Volcanic Ash Research Articles

A Simple Neural Network for Estimating Fine Sediment Sources Using XRF and XRD

Suspended sediment (SS) has a wide range of negative effects such as increased water turbidity, altered habitat structures, sedimentation, and effects on hydraulic systems and environmental engineering projects. Nevertheless, the methods for accurately determining SS sources on a basin-scale are poorly understood. Herein, we used a simplified neural network analysis (NNA) model to identify the sources of SS in Japan’s Oromushi River Catchment Basin. Fine soil samples were collected from different locations of the catchment basin, processed, and separately analysed using X-ray fluorescence (XRF) and X-ray diffraction (XRD). The sampling stations were grouped according to the type of soil cover, vegetation type and land-use pattern. The geochemical components of each group were fed into the same neural network layer, and a series of equations were applied to estimate the sediment contribution from each group to the downstream side of the river. Samples from the same sampling locations were also analysed by XRD, and the obtained peak intensity values were used as the input in the NNA model. SS mainly originated from agricultural fields, with regions where the ground is covered with volcanic ash identified as the key sources through XRF and XRD analysis, respectively. Therefore, based on the nature of the surface soil cover and the land use pattern in the catchment basin, NNA was found to be a reliable data analytical technique. Moreover, XRD analysis does not incorporate carbon, and also provides detailed information on crystalline phases. The results obtained in this study, therefore, do not depend on seasonal uncertainty due to organic matter.

Improving communication between volcano observatories and volcanic ash advisory centres in Europe—outcomes from a first workshop

AbstractEffective aviation response to atmospheric emissions from volcanic eruptions relies upon timely communication and information exchange. To explore the current and best practices in this area, a workshop was held in February 2019 under the framework of the European H2020 EUROVOLC project (2018–2021). The objective of the workshop was to bring together the volcano observatories (VOs), volcanic ash advisory centres (VAACs), and volcanological research institutes in Europe. The workshop included scientists and operational staff from six of Europe’s VOs (Iceland, Italy, France, Spain, Portugal, and Greece), the London and Toulouse VAACs, and seven supporting institutions and organisations. During the workshop, participants identified future improvements to the way the VOs and VAACs communicate and share information. Recommendations include refining the guidance and local documentation on the correct use of the Volcano Observatory Notice for Aviation (VONA), improving the two-way feedback between the VAAC and VOs, regular sharing of volcano status updates by the VO, and inclusion of all VOs in regular VAAC and aviation exercises. These are applicable to VOs and VAACs elsewhere in the world.

Impact of submarine volcanic versus hydrothermal activity onto the strontium and lithium isotopic signatures of the water column (TONGA)

During the TONGA cruise (2019), seawater samples were collected to assess the effect of volcanic eruption versus submarine hydrothermal system on the water column. For this purpose, two locations were investigated, the first one located directly under the influence of the New Late’iki island (eruption in October 2019), and the second one showing ongoing submarine hydrothermal activity. At both locations, the total strontium (TSr) and lithium (TLi) concentrations vary between 94.4 and 152.3 µmol/L and 13.2 and 203.5 µmol/L, respectively. When combined, TSr and TLi concentrations of all samples in the water column are higher than those of the oligotrophic water. Both volcanic eruption and submarine hydrothermal activity (e.g. volcanic ashes, particles, gas condensate) can deliver substantial amount of TSr and TLi to the water column. The distribution of TSr versus TLi evidences linear trends either with a negative or positive slope. The negative correlation is observed in the water column at both sites, directly under the influence of the eruption and in the vicinity of the volcano with hydrothermal activity. The positive TSr versus TLi correlation is observed at site under submarine hydrothermal influence and is in line with black smokers related hydrothermal plumes. The 87Sr/86Sr ratios vary between 0.709147 and 0.709210 and δ7Li values vary between +10.1 and +37.6 ‰. While 92% of the measured 87Sr/86Sr ratios are in line with the mean value of oligotrophic waters, once combined with the δ7Li values, only 20% of them remains within this field. The wide range of δ7Li values decreases from sea-surface down to ~140 mbsl, before increasing at greater depth, while defining different linear trend according to the dissolved inorganic carbon concentrations. The variability of δ7Li values reflect hydrothermal contribution, mineral–seawater interaction and potentially biology–environment interaction. In the particular geological setting of the study, where both hydrothermal and volcanic activities were at play, disentangling both contributions on water column implies a combined use of elemental and isotopic signatures of Sr and Li tracers.

