provide insights into a range of ecohydrological processes and enable a suite of analyses into hydrologic and biogeochemical catchment functioning.

Spatial and temporal stable water isotope data from the upper snowpack at the EastGRIP camp site, NE Greenland, sampled in summer 2018

Abstract. Stable water isotopes stored in snow, firn and ice are used to reconstruct climatic parameters. The imprint of these parameters at the snow surface and their preservation in the upper snowpack are determined by a number of processes influencing the recording of the environmental signal. Here, we present a dataset of approximately 3800 snow samples analysed for their stable water isotope composition, which were obtained during the summer season next to the deep drilling site of the East Greenland Ice Core Project in northeast Greenland (75.635411° N, 36.000250° W). Sampling was carried out every third day between 14 May and 3 August 2018 along a 39 m long transect. Three depth intervals in the top 10 cm were sampled at 30 positions with a higher resolution closer to the surface (0–1 and 1–4 cm depth vs. 4–10 cm). The sample analysis was carried out at two renowned stable water isotope laboratories that produced isotope data with the overall highest uncertainty of 0.09 ‰ for δ18O and 0.8 ‰ for δD. This unique dataset shows the strongest δ18O variability closest to the surface, damped and delayed variations in the lowest layer, and a trend towards increasing homogeneity towards the end of the season, especially in the deepest layer. Additional information on the snow height and its temporal changes suggests a non-uniform spatial imprint of the seasonal climatic information in this area, potentially following the stratigraphic noise of the surface. The data can be used to study the relation between snow height (changes) and the imprint and preservation of the isotopic composition at a site with 10–14 cm w.e. yr−1 accumulation. The high-temporal-resolution sampling allows additional analyses on (post-)depositional processes, such as vapour–snow exchange. The data can be accessed at https://doi.org/10.1594/PANGAEA.956626 (Zuhr et al., 2023a).

Shifting groundwater fluxes in bedrock fractures: Evidence from stream water radon and water isotopes

Geologic features (e.g., fractures and alluvial fans) can play an important role in the locations and volumes of groundwater discharge and degree of groundwater-surface water (GW-SW) interactions. However, the role of these features in controlling GW-SW dynamics and streamflow generation processes are not well constrained. GW-SW interactions and streamflow generation processes are further complicated by variability in precipitation inputs from summer and fall monsoon rains, as well as declines in snowpack and changing melt dynamics driven by warming temperatures. Using high spatial and temporal resolution radon and water stable isotope sampling and a 1D groundwater flux model, we evaluated how groundwater contributions and GW-SW interactions varied along a stream reach impacted by fractures (fractured-zone) and downstream of the fractured hillslope (non-fractured zone) in Coal Creek, a Colorado River headwater stream affected by summer monsoons. During early summer, groundwater contributions from the fractured zone were high, but declined throughout the summer. Groundwater contributions from the non-fractured zone were constant throughout the summer and became proportionally more important later in the summer. We hypothesize that groundwater in the non-fractured zone is dominantly sourced from a high-storage alluvial fan at the base of a tributary that is connected to Coal Creek throughout the summer and provides consistent groundwater influx. Water isotope data revealed that Coal Creek responds quickly to incoming precipitation early in the summer, and summer precipitation becomes more important for streamflow generation later in the summer. We quantified the change in catchment dynamic storage and found it negatively related to stream water isotope values, and positively related to modeled groundwater discharge and the ratio of fractured zone to non-fractured zone groundwater. We interpret these relationships as declining hydrologic connectivity throughout the summer leading to late summer streamflow supported predominantly by shallow flow paths, with variable response to drying from geologic features based on their storage. As groundwater becomes more important for sustaining summer flows, quantifying local geologic controls on groundwater inputs and their response to variable moisture conditions may become critical for accurate predictions of streamflow.

