Volatile Delivery Research Articles

Inhaled Volatiles for Status Asthmaticus, Epilepsy, and Difficult Sedation in Adult ICU and PICU: A Systematic Review.

Inhaled volatile anesthetics support management of status asthmaticus (SA), status epilepticus (SE), and difficult sedation (DS). This study aimed to evaluate the effectiveness, safety, and feasibility of using inhaled anesthetics for SA, SE, and DS in adult ICU and PICU patients. MEDLINE, Cochrane Central Register of Controlled Trials, and Embase. Primary literature search that reported the use of inhaled anesthetics in ventilated patients with SA, SE, and DS from 1970 to 2021. Study data points were extracted by two authors independently. Quality assessment was performed using the Joanna Briggs Institute appraisal tool for case studies/series, Newcastle criteria for cohort/case-control studies, and risk-of-bias framework for clinical trials. Primary outcome was volatile efficacy in improving predefined clinical or physiologic endpoints. Secondary outcomes were adverse events and delivery logistics. From 4281 screened studies, the number of included studies/patients across diagnoses and patient groups were: SA (adult: 38/121, pediatric: 28/142), SE (adult: 18/37, pediatric: 5/10), and DS (adult: 21/355, pediatric: 10/90). Quality of evidence was low, consisting mainly of case reports and series. Clinical and physiologic improvement was seen within 1-2 hours of initiating volatiles, with variable efficacy across diagnoses and patient groups: SA (adult: 89-95%, pediatric: 80-97%), SE (adults: 54-100%, pediatric: 60-100%), and DS (adults: 60-90%, pediatric: 62-90%). Most common adverse events were cardiovascular, that is, hypotension and arrhythmias. Inhaled sedatives were commonly delivered using anesthesia machines for SA/SE and miniature vaporizers for DS. Few (10%) of studies reported required non-ICU personnel, and only 16% had ICU volatile delivery protocol. Volatile anesthetics may provide effective treatment in patients with SA, SE, and DS scenarios but the quality of evidence is low. Higher-quality powered prospective studies of the efficacy and safety of using volatile anesthetics to manage SA, SE, and DS patients are required. Education regarding inhaled anesthetics and the protocolization of their use is needed.

Eccentricity Distribution beyond the Snow Line and Implications for Planetary Habitability

A fundamental question in the study of planetary system demographics is: how common is the solar system architecture? The primary importance of this question lies in the potential of planetary systems to create habitable environments, and dissecting the various components of solar system evolution that contributed to a sustainable temperate surface for Earth. One important factor in that respect is volatile delivery to the inner system and the dependence on giant planets beyond the snow line as scattering agents, particularly as such cold giant planets are relatively rare. Here, we provide an investigation of the eccentricity distribution for giant planet populations both interior and exterior to their system snow lines. We show that the median eccentricity for cold giants is 0.23, compared with a far more circular orbital regime for inner planets. We further present the results of a dynamical simulation that explores the particle scattering potential for a Jupiter analog in comparison with a Jupiter whose eccentricity matches that of the median cold giant eccentricity. These simulations demonstrate that the capacity for such an eccentric cold giant system to scatter volatiles interior to the snow line is significantly increased compared with the Jupiter analog case, resulting in a far greater volume of Earth-crossing volatiles. Thus, many of the known systems with cold giant planets may harbor water worlds interior to the snow line.

Surrounded by Giants: Habitable Zone Stability Within the HD 141399 System

The search for exoplanets has revealed a diversity of planetary system architectures, the vast majority of which diverge significantly from the template of the solar system. In particular, giant planets beyond the snow line are relatively rare, especially for low-mass stars, placing the solar system within a small category of systems with multiple giant planets at large separations. An exoplanetary system of note is that of HD 141399, consisting of a K-dwarf host star that harbors four giant planets with separations extending to ∼4.5 au. The architecture of the system creates a complex pattern of mean motion resonances and gravitationally perturbed regions that may exclude the presence of other planets, including within the habitable zone of the system. Here, we present the results of dynamical simulations that explore the interaction of the known planets of the system, their apsidal trajectories, resonance locations, and dynamical evolution. We further investigate the results of injecting Earth-mass planets and provide the regions of dynamical viability within the habitable zone where terrestrial planets may maintain long-term stability. We discuss these results in the context of the importance of giant planets for volatile delivery and planetary habitability considerations.

