Volcano-sedimentary Sequence Research Articles

Pre-Choiyoi volcanism at Cordillera del Viento, southwestern margin of Gondwana (∼37° S): Geological characterisation, geochronology and regional implications

This contribution provides a comprehensive description and classification of fifteen lithofacies within the Carboniferous rocks attributed to the Arroyo del Torreón Formation and Sofía Dacite in order to understand the eruptive dynamics and the evolution of volcanism associated with the onset of the Gondwanan Orogenic Cycle at the Cordillera del Viento (Argentina). The outcrops of Carboniferous volcanic and volcaniclastic rocks linked to this cycle are restricted to the Cordilllera del Viento range. In consequence, they offer a valuable opportunity to research the volcanic arc products of the pre-Choiyoi magmatism.The Arroyo del Torreón Formation lithofacies interpretation and its distribution indicate that the volcanism commenced with local andesitic lava flows followed by a volcano-sedimentary sequence formed by multiple pumice-rich quasi-steady concentrated pyroclastic density currents alternating with episodes of epiclastic sedimentation. The latter are covered ignimbrites developed by boiling over eruptions. Crystal-rich tuffs overlie the ignimbrites and represent a transition to a plinian eruption. This eruption style continued, developing concentrated pyroclastic density currents with highly unsteadiness conditions and scarce fall-out deposits. Conversely, the Sofía Dacite, represent a notable shift in the volcanism style, characterized by dacitic to rhyolitic lava flows with minor pyroclastic beds. Zircon dating of a pumice-rich lapilli-tuff from the Arroyo del Torreón Formation yielded a minimum age of 327.77 ± 1.79 Ma that was interpreted as the maximum depositional age for this unit. Similarly, zircons from a porphyritic dacite representing the Sofía Dacite provided a Concordia age of 329.11 ± 1.31 Ma that was interpreted as the crystallisation age of this rock.Consequently, we propose a new stratigraphic division of the Arroyo del Torreón Formation into two members. The Cerro San Pedro Member will comprise the pyroclastic rocks at the base of the sequence, while the Sofía Member will include the upper lava-dominated portion of the unit. In this sense, the whole lithostratigraphic unit represents a distinctive Carboniferous basin associated with arc-related volcanism representative from the pre-Choiyoi magmatism.

Isotopic distribution of bioavailable Sr, Nd, and Pb in Chungcheongbuk-do Province, Korea

BackgroundMapping the distribution of bioavailable isotope ratios across landscapes serves as an efficient geochemical tool for delineating the origins and migration trajectories of humans and animals. Chungcheongbuk-do Province in central Korea, known for its geological diversity and inland location isolated from coastal influences, provides an ideal area to study the contributions of geological and environmental factors to the isotope landscape (isoscape). This study analyzed the distribution of bioavailable Sr, Nd, and Pb isotopes in the province using plant and soil data obtained in this study and from previous works.FindingsChungcheongbuk-do features diverse geological elements, including Precambrian basement, Paleozoic metasedimentary rocks, and Mesozoic granitoids and volcano-sedimentary sequences. The 87Sr/86Sr ratios of bulk soil samples from 44 sites primarily range from 0.781 to 0.706, with two ratios exceeding 0.9 originating from Precambrian basement and Cretaceous granitoid areas. Fractions of soils treated with 1 M ammonium nitrate and acetic acid exhibit indistinguishable 87Sr/86Sr ratios (R2 = 0.99, except for one point), spanning from 0.804 to 0.707. Plant 87Sr/86Sr ratios demonstrate a robust positive correlation with leachate ratios (for ammonium nitrate data, (87Sr/86Sr)plant = 0.938 × (87Sr/86Sr)leachate + 0.045, R2 = 0.98). The εNd values of bulk soils from Precambrian basement areas (–18 to –30) plot against Sm/Nd ratios around the reference line corresponding to 3 Ga, while other bulk soil samples (εNd = –1 to –21) align with a younger (~ 2 Ga) reference line. Plant εNd values, ranging from –4 to –24, exhibit a prominent positive correlation with ammonium nitrate leachates (plant εNd = 0.77 × leachate εNd – 3.83, R2 = 0.89). Plant samples do not show consistent variation between 87Sr/86Sr and εNd. The 206Pb/204Pb and 207Pb/204Pb ratios of bulk soils show a ~ 2 Ga trend, typical for Korean basement rocks. The Pb isotopic ratios of ammonium nitrate and acetic acid leachates match perfectly with each other (R2 = 0.99). The 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios of plant samples vary narrowly (19.2–17.9; 15.8–15.5; 39.0–38.0) and are distinctly different from those of bulk soils (24.4–17.9; 16.5–15.6; 42.5–37.9) and their leachates (23.1–17.7; 16.2–15.6; 41.0–38.1). Plant and soil data from this study and previous works were used to construct Sr and Nd isoscapes, employing interpolation models based on inverse distance weighting, simple kriging, empirical Bayesian kriging, and geology and topography-considered empirical Bayesian kriging regression prediction. These maps await validation through analysis of additional archives.ConclusionsThe isotope data obtained in this study highlight a strong geological control over bioavailable Sr and Nd, in contrast to a dominant environmental influence on bioavailable Pb. The Sr and Nd isoscapes presented here are potentially valuable for addressing archaeological or forensic inquiries in their current state. Nevertheless, the maps would benefit from additional refinement with increased sample density and enhanced interpolation models.