Spatio-temporal variations of lacustrine groundwater discharge and related nutrient fluxes in a typical lake in front of hillocks

Lacustrine groundwater discharge (LGD) as a hidden hydrologic process has been widely found to affect water and nutrient balance in various lakes, but a comprehensive research on both spatial and temporal variations of LGD and associated nutrient fluxes was poorly conducted. Herein, this study elucidated their spatio-temporal variations and underlying factors of a typical lake in front of hillocks with spatially variable topography and hydrogeology, and intense seasonal groundwater-lake exchange, within central Yangtze River basin. The 222Rn mass balance model was used in conjunction with hydrochemistry, water isotope, and nutrient data. The results showed that the overall LGD rate and related N/P fluxes were clearly higher in the wet season than in the dry season, for which the stronger evaporation relative to precipitation, more groundwater recharge from agricultural irrigation or aquacultural pond infiltration, and more N/P input from anthropogenic or aquacultural activities could be responsible. In the wet season, the area with more recharge from irrigating water or fish pond water infiltration and associated extensive agricultural or aquacultural activities, had the significantly highest LGD rate and related N/P fluxes. In the dry season, the area with the deepest water depth and largest topographic slope, exhibited the significantly highest LGD rate and slightly higher LGD-related N/P fluxes due to relatively low groundwater N/P concentrations. This study enriched the understanding on LGD and related nutrient fluxes in the perspective of both spatial and temporal variations, taking a new type of lakes (i.e., lakes in the transitional zone of hills and plains in temperate climate) as a typical case.

Tight coupling between leaf δ13 C and N content along leaf ageing in the N2 -fixing legume tree black locust (Robinia pseudoacacia L.).

N2 -fixing legumes can strongly affect ecosystem functions by supplying nitrogen (N) and improving the carbon-fixing capacity of vegetation. Still, the question of how their leaf-level N status and carbon metabolism are coordinated along leaf ageing remains unexplored. Leaf tissue carbon isotopic composition (δ13 C) provides a useful indicator of time-integrated intrinsic water use efficiency (WUEi). Here, we quantified the seasonal changes of leaf δ13 C, N content on a mass and area basis (Nmass , Narea , respectively), Δ18 O (leaf 18 O enrichment above source water, a proxy of time-integrated stomatal conductance) and morphological traits in an emblematic N2 -fixing legume tree, the black locust (Robinia pseudoacacia L.), at a subtropical site in Southwest China. We also measured xylem, soil and rainwater isotopes (δ18 O, δ2 H) to characterize tree water uptake patterns. Xylem water isotopic data reveal that black locust primarily used shallow soil water in this humid habitat. Black locust exhibited a decreasing δ13 C along leaf ageing, which was largely driven by decreasing leaf Nmass , despite roughly constant Narea . In contrast, the decreasing δ13 C along leaf ageing was largely uncoupled from parallel increases in Δ18 O and leaf thickness. Leaf N content is used as a proxy of leaf photosynthetic capacity; thus, it plays a key role in determining the seasonality in δ13 C, whereas the roles of stomatal conductance and leaf morphology are minor. Black locust leaves can effectively adjust to changing environmental conditions along leaf ageing through LMA increases and moderate stomatal conductance reduction while maintaining constant Narea to optimize photosynthesis and carbon assimilation, despite declining leaf Nmass and δ13 C.

How do non‐halophyte locust trees thrive in temperate coastal regions: A study of salinity and multiple environmental factors on water uptake patterns

