Void Density Research Articles

The universal multiplicity function: counting haloes and voids

We present a novel combination of the excursion-set approach with the peak theory formalism in Lagrangian space and provide accurate predictions for halo and void statistics over a wide range of scales. The set-up is based on an effective moving barrier. Besides deriving the corresponding numerical multiplicity function, we introduce a new analytical formula reaching the percent level agreement with the exact numerical solution obtained via Monte Carlo realisations down to small scales, ∼ 1012 h -1M⊙. In the void case, we derive the dependence of the effective moving barrier on the void formation threshold, δ v, by comparison against the Lagrangian void size function measured in the DEMNUni simulations. We discuss the mapping from Lagrangian to Eulerian space for both haloes and voids; adopting the spherical symmetry approximation, we obtain a strong agreement at intermediate and large scales. Finally, using the effective moving barrier, we derive Lagrangian void density profiles accurately matching measurements from cosmological simulations, a major achievement towards using void profiles for precision cosmology with the next generation of galaxy surveys.

Atomistic analysis of the mechanisms underlying irradiation-hardening in Fe–Ni–Cr alloys

This work presents a comprehensive examination of the physical mechanisms driving hardening in irradiated face-centered cubic FeNiCr alloys. The evolution of irradiation-induced defects during shear deformation is modeled by atomistic simulations through overlapping cascade simulations, where the nucleation and evolution of dislocation loops is validated by transmission electron microscopy images obtained from irradiated FeNiCr alloys using tandem accelerator. The effect of different shear rates on the microstructure of irradiated materials with a specific focus on the changes in the density of voids and dislocation loops induced by irradiation was analyzed. Additionally, the fundamental interaction processes between single irradiation-induced defects contributing to irradiation hardening, such as voids and dislocation loops in the alloy are explained. The analysis at atomic level indicates that both the dislocation loops and the voids exhibit strengthening effects. Furthermore, the nanometric voids are much stronger obstacles than dislocation loops of comparable size. The mechanism of cutting the voids leads to an increase of voids density and thus contributes to an increase in irradiation hardening. The mechanism of collapse of small voids into dislocation loops leads to decrease of voids density and at the same time increase of loops density. The coupling effect between the density of voids and dislocation loops is determined. Finally, the novel, physical mechanisms-based model of irradiation hardening and dislocation-radiation defect reaction kinetics are developed, which consider the mechanisms of void cutting, void shrink and void collapse to dislocation loop.

Characterization of Fe-Cr alloys irradiated by neutrons at intermediate temperature

A series of Fe-Cr alloys, with 3 at.% - 18 at.% Cr, was irradiated in the Advanced Test Reactor (ATR) at the Idaho National Labs (INL), USA, up to a dose of ∼6.7 dpa at a temperature of ∼456 °C. Transmission electron microscopy (TEM) samples were extracted using a focused ion beam (FIB) instrument, and the resulting microstructural defects, such as voids, dislocation loops, network dislocations, Cr rich precipitates, etc., were characterized using a TEM. It was found that the size and number density of these defects varied widely over the different alloys with varying Cr content. As expected, there were no Cr rich precipitates in samples with Cr up to 9 %, and they started appearing only in samples with 12 at.% Cr and above. The particle size decreased from about 15 nm at 12 % Cr to 8 nm at 18 % Cr, while the number density increased from ∼7e20 /m3 to 6e22 /m3 for the same Cr contents. Grain boundary segregation of Cr, along with a precipitate free zone, was observed in the cases where a boundary was present in the sample. Large voids (>1–2 nm) were almost invisible in the Fe-3at.%Cr sample, while the average void size remained almost constant between 15 and 18 nm for samples with 6–15 at.% Cr and increased slightly at 18 at.% Cr to ∼22 nm. Fe-3 %Cr showed a high density of small voids(<2 nm), estimated to be about 1e23/m3. The number density of large voids increased from ∼0 at 3 % Cr to a peak of ∼6.4e20 /m3 at 12 % Cr, then decreased to about 1.1e20 /m3 at 18 % Cr. The dislocation loops, which appeared in linear arrays in the Fe-9 %Cr sample, were analysed in detail using both invisibility criteria and image simulations using the Oxford University TEMACI software, and it was found that they are most likely to be ½ 〈111〉 type loops on {100} planes. These loops seem shaped like sections of helices in some places and are most likely formed by loops near screw dislocations climbing into a helix and then collapsing into a loop array. Similar dislocation analysis was performed in the other samples as well wherever feasible, and it was found that there is a mixture of ½ 〈111〉 and [100] dislocation loops.