Magmatic and sedimentological arguments for an Ediacaran active margin in the Bayankhongor Zone in western Mongolia, Central Asian Orogenic Belt

Geochronological and geochemical investigation of the magmatic and sedimentary rocks from the south-eastern tip of the Bayankhongor Zone (central Mongolia) constrains the Neoproterozoic evolution of the northern margin of the Baidrag Block. There, ultramafic to felsic igneous rocks of the Khan-Uul Massif intruded the volcano-sedimentary sequence of the Ulziit Gol Unit. U–Pb zircon ages show that both the plutonic and volcanic rocks were coeval products of the same Ediacaran (598–564 Ma) magmatism. Most of the samples have low contents of high field strength elements typical of arc-related magmas; however, some mafic rock samples display N-MORB-like chemistry. Magmatic rocks in the Khan-Uul Massif and Ulziit Gol Unit yielded exclusively positive initial εHf in zircon values (+4.9 to +13.8), implying derivation from depleted-mantle sources. Furthermore, heterogeneity of the whole-rock initial εNd values (–4.0 to +2.1) documents that fractional crystallization was accompanied by variable crustal contamination. The detrital zircon age patterns of the sandstone and tuffites in the Ulziit Gol Unit indicate that the sequence was filled dominantly by Ediacaran magmatic detritus derived from the Khan-Uul Massif and its volcanic equivalents, while the older cratonic material from the Baidrag basement represented only a subordinate component. Combined magmatic and sedimentary records imply that both the Khan-Uul Massif and the Ulziit Gol Unit may have formed in the same back-arc basin environment. This challenges the previous view that the entire Bayankhongor Zone was ophiolitic in nature. Distribution of coeval Ediacaran supra-subduction systems on the scale of the Mongolian Collage indicates the closure of multiple oceanic basins rimming the Siberian Continent. Following Rodinia break-up, this peri-Siberian realm was presumably formed by sub-parallel continental ribbons and oceanic basins. It is proposed that the amalgamation of these blocks and closure of intervening oceans reflected the Ediacaran advancing mode of the Palaeo-Pacific subduction.

Application of Geophysical Methods in the Identification of Mineralized Structures and Ranking of Areas for Drilling as Exemplified by Alto Guaporé Orogenic Gold Province

Mineral exploration works conducted in the Alto Guaporé Gold Province (AGGP), situated in the southwest region of the Amazon Craton in Brazil, faces the challenges of many gold provinces around the world, i.e., declines in the discoveries of new economic deposits and increases in exploration costs. Ground geophysical methods, combined with structural analyses and geological mapping, are valuable tools that have potential to improve accuracy in selecting exploration targets and in determining drilling locations. AGGP deposits are primarily associated with regional N20°–W50° inverse faulting and sheared geologic contacts between Meso-Neoproterozoic siliciclastic metasedimentary rocks and Mesoproterozoic basement (granite and volcano–sedimentary sequences). Mining currently occurring in the central portion of the province drives exploration works towards the many existing targets at the area. Among them, the ABP target is one of the most promising for being located few kilometers north of the Pau-a-Pique mine. At the ABP target, gold is associated with hydrothermal alteration located in the sheared contacts and in the hinge zone of folded metasedimentary sequence. Hydrothermal phases include Fe-oxides, sulfide (py), muscovite and quartz veins. In this study, we use magnetic and geoelectric (induced polarization) surveys coupled with structural and geological mapping to identify potential footprints within the ABP target. The results from induced polarization (IP) profiles successfully mapped the shape and orientation of the main structures down to approximately 350 m at the ABP target, indicating potential locations for hydrothermal alteration hosting gold. Additionally, 3D magnetic data inversions illustrated the distribution of magnetic susceptibilities and magnetization vectors associated with shear zone structures and isolated magnetic bodies. Magnetic data highlighted fault zones along the contacts between metamorphic rocks and granites, while IP data identified areas with high chargeability, correlating with sulfidation zones mineralized with gold. These findings suggest a metallogenic model where gold deposits are transported through deep structures connected to regional faults, implying significant tectonic and structural control over gold deposition. The results underscore the potential of multiparameter geophysics in identifying and characterizing deposits in both deep and strike, thereby advancing our understanding of mineral occurrences in the region and enhancing the search for new mineralized zones.