Effect of Using Fine Volcanic Ash Instead of Crushed Basalt Filler in Hot Mix Asphalt

Numerous studies over the years have demonstrated the significance and impact of filler in influencing the physical and mechanical properties of Hot Mix Asphalts (HMAs). To overcome such issues, as environmentally friendly alternatives, several different materials for construction have been proposed. This led to an investigation into the potential use of fine volcanic ash (FVA) as a hot mix asphalt filler alternative. In order to prepare bituminous concrete mix sample with conventional basalt filler (BF) as control mix. The Marshall Mix design approach was used to calculate the effective bitumen content. A total of 15 bituminous concrete mix specimens with bitumen content of 4%, 4.5%, 5%, 5.5%, and 6% were created, and the optimum asphalt content was 5.24 %. The impacts of five different (FVA) samples with filler contents of 15%, 30%, 45%, and 60% by weight were compared with respect to bituminous concrete performance. The Marshall stability of a total of 30 samples with varying amounts of (FVA) were investigated. The outcomes were compared with a conventional bituminous concrete mixture. The results showed that fine volcanic ash may substitute 30% of the basalt filler at a bitumen content of 5.24%, 13.84 KN Marshall stability value, 4.0% air voids, 74.77% VFB, 2.380 g/cm3 bulk density and 3.54 mm flow. Therefore, the combination of 30% Fine Volcanic Ash by weight of Basalt Filler satisfies the ASTM Specifications, while the remaining VA content satisfies the basic requirements of the ASTM Specifications.

The Impacts of Volcanic Activity on Microbial Growth—A Simulation Experiment in the Qiliao Section in Shizhu County, Chongqing, China

The impact of volcanic activity on microorganisms has always been a hot topic of discussion during geological history. Further studies are needed on the effects of volcanic activity on microbial growth in shale and the differences in nutrients provided by volcanic ash and other weathered rocks. This study’s results indicated that TOC contents at the bottom of the shale layer are 1.93–4.44% and 3.0% on average. The TOC contents at the top of the layer are 3.38–5.13% and 4.0% on average. It indicated that TOC contents at the bottom of the shale layer are smaller than the TOC contents at the top of the layer, suggesting that volcanic activity posed a long-term effect on biological growth. Seven different leachate concentrations were set in this experiment as follows: 1/10, 1/100, 1/500, 1/1000, 1/1500, 1/2000, and 1/2500. The results showed that the growth status of Pseudourostyla crassipes was affected by the addition of leachates with different concentrations compared to the control group. Additionally, the synthesis of chlorophyll a by Anabaena pseudoichthyoides was the most efficient with the 1/10 volcanic ash leachate. Through the analysis of major and trace elements in the solution before labeland after cultivation, the main elemental content of Ca2+, Mg2+, Na+, and K+ decreased by 3.8~87.24%, 75.96~92.70%, 86.56~95.67%, and 5.42~20.52% in the solution after microbial growth respectively. The trace elements B, Ba, Zn, and Fe decreased by 27.54~94.39%, 20~82.03%, 70.45~98.29%, and 99%. It was found that the B, Ba, Fe, and Zn elements decreased significantly. The nutrients from volcanic ash are the main factor promoting microbial growth. It can be indicated that the volcanic ash soaking solution has a higher content of nutrients when compared to the solubility of nutrients in volcanic ash compared to that of granite. A higher content of nutrients promotes microbial growth. The calculation results indicate that a volcanic eruption with a quantity of several 1010 m3 has a significant impact on microorganisms, lasting from tens of thousands to hundreds of thousands of years.