MagAO-X and HST High-contrast Imaging of the AS209 Disk at Hα

The detection of emission lines associated with accretion processes is a direct method for studying how and where gas giant planets form, how young planets interact with their natal protoplanetary disk, and how volatile delivery to their atmosphere takes place. Hα (λ = 0.656 μm) is expected to be the strongest accretion line observable from the ground with adaptive optics systems, and is therefore the target of specific high-contrast imaging campaigns. We present MagAO-X and Hubble Space Telescope (HST) data obtained to search for Hα emission from the previously detected protoplanet candidate orbiting AS209, identified through Atacama Large Millimeter/submillimeter Array observations. No signal was detected at the location of the candidate, and we provide limits on its accretion. Our data would have detected an Hα emission with F Hα > 2.5 ± 0.3 × 10−16 erg s−1 cm−2, a factor 6.5 lower than the HST flux measured for PDS70 b. The flux limit indicates that if the protoplanet is currently accreting it is likely that local extinction from circumstellar and circumplanetary material strongly attenuates its emission at optical wavelengths. In addition, the data reveal the first image of the jet north of the star as expected from previous detections of forbidden lines. Finally, this work demonstrates that current ground-based observations with extreme adaptive optics systems can be more sensitive than space-based observations, paving the way to the hunt for small planets in reflected light with extremely large telescopes.

The Effect of Dust Evolution and Traps on Inner Disk Water Enrichment

Abstract Substructures in protoplanetary disks can act as dust traps that shape the radial distribution of pebbles. By blocking the passage of pebbles, the presence of gaps in disks may have a profound effect on pebble delivery into the inner disk, crucial for the formation of inner planets via pebble accretion. This process can also affect the delivery of volatiles (such as H2O) and their abundance within the water snow line region (within a few au). In this study, we aim to understand what effect the presence of gaps in the outer gas disk may have on water vapor enrichment in the inner disk. Building on previous work, we employ a volatile-inclusive disk evolution model that considers an evolving ice-bearing drifting dust population, sensitive to dust traps, which loses its icy content to sublimation upon reaching the snow line. We find that the vapor abundance in the inner disk is strongly affected by the fragmentation velocity (v f) and turbulence, which control how intense vapor enrichment from pebble delivery is, if present, and how long it may last. Generally, for disks with low to moderate turbulence (α ≤ 1 × 10−3) and a range of v f, radial locations and gap depths (especially those of the innermost gaps) can significantly alter enrichment. Shallow inner gaps may continuously leak material from beyond it, despite the presence of additional deep outer gaps. We finally find that for realistic v f (≤10 m s−1), the presence of gaps is more important than planetesimal formation beyond the snow line in regulating pebble and volatile delivery into the inner disk.

Evidence for a carbon-rich Mercury from the distribution of low-reflectance material (LRM) associated with large impact basins

Low-reflectance material (LRM) on the surface of Mercury is thought to be darkened by 2-7 wt.% carbon, making Mercury's surface the most carbon-rich among the terrestrial planets, but the origin of this carbon is debated. We observe exposures of LRM within large impact basins, which naturally sample Mercury's outer layers, to produce the first observationally constrained estimate of the absolute quantity of carbon present in Mercury's shallow interior. We observe LRM and other spectrally distinct material associated with craters within large basins and use scaling laws to relate these observations to the stratigraphy and composition of the subsurface. We find that many large basins across Mercury's surface have thick layers of LRM in their subsurface. Based on inferences regarding the thickness of these layers, we estimate the absolute quantity of carbon present in Mercury's crust and upper mantle to be at least 1.8×1019−2.3×1020 kg, which permits evaluation of hypotheses as to its origin. This quantity rules out the hypothesis that carbon near Mercury's surface was delivered during late accretion of carbon-rich material, with implications for the delivery of carbon and volatiles to the terrestrial planets. It is also only marginally compatible with a magma ocean origin. Therefore, if Mercury's core and mantle equilibrated with respect to carbon, we infer that Mercury was probably carbon-saturated early in its evolution and that carbon is an abundant light element in its core, with important implications for Mercury's thermal and geological evolution.