High-precision U[sbnd]Pb zircon dating of explosive volcanism in an early bi-modal volcano-sedimentary sequence from the Isle of Mull, North Atlantic Igneous Province

The North Atlantic Igneous Province (NAIP) forms one of the best studied Large Igneous Provinces (LIP) on the planet, however, significant uncertainties regarding the age and nature of the early onset of volcanism across the province remain. In order to better understand the onset and timing of volcanism within the NAIP, we present a new study of the mixed volcano-sedimentary deposits exposed at the base of the Isle of Mull lava pile, Inner Hebrides, Scotland. The study area comprises organic rich estuarine sediments, intimately mixed and interdigitated with bi-modal composition volcaniclastic and pyroclastic interlayers, including a prominent stratigraphically constrained c. 30 cm thick water-lain rhyolitic ignimbrite. Pristine magmatic zircons liberated from the ignimbrite reveal a high precision UPb age of 62.035 ± 0.041 Ma (2σ) giving a robust age for early volcanism in this part of the province. Field observations reveal evidence for mafic phreatomagmatic eruptive deposits both above and below the rhyolite documenting the bimodal explosive nature of the initial magmatism in this area and, importantly, that mafic magmatism initiated before the dated unit. The bi-modal explosive eruptions periodically inundated an otherwise quiet and low energy Danian aged estuarine environment prior to its inundation with lava as magmatism took hold in the region.

Constraints on the subduction and closure of the Hegenshan Ocean: Magmatic and sedimentary records from central Inner Mongolia, China

Petrological, geochronological, and geochemical data from the volcano-sedimentary sequences, granitoids, and ophiolite relics of central Inner Mongolia, China, were used to reconstruct the subduction and final closure of the Hegenshan Ocean. Geochronological dating and compilation reveal four phases (ca. 360−355 Ma, 348−320 Ma, 320−310 Ma, and 310−275 Ma) of magmatism in the Uliastai continental margin. The ca. 356 Ma I-type Halatumiao granodiorite and Amanwusu ophiolite relics are subduction-related, and the Halatumiao granodiorite provides solid evidence of the northward subduction of the Hegenshan Ocean beneath the Uliastai continental margin at ca. 360−355 Ma. The ca. 348−320 Ma and 320−310 Ma volcanic rocks and granitoids constitute two linear magmatic belts roughly parallel to the Erenhot-Hegenshan ophiolite belt, which record two phases of continental arc magmatism in the Uliastai continental margin. Overall, the ca. 360−310 Ma arc magmatism shows landward migration and then oceanward migration in the Uliastai continental margin, which indicates advancing subduction and subsequent slab steepening of the Hegenshan Ocean. By contrast, the ca. 310−275 Ma magmatic rocks are dominated by I- and A-type felsic volcanic rocks, granites, and dikes, which are post-accretionary, extension-related, and pervasive in the Uliastai continental margin and Erenhot-Hegenshan ophiolite belt. A provenance shift was identified between the Benbatu and Amushan formations of the Amanwusu area of the Erenhot-Hegenshan ophiolite belt. The early detritus was derived from the early Paleozoic rocks in the Sonid Zuoqi arc belt, whereas the late detritus originated from the Early Carboniferous ophiolite relics in the Erenhot-Hegenshan ophiolite belt. The provenance shift and emplacement of pervasive extension-related magmatic rocks imply a Late Carboniferous closure of the Hegenshan Ocean. The Late Carboniferous oceanic closure event in the north of the southeast Central Asian Orogenic Belt is also evidenced by the transition of Hf isotopic composition of zircons dated between ca. 360−310 Ma and 310−275 Ma.

Structural analysis applied to the tectonostratigraphic reconstruction of the Abadia dos Dourados Metavolcano-sedimentary Sequence, southern Brasília Orogen: Implications for the West Gondwana assemblage

Structural analysis is a valuable tool for organizing the stratigraphy of metamorphic terranes. It allows the reconstruction of pre-to sin-orogenic geological scenarios by unraveling the main transformations, such as distortion, rotation and translation, associated with the collisional process in orogenic belts. The Brasília Orogen, for example, encompasses a complex spectrum of lithological associations and structural patterns that are not well understood because this orogenic belt still has a limited coverage of detailed structural analysis work. The implications of this are problematic for the reconstruction of pre- and sin-collisional processes related to the evolution of western Gondwana. Therefore, this contribution focuses on the Abadia dos Dourados Metavolcano-sedimentary Sequence located between the states of Minas Gerais and Goiás, Brazil. The study includes a field-based structural investigation, including geologic mapping and structural analysis at various scales of observation. It was recognized that the Abadia dos Dourados Metavolcano-sedimentary Sequence comprises a bimodal volcanic association with metarhyolite, metabasalt, banded iron formation and tourmalinite, as well as metapelites and metapsamites from base to top. The data provide additional evidence for a rift-related or back-arc basin-related model for the origin of the Meso-to Neoproterozoic volcano-sedimentary sequences in the Brasília orogen. The structural framework indicates a northeast-southwest crustal shortening event associated with the collision of the Paranapanema and São Francisco-Congo crustal blocks. The event initially produced a large (about 10 km) northeast-verging recumbent fold nappe in the area, which caused a stratigraphic inversion of the metavolcanic-sedimentary sequence. The structure underwent progressive deformation, resulting in superposition patterns between folds, foliations, and intersection lineations. In addition, the structural framework suggests that the West Gondwana collage may be related to a progressive rather than a multiphase structural evolution in the southern Brasília Orogen.