Why cosmic voids matter: mitigation of baryonic physics

We utilize the Magneticum suite of state-of-the-art hydrodynamical, as well as dark-matter-only simulations to investigate the effects of baryonic physics on cosmic voids in the highest-resolution study of its kind. This includes the size, shape and inner density distributions of voids, as well as their radial density and velocity profiles traced by (sub-) halos, baryonic and cold dark matter particles. Our results reveal observationally insignificant effects that slightly increase with the inner densities of voids and are exclusively relevant on scales of only a few Mpc. Most notably, we identify deviations in the distributions of baryons and cold dark matter around halo-defined voids, relevant for weak lensing studies. In contrast, we find that voids identified in cold dark matter, as well as in halos of fixed tracer density exhibit nearly indistinguishable distributions and profiles between hydrodynamical and dark-matter-only simulations, consolidating the universality and robustness of the latter for comparisons of void statistics with observations in upcoming surveys. This corroborates that voids are the components of the cosmic web that are least affected by baryonic physics, further enhancing their use as cosmological probes.

The effect of hydrogen co-injection on the microstructure of triple ion irradiated F82H

The reduced activation ferritic/martensitic steel F82H-IEA was studied through a systematic set of dual (Fe2++He2+) and triple (Fe2++He2++H+) ion irradiations to determine the effect of hydrogen co-injection with helium and radiation damage on the irradiated microstructure and in particular, cavity evolution. Irradiations were conducted in four distinct permutations from a set of nominal irradiation parameters of 50 dpa, 1 × 10–3 dpa/s, 500 °C, and 40/10 appm/dpa of H/He or 10 appm/dpa of He. A temperature series of dual and triple ions ranging from 400 to 600 °C was conducted where swelling values of 1.3–2.4x were obtained with the co-injection of hydrogen. A damage level (50 to 150 dpa) and damage rate (2.5 × 10–4 to 2.5 × 10–3 dpa/s) series were also conducted where hydrogen was again observed to cause a ∼1.2–1.8x increase in swelling in triple ion irradiation versus dual ions. The effect of hydrogen was also observed to increase the overall steady state swelling rate from 0.02%/dpa in dual ions to 0.034%/dpa under triple ions at 500 °C by 150 dpa. A final series of triple ion experiments was conducted at 450 °C and 500 °C at 80 appm/dpa of H where swelling was suppressed by 50% compared to the dual ion irradiated case due to over-nucleation of small bubbles. The effect of hydrogen on bubble nucleation was to stabilize higher densities of smaller helium bubbles possibly through increasing nucleation rates and reduction of the stable bubble radius. The effect on swelling was in the promotion of higher densities of larger voids experiencing bias-driven growth. Hydrogen was shown to have a moderate influence on the nucleation and growth of dislocation loops, although these effects appear to be convoluted by the changes in cavity microstructure dominating sink strength across conditions. Hydrogen co-injection was also loosely correlated with enhanced dissolution of M23C6 precipitates across temperature and damage level regimes.

Damage evolution and ductile fracture of commercially-pure titanium sheets subjected to simple tension and cyclic bending under tension

This paper describes a study into the evolution of damage in commercial-purity titanium (CP–Ti) sheets subjected to cyclic bending under tension (CBT) and uniaxial tension (simple tension, ST). Sections were taken from sheets that were strained to various levels under both methods and were imaged using X-ray computed tomography (XCT) to reveal insights into the size, density, and distribution of microvoids in the sheets. Digital image correlation (DIC) was also used to observe the surface strain of CBT and ST sheets during testing. These results showed that elongation to failure (ETF) for CBT deformation is about 2.5× higher than for ST, local longitudinal strains in the bulk of the CBT sample are around 1.3× higher than the peak strain in the ST necked region, and 1.7× higher in the localized region of CBT failure. It was found that the volume-density of voids in both sheets followed a similar exponential increase with strain, reaching nearly 45× higher in the CBT than the ST sheets before the onset of failure, mainly due to the higher strain levels achieved. A higher volume density of voids developed in the center of sheets at high levels of strain, for both processes, with the density in the sheet center becoming approximately double that found near the edges. Scanning electron microscopy (SEM) was used to examine the fracture surface of CBT and ST sheets after failure. The observations are presented and discussed highlighting the CBT process as effective to delay ductile fracture of the CP-Ti sheets.