Noble gas insights into early impact delivery and volcanic outgassing to Earth's atmosphere: A limited role for the continental crust

Earth's atmosphere, crust and mantle have evolved together through continuous geochemical exchange throughout Earth's history. Constraints on the transport of volatile elements and compounds between these reservoirs are crucial for understanding how Earth could have stayed habitable for extended periods of time. Here we present a new forward model of He, Ne and Ar in the mantle, crust and atmosphere. We explore concentrations of noble gases at the end of accretion, bulk silicate Earth K/U ratios, crustal growth scenarios, and upper mantle processing rates throughout Earth's history. We search for parameter combinations that simultaneously satisfy observational constraints on present-day mantle 4He/3He and 40Ar/36Ar (sensitive to mantle outgassing and continental crust growth, which depletes the mantle of U, Th and K), atmospheric 20Ne/22Ne (which tracks the mix of outgassed vs. delivered Ne in the atmosphere), and atmospheric 40Ar/36Ar in the past and today (sensitive to volatile delivery, mantle outgassing and crustal growth). Leveraging this intertwined set of noble gas abundances and isotopic compositions yields new constraints on initial noble gas abundances in the mantle and on the proportions of atmospheric volatiles originating from delivery by impact degassing, mantle outgassing, and degassing of the continental crust. We find that atmospheric Ar isotopic evolution is primarily sensitive to the mantle processing rate history; the atmospheric Ar isotopic record should therefore not be used to reconstruct continental crust growth, but instead provides valuable insights into mantle processing rates. Our model predicts a measurably low 20Ne/22Ne ratio of ∼9.7 in Archean atmospheric samples. Most of atmospheric primordial 36Ar was directly delivered by chondritic bodies and not transferred to the atmosphere during an intense early episode of mantle outgassing. Nitrogen delivered by impact degassing could account for the present-day atmospheric nitrogen inventory.

Anatomy of rocky planets formed by rapid pebble accretion

Volatile molecules containing hydrogen, carbon, and nitrogen are key components of planetary atmospheres. In the pebble accretion model for rocky planet formation, these volatile species are accreted during the main planetary formation phase. For this study, we modelled the partitioning of volatiles within a growing planet and the outgassing to the surface. The core stores more than 90% of the hydrogen and carbon budgets of Earth for realistic values of the partition coefficients of H and C between metal and silicate melts. The magma oceans of Earth and Venus are sufficiently deep to undergo oxidation of ferrous Fe2+to ferric Fe3+. This increased oxidation state leads to the outgassing of primarily CO2and H2O from the magma ocean of Earth. In contrast, the oxidation state of Mars’ mantle remains low and the main outgassed hydrogen carrier is H2. This hydrogen easily escapes the atmosphere due to the irradiation from the young Sun in XUV wavelengths, dragging with it the majority of the CO, CO2, H2O, and N2contents of the atmosphere. A small amount of surface water is maintained on Mars, in agreement with proposed ancient ocean shorelines, for moderately low values of the mantle oxidation. Nitrogen partitions relatively evenly between the core and the atmosphere due to its extremely low solubility in magma; the burial of large reservoirs of nitrogen in the core is thus not possible. The overall low N contents of Earth disagree with the high abundance of N in all chondrite classes and favours a volatile delivery by pebble snow. Our model of rapid rocky planet formation by pebble accretion displays broad consistency with the volatile contents of the Sun’s terrestrial planets. The diversity of the terrestrial planets can therefore be used as benchmark cases to calibrate models of extrasolar rocky planets and their atmospheres.