Research Progress on the Activity Stimulation of Lithium Slag in Concrete

Lithium slag (LS), an industrial waste byproduct generated during lithium salt production, is characterized by its harmful trace elements, significant stockpiles and low pozzolanic activity. By 2003, the annual discharge of lithium slag in China surpassed 15 million tons, creating an urgent need for established large-scale disposal technologies. One of the primary strategies for the effective utilization of LS is its application as an auxiliary cementitious material in concrete. However, the low reactivity of LS and challenges associated with its large-scale application impede its effective utilization. Enhancing the pozzolanic activity of LS is pivotal for its substantial incorporation into concrete. This study begins by analyzing the physicochemical properties and volcanic ash reactivity of LS derived from various lithium extraction techniques. It subsequently explores the diverse activation techniques aimed at improving the reactivity of LS within concrete. Ultimately, this paper highlights the significance of synergistic activation strategies, particularly physicochemical co-excitation and multi-exciter composite excitation. These approaches are identified as critical pathways for enhancing the activity of LS. Through this exploration, this study aims to unveil innovative strategies that bolster the resource utilization efficiency of LS, thereby facilitating its effective application in the concrete domain.

Enhancing sustainability in concrete construction: Utilizing copper slag for improved properties of geopolymer concrete

Geopolymer concrete (GPC), utilizing aluminosilicate precursor materials as binders, stands as an eco-friendly alternative to Portland cement concrete. These precursors commonly include natural resources like metakaolin, volcanic ash, and industrial solid waste such as fly ash (FA) and ground granulated blast furnace slag (GGBFS). However, despite not utilizing cement, GPC still faces environmental challenges due to the use of natural aggregates, leading to resource depletion. To mitigate this issue, researchers have explored replacing natural aggregates with waste materials, aiding both resource conservation and waste management. Copper slag (CS) is one such waste material with potential as fine aggregate in GPC. This study conducts a comprehensive evaluation of FA-GGBFS-based GPC incorporating CS as fine aggregate, revealing notable enhancements in transport, durability, and strength properties. The optimal replacement of 60 % natural sand with CS in GPC resulted in a 20–25 % increase in compressive strength, a 10–15 % improvement in slake durability, an 18–40 % reduction in water absorption, a 30–39 % decrease in permeable voids, and a 26–47 % reduction in depth of wear, all in comparison to the control specimen made with natural sand only. Thus, incorporating CS as a fine aggregate in GPC is recommended as an effective approach to enhance mechanical performance and durability, while contributing to sustainable construction practices.

Analysis of lake level fluctuations in the Early Cretaceous Songliao Basin supports aquifer eustacy

Clear geochronology and precise interpretation of sequence stratigraphy enhance our understanding of continental lake-level evolution. The Songliao Basin features well-preserved Cretaceous continental strata. Nevertheless, the correlation between lake-level fluctuations and global sea-level changes remains ambiguous. High-resolution gamma ray logging data were used to analyze the cyclical stratigraphy of the lower member of the Early Cretaceous Shahezi Formation in the Songliao Basin. X-ray fluorescence experiments characterized the sedimentary environment of this formation. Lake-level variations in the lower part of the Early Cretaceous Shahezi Formation were reconstructed using sedimentary noise modeling based on finely tuned gamma ray logging data. Time series analysis using the tuned gamma ray data established an astronomical timescale of approximately 2.4 Myr within the lower section of the early Cretaceous Shahezi Formation in the Songliao Basin. A volcanic ash layer dating (118.20 ± 1.5) Ma from the base of the Shahezi Formation served as an anchor point, providing an absolute astronomical timescale ranging from 115.80 to 118.20 Ma for the study region. The sedimentary model indicates that variations in paleowater depth within the lower section of the Shahezi Formation closely match fluctuations observed in the Fe/Mn index, which reflects paleowater depth changes. This introduces a novel approach to assess changes in continental lake levels. The sedimentary noise model revealed a notable obliquity cycle of about 1.2 million years, strongly associated with fluctuations in lake levels. This indicates that prolonged obliquity periods affect lake level variations. Intriguingly, when lake levels rise, global sea levels concurrently decline, highlighting an inverse relationship between these phenomena. This observation offers insights into how long-term obliquity-driven climate changes regulate sea and lake levels.

