Volcanic Crust Research Articles

Geophysical characteristics of internal weathered volcanic crust in the Songliao Basin

Geophysical characteristics of internal weathered volcanic crust in the Songliao Basin

Hydrothermal Seepage of Altered Crustal Formation Water Seaward of the Middle America Trench, Offshore Costa Rica

AbstractChemical compositions of sediment pore waters are presented from 13 piston and gravity cores that were collected on ∼24 Ma crust of the Cocos Plate seaward of the Middle America Trench and near the onset of crustal faulting from subduction. Cores were collected mainly within a 1.75 km2 area overlying a buried basement topographic high that supports an elevated heat flux, consistent with seawater transport within the upper volcanic crust. Systematic variations in pore water chemical profiles indicate upward seepage speeds (up to 1.7 cm yr−1 providing a net flux of 0.1 L s−1), constrain the chemical composition of the formation water within the underlying upper basaltic basement, and elucidate diagenetic reactions in the sediment. Relative to seawater, formation water has an elevated temperature (70–80°C) and concentrations or values of Ca, chlorinity, Sr, Ba, Li, Fe, Mn, Si, Cs, D/H, and Mo, and lower concentrations or values of Mg, Na, sulfate, alkalinity, TCO2, K, B, F, phosphate, 87Sr/86Sr, δ13C, δ18O, U, and Rb. Although this site is located only 30 km from the trench axis, there is no chemical evidence for subduction‐related hydrologic influences. Instead, the data are explained by a combination of seawater‐basalt reactions within the upper basement and diffusive exchange with overlying sediment, as part of a shallow, ridge‐flank hydrothermal system. It is unclear why this site has an elevated heat flux relative to neighboring crust, but this may result from variations in crustal properties or modification related to flexural faulting outboard of the trench.

Lateral changes of crustal extension and passive margin type along the Brazilian southeastern margin

For the last half century, studies based on an increasing, diverse data set, have focused on passive continental margin evolution, as a result of a sequence of tectonic processes that occur in crustal scale and in the geological time. Where extensive subsurface data exists, two distinct endmembers of continental margin architectures were first described along specific margins of the North Atlantic: 1) wide continent-ocean transitions or hyper-extended; 2) narrow continent-ocean transitions or hypo-extended. The lateral transition between these endmember margins, which can occur laterally in short distances, is still not fully understood. The same two endmember margin types are observed across passive margins around the world and notably along the South Atlantic margin. In an area known for controversial interpretations about the crustal nature and the limits of thinned continental crust, this investigation integrates crustal thickness, seismic interpretation, and facies analyses across ∼150,000 km of seismic data along the Brazilian southeastern margin. This study has implications for those investigating the crustal geometry variations for basin analysis and results impact hydrocarbon assessments for the southeastern margin of Brazil. We resume continental margin analyses, in a critical moment as hydrocarbon exploration advances from the continental slope to ultra-deep waters. Results indicate a marked change from a narrow, hypo-extended, sub-aerial, Iceland-like, plume-related volcanic crust in the Pelotas Basin, to a hyper-extended, Iberia-like, magma-rich crust in the Santos Basin, which is separated by a pronounced oceanic transform-fault zone. Dextral movement along this NW-oriented fault zone accommodated differential extensional rates between the hypo- and the hyper-extended margins. Lateral variations in magmatic content within these margin types are interpreted as result from the interaction with mantellic plumes. Margin architecture can locally be affected by pre-existing fault zones and be later modified by oceanic transform faults. The interactions between crustal extensional rates, crustal rheology, mantle underplating, and volcanic material exhumed through mantle-derived plumes, are the key controls for the evolution of continental margins. Tectonic framework classification proposed in this study presents an alternative, original model for continental passive margins evolution.