The Abundance of Belatedly Habitable Planets and Ambiguities in Definitions of the Continuously Habitable Zone

A planet’s history dictates its current potential to host habitable conditions and life. The concept of the continuously habitable zone (CHZ) has been used to define the region around a star most likely to host planets with long-term habitability. However, definitions of the CHZ vary in the literature and often conflict with each other. Calculating the fraction of habitable zone planets in the CHZ as a function of stellar properties, we find that the quality of a star as a host for planets with long-term habitability and biosignatures depends strongly on the formulation of the CHZ used. For instance, older M stars are either excellent or suboptimal hosts for CHZ planets, depending on whether one’s definition of habitability prioritizes the total time spent in the habitable zone or the continuity of habitable conditions from the delivery of volatiles to its current age. In this study, we focus on belatedly habitable zone (BHZ) planets, i.e., planets that enter the habitable zone after formation due to the evolution of their host star. We find that between ∼29% and 74% of planets in the habitable zone belong to this class of BHZ planets, depending on the timescale for the delivery of volatiles. Whether these planets can retain their volatiles and support habitable conditions is unclear. Since BHZ planets comprise a large portion of the planets we expect to survey for biosignatures with future missions, the open question of their habitability is an important factor for mission design, survey strategies, and the interpretation of results.

Comparisons of the core and mantle compositions of earth analogs from different terrestrial planet formation scenarios

The chemical compositions of Earth's core and mantle provide insight into the processes that led to their formation. N-body simulations, on the other hand, generally do not contain chemical information, and seek to only reproduce the masses and orbits of the terrestrial planets. These simulations can be grouped into four potentially viable scenarios of Solar System formation (Classical, Annulus, Grand Tack, and Early Instability) for which we compile a total of 433 N-body simulations. We relate the outputs of these simulations to the chemistry of Earth's core and mantle using a melt-scaling law combined with a multi-stage model of core formation. We find the compositions of Earth analogs to be largely governed by the fraction of equilibrating embryo cores (kcore_emb) and the initial embryo masses in N-body simulations, rather than the simulation type, where higher values of kcore_emb and larger initial embryo masses correspond to higher concentrations of Ni, Co, Mo, and W in Earth analog mantles and higher concentrations of Si and O in Earth analog cores. As a result, larger initial embryo masses require smaller values of kcore_emb to match Earth's mantle composition. On the other hand, compositions of Earth analog cores are sensitive to the temperatures of equilibration and fO2 of accreting material. Simulation type may be important when considering magma ocean lifetimes, where Grand Tack simulations have the largest amounts of material accreted after the last giant impact. However, we cannot rule out any accretion scenarios or initial embryo masses due to the sensitivity of Earth's mantle composition to different parameters and the stochastic nature of N-body simulations. We use our compiled simulations to explore the relationship between initial embryo masses and the melting history of Earth analogs, where the complex interplay between the timing between impacts, magma ocean lifetimes, and volatile delivery could affect the compositions of Earth analogs formed from different simulation types. Comparing the last embryo impacts experienced by Earth analogs to specific Moon-forming scenarios, we find the characteristics of the Moon-forming impact are dependent on the initial conditions in N-body simulations where larger initial embryo masses promote larger and slower Moon-forming impactors. Mars-sized initial embryos are most consistent with the canonical hit-and-run scenario onto a solid mantle. Our results suggest that constraining the fraction of equilibrating impactor core (kcore) and the initial embryo masses in N-body simulations could be significant for understanding both Earth's accretion history and characteristics of the Moon-forming impact.

Cadmium isotope fractionation during metal-silicate partitioning – Results and implications for Earth's volatile accretion

Metal-silicate partitioning experiments were carried out at 1.5 GPa and 1508 to 1843 K to constrain Cd partitioning and isotope fractionation during core formation. At the studied conditions, there was no significant stable isotope fractionation during Cd partitioning between metal and silicate phases with a mean ∆114Cdmet-sil = −0.02 ± 0.09‰ (2SD, n = 7). Two experiments that investigated sulphide-silicate partitioning of Cd yielded fractionation factors of −0.04 ± 0.06‰ and − 0.23 ± 0.07‰ (2SE), whereby the latter result was obtained for a short run that may not represent full equilibrium. In summary, the findings suggest that Cd isotope fractionation during segregation of Earth's core was either absent or very minor. The Cd partitioning data of this and previous investigations were combined in multiple linear regression analyses to better constrain Cd metal-silicate partitioning during core formation. In accord with earlier work, the analyses reveal that Cd metal-silicate partitioning is not significantly impacted by temperature and pressure but affected by the S content of the metal phase. In addition, it is shown that the presence of C and Si in the metal reduce the siderophile character of Cd. Based on estimates for the composition of Earth's core, the data suggest a metal-silicate partition coefficient DCd of about 0.4 for a single-stage core formation event. However, given uncertainties about the light element composition of Earth's core, DCd values larger than 1 cannot be ruled out at present for core formation. The results of this study and data on the composition of the bulk silicate Earth and chondritic meteorites were applied in mass balance calculations to constrain the Cd signature of Earth's main stage accretion material prior to delivery of the late veneer. The modelling indicates Earth's main stage of accretion involved material with an average Cd isotope composition that was lighter than that of known carbonaceous and enstatite chondrites. Most likely, this reflects either poor characterisation of these meteorites by the few precise data currently available or that a significant fraction of the terrestrial volatile inventory was acquired from material not directly related to carbonaceous and enstatite chondrites. Furthermore, terrestrial accretion most likely did not encompass the addition of a volatile-rich late veneer exceeding 2% of Earth's mass, in accord with accretion models, which invoke that volatile delivery occurred primarily during main stage accretion, alongside core formation.