Unravelling eruption dynamics at El Reventador, Ecuador: linking the physiochemical properties of volcanic ash with geophysical, geochemical and satellite remote sensing data

The physiochemical properties of volcanic ash are determined by magma ascent and eruption dynamics and provide important insights into controls on the timing and style of volcanic eruptions. However, linking petrological observations to monitoring parameters remains challenging. Here we investigate the relationships between geophysical, geochemical and satellite remote sensing data with the physiochemical properties of volcanic ash to better understand eruptive dynamics at El Reventador volcano, Ecuador. Between 2016 and 2019, eruptive activity at El Reventador was characterised by frequent explosions interspersed with effusive activity from two summit vents. We found that: (1) periods of predominantly effusive behaviour were defined by ash samples with the lowest proportions of juvenile grains, frequent, more intense thermal anomalies and frequent (ca. every 25 min) but low-energy explosions that produced lower average ash column heights (< 1200 m above the summit) and; (2) periods of predominantly explosive behaviour were defined by ash samples with the highest proportions of juvenile grains and also vesicular juvenile grains, low thermal anomalies and less frequent (ca. every 70 min), higher-energy explosions that produced higher average eruption column heights (> 1500 m above the summit). Our study shows that there are strong correlations between the physiochemical properties of erupted material and the multiparametric monitoring data which in turn link to the type of surface activity observed. As a result, the development of physical conduit models and interpretations of eruptive dynamics are made more robust combining both monitoring data and the physical properties of eruptive products.

Short-term mechanical properties and microstructure of coastal cement soil modified by sugarcane bagasse ash

Sugarcane bagasse ash is a kind of agricultural waste with a large quantity and good volcanic ash reactivity, it is necessary to find a way to reasonably utilize it to prevent environmental pollution caused by long-term accumulation. In this paper, the effect of sugarcane bagasse ash on the short-term mechanical properties of coastal cement soil were studied, and unconfined compressive tests and triaxial shear tests were carried out. The sugarcane bagasse ash content was set to 0 %, 1 %, 2 %, 3 %, 4 % and 5 %, respectively, the cement content was set to 5 %, and the curing age was set at 7d. The test results show that sugarcane bagasse ash can effectively improve the unconfined compressive strength and triaxial shear strength of cement soil, exhibiting a trend of increasing first and then decreasing with the increase of its content. When the sugarcane bagasse ash content is 1 %, the unconfined compressive strength reaches the maximum value of 2040 kPa, which is 56 % and 8 % higher than that of cement soil with 5 % and 7 % cement content, respectively. Compared with cement soil with 5 % cement content, the triaxial shear strength increases by 12 %∼17 %, the internal friction angle φ and cohesion c increases by 3 %∼8 % and 2 %∼11 %, respectively. The SEM test results show that the addition of bagasse ash can promote the hydration of cement to produce hydrated calcium silicate and other hydration products, fill the internal pores of the sample, and make the microstructure of the modified cement soil tend to be dense. The research results provide a reference for the application of sugarcane bagasse ash modified cement soil in practical engineering.

Metabolome and Transcriptome Analysis Reveals Molecular Mechanisms of Soil Amendment (Volcanic Ash) Alleviating Salt–Alkali Stress in Melons (Cucumis melo L.)

Metabolome and Transcriptome Analysis Reveals Molecular Mechanisms of Soil Amendment (Volcanic Ash) Alleviating Salt–Alkali Stress in Melons (Cucumis melo L.)

The potential cutaneous benefits of bentonites and montmorillonites.