Initial sedimentation after the closure of the Sumdo Paleo-Tethys Ocean: Implications for early Mesozoic tectonics in the East Tethys domain

The closure of the Paleo-Tethys Ocean and subsequent collisional orogenesis in the early Mesozoic played an important role in the formation of the Qinghai–Tibetan Plateau. However, the final closure of the southernmost Paleo-Tethys branching ocean basin in the Qinghai–Tibetan Plateau—known as Sumdo Paleo-Tethys Ocean—and collision between Central and Southern Lhasa terranes remain controversial. In particular, the tectonic significance of early Mesozoic volcanism and sedimentation in the Lhasa terrane is unknown, but crucial for understanding the final stages of ocean closure. Here, we investigate the depositional ages and provenance of detrital zircon in clastic sedimentary rocks, as well as the petrogenesis of the interbedded andesite from the volcano-sedimentary sequence of the Late Triassic to Early Jurassic Xionglai Formation in the Tangjia-Sumdo area. Detrital zircon dates from the Xionglai Formation define five age peaks at 180–200 Ma, 230–340 Ma, 500–620 Ma, 1000–1240 Ma, and 1600–1800 Ma. Detrital zircon trace elements and Hf isotopic characteristics are interpreted to represent derivation from an accretionary wedge and later magmatism related to oceanic slab break-off as well as a minor component from coeval magmatic rocks in the Nyainrong-Nang area in northern Lhasa terrane. Interbedded andesite has a magnesian andesite signature and yields ages of 192–184 Ma with zircon εHf(t) values that range from −3 to +1. We interpret these data as the andesite being sourced from sediment-derived melts that interacted with the overlying mantle wedge in a post-collision extensional setting. Our study suggests that the closure of the Sumdo Paleo-Tethys Ocean and subsequent collision between Central Lhasa and Southern Lhasa terrane may have happened in Late Triassic-Early Jurassic. The final closure of the multi-Paleo-Tethys Ocean and subsequent collision in the Qinghai–Tibetan Plateau may have induced initial subduction of the Meso-/Neo-Tethys Ocean, representing the tectonic transition from collision/post-collision to subduction/accretion in the Qinghai–Tibetan Plateau during the Late Triassic to Early Jurassic.

Fe–Cu mineralization of Tangal-e-Sefid; a magnetite rich massive sulfide deposit from Kuh-e-Sarhangi district, Central Iran

The Tangal-e-Sefid Fe–Cu mineralization forms syngenetic stratiform deposit in the Late Neoproterozoic volcano sedimentary sequence from the Central Iran. Early Cambrian metamorphic rocks are associated ore-bearing geologic units. The mineralization includes early oxide phase as a magnetite-rich bodies that are overprinted by a pyrite-chalcopyrite-rich sulfide phase. The most current alteration zone includes propylitic-carbonate, chlorite, sericite and silicic with a well-developed distribution of chloritization, especially in the layered part. Magnetite, pyrite and chalcopyrite comprise the primary main mineral assemblage, which is accompanied by malachite, covellite, hematite and goethite as the secondary minerals associated with epidote, chlorite, quartz and calcite minerals. Magnetite chemistry reveals the hydrothermal evolution of mineralization, and all the examined magnetite fall within fields of magnetite from VMS deposits. Fluid inclusion analysis of quartz and calcite coexisting with magnetite represent homogenization temperature range of 198 °C and 357 °C with a cooling trend from the massive toward the layered parts. The measured fluid salinity identifies two distinct medium-salinity fluids with mean values corresponding to 15 and 22 wt% NaCl. There is no significant difference in terms of temperature and salinity measured in calcite and quartz minerals. However, the average measured temperature values of fluids trapped in calcite (189–336 °C) are slightly lower than quartz (227–357 °C). Since the ore deposit distribution is spatially associated with actinolite schist, thermometric data of actinolite show temperature fluctuations of 310–315 °C and mineral formation pressures of 2.5–3 Kbar, which are correlated with the low-grade metamorphism.Primary hydrothermal fluids derived from submarine magmatism in an extensional system of seafloor were enriched in Fe and Cu (± Zn and possibly Pb) and it is the responsible for the first stage of magnetite formation and following the overprinting pyrite and chalcopyrite mineralization. The ore deposit geometries associated with magnetite mineralization and sulfide replacement styles; reveals that in the second stage of mineralization, hydrothermal fluid is mixed with oceanic water and eventually metal sulfides are deposited. The mineralizaton zone associated with the volcano-sedimentary sequence is affected by low-grade regional metamorphism related to Pan-African orogeny and represent the green schist territory as the VMS deposits related to Archean.