The future of lidar in planetary science

Lidar has enabled advances in the knowledge of the Solar System through geophysical and atmospheric studies of the Moon, Mercury, Mars, and several asteroids. The technique will continue to be used to obtain high-precision topographic data from orbit, but new techniques on the horizon are suited to uniquely address fundamental planetary science questions related to the evolution of airless bodies, volatile delivery and sequestration, atmospheric transport, and small body formation and evolution. This perspective highlights the history of lidar in planetary science and identifies several measurement approaches that may be adopted in the coming years.

Characterization of Retronasal Airflow Patterns during Intraoral Fluid Discrimination Using a Low-Cost, Open-Source Biosensing Platform.

Nasal airflow plays a critical role in olfactory processes, and both retronasal and orthonasal olfaction involve sensorimotor processes that facilitate the delivery of volatiles to the olfactory epithelium during odor sampling. Although methods are readily available for monitoring nasal airflow characteristics in laboratory and clinical settings, our understanding of odor sampling behavior would be enhanced by the development of inexpensive wearable technologies. Thus, we developed a method of monitoring nasal air pressure using a lightweight, open-source brain–computer interface (BCI) system and used the system to characterize patterns of retronasal airflow in human participants performing an oral fluid discrimination task. Participants exhibited relatively sustained low-rate retronasal airflow during sampling punctuated by higher-rate pulses often associated with deglutition. Although characteristics of post-deglutitive pulses did not differ across fluid conditions, the cumulative duration, probability, and estimated volume of retronasal airflow were greater during discrimination of perceptually similar solutions. These findings demonstrate the utility of a consumer-grade BCI system in assessing human olfactory behavior. They suggest further that sensorimotor processes regulate retronasal airflow to optimize the delivery of volatiles to the olfactory epithelium and that discrimination of perceptually similar oral fluids may be accomplished by varying the duration of optimal airflow rate.

Bombardment history of the Moon constrained by crustal porosity

The formation and evolution of the terrestrial planets were shaped by a bombardment of large impactors in a cluttered early Solar System. However, various surface processes degrade impact craters, and the early impact history of the Moon and the ages of its ancient impact basins remain uncertain. Here we show that the porosity of the lunar crust, generated by the cumulative crustal processing of impacts, can be used to determine the Moon’s bombardment history. We use a numerical model constrained by gravity data to simulate the generation of porosity by basin-forming impacts and the subsequent removal by smaller impacts and overburden pressure. We find that, instead of steadily increasing over the history of the Moon, lunar crustal porosity was largely generated early in lunar evolution when most basins formed and, on average, has decreased after that time. Using the Moon as a proxy for the terrestrial planets, we find that the terrestrial planets experienced periods of high crustal porosity early in their evolution. Our modelled porosities also provide an independent constraint on the chronological sequence of basin-forming impacts. Our results suggest that the inner solar system was subject to double the number of smaller impacts producing craters exceeding 20 km in diameter than has been previously estimated from traditional crater-counting analyses, whereas the bombardment record for the lunar basins (>200 km in diameter) is complete. This implies a limited late delivery of volatiles and siderophile elements to the terrestrial planets by impactors.

Krypton in the Chassigny meteorite shows Mars accreted chondritic volatiles before nebular gases.