Bentonites and montmorillonites, natural clay minerals originating from volcanic ash, possess unique properties that have traditionally been utilized in industrial applications. Recently, their potential biomedical applications, particularly in dermatology, have garnered significant interest. This review explores the cutaneous benefits of bentonites and montmorillonites, highlighting their anti-inflammatory, wound-healing, oil-absorbing, drug delivery, photoprotective, and anti-aging effects. Evidence from in vitro experiments, animal studies, and preliminary clinical trials demonstrate that these clays can significantly reduce inflammation, accelerate wound healing, absorb excess oil, enhance drug delivery, protect against ultraviolet radiation, and improve skin hydration and elasticity. Larger scale randomized clinical trials (RCTs) are needed to further establish the safety and efficacy of bentonites and montmorillonites. Given the increasing consumer demand for natural ingredients in skincare, bentonites and montmorillonites present a promising area for further research and development in dermatologic applications.

Crustal bobbing in response to lithospheric foundering recorded by detrital proxy records from the central Andean Plateau

Lithospheric foundering is an important mechanism of crustal deformation and recycling, basin subsidence, and surface uplift in orogenic systems. The Arizaro Basin, in the Puna region of NW Argentina, is a place where foundering was proposed to have taken place during the late Miocene. The Arizaro Basin has been described as a “bobber” basin produced by Miocene lithospheric foundering. The geometry, sedimentology, deformation, and paleoelevation history of the Arizaro Basin and surrounding arc suggest dynamic processes associated with lithospheric removal. Although analogue and numerical models support this hypothesis, the history of crustal thickness in response to lithospheric removal remains unconstrained. Here, we used a novel approach exploiting the geochemistry of detrital zircons from volcanic ashes intercalated within the Arizaro Basin stratigraphy to reconstruct the paleocrustal thickness of the neighboring magmatic sources throughout the Cenozoic. Our data indicate that the sources of volcanism for the Arizaro Basin were characterized by relatively thick crust (∼53 km) since ca. 36 Ma. Thickening between ca. 20 and 13 Ma and thinning after ca. 13 Ma are consistent with formation and subsequent removal of a crustal root under the nearby arc and Aguas Calientes caldera.

Analytic network process–based study of the importance and interconnectivity of facilities under volcanic ash risk

Analytic network process–based study of the importance and interconnectivity of facilities under volcanic ash risk

Effect of recycled polyester fiber reinforcement on the mechanical behavior and microstructure of red mud-improved volcanic ash

Effect of recycled polyester fiber reinforcement on the mechanical behavior and microstructure of red mud-improved volcanic ash

Dissolution of Volcanic Ash in Alkaline Environment for Cold Consolidation of Inorganic Binders.

A systematic study on the dissolution in concentrated alkali of two volcanic ashes from Cameroon, denoted as DAR and VN, is presented here. One volcanic ash, DAR, was 2 wt% richer in Fe and Ca and 4 wt% lower in Si than the other, designated as VN. Such natural raw materials are complex mixtures of aluminosilicate minerals (kaersutite, plagioclase, magnetite, diopside, thenardite, forsterite, hematite, and goethite) with a good proportion of amorphous phase (52 and 74 wt% for DAR and VN, respectively), which is more reactive than the crystalline phase in alkaline environments. Dissolution in NaOH + sodium silicate solution is the first step in the geopolymerisation process, which, after hardening at room temperature, results in solid and resistant building blocks. According to XRD, the VN finer ash powders showed a higher reactivity of Al-bearing soluble amorphous phases, releasing Al cations in NaOH, as indicated by IPC-MS. In general, dissolution in a strong alkaline environment did not seem to be affected by the NaOH concentration, provided that it was kept higher than 8 M, or by the powder size, remaining below 75 µm, while it was affected by time. However, in the time range studied, 1-120 min, the maximum element release was reached at about 100 min, when an equilibrium was reached. The hardened alkali activated materials show a good reticulation, as indicated by the low weight loss in water (10 wt%) when a hardening temperature of 25 °C was assumed. The same advantage was found for of the room-temperature consolidated specimens' mechanical performance in terms of resistance to compression (4-6 MPa). The study of the alkaline dissolution of volcanic ash is, therefore, an interesting way of predicting and optimising the reactivity of the phases of which it is composed, especially the amorphous ones.