Unravelling the genesis and depositional setting of Neoproterozoic banded iron formation from central Eastern Desert, Egypt

The Neoproterozoic banded iron formations (BIFs) are widely occurred in the Egyptian Eastern Desert. This study integrates field observations, petrographic studies, geochemical data, and lead isotopes to construct the genesis and depositional environment of Wadi El-Mis hama BIF deposits. The iron layers, primarily of oxide facies within a volcano-sedimentary sequence, comprise magnetite-rich beds alternating with jaspilite or silicate laminae. The studied BIFs exhibit a dominant composition of SiO2 and Fe2O3t with relatively low contents of TiO2 and Al2O3. The positive correlation of REEs (La, Sm, Yb) with Zr and low concentrations of HFSEs (Ta, Nb, Th, Hf) indicate a primary formation mechanism of chemical precipitation, maintaining original geochemical signatures. Geochemical patterns show depletion in LREEs, enrichment in HREEs (La/YbPAAS = 0.08–0.12), and positive La anomalies (La/LaPAAS = 1.15–8.57), consistent with seawater influence. Additionally, various geochemical discrimination diagrams supported by elevated super-chondritic Y/Ho values (29.6–38.7), weak positive Eu anomalies, and low contents of transition metals (Cu and Zn), point to the interaction of low-temperature (<200°C) hydrothermal fluids (bearing Fe and Si) with seawater during the deposition of the BIFs. The lack of significant negative Ce anomalies along with low Ni/Co, U/Th, and Cu/Zn ratios, imply that the iron mineralization was precipitated from dysoxic to oxic conditions. The geochemical and Pb isotopic data suggest that the iron deposits formed in an extensional geodynamic setting (intra-oceanic arc basin environment) due to the subduction of the Mozambique Plate, with signatures closely matching other Precambrian Algoma-type BIFs.

Hadgarh Greenstone Belt: An extension of Tomka Daitari Greenstone Belt, Singhbhum Craton, India

Peripheral volcano sedimentary belts around the nucleus of Singhbhum-Granite-Complex are a part of one of the oldest continental crusts, known as the Singhbhum Craton (SC). Deciphering mutual relationship among these volcano-sedimentary packages offers considerable challenges. Badampahar-Gorumahisani Belt (BG Belt), Tomka Daitari Belt (TD Belt) and Bonai-Kendujhar Belt (BK Belt) draping Singhbhum-Granite-Complex as long linear belts from east, south and west, have some certain difference, primarily in terms of lithology. While the sedimentaries of BG Belt is mainly chemogenic, BK Belt is dominated by terrestrial sediments and TD Belt contains the both. Available data suggests the younger age of BK Belt than the rest couple of belts. Between TD Belt and BG Belt, another volcano sedimentary belt, commonly known as Hadgarh Belt, is present and it is less studied. The present study aims to characterize the Hadgarh Belt based on lithology and structure, which indicates its similarity with TD Belt. Almost identical lithologies are manifested by these two volcano sedimentary sequences barring the fact that the Hadgarh Belt has minor dominance of metasediments over metavolcanics, which is in subequal proportion in Tomka-Daitari and sensustricto BIF bands are absent in Hadgarh Belt. Both the belts have undergone uniform polyphase deformation and metamorphism. In both the belts, volcano sedimentary sequence of IOG is overlain by less deformed younger Mahagiri Quartzites and they are separated by an angular unconformity, marked by an impersistent conglomerate horizon. The intermediate area also sustains the similarities in depositional and deformational history with respect to the TD and Hadgarh belts on either side. Petrological studies also invoke similar mineral assemblage in the two belts, which is also in corroboration with the petrochemistry of the litho-units concerned. All the data thus generated, shows that the area, in totality, was evolved in an island arc setting varying from deep to shallow marine environments and sequence of deformations, intrusion of ultramafics followed by granite are also similar. In a nut shell, Hadgarh Belt can be referred as an extended part of the TD Belt.