Volatile elements are thought to have been delivered to Solar System terrestrial planets late in their formation through accretion of chondritic meteorites. Mars can provide information on inner Solar System volatile delivery during the earliest planet formation stages. We measured krypton isotopes in the martian meteorite Chassigny, representative of the planet's interior. We found chondritic krypton isotope ratios, which imply early incorporation of chondritic volatiles. The atmosphere of Mars has different (solar-type) krypton isotope ratios, indicating that it is not a product of magma ocean outgassing or fractionation of interior volatiles. Atmospheric krypton instead originates from accretion of solar nebula gas after formation of the mantle but before nebular dissipation. Our observations contradict the common hypothesis that during planet formation, chondritic volatile delivery occurred after solar gas acquisition.

The Helium and Carbon Isotope Characteristics of the Andean Convergent Margin

Subduction zones represent the interface between Earth’s interior (crust and mantle) and exterior (atmosphere and oceans), where carbon and other volatile elements are actively cycled between Earth reservoirs by plate tectonics. Helium is a sensitive tracer of volatile sources and can be used to deconvolute mantle and crustal sources in arcs; however it is not thought to be recycled into the mantle by subduction processes. In contrast, carbon is readily recycled, mostly in the form of carbon-rich sediments, and can thus be used to understand volatile delivery via subduction. Further, carbon is chemically-reactive and isotope fractionation can be used to determine the main processes controlling volatile movements within arc systems. Here, we report helium isotope and abundance data for 42 deeply-sourced fluid and gas samples from the Central Volcanic Zone (CVZ) and Southern Volcanic Zone (SVZ) of the Andean Convergent Margin (ACM). Data are used to assess the influence of subduction parameters (e.g., crustal thickness, subduction inputs, and convergence rate) on the composition of volatiles in surface volcanic fluid and gas emissions. He isotopes from the CVZ backarc range from 0.1 to 2.6 RA (n = 23), with the highest values in the Puna and the lowest in the Sub-Andean foreland fold-and-thrust belt. Atmosphere-corrected He isotopes from the SVZ range from 0.7 to 5.0 RA (n = 19). Taken together, these data reveal a clear southeastward increase in 3He/4He, with the highest values (in the SVZ) falling below the nominal range associated with pure upper mantle helium (8 ± 1 RA), approaching the mean He isotope value for arc gases of (5.4 ± 1.9 RA). Notably, the lowest values are found in the CVZ, suggesting more significant crustal inputs (i.e., assimilation of 4He) to the helium budget. The crustal thickness in the CVZ (up to 70 km) is significantly larger than in the SVZ, where it is just ∼40 km. We suggest that crustal thickness exerts a primary control on the extent of fluid-crust interaction, as helium and other volatiles rise through the upper plate in the ACM. We also report carbon isotopes from (n = 11) sites in the CVZ, where δ13C varies between −15.3‰ and −1.2‰ [vs. Vienna Pee Dee Belemnite (VPDB)] and CO2/3He values that vary by over two orders of magnitude (6.9 × 108–1.7 × 1011). In the SVZ, carbon isotope ratios are also reported from (n = 13) sites and vary between −17.2‰ and −4.1‰. CO2/3He values vary by over four orders of magnitude (4.7 × 107–1.7 × 1012). Low δ13C and CO2/3He values are consistent with CO2 removal (e.g., calcite precipitation and gas dissolution) in shallow hydrothermal systems. Carbon isotope fractionation modeling suggests that calcite precipitation occurs at temperatures coincident with the upper temperature limit for life (122°C), suggesting that biology may play a role in C-He systematics of arc-related volcanic fluid and gas emissions.