Low-cost method to reduce interlayer voids in material extrusion: in situ layer-by-layer solvent treatment

Material extrusion (MEX) is worldwide known as one of the most flexible additive manufacturing (AM) technologies for the fabrication of complex polymeric structures. However, the extremely high geometrical freedom has a price to pay: the presence of interlayer voids between consecutive extruded layers is the main backwards of MEX technology. Interlayer voids make 3D printed parts weaker (poor mechanical properties) compared to polymeric components fabricated by means of counterpart processes (i.e., injection molding). The present research work introduces a novel approach for the reduction of voids based on the layer-by-layer application of solvent vapor during the fabrication process, to smooth every single deposited layer. In this way, the new extruded layer has a greater area to bond with the previously extruded layer, resulting in an overall reduction of the porosity. The proposed approach is cost-effective, and it is based on the stop and go method enabled by MEX technologies: the fabrication process is paused after every layer, and when the solvent treatment is performed, the 3D printing process is resumed. The effectiveness of the layer-by-layer solvent vapor approach was evaluated, thereby resulting in a great reduction of the void density and average void area of 96%, and 79% respectively, and an increase of the wetting factor of 34%. Such findings pave the way for the exploitation of the proposed approach for the fabrication of complex structures with a reduced number of voids to be employed as structural components.

Comparative Evaluation of the Quality of Obturation Between Three Obturation Techniques in Primary Canines: An In Vitro Study.

Aims This study compares three obturation techniques (rotary lentulo spiral, handheld lentulo spiral, and pressure syringe) for the quality of two filling pastes (zinc oxide eugenol (ZOE) paste and Metapex (Meta Biomed Co., Ltd., Chungcheongbuk-do, Korea). Methods and materials Sixty extracted primary canines were instrumented and obturated by filling materials. The obturation techniques were divided into three groups according to different obturation techniques.Obturation quality was evaluated for length, density, and presence of voids by using digital radiography. Results This study showed that the handheld lentulo spiral technique using Metapex and ZOE exhibited more optimal fillings for obturation length. The highest density obturation was achieved using the syringe injection approach with Metapex and ZOE. The highest incidence of both external and internal voids was observed in the group using ZOE with the handheld lentulo spiral technique Conclusions Based on the findings of this study, for both filling materials, the handheld lentulo spiral technique had the greatest number of optimal lengthsbut there were also more voids.

Atomic-scale three-dimensional irradiation-induced defect kinetics models for bcc Fe-based alloys

The interaction between irradiation defects and dislocations could lead to macroscopic hardening and embrittlement. In this study, molecular dynamics (MD) and machine learning were conducted to study three-dimensional void- and Cu-cluster-induced kinetics models under interaction with dislocations in body-centered cubic Fe-based alloys. MD Results show that dislocation climb and shear are two types of interaction mechanism based on the defect size. Combined MD results and machine learning, it was found that the dislocation length increased linearly with an increase in the size of the defects after the interaction. In addition, the number of atoms in the Cu-rich cluster and the reduced number of vacancies in the voids had a square relationship with the defect size where 0.85D2 is for Cu-rich cluster and 0.50D2 is for void. Furthermore, atomic-scale three-dimensional irradiation-induced defect kinetics models were developed and incorporated into the crystal plasticity finite element model (CPFEM). We also analyzed the contributions of various defects to the increase in the yield stress during CPFEM simulation. Compared with DBH model, the prediction of MD data-driven CPFEM matches better with the experimental data. Cluster contributed the most to hardening with low obstacle strength due to the higher number density compared with dislocation loops and voids. The loops also contributed to hardening; however, their contribution was smaller than that of the clusters. Although the number density and size of voids were minimized, they may have contributed because of the high obstacle strengths. This work can indeed deepen the understanding of irradiation effect in Fe-based alloys.

Improving the Device Stability by Controlling the Morphology of Quantum Dot Emissive Layer Via a Coating Process in Blue QLEDs

AbstractBlue light‐emitting CdSe@ZnS/ZnS quantum dot (QD) nanoparticles (NPs) were synthesized and their photophysical properties in both solution and film phases were investigated. The morphological properties of films prepared by different coating methods i. e. single layer coating from low to high concentrations of QD solutions and layer‐by‐layer (multilayer) coating within constant low QD solution concentration, were also examined in detail. Varying the concentration (1–10 mg/mL) and the number of layers (from 1–16) did not essentially affect the photophysical properties of QD films, although it resulted in a direct increment in QD film thickness. The concentration and layer‐dependent films were used as an emissive layer (EML) in QD light‐emitting diodes (QLEDs). Although the “6 mg/ml−1 Layer” QD EML‐based device exhibited relatively high device efficiency compared to the “1 mg/ml−10 Layers” based one at working voltage region, it had ~2‐fold higher efficiency roll‐off at high voltage region. The performance differences for both devices with the same QD EML thickness were attributed to the morphological variations for the QD layer in terms of surface roughness, void density, aggregates/clusters, and trap sites that were directly related to the charge injection balance and Auger recombination.