Insight into the 2021 Semeru volcano eruption from rapid monitoring of its pyroclastic deposits using Google Earth Engine and multi-sensor data

The objective of this study is to map the pyroclastic deposits resulting from the Semeru eruption in 2021 and to analyse the process of pyroclastic deposit formation, including the tephra and lithification phases, using multi-sensor data. The distribution of pyroclastic deposits was mapped using machine learning algorithms, Sentinel 2 and Sentinel 1 imagery on Google Earth Engine. Data acquisition in the Semeru volcano area was conducted both prior to and following the 2021 eruption. Additionally, field investigations were conducted to analyse the distribution of pyroclastic deposits, including the characteristics of individual layers, the lithification process of pyroclastic layers, and their relationship with the characteristics of the eruption. The results demonstrate that pyroclastic deposits in the proximal facies are composed of lithic, lapilli tuff, lava and tuff. The mapping results also indicate the presence of volcanic ash deposits in the central facies or summit area of Semeru, exhibiting distinctive characteristics associated with volcanic ash. The 2021 eruption has also resulted in rapid changes to river morphometry, as evidenced by notable shifts in a significant decrease in pixel values for NDVI (−0.0781-0.0625), a significant increase in pixel frequency of EVI (1800–6000), and MNDWI (1700–3000), respectively. The change of pyroclastic fall into consolidated tephra occurred from December 2021 to May 2023, where in May 2023 volcanic ash had changed into tuff and lapilli had changed into lapilli tuff. Furthermore, data from Sentinel-1 indicated that pyroclastic flows could be identified using both vertical and horizontal polarization. It can therefore be concluded that the 2021 eruption of Semeru exhibited distinctive characteristics of pyroclastic deposits, where some of the characteristics of the pyroclastic distribution can be monitored rapidly with Google Earth Engine. Therefore, the use of Google Earth Engine with integration of radar and optical data can be recommended to mapping pyroclastic deposits rapidly.

Sedimentary Environment of the Permian Marine Shale in the Kaijiang‐Liangping Trough, Sichuan Basin, China: Implications for Organic Matter (OM) Accumulation

ABSTRACTThe Permian shales in the Kaijiang‐Liangping Trough within the Sichuan Basin represent a promising frontier for marine shale gas exploration, whereas there has been limited systematic research on their sedimentary environment and organic matter (OM) enrichment mechanisms. Therefore, we present total organic carbon (TOC) analysis, major/trace element analyses and scanning electron microscope experiments for the Permian marine shales from the trough to determine their paleoenvironmental conditions and influencing factors of OM enrichment. The results show that the paleoclimate changed from dry climate to humid and warm climate (P3w1 [the first member of the Wujiaping Formation]) and semi‐humid to semi‐arid climate (P3w2 [the second member of the Wujiaping Formation]) and P3d‐I (Dalong Formation‐I) and then to arid climate again during the shale deposition period from the P2g (Gufeng Formation) to the P3d‐II. The shales with the highest TOC contents (TOC &gt; 3%, P3d‐I and P2g), lower TOC contents (TOC &lt; 1%, P3w1 and P3w2) and higher TOC contents (1% &lt; TOC &lt; 2%, P3d‐II) were formed under the control of anoxic environment and high paleoproductivity, oxic‐suboxic environment and high paleoproductivity, anoxic‐euxinic environment and lower productivity, respectively. Only appropriate sedimentation rates promote OM enrichment. Terrestrial input, paleoclimate, volcanic activity and hydrothermal upwelling mainly indirectly affect OM accumulation by influencing paleoproductivity. The degree of redox conditions is the primary factor affecting OM enrichment, followed by paleoproductivity. Nonetheless, anoxic to euxinic environments are most appropriate for OM preservation. Weak volcanic activity can boost paleoproductivity, but severe volcanic activity might introduce excessive harmful compounds that limit organism survival, resulting in a fall in paleoproductivity. Additionally, element P brought by volcanic ashes doesn't contribute to OM accumulation.