Habitable Planet Formation around Low-mass Stars: Rapid Accretion, Rapid Debris Removal, and the Essential Contribution of External Giants

Abstract In recent years, a paradigm shift has occurred in exoplanet science, wherein low-mass stars are increasingly viewed as a foundational pillar of the search for potentially habitable worlds in the solar neighborhood. However, the formation processes of this rapidly accumulating sample of planet systems are still poorly understood. Moreover, it is unclear whether tenuous primordial atmospheres around these Earth analogs could have survived the intense epoch of heightened stellar activity that is typical for low-mass stars. We present new simulations of in situ planet formation across the M-dwarf mass spectrum, and derive leftover debris populations of small bodies that might source delayed volatile delivery. We then follow the evolution of this debris with high-resolution models of real systems of habitable zone planets around low-mass stars such as TRAPPIST-1, Proxima Centauri, and TOI-700. While debris in the radial vicinity of the habitable zone planets is removed rapidly, thus making delayed volatile delivery highly unlikely, we find that material ubiquitously scattered into an exo-asteroid belt region during the planet-formation process represents a potentially lucrative reservoir of icy small bodies. Thus, the presence of external approximately Neptune–Saturn mass planets capable of dynamically perturbing these asteroids would be a sign that habitable zone worlds around low-mass stars might have avoided complete desiccation. However, we also find that such giant planets significantly limit the efficiency of asteroidal implantation during the planet-formation process. In the coming decade, long-baseline radial velocity studies and Roman Space Telescope microlensing observations will undoubtedly further constrain this process.

Exogenic origin for the volatiles sampled by the Lunar CRater Observation and Sensing Satellite impact

Returning humans to the Moon presents an unprecedented opportunity to determine the origin of volatiles stored in the permanently shaded regions (PSRs), which trace the history of lunar volcanic activity, solar wind surface chemistry, and volatile delivery to the Earth and Moon through impacts of comets, asteroids, and micrometeoroids. So far, the source of the volatiles sampled by the Lunar Crater Observation and Sensing Satellite (LCROSS) plume has remained undetermined. We show here that the source could not be volcanic outgassing and the composition is best explained by cometary impacts. Ruling out a volcanic source means that volatiles in the top 1-3 meters of the Cabeus PSR regolith may be younger than the latest volcanic outgassing event (~1 billion years ago; Gya).

Collisional fragmentation and bulk composition tracking in rebound

ABSTRACT We present a fragmentation module and a composition tracking code for the N-body code rebound. Our fragmentation code utilizes previous semi-analytical models and follows an implementation method similar to fragmentation for the N-body code mercury. In our N-body simulations with fragmentation, we decrease the collision and planet formation time-scales by inflating the particle radii by an expansion factor f and experiment with various values of f to understand how expansion factors affect the collision history and final planetary system. As the expansion factor increases, so do the rate of mergers which produces planetary systems with more planets and planets at larger orbits. Additionally, we present a composition tracking code which follows the compositional change of homogeneous bodies as a function of mass exchange and use it to study how fragmentation and the use of an expansion factor affects volatile delivery to the inner terrestrial disc. We find that fragmentation enhances radial mixing relative to perfect merging and that on average, as f increases so does the average water mass fraction of the planets. Radial mixing decreases with increasing f as collisions happen early on, before the bodies have time to grow to excited orbits and move away from their original location.

Deep-mantle krypton reveals Earth's early accretion of carbonaceous matter.

Establishing when, and from where, carbon, nitrogen and water were delivered to Earth is a fundamental objective in understanding the origin of habitable planets such as Earth. Yet, volatile delivery to Earth remains controversial1-5. Krypton isotopes provide insights on volatile delivery owing to their substantial isotopic variations among sources6-10, although pervasive atmospheric contamination has hampered analytical efforts. Here we present the full suite of krypton isotopes from the deep mantle of the Galápagos and Iceland plumes, which have the most primitive helium, neon and tungsten isotopic compositions11-16. Except for 86Kr, the krypton isotopic compositions are similar to a mixture of chondritic and atmospheric krypton. These results suggest early accretion of carbonaceous material by proto-Earth and rule out any combination of hydrodynamic loss with outgassing of the deep or shallow mantle to explain atmospheric noble gases. Unexpectedly, the deep-mantle sources have a deficit in the neutron-rich 86Kr relative to the average composition of carbonaceous meteorites, which suggests a nucleosynthetic anomaly. Although the relative depletion of neutron-rich isotopes on Earth compared with carbonaceous meteorites has been documented for a range of refractory elements1,17,18, our observations suggest such a depletion for a volatile element. This finding indicates that accretion of volatile and refractory elements occurred simultaneously, with krypton recording concomitant accretion of non-solar volatiles from more than one type of material, possibly including outer Solar System planetesimals.