The influence of permeability anisotropy in the upper ocean crust on advective heat transport by a ridge-flank hydrothermal system

In this study, we highlight the importance of permeability anisotropy on the hydrogeological regime of a ridge-flank hydrothermal system. Our study site, North Pond, is a marine sediment pond on ∼8 Ma seafloor in the North Atlantic, and represents a low-temperature, end-member ridge-flank hydrothermal system. Previous simulations of North Pond elucidated long-standing hypotheses concerning hydrothermal fluid and heat transport in the upper volcanic crust but failed to fully explain observed patterns of seafloor heat flux in this area. Here we use variography, a geostatistical method, to quantify relations between seafloor heat-flux measurements, and coupled numerical simulations of fluid and heat flow to simulate the hydrogeologic regime. Directional variography shows that heat-flux observations are correlated along-strike of the regional crustal fabric. Three-dimensional simulations that include permeability anisotropy are able to replicate seafloor heat-flux patterns across North Pond. The simulations that result in the best match to thermal data incorporate permeability anisotropy in the horizontal plane. We find that the feedback between permeability anisotropy and the asymmetric geometry of North Pond combine to promote advective removal of heat and mass within the crustal aquifer. These findings suggest that permeability anisotropy in the oceanic crust may influence ridge-flank hydrothermal circulation more broadly.

Bathymetry of Valdivia Bank, Walvis Ridge, South Atlantic Ocean: Implications for Structure and Geologic History of a Hot Spot Plateau

AbstractValdivia Bank is an oceanic plateau in the South Atlantic formed by hot spot magmatism at the Mid‐Atlantic Ridge during the Late Cretaceous. It is part of the Walvis Ridge, an aseismic ridge and seamount chain widely considered to be formed by age‐progressive volcanism from the Tristan‐Gough plume. To better understand the formation and history of this edifice, we developed a bathymetric map of Valdivia Bank by merging available multibeam echosounder data sets with a bathymetry grid based mainly on satellite altimetry (SRTM15+). The bathymetric map reveals previously unresolved features including extensive rift grabens, volcanic mounds and knolls, and large‐scale sediment transport systems. After Valdivia Bank was emplaced and probably eroded at sea level, it underwent a period of rifting, followed by a secondary magmatic pulse that caused regional uplift to sea‐level, followed by subsidence to current depths. Shallow banks at depths of ∼1,000 m are the result of a thick sediment pile atop uplifted volcanic crust. Several shallower mounds (∼1,000–520 m) and a guyot (∼220 m) likely resulted from coral reef growth atop one or more volcanic pedestals formed during the younger Cenozoic magmatic event. As sediments accumulated on the shallow platforms, sediment transport systems developed as gullies, channels and mass transport deposits carved valleys and troughs, shedding sediment into abyssal fans at the plateau base. The new bathymetric map demonstrates that oceanic plateaus are geologically active long after initial emplacement.

The relation of the “four properties” and fluid identification of the carboniferous weathering crust volcanic reservoir in the Shixi Oilfield, Junggar Basin, China

This study addresses the poorly understood physical properties of the Shixi Oilfield reservoir, which consists of a weathered Carboniferous volcanic rocks with strong heterogeneity and in which logging identification and evaluation are difficult. Using the lithology, lithofacies, and reservoir space characteristics of volcanic materials, this comprehensive study uses core, well logging, mud logging, and production testing data to analyze the relationship among the lithology, physical properties, electrical properties, and oil-bearing properties (referred to as the “four properties”) of weathered Carboniferous volcanic crust in addition to fluid identification. 1) The lithology of Carboniferous volcanic crust is dominated by breccia lava, agglomerate, banded lava, and compact tuff, and the lithofacies are mainly effusive facies. Secondary pores and tectonic fissures are important reservoir spaces, and the corrosion-fracture pores are significant for reservoir properties. 2) The “four properties” of volcanic reservoirs in the study area have clear relationships. On this basis, data on the electrical properties of the material, such as interval transit time, density, and neutron, were used to establish a logging interpretation model of the properties and oil saturation of the volcanic rock. 3) Using the resistivity-porosity cross-plot method, normal probability distribution method, and Rt/Rxo-Rt cross-plot method, volcanic reservoir fluids were identified with coincidence rates of 80%, 63.63%, and 63.63%, respectively. The cross-plot method determines lower limits of the reservoir’s physical properties and oil saturation, yielding porosity>9%, permeability>0.2 mD, and oil saturation>45%.