Study on the Influence of Thermoplastic Microcapsules on the Sulfate Resistance and Self-Healing Performance of Limestone Calcined Clay Cement Concrete.

Limestone calcined clay cement (LC3), enhanced through reactions with volcanic ash and the interaction between limestone and clay, significantly improves the performance of cementitious materials. It has the potential to cut CO2 emissions by up to 30% and energy consumption in cement manufacture by 15% to 20%, providing a promising prospect for the large-scale production of low-carbon cement with a lower environmental effect. To effectively manufacture LC3 concrete, this study utilized limestone (15%), calcined clay (30%), and gypsum (5%) as supplementary cementitious materials (SCMs), replacing 50% of ordinary Portland cement (OPC). However, in regions abundant in sulfate, sulfate attack can cause interior cracking of concrete, reducing the longevity of the building. To address this issue, microcapsules containing microcrystalline wax, ceresine wax, and nano-CaCO3 encapsulated in epoxy resin were prepared and successfully incorporated into LC3 concrete. Sulfate resistance tests were conducted through sulfate dry-wet cycles, comparing samples with and without microcapsules. The findings revealed that the initial mechanical and permeability properties of LC3 concrete did not significantly differ from OPC concrete. LC3 concrete with added microcapsules (SP4) exhibited enhanced resistance to sulfate attack, reducing mass loss and compressive strength degradation. SEM images displayed a mesh-like structure of repair products in SP4. After 14 days of self-repair, SP4 exhibited a 44.2% harmful pore ratio, 98.1% compressive strength retention, 88.7% chloride ion diffusion coefficient retention, 91.12 mV maximum amplitude, and 9.14 mV maximum frequency amplitude. The experimental results indicate that the presence of microcapsules enhances the sulfate attack self-healing performance of LC3 concrete.

The influence of volcanic ash (VA) on the mechanical properties and freeze-thaw durability of lime kiln dust (LKD)-stabilized kaolin clayey soil

Improving soft clay soil's mechanical properties and durability has been the subject of intense research. In this context, traditional stabilizers such as cement and lime have been introduced as the most widely used materials. However, the utilization of these conventional additives poses several challenges due to recent global concerns regarding the reduction of greenhouse gas emissions. Therefore, international research is shifting toward using environmentally friendly soil-stabilizing waste materials. This study, for the first time, evaluates the stabilization of kaolin clay soil using lime kiln dust (LKD) as a high CaO content waste pozzolan and volcanic ash (VA) as a natural pozzolan with considerable SiO2 and Al2O3 contents. In general, the research aims to demonstrate the effective performance of these two inexpensive and environmentally friendly additives in improving the mechanical characteristics and durability of kaolin clay soil, thereby providing the essential groundwork for the practical application of this method in stabilizing soft clay soil. This study included preparing samples with LKD at 3%, 5%, 7%, and 10% of the dry weight of clay and replacing LKD with VA at 0%, 25%, 75%, and 100%. The specimens were cured for 3, 7, and 28 days. Following the curing process, the optimal sample was subjected to varying numbers of freeze-thaw (F-T) cycles. The samples were examined by conducting a series of standard compaction, unconfined compressive strength (UCS), ultrasonic pulse velocity (UPV), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) tests at different stages of adding stabilizers, as well as before and after exposure of F-T cycles. The findings revealed that adding LKD and VA increased the UCS by accelerating and improving the pozzolanic and hydration reactions. Also, the combination of LKD and VA in kaolin soil enhanced F-T durability, resulting in less strength deterioration even after 10 cycles, when compared to the untreated control sample. In particular, the optimal mixture containing 5% LKD and 25% VA replacement improved 11 times in UCS compared to untreated kaolin clay and showed a slight reduction of only 7% after 10 F-T cycles. Overall, the incorporation of LKD and VA enhanced the mechanical properties and F-T durability of kaolin clay soil, making it a low-cost, sustainable, and eco-friendly option for soil improvement.