Pillow Morphology of Bathani Volcano-sedimentary Sequence of Eastern Indian Shield: Inferences on the Geotectonic and Geo-Environments

Abstract The Palaeo-proterozoic Bathani volcano-sedimentary sequence (BVSs) at the northeastern fringe of the Central Indian Tectonic Zone (CITZ), comprises three distinct litho-domains: (i) intrusive granitoid, having xenoliths of basalt, pyroxenite-gabbro-anorthosite suits (Northern Domain), (ii) low-grade volcano-sedimentary sequence along with concordant mafic-ultramafic intrusion (Central Domain) and (iii) folded clastic metasedimentary rocks (Southern Domain). The granitoid is intruded into the Central Domain, where pillow basalt with primary structure is well exposed. The volcanological and morphometric study of the pillows of Central Domain is attempted to understand the physicochemical characteristics and tectonic setup of the magma emplacement. The pillows are small to medium normal-sized with spheroidal, lozenge, and tubular shapes and preserve the primary features like radial and concentric cracks, selvage, pipe vesicles, voids, drain away cavities, way-up features, etc. A low-viscosity magma outpouring over a steep to moderate depositional slope is being deciphered from the morphological study of pillows. The stretching and fast-spreading growth mechanisms with low effusion under a rapid cooling rate have been inferred for these pillows. The morphological features of the rock types and pillows of the BVSs suggest a shallow water (<1000m) divergent rift basin of the back-arc tectonic setting. The trace elemental discrimination plots support the basaltic composition of pillows with E-MORB and back-arc basin environment. The lithological setup, tectonic setting, and regional correlation of BVSs advocate it as an eastern continuation of the Palaeo-proterozoic Mahakoshal belt within the Son Narmada Lineament (SNL) zone of CITZ.

A late Carboniferous transition from subduction to collision: Tectono-sedimentary evidence from southern Junggar, NW China

The Carboniferous to Permian tectono-sedimentary evolution of the southern Junggar area brings new insights into understanding the subduction-collision processes in the northern Tianshan region. Integrating geophysics, geochemistry, and geochronology approaches, this study investigates the Carboniferous–Permian strata in the southern Junggar Basin. The results have revealed three distinct tectono-stratigraphic evolutionary stages, each marked by a distinctive volcano-sedimentary sequence. The Early Carboniferous strata suggest intense volcanic activities in the southern Junggar area. During the Late Carboniferous, the southern Junggar Basin was controlled by normal faulting in an extensional setting, receiving sedimentary inputs from the Junggar terrane. The Lower Permian, unconformably overlying the Upper Carboniferous, was shaped by an extensional regime and is comprised by volcano-clastic sequences that received detritus from the Yili-Central Tianshan block. These findings indicate that a Late Carboniferous forearc basin developed in the southern Junggar area, and it evolved into a post-collisional rift in the Early Permian. This period marked a dynamic shift from bidirectional subduction (rollback) to the detachment of the North Tianshan oceanic slab. We propose that the collision between the Yili-Central Tianshan block and the Junggar terrane, along with the closure of the North Tianshan Ocean, likely occurred in the Late Carboniferous (ca.306–303 Ma).

Origin of calcite by magma mixing in mingled rocks of the Ghansura Rhyolite Dome, Bathani volcano-sedimentary sequence, eastern India

Abstract The Ghansura Rhyolite Dome (GRD) is an integral part of the Bathani volcano-sedimentary sequence (BVSs), which in turn is a vital component of the Chotanagpur Granite Gneiss Complex (CGGC), eastern India. The rhyolite dome represents a shallow-level felsic magma chamber that underwent intrusion by basaltic magma during its evolution. The rocks present in the felsic dome such as basalts, rhyolites, and intermediate hybrid rocks preserve evidence of magma mixing and mingling. The objective of this contribution is to take into account, for the first time, that magma mixing processes can play an important role in the generation of calcite in magmatic rocks. The present study focuses on the mingled rocks exposed within the rhyolite dome. Previous reports have documented the existence of two distinct zones (mafic and felsic) interfacing each other in the mingled rocks of the rhyolite dome. The mafic zones dominantly consist of mineral phases such as actinolite, hornblende, biotite, plagioclase, ilmenite, calcite, and titanite. The felsic zones comprise quartz, K-feldspar, plagioclase, and biotite. When mafic magma intruded into the felsic magma chamber, interaction between the mafic and felsic magmas caused diffusion of H, Al, and K ions from the felsic to the mafic endmember. Such diffusive activities resulted in the breakdown of augite, already crystallized in the mafic magma, to form newer minerals like actinolite, hornblende, biotite, calcite, and ilmenite. The presence of ilmenite in the mingled rocks indicates the prevalence of reducing conditions during magma interaction and evolution. Breakdown of hornblende to biotite in such a reduced environmental condition led to the formation of calcite in the mingled rocks. From the results presented in this work, we are proposing that magma mixing can be a viable mechanism to form calcite in igneous rocks by magmatic processes.