Quantitative characterization of fracture-pore distribution and effects on production capacity of weathered volcanic crust reservoirs: Insights from volcanic gas reservoirs of the Dixi area, Junggar Basin, Western China

Igneous hydrocarbon reservoirs worldwide are of significant importance to the petroleum industry for oil and gas exploration. The Carboniferous weathered volcanic crust reservoirs of the Dinan salient in the northern Junggar Basin are major exploration targets of PetroChina. The present study analyzes the geological, well logging, and production data to formulate development and distribution methods for quantitative characterization of weathered volcanic crust fractures and examine their fracture-pore distributions. The effects of the fracture-pore distribution on the productivity of various lithologies of weathered volcanic crust reservoirs were investigated. Various volcanic lithofacies demonstrate the lithological differences in their physical properties, fracture development, and distributions due to the conspicuous variations in weathering resistance among different volcanic rock types. The present study revealed the level of physical properties of volcanic rocks, which are ranked as follows: volcanic breccia > mafic lava > tuff > felsic intrusive rock. However, the degree of fracture development ranked differently from most developed to least developed as follows: felsic intrusive rock > mafic lava > volcanic breccia > tuff. The fracture distribution was primarily controlled by lithology, rock stratum thickness, degree of weathering and leaching, along with tectonism. Compared to other rock types, felsic intrusive rock and mafic lava were more prone to fracturing owing to different petrophysical properties. Additionally, fractures typically developed in single lithological bodies with a thickness of less than 15 m and were characterized by the “single-section” developing mode. For lithological bodies of thickness greater than 15 m, fracture development was more limited, primarily concentrated at the top and bottom of the lithological body and characterized by the “bi-section” or “tri-section” developing modes. These differences can be quantitatively characterized by the fracture development thickness, fracture layer density, and fracture development thickness ratio. Moreover, the influence of the degree of fracture development on the productivity of mafic lava and felsic intrusive gas reservoirs was higher than that of the porosity; however, volcanic breccia and tuff exhibited the opposite effect. The production capacity of weathered volcanic crust reservoirs is affected by the following factors in the order of degree of fracture development > porosity > lithology > thickness of a single lithological body > distance from the top surface of the weathered crust. These quantitative characterization methods can provide valuable technical support for optimizing favorable exploration targets.

Computation of Vertex‐Based Topological Indices of Middle Graph of Alkane (CtH2t+2)

Alkanes are the primary constituents of methane or natural gas that can also be found in volcanic crust. As a result of methane as a heat source, humans may cook without using any fuel in a volcanic environment. Propane which is an alkane derivative is safer alternative to methane and is commonly present in gas cooking fuel, as well as a tiny amount of gasoline and matches. The primary ingredient in automobile especially gasoline is also alkane in the form of octane. Topological indices are largely applied in chemistry to improve the quantitative structure relationship in which the properties of the molecules can be linked with their chemical structures. In this research work, we will calculate the certain well‐known topological indices of the middle graph of alkane based on vertex degree and also present a numerical and graphical comparison of computed topological indices.

Numerical Simulation of Cool Hydrothermal Processes in the Upper Volcanic Crust Beneath a Marine Sediment Pond: North Pond, North Atlantic Ocean

AbstractLow temperature hydrothermal systems hosted in the volcanic oceanic crust are responsible for ∼20% of Earth's global heat loss. Marine sediment ponds comprise an important type setting on young ridge flanks where hydrothermal circulation advectively extracts lithospheric heat, but the nature of coupled fluid‐heat transport in these settings remains poorly understood. Here we present coupled (fluid‐heat) numerical simulations of ocean crustal hydrogeology in and below North Pond, a sediment pond on ∼8 Ma seafloor of the North Atlantic Ocean. Two‐ and three‐dimensional simulations show that advective transport beneath North Pond is complex and time varying, with multiple spatial and temporal scales, consistent with seafloor and borehole observations. A unidirectional, single‐pass flow system is neither favored nor needed to match the spatial distribution of seafloor heat flux through North Pond sediments. When the permeability of the crustal aquifer is relatively high (10−10–10−9 m2), simulations can replicate much of the observed variability and suppression of seafloor heat flux and can explain basement overpressures and transient perturbations in pressure and temperature in the upper volcanic crust. Simulation results can also help explain heterogeneity in pore fluid chemistry and microbiology in the crust. Although driven by the same physical processes, the dynamics of hydrothermal circulation below North Pond are different from those seen on "discharge‐dominated" ridge flanks, where the permeability and exposed area of isolated basement outcrops control the extent of regional heat extraction.