Forming limit and failure characterization of as-received and bi-axial prestrained Cu-Cr-Zr-Ti alloy sheets in the context of multistage forming

The characterization of forming limit utilizing Cu-Cr-Zr-Ti alloy sheets during the multistage forming process is imperative for successfully fabricating thrust chamber liners used in satellite launch vehicles. Therefore, the present work studies the effect of prestrain on the forming limit and failure behaviour of this alloy under different deformation paths. A stretch-forming setup was utilized to induce 8% equi-biaxial prestrain (EBP), and subsequently, these prestrained specimens were deformed till the onset of failure using the same setup. After prestraining, a shift in the failure strains was observed in the principal strain space, whereas it was found to be absent in the polar effective plastic strain, principal stress and effective plastic strain-stress triaxiality loci. The cup height along different deformation paths was marginally decreased in the prestrained specimens because of the reduction in failure strains, and the fracture occurred in the prestrained region. Further, failure analysis revealed intergranular cracks in the specimens deformed along plane strain and uniaxial deformation paths due to the presence of micron-size Cr-rich precipitates along grain boundaries. However, intergranular and transgranular cracks were present in the prestrained specimens, which were deformed equi-biaxially similar to the as-received specimens. The presence of nano-size Cr-rich precipitates inside the grains acted as nucleation sites for voids during equi-biaxial stretching, leading to transgranular cracks. It was also observed that failure in the prestrained and as-received specimens occurred at a similar effective plastic strain value due to the combined effect of void density and void size. Based on experimental observations, it was inferred that the forming limit of Cu-Cr-Zr-Ti sheets under a two-stage forming process was primarily affected by the presence of micro and nano-size Cr-rich precipitates.

Void swelling in pure iron after sequential self-ion-irradiation at different energies: Effect of injected interstitials and additional damage in regions containing pre-existing voids

The use of ion irradiation to add displacement dose onto previously neutron-irradiated material is becoming popular, especially since ion irradiation precedes on neutron-typical microstructures and microchemical distributions that would not be produced with ion irradiation alone. One issue to be addressed in these “neutron-preconditioned” specimens concerns the consequences of ion-injected interstitials on preexisting neutron-produced voids, especially since voids have been observed to disappear over a significant portion of the ion range in some recent preconditioning experiments. This situation can be explored using innovative ion simulation, thereby avoiding working with radioactive material.Two self-ion irradiation series of pure single-crystal iron were performed at 475 °C. The first series used 5 MeV Fe2+, reaching 50, 100 and 150 peak dpa, producing voids to ∼2 µm depth. The second series used 2.5 MeV Fe2+ to introduce additional 50 peak dpa onto each of the three first-step specimens with the ion range reaching ∼1.2 µm. Importantly, 1.2 × 10−3 peak dpa/s was used for both ions to minimize the influence of dpa rate. The major objective was to measure the influence of injected interstitials from the 2.5 MeV Fe2+ irradiation on previously existing voids. Another objective was to observe the behavior of voids exposed to additional dose and time, focusing not only on injected interstitials, but also on the effects of coalescence, ripening, and aging.There were significant changes in depth distribution of swelling following the second irradiation, especially void density. Whereas injected interstitials are well-known to suppress void nucleation at the end of ion range, it was shown in this study that injected interstitials are important in another manner, reducing growth of previously existing voids, producing a ‘notch” in both the swelling vs. depth profile and void size profile. At depths where the injected atoms for both ion energies are not significant, swelling proceeds at ∼0.2 %/dpa.

3D porosity, flow, and transport characteristics of two L chondrites reveal wet accretion-related cosmic web-like porosity