AbstractUnderstanding plant water use patterns is crucial for comprehending the dynamics of the soil–plant‐atmosphere continuum and evaluating the adaptability of plants across diverse ecosystems. However, there remains a gap in our comprehension of non‐halophyte plants' water uptake patterns and driving factors in temperate coastal regions. For this reason, we used locust trees (a widely planted non‐halophyte tree species in northern China) as a study subject. We collected water isotope data (δ2H and δ18O) for locust trees xylem and soil over two consecutive growing seasons. The MixSIAR model was used along with five distinct sets of input data (single isotopes, uncorrected dual isotopes, and corrected dual isotopes incorporating δ2H data obtained by soil water line or cryogenic vacuum distillation methods) to infer water utilization patterns. The results indicated that locust trees primarily absorb shallow soil water (0–20 cm, 29.4% ± 16.9%) and deep soil water (120–180 cm, 24.7% ± 5.8%). Pearson's correlation analysis revealed the key driving factors behind water uptake patterns were vegetation transpiration and soil salinity. Remarkably, the build up of salts in the lower soil layer (60–120 cm) hinders the absorption of water by plants. To prevent high salt concentrations from affecting water uptake in non‐halophyte plants, we recommend implementing sufficient irrigation from March to April each year to meet the water needs of plant growth and regulate the accumulation of salts in various soil layers. This study reveals the dynamic water utilization strategy of non‐halophyte plants in temperate coastal regions, offering valuable information for water resources management.

Complexity of Arctic Ocean water isotope (δ18O, δ2H) spatial and temporal patterns revealed with machine learning

The stable isotope compositions of water (δ18O, δ2H, deuterium-excess) are important tracers that help illuminate the changing Arctic water cycle and how Arctic-sourced water can influence lower latitudes. We present simultaneous boundary layer water vapor and ocean water isotope data that were measured continuously in the western Arctic Ocean. Sea surface water isotopes varied between the shallower continental Chukchi Shelf and the deeper Chukchi Borderlands to the north. The Chukchi Borderlands surface waters were less saline than the offshore Chukchi Shelf, as the Borderlands are influenced by greater sea ice cover and contribution of sea ice melt to surface freshwater. This greater contribution of sea ice melt resulted in lower deuterium-excess (δ2H − 8*δ18O) in surface water values in the deeper Chukchi Borderlands than on the shallower Chukchi Shelf. Additionally, the sea ice melt contributions to freshwater were less prominent than river runoff, but freshwater from both sources decreased substantially below 70 m depth in the Chukchi Borderlands. Our observed water isotope values provided the foundation for producing water isotope maps (isoscapes) based on remote sensing and machine learning which incorporate parameters that can influence ocean circulation and thus water isotopes (e.g., salinity, sea surface temperature, water depth). These isoscapes suggest spatial complexity in the distribution of stable water isotopes in the Arctic, including sharp gradients in the distribution of the isotopes in seawater that were studied. These isoscapes can be improved in future iterations, for example, with the availability of more spatially continuous, remotely sensed oceanic variables or continuous ship-based measurements to use as additional predictors. As a result, the generation of these isoscapes could become a useful tool for understanding the past, present, and future Arctic water cycle in the context of the global hydrologic cycle.

Effects of urbanization on the water cycle in the Shiyang River basin: based on a stable isotope method

Abstract. In water-scarce arid areas, the water cycle is affected by urban development and natural river changes, and urbanization has a profound impact on the hydrological system of the basin. Through an ecohydrological observation system established in the Shiyang River basin in the inland arid zone, we studied the impact of urbanization on the water cycle of the basin using isotope methods. The results showed that urbanization significantly changed the water cycle process in the basin and accelerated the rainfall-runoff process due to the increase in urban land area, and the mean residence time (MRT) of river water showed a fluctuating downward trend from upstream to downstream and was shortest in the urban area in the middle reaches, and the MRT was mainly controlled by the landscape characteristics of the basin. In addition, our study showed that river water and groundwater isotope data were progressively enriched from upstream to downstream due to the construction of metropolitan landscape dams, which exacerbated evaporative losses of river water and also strengthened the hydraulic connection between groundwater and river water around the city. Our findings have important implications for local water resource management and urban planning and provide important insights into the hydrologic dynamics of urban areas.