Extrusive upper crust formation at slow-spreading ridges: Fault steering of lava flows

The structure of the oceanic upper volcanic crust is less understood at slow-spreading ridges than at faster ones. Its construction is dominated by pillow lavas, reflecting lower effusion rates than those at fast spreading ridges, where sheet and lobate flows are common and flow off-axis while thickening the extrusive volcanic layer. Based on optical and high-resolution bathymetry data from the Lucky Strike segment (Mid-Atlantic Ridge), we document a mode of volcanic emplacement that likely operates at some magmatically robust slow- and ultra-slow spreading ridge segments, in the presence of strong gradients in magma supply. In these settings, sheet flows may efficiently transport melt away from magmatically robust segment centers in the along-axis direction, steered by normal faults, and exploiting along-axis topographic gradients, with limited across-axis flow. Surface lineations of sheet lava flows tend to be subparallel to fault scarps and the overall segment orientation, and show whorls, well-developed lava channels with associated levees, and surface fold structures at flow fronts. This mode of lava emplacement transitions away from the segment center to pillow-dominated seafloor near the segment ends, associated often with hummocks and axial volcanic ridges. This results in local lava emplacement due to a melt supply that is lower than at the segment center. We propose that fault-steering of lava flows along-axis, limiting off-axis transport as observed at fast-spreading systems, may be common at both slow- and ultra-slow spreading ridges with significant along-axis changes in magma supply linked to topographic gradients. As a result, the nature and properties of the extrusive volcanic layer may vary significantly along axis owing to changes in the modes of volcanic emplacement, as transitions from sheet flows to pillow lavas may impact the porosity structure and hence the seismic properties of the extrusive layer in the oceanic upper crust.

Mineralogy and density of Archean volcanic crust in the mantle transition zone

The composition of Archean volcanic crust can be characterized by a higher Mg/Si ratio than modern mid-ocean ridge basalt (MORB), because of the higher degree melting from the warmer mantle in the Archean. Although modern MORB may become less dense than the surrounding mantle beneath the mantle transition zone (MTZ), the Mg-rich composition of Archean volcanic crust may result in the different density, and therefore different sinking behavior near the MTZ. In order to understand the compositional effect of Archean volcanic crust on the sinking behaviors and the scale of mantle mixing in the Archean, we investigated the mineralogy and density of Archean volcanic crust near the MTZ (470–910 km-depth). We conducted experiments at 19–34 GPa and 1400–2400 K using the laser-heated diamond anvil cell (LHDAC) combined with in-situ X-ray diffraction (XRD). The in-situ XRD and the chemical analysis revealed that Archean volcanic crust forms garnet and ringwoodite (84 and 16 vol%, respectively), which gradually transforms to Brg and CaPv (82 and 18 vol%, respectively) at 23–25 GPa and 1800 K. Our in-situ XRD experiments allowed us to measure the volumes of stable phases and to estimate their densities at high pressure and temperature. The results suggest that Archean volcanic crust maintains greater density than the pyrolitic mantle in the Archean regardless of temperature at 20–34 GPa (570–850 km-depth), promoting further sinking into the deeper mantle in the Archean. We also considered the density of the subducting slab in the Archean. The density model showed that the subducting slab is still denser or at least equally dense as the surrounding pyrolitic mantle in the Archean.

Subseafloor Cross‐Hole Tracer Experiment Reveals Hydrologic Properties, Heterogeneities, and Reactions in Slow‐Spreading Oceanic Crust

AbstractThe permeability, connectivity, and reactivity of fluid reservoirs in oceanic crust are poorly constrained, yet these reservoirs are pathways for about a quarter of the Earth's heat loss, and seawater‐rock exchange within them impact ocean chemical cycles. We present results from the second ever cross‐hole tracer experiment within oceanic crust and the first conducted during a single expedition and in slow‐spreading crust west of the Mid‐Atlantic Ridge at North Pond. Here we employed boreholes that were drilled by the Integrated Ocean Drilling Program (Sites U1382 and U1383) that were instrumented and sealed. A cesium salt solution and bottom seawater tracer experiment provided a measure of the minimum Darcy fluid velocity (2 to 41 m/day) within the upper volcanic crust, constraining the minimum permeability of 10−11 to 10−9 m2. We also document chemical heterogeneities in crustal fluid compositions, rebound from drilling disturbances, and nitrification within the basaltic crust, based on systematic differences in borehole fluid compositions over a 5‐year period. These results also show heterogeneous fluid compositions with depth in the borehole, indicating that hydrothermal circulation is not vigorous enough to homogenize the fluid composition in the upper permeable basaltic basement, at least not on the time scale of 5 years. Our work verifies the potential for future manipulative experiments to characterize hydrologic, biogeochemical, and microbial process within the upper basaltic crust.