Tectonics and evolution of the Palmeiras and Xai-Xai Grabens, offshore southern Mozambique

The tectonic evolution of the Mozambique Basin was controlled by the break-up of Gondwana which led to the development of extensional domains along the East African margin. As a result, multiple grabens systems were formed both onshore and offshore southern Mozambique. Two of them are the Palmeiras and Xai-Xai grabens, which are discussed in greater details in this study using an extensive seismic dataset, together with regional gravity and magnetic data. The data show that the Palmeiras Graben evolved from a single extensional phase in the Middle to Late Jurassic (Kimmeridgian?). In contrast, the Xai-Xai Graben records three extensional phases. The first extensional phase occurred in the Late Jurassic (Tithonian?) to Early Cretaceous (Berriasian), the second during the Aptian-Albian and the third in the Late Miocene. The tectonic evolution of these grabens strongly controlled their sedimentary infill during Late Jurassic and Early Cretaceous rifting.Volcanism associated to these tectonic events is documented by onshore and offshore boreholes, as well as by the presence of buried volcanic bodies, lava extruded along fault planes and intrusions of Mesozoic age. Furthermore, a volcano-sedimentary sequence and dome type volcanoes were imaged in seismic data.Differences in tectonic activity impacted the oil and gas potential of both the Palmeiras and Xai-Xai grabens. The sedimentary sequences deposited in the Palmeiras Graben were preserved due to a period of relative tectonic stability predominating from the Aptian to the present day. The burial of the Palmeiras Graben during this period of tectonic stability under a thermal subsidence favoured the generation and preservation of hydrocarbons. In contrast, the Xai-Xai Graben was impacted by intense tectonics, which led to a limited or restricted deposition of strata since the Late Cretaceous to the Paleocene – Early Eocene. As a consequence of a long lasting tectonic activity in the Xai-Xai Graben, uplifting and erosion of potential reservoirs and destruction of existing traps, impacted on the prospectivity for hydrocarbons.

Sub-basalt hydrocarbon prospect assessment in Peninsular India using seaward dipping reflectors

Conventionally, volcanic margins have been considered devoid of hydrocarbon, but many discoveries and research in recent past have proved the presence of hydrocarbon prospects within them. However, hydrocarbon exploration within volcanic margin is constrained by seismic imaging. Further, identification of continent to oceanic boundary (COB) is critical to hydrocarbon search as hydrocarbon is found mostly over continental crust. Seaward dipping reflectors, associated with volcano-sedimentary sequences, located along rifted continental margins and represented by highly dipping strong amplitude seismic reflectors, play an important role to study volcanic margins. Keeping in view the problems of hydrocarbon exploration within volcanics, seaward dipping reflectors (SDRs) in Indian context have been studied in detail in this paper. It facilitates mapping of continent-oceanic boundary (COB). It has impact on hydrocarbon prospectivity in volcanic margins as it can provide formidable seal and secondary induced maturity. In India, several discoveries have been made in volcanic margins along west coast, from weathered, fractured basalt and sub-basalt sediments. In the present work, long offset regional seismic data (18 dip lines and 1 cross line), along east coast, have been interpreted. SDRs help in hydrocarbon prospectivity assessment for both discrimination of interbedded sediments and preferential accumulation of hydrocarbon. Mapping of linear features not only helped to demarcate COB but also their presence at 6–10 km depth. For the first time, such comprehensive study on SDRs has been done along Indian peninsular region with indications for hydrocarbon prospectivity at deeper levels along Indian peninsular region.

The Artulândia prospect area: A newly discovered Paleoproterozoic Zn–Pb–Cu-(±Ag–Bi) VHMS mineralization in Campinorte Magmatic Arc, Central Brazil

The Artulândia prospect area is a recently-mapped, non-auriferous VHMS mineralization within Paleoproterozoic rocks in Central Brazil. The mineralization is hosted in a felsic-dominated bimodal volcano-sedimentary sequence that formed during the onset of Campinorte Magmatic Arc. The Zn–Pb–Cu-(±Ag–Bi) VHMS mineralization occurs as massive sulfide lenses and sulfide disseminations. Surrounding the sulfide lenses, two proximal hydrothermal assemblages are identified: (i) Tremolite-spessartine (±clinochlore-epidote) assemblage, associated with the sphalerite-pyrite aggregates and (ii) Clinochlore-carbonate (±tremolite-talc-serpentine) assemblage encompassing chalcopyrite, galena, and sphalerite. Besides these two assemblages, three others are considered distal to the mineralization, and interpreted to represent the stringer zone: (i) Biotite-spessartine (±chamosite-tourmaline) assemblage, with disseminated sphalerite + pyrite + galena, (ii) Biotite-sericite-carbonate (±chamosite) assemblage, with disseminated pyrite + sphalerite and (iii) Biotite-carbonate assemblage, with pyrite and traces of sphalerite intergrown with biotite lamellae. The mineralogy of the assemblages results from the Paleoproterozoic, syn-volcanic metamorphism (Neoproterozoic, Brasiliano Orogeny) of hydrothermal alteration minerals. The mineralogy and mineral chemistry data of the assemblages show that proximal assemblages formed under great influence of Fe–Mg–Ca-rich fluids. The highest grades of base metals are restricted to the sulfide lenses: Zn (1.4% wt.), Pb (1.0% wt.%), and Cu (1.8% wt.). Anomalous contents of Mo (>180 ppm), Bi (>700 ppm) and Ag (>60 g/t) occur in the proximal hydrothermal assemblages. Gold grades as high as 270 ppb are directly related to chalcopyrite-enriched zones. The δ34S measurements in pyrite vary from +8.77‰ to +10.99‰. These values are compatible with Paleoproterozoic deposits in which the isotope composition reflects a mix of seawater and leached sulfur from host rocks.