Porosity, with its structure-dependent flow properties (permeability and tortuosity) and transport properties (thermal conductivity and thermal diffusivity), is closely related to the accretion, thermal metamorphism, and associated hydrothermal alteration of ordinary chondrite (OC) parent bodies. Using synchrotron radiation microtomography (SRμCT), we reveal the varying porosity structures in two L chondrite falls of low (Mezö-Madaras L3.7) and high (Bath Furnace L6) petrologic types and quantify porosity properties, such as shape and connectivity, and related effective permeability and tortuosity factor. Although the two specimens demonstrate similar effective permeabilities, they exhibit significantly different tortuosity factors and textures of porosity, which include notable differences in void throat diameters, complexity and density of the interconnected void network, heterogeneity in void distribution, and the extent of primary and secondary porosity. The complex relationships among porosity, permeability, tortuosity, and thermal conductivity can be explained by the varying void arrangements related to varying grain sizes among the petrologic types of OCs, which in turn reflect their varying evolutionary paths.Electron microprobe and attached energy-dispersive X-ray spectrometer reveal signs of hydrothermal alteration in both petrologic types. High-energy SRμCT imaging (0.65 μm voxel size) reveals the presence of a new microporosity substructure resembling a microscopic cosmic web, which may be linked to fluid-assisted metamorphism and hydrothermal alteration during wet accretion of the parent body. Furthermore, the proportion of this continuous porosity may be related to the temperatures associated with different petrologic types, and the wet accretion model may resolve the lack of correlation between petrologic types and porosity of OCs. Finally, the uncovered cosmic web-like microporosity structure may explain the observed concurrent high thermal conductivity, low permeability, and high porosity of the high-petrologic-type OCs.

The effect of Fe content on the dielectric properties of TlGa(0,999)Fe(0,001)S2 thin films

0,1 % iron containing Thallium Gallium Sulfide (TlGaS2 and TlGa(0,999)Fe(0,001)S2) thin films were deposited by thermal evaporation in the thickness range 20–200 nm. Raw bulk TlGaS2 and TlGa(0,999)Fe(0,001)S2 crystals were produced using the Bridgman technique. Iron (Fe) content was free, and the bonding content of a polarized charged group in the crystal and thin films was detected in the X-ray diffraction patterns. The dielectric characteristics of the thin films were determined by dielectric spectroscopy. The dielectric results showed Fe content polarizing in space-charge characteristics in the 1–100 Hz frequency range. Besides, the position and magnitude of dipolar polarization supported the presence of dipolar polarized charged groups having Fe content. In addition, it was realized that the void density explicitly affects the dielectric constant. The void density decreased toward higher thicknesses, whereas the dielectric constant increased. The ac conductivity results contributed to evaluating the effect of thickness for each thin film. The overall analysis indicated that even a small percentage of Fe (0,1 %) has a remarkable impact on the dielectric properties and electrical conduction of TlGa(0,999)Fe(0,001)S2 thin films. This analysis can provide opportunities to improve the electrical abilities of Thallium Gallium Sulfide (TlGaS2) thin films, which have applications as receivers of visible and infrared emission, X-ray and gamma-ray detectors, neutron detectors, barometers, and piezoelectric photoresistors if the presence of Fe is considered as investigated in TlGa1−xFexS2 thin films.

Thermal-based efficient modeling for mechanical properties of thermoplastic polymers in material extrusion

The process-induced void defects play an important role in the mechanical properties of thermoplastic polymers fabricated by material extrusion (ME). Thus, it is meaningful to accurately and efficiently determine the impact of void defects on the ultimate mechanical properties of ME-printed parts. However, the straightforward relation between process parameters, void density, and mechanical properties remains unclear. In this paper, semi-analytical modeling is presented to efficiently predict the effective properties of ME-printed thermoplastic polymers. The void density related to process variables in the ME process is numerically determined based on a thermal sintering model. Subsequently, the effective properties of as-printed thermoplastic polymers are analytically predicted using the unit-cell-based homogenization method. The predicted results by the proposed semi-analytical model are validated by the comparison with experiments and finite element analysis. Furthermore, the effect of primary printing parameters on the degree of fusion, void density, and effective properties is examined. The results show that the elevated extrusion and substrate temperatures, as well as the decreased printing speed, layer height, and nozzle radius, contribute to the higher degree of fusion, leading to lower void density and superior elastic properties. In addition, moderate feeding speed and environmental temperature can enhance the elastic properties of ME-printed thermoplastic parts. These results offer useful guidelines for the design and manufacturing of thermoplastic parts with high performance.

Physicomechanical, water absorption and thermal properties and morphology of Paederia foetida fiber–Al2O3 powder hybrid‐reinforced epoxy composites

AbstractHybridization of natural fibers with ceramic materials for reinforcing composites allows the optimization of the properties of these materials. For this reason, the present study aims to investigate physical, mechanical, water absorption, swelling and thermal properties as well as morphological characteristics of a hybrid Paederia foetida fibers–alumina powder (PFs–Al2O3)‐reinforced epoxy composite. Epoxy resin served as the matrix, while PFs and Al2O3 were employed as reinforcement. Five types of composites were fabricated using the hot‐pressing technique. The corresponding ratios of PFs:Al2O3 volume fractions (%) considered here were 0:40 (SFA), 10:30 (SFB), 20:20 (SFC), 30:10 (SFD) and 40:0 (SFE). The results