Melt movement through the Icelandic crust.

We use both seismology and geobarometry to investigate the movement of melt through the volcanic crust of Iceland. We have captured melt in the act of moving within or through a series of sills ranging from the upper mantle to the shallow crust by the clusters of small earthquakes it produces as it forces its way upward. The melt is injected not just beneath the central volcanoes, but also at discrete locations along the rift zones and above the centre of the underlying mantle plume. We suggest that the high strain rates required to produce seismicity at depths of 10-25 km in a normally ductile part of the Icelandic crust are linked to the exsolution of carbon dioxide from the basaltic melts. The seismicity and geobarometry provide complementary information on the way that the melt moves through the crust, stalling and fractionating, and often freezing in one or more melt lenses on its way upwards: the seismicity shows what is happening instantaneously today, while the geobarometry gives constraints averaged over longer time scales on the depths of residence in the crust of melts prior to their eruption. This article is part of the Theo Murphy meeting issue 'Magma reservoir architecture and dynamics'.

The plutonic crust of Kohistan and volcanic crust of Kohistan–Ladakh, north Pakistan/India: lessons learned for deep and shallow arc processes

Abstract The Kohistan–Ladakh terrane, northern Pakistan/India, offers a unique insight into whole-arc processes. This research review presents summaries of fundamental crustal genesis and evolution models. Earlier work focused on arc sequence definition. Later work focused on holistic petrogenesis. A new model emerges of an unusually thick ( c. 55 km) arc with a c. 30 km-thick batholith. Volatile-rich, hornblende ± garnet ± sediment assimilation-controlled magmatism is predominant. The thick batholith has a complementary mafic–ultramafic residue. Kohistan crustal SiO 2 contents are estimated at >56%. The new-Kohistan, silicic-crust model contrasts with previous lower SiO 2 estimates ( c. 51% SiO 2 crust) and modern arcs that imply <35 km crustal thicknesses and arc batholith thicknesses of c. 7 km. A synthetic overview of Kohistan–Ladakh volcanic rocks presents a model of an older, cleaved/deformed Cretaceous volcanic system at least 800 km across strike. The Jaglot–Chalt–Dras–Shyok volcanics exhibit predominant tholeiitic-calc-alkaline signatures, with a range of arc-related facies/tectonic settings. A younger, post-collisional, Tertiary silicic volcanic system (the Shamran–Dir–Dras-2–Khardung volcanics) lie unconformably upon Cretaceous basement, and erupted within an intra-continental tectonic setting. Kohistan–Ladakh tectonic model controversies remain. In essence, isotope-focused researchers prefer later (Tertiary) collisions, whilst structural field-geology-orientated researchers prefer an older (Cretaceous) age for the Northern/Shyok Suture.

Field-scale permeability and temperature of volcanic crust from borehole data: Campi Flegrei, southern Italy

We report combined measurements of petrophysical and geophysical parameters for a 501-m deep borehole located on the eastern side of the active Campi Flegrei caldera (Southern Italy), namely (i) in situ permeability by pumping tests, (ii) laboratory-determined permeability of the drill core, and (iii) thermal gradients by distributed fiber optic and thermocouple sensors. The borehole was drilled during the Campi Flegrei Deep Drilling Project (in the framework of the International Continental Scientific Drilling Program) and gives information on the least explored caldera sector down to pre-caldera deposits. The results allow comparative assessment of permeability obtained from both borehole (at depth between 422 a 501 m) and laboratory tests (on a core sampled at the same depth) for permeability values of ~10−13 m2 (borehole test) and ~10−15 m2 (laboratory test) confirm the scale-dependency of permeability at this site. Additional geochemical and petrophysical determinations (porosity, density, chemistry, mineralogy and texture), together with gas flow measurements, corroborate the hypothesis that discrepancies in the permeability values are likely related to in-situ fracturing. The continuous distributed temperature profile points to a thermal gradient of about 200 °C km−1. Our findings (i) indicate that scale-dependency of permeability has to be carefully considered in modelling of the hydrothermal system at Campi Flegrei, and (ii) improve the understanding of caldera dynamics for monitoring and mitigation of this very high volcanic risk area.