Paleoproterozoic Variolitic Lavas from the Onega Basin, Fennoscandian Shield: Mineralogy, Geochemistry and Origin

The Yalguba Ridge volcanic rocks form part of the Middle Paleoproterozoic (ca. 1.97 Ga) volcano-sedimentary sequence within the Karelian Craton in the Fennoscandian Shield. Yalguba variolitic textures are known worldwide and have been previously considered to originate from liquid immiscibility. The present study reveals two new variolite types recognized in the Yalguba sequence: (1) Variolites with unzoned varioles have distinct chemical and mineralogical compositions of varioles and matrix that support an origin by liquid immiscibility. They were recognized in quenched zones of pillows, so it might be assumed that melt separation caused by liquid immiscibility occurred before magma emplacement. The difference from the previously described variolites lies in the variole microtexture and might be caused by the various cooling conditions. (2) Spherulitic variolites have varioles composed of andesine–oligoclase spherulites embedded in the cryptocrystalline matrix with oligoclase–anorthoclase composition, thus the variole and matrix have similar chemical and mineralogical composition. The mineralogical and textural features of these variolites suggest that the spherulites have a primary magmatic origin due to the rapid cooling of superheated magma. The variety of variolitic textures in the Yalguba section might be caused by the different H2O saturation of parental magma and cooling conditions.

Remote Sensing, Petrological and Geochemical Data for Lithological Mapping in Wadi Kid, Southeast Sinai, Egypt

The Wadi Samra–Wadi Kid district in southeastern Sinai, Egypt, has undergone extensive investigation involving remote sensing analysis, field geology studies, petrography, and geochemistry. The main aim of this study is the integration between remote sensing applications, fieldwork, and laboratory studies for accurate lithological mapping for future mineral exploration in the study region. The field relationships between these coincident rocks were studied in the study area. Landsat-8 (OLI) data that cover the investigated area were used in this paper. The different rock units in the study area were studied petrographically using a polarizing microscope, in addition to major and trace analysis using ICP-OES tools. The Operational Land Imager (OLI) images were used with several processing methods, such as false color composite (FCC), band ratio (BR), principal component analysis (PCA), and minimum noise fraction (MNF) techniques for detecting the different types of rock units in the Wadi Kid district. This district mainly consists of a volcano-sedimentary sequence as well as diorite, gabbro, granite, and albitite. Geochemically, the metasediments are classified as pelitic graywackes derived from sedimentary origin (i.e., shales). The Al2O3 and CaO contents are medium–high, while the Fe2O3 and TiO2 contents are very low. Alkaline minerals are relatively low–medium in content. All of the metasediment samples are characterized by high MgO contents and low SiO2, Fe2O3, and CaO contents. The granitic rocks appear to have alkaline and subalkaline affinity, while the subalkaline granites are high-K calc-alkaline to shoshonite series. The alkaline rocks are classified as albitite, while the calc-alkaline series samples vary from monzodiorites to granites. The outcomes of this study can be used for prospecting metallic and industrial mineral exploration in the Wadi Kid district.

Identification of non-conventional groundwater resources by means of machine learning in the Aconcagua basin, Chile

Study regionOur study region is the Aconcagua basin, central Chile. The catchment, home to over 500,000 people, currently experiences a multiyear drought that threatens water security. In this context, there is an impending need to explore unconventional groundwater resources, such as peripheral hard rock and deep aquifers. Study focusThe focus of this study is the application of machine learning techniques to identify areas of potentially untapped groundwater resources in the middle and upper reaches of the Aconcagua basin. New hydrological insights for the regionMachine learning classifiers accurately depict those areas known for their high groundwater potential, including the San Felipe, Putaendo, Panquehue, Catemu and Llay-Llay sectors. The Mesozoic sedimentary sequences and intrusive units of the coastal range, together with the Neogene units of the Andes range, are correctly identified as areas of very low hydrogeological interest. A major novelty of this study is the delineation of several new areas of potentially high groundwater prospect, namely, the geological domain associated with the Pocuro fault system, the Teatinos-Volcan-River fault system, and the Las Chilcas volcano-sedimentary sequence, in the Chacabuco Range. These findings are in line with the results of complementary studies, thus suggesting that machine learning applications may successfully underpin groundwater exploration across other groundwater basins in the coastal Andean region.