Investigating the Seasonal Variations of Event, Recent, and Pre-Recent Runoff Components in a Pre-Alpine Catchment using Stable Isotopes and an Iterative Hydrograph Separation Approach

An analysis of the runoff generation processes in terms of event, recent, and pre-recent runoff components is demonstrated for the Swiss pre-Alpine Alp catchment (46.4 km2) and two smaller tributaries (Erlenbach, 0.7 km2, and Vogelbach, 1.6 km2), whereas, recent water is understood as the contribution of the respective three prior rainfall-runoff events. A four-years time series of daily stable water isotope data in stream water and precipitation is used for the analysis of seasonal variations. In addition, high-frequency data (10 minutely intervals) are used for a detailed visualization of the rapid mobilization of recent water for single events. An iterative extension of the standard two-component hydrograph separation method is applied; this approach can be interpreted as a discretization of the catchment water and tracer mass balance along the event and pre-event time axis. Furthermore, the calculated event, recent, and pre-recent runoff components can be used to estimate time-varying backward travel time distributions.

Spatio-temporal variation characteristics of stable isotopes of tap water and its potential as a proxy for surface water in Sichuan, China

The stability and safety of tap water are essential for human health and economic and social development. The stable isotopes can be used to reveal characteristics of tap water and link it with its source. In this paper, 1556 tap water samples were collected from Sichuan, China and the stable isotope ratios for these samples were determined. The δ2H ranges from −126.4 ‰ to −26.4 ‰, and the range of δ18O is −17.04 ‰ to −2.08 ‰, reflecting the tap water sources are affected by complex spatial features and changing meteorological elements. Stable isotopes in tap water usually reach the maximum values in summer, indicating that heavy isotope enrichment is easily achievable by the large amount of evaporation from water sources during the summer season. By using spatial interpolation and isoscapes, we can find that there is a strong correlation between both simulated tap water δ2H and river water δ2H, with the maximum difference not exceeding 10.0 ‰, while the overall mean relative error is 6 %. Consequently, it is feasible to use tap water isotopes as a proxy for surface water isotopes in representative watersheds where surface water is the main source of water. The study shows the variation characteristics and influencing factors of tap water isotopes and enriches the isotope database of tap water in China. Meanwhile, the utilize of stable isotopes in tap water as a proxy for surface water expands the application field of tap water stable isotopes and opens new perspectives for indirectly obtaining isotope data of surface water.

A Comprehensive Study on the Hydrogeochemical and Isotope Characteristics and Genetic Mechanism of Geothermal Water in the Northern Jinan Region

Geothermal water (GW) resources are highly valued as clean, renewable energy sources. In this study, a comprehensive analysis of water chemistry and isotope data from 25 GW samples was conducted to gain insights into the hydrochemical characteristics and formation mechanisms of the GW in the northern Jinan region (NJR). Statistical analysis and hydrochemical methods were employed for relevant analysis. The findings reveal that the GW in the NJR exhibits high salinity, with an average total dissolved solids (TDS) concentration of 9009.00 mg/L. The major ions identified are Na+ and Cl−, with mean concentrations of 2829.73 mg/L and 4425.77 mg/L, respectively, resulting in a hydrochemical type of Cl−Na. The analysis of δ2H and δ18O isotopes indicates that the GW originates from atmospheric precipitation that undergoes deep cycling and interaction with older groundwater. The composition of 3H suggests that the GW in the NJR is a mixture of waters, while radiocarbon dating (14C) suggests that the recharge of the GW may have occurred in the late Pleistocene era. The GW in the NJR is classified as partially equilibrated waters. The temperature range of geothermal reservoirs is 57.13 to 99.74 °C. The hydrochemical components primarily result from water–rock interactions, including silicate weathering, cation exchange, as well as carbonate weathering and the dissolution of halite and gypsum. Moreover, taking into account the hydrogeological conditions, hydrochemistry, and isotope analysis, a conceptual model of the geothermal reservoir in the NJR was developed. The research findings serve as a valuable reference and foundation for the development and utilization of geothermal resources in the Jinan region. These originate from the Taiyi mountains in the south or the Taihang mountains in the west, and experience deep circulation and long runoff times. This study provides a reference for the sustainable development and utilization of regional geothermal resources.

How best to recover water-isotope data from ice cores

How best to recover water-isotope data from ice cores