Microbial decomposition of marine dissolved organic matter in cool oceanic crust

Marine dissolved organic carbon (DOC) is one of the largest active reservoirs of reduced carbon on Earth. In the deep ocean, DOC has been described as biologically recalcitrant and has a radiocarbon age of 4,000 to 6,000 years, which far exceeds the timescale of ocean overturning. However, abiotic removal mechanisms cannot account for the full magnitude of deep-ocean DOC loss. Deep-ocean water circulates at low temperatures through volcanic crust on ridge flanks, but little is known about the associated biogeochemical processes and carbon cycling. Here we present analyses of DOC in fluids from two borehole observatories installed in crustal rocks west of the Mid-Atlantic Ridge, and show that deep-ocean DOC is removed from these cool circulating fluids. The removal mechanism is isotopically selective and causes a shift in specific features of molecular composition, consistent with microbe-mediated oxidation. We suggest organic molecules with an average radiocarbon age of 3,200 years are bioavailable to crustal microbes, and that this removal mechanism may account for at least 5% of the global loss of DOC in the deep ocean. Cool crustal circulation probably contributes to maintaining the deep ocean as a reservoir of ‘aged’ and refractory DOC by discharging the surviving organic carbon constituents that are molecularly degraded and depleted in 14C and 13C into the deep ocean. Microbe-mediated oxidation may account for at least 5% of the global dissolved organic carbon loss from the deep ocean, according to carbon isotope analyses on cool crustal fluids circulating through the Mid-Atlantic Ridge.

Constructional Volcanic Edifices on Mercury: Candidates and Hypotheses of Formation

AbstractMercury, a planet with a predominantly volcanic crust, has perplexingly few, if any, constructional volcanic edifices, despite their common occurrence on other solar system bodies with volcanic histories. Using image and topographical data from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft, we describe two small (<15‐km diameter) prominences with shallow summit depressions associated with volcanically flooded impact features. We offer both volcanic and impact‐related interpretations for their formation, and then compare these landforms with volcanic features on Earth and the Moon. Though we cannot definitively conclude that these landforms are volcanic, the paucity of constructional volcanic edifices on Mercury is intriguing in itself. We suggest that this lack is because volcanic eruptions with sufficiently low eruption volumes, rates, and flow lengths, suitable for edifice construction, were highly spatiotemporally restricted during Mercury's geological history. We suggest that volcanic edifices may preferentially occur in association with late‐stage, postimpact effusive volcanic deposits. The European Space Agency/Japan Aerospace Exploration Agency BepiColombo mission to Mercury will be able to investigate further our candidate volcanic edifices; search for other, as‐yet unrecognized edifices beneath the detection limits of MESSENGER data; and test our hypothesis that edifice construction is favored by late‐stage, low‐volume effusive eruptions.

ERRATUM: Widespread seawater circulation in 18–22 Ma oceanic crust: Impact on heat flow and sediment geochemistry

On the basis of heat-flow measurements, seismic mapping, and sediment pore-water analysis, we demonstrate widespread and efficient ventilation of the 18–22 Ma oceanic crust of the northeast equatorial Pacific Ocean. Recharge and discharge appear to be associated with basement outcrops, including seamounts and north-south–trending faults, along which sediment cover thins out and volcanic rocks are exposed. Low-temperature hydrothermal circulation through the volcanic crust leads to the reduction of heat flow through overlying sediments, with measured heat-flow values that are well below those expected from conductive cooling curves for lithosphere of this age. Typically, dissolved pore-water oxygen decreases from the sediment surface downward, reaching minimum values at mid-depth and rising again in the lower part of the cores investigated, clearly indicating oxygen-rich seawater circulation through the oceanic crust underneath the sediments. If the residence time of the circulating fluids in the upper crust is short or the fluid flux is large, oxic conditions may be preserved, and oxygen can diffuse upwards into the sediments. This process, leading to widespread oxic conditions in the near-basement sediments, may cause the oxidation of residual reduced material stored in the deeper sediments, resulting in downward fluxes of the reaction products into the basement and from there back into the oceans. Considering the widespread existence of this type of off-axis ventilation, the net effect of the resulting return flow of reaction products on biogeochemical cycles and element fluxes (e.g., carbon and nitrogen) may be very large.

Incipient boninitic arc crust built on denudated mantle: the Khantaishir ophiolite (western Mongolia)

The ~ 570 Ma old Khantaishir ophiolite is built by up to 4 km harzburgitic mantle with abundant pyroxenites and dunites followed by ~ 2 km of hornblende-gabbros and gabbronorites and by a ~ 2.5 km thick volcanic unit composed of a dyke + sill complex capped by pillow lavas and some volcanoclastics. The volcanics are mainly basaltic andesites and andesites (or boninites) with an average of 58.2 ± 1.0 wt% SiO2, X Mg = 0.61 ± 0.03 (X Mg = molar MgO/(MgO + FeOtot), TiO2 = 0.4 ± 0.1 wt% and CaO = 7.5 ± 0.6 wt% (errors as 2σ). Normalized trace element patterns show positive anomalies for Pb and Sr, a negative Nb-anomaly, large ion lithophile elements (LILE) concentrations between N- and E-MORB and distinctly depleted HREE. These characteristics indicate that the Khantaishir volcanics were derived from a refractory mantle source modified by a moderate slab-component, similar to boninites erupted along the Izu-Bonin-Mariana subduction system and to the Troodos and Betts Cove ophiolites. Most strikingly and despite almost complete outcrops over 260 km2, there is no remnant of any pre-existing MORB crust, suggesting that the magmatic suite of this ophiolite formed on completely denudated mantle, most likely upon subduction initiation. The architecture of this 4–5 km thick early arc crust resembles oceanic crust formed at mid ocean ridges, but lacks a sheeted dyke complex; volcanic edifices are not observed. Nevertheless, low melting pressures combined with moderate H2O-contents resulted in high-Si primitive melts, in abundant hornblende-gabbros and in a fast enrichment in bulk SiO2. Fractional crystallization modeling starting from the observed primitive melts (56.6 wt% SiO2) suggests that 25 wt% pyroxene + plagioclase fractionation is sufficient to form the average Khantaishir volcanic crust. Most of the fractionation happened in the mantle, the observed pyroxenite lenses and layers in and at the top of the harzburgites account for the required cumulate volumes. Finally, the multiply documented occurrence of highly depleted boninites during subduction initiation suggests a causal relationship of subduction initiation and highly depleted mantle. Possibly, a discontinuity between dense fertile and buoyant depleted mantle contributes to the sinking of the future dense subducting plate, while the buoyant depleted mantle of the future overriding plate forms the infant mantle wedge.

Cool seafloor hydrothermal springs reveal global geochemical fluxes

We present geochemical data from the first samples of spring fluids from Dorado Outcrop, a basaltic edifice on 23 M.y. old seafloor of the Cocos Plate, eastern Pacific Ocean. These samples were collected from the discharge of a cool hydrothermal system (CHS) on a ridge flank, where typical reaction temperatures in the volcanic crust are low (2–20 °C) and fluid residence times are short. Ridge-flank hydrothermal systems extract 25% of Earth's lithospheric heat, with a global discharge rate equivalent to that of Earth's river discharge to the ocean; CHSs comprise a significant fraction of this global flow. Upper crustal temperatures around Dorado Outcrop are ∼15 °C, the calculated residence time is <3 y, and the composition of discharging fluids is only slightly altered from bottom seawater. Many of the major ions concentrations in spring fluids are indistinguishable from those of bottom seawater; however, concentrations of Rb, Mo, V, U, Mg, phosphate, Si and Li are different. Applying these observed differences to calculated global CHS fluxes results in chemical fluxes for these ions that are ≥15% of riverine fluxes. Fluxes of K and B also may be significant, but better analytical resolution is required to confirm this result. Spring fluids also have ∼50% less dissolved oxygen (DO) than bottom seawater. Calculations of an analytical model suggest that the loss of DO occurs primarily (>80%) within the upper basaltic crust by biotic and/or abiotic consumption. This calculation demonstrates that permeable pathways within the upper crust can support oxic water–rock interactions for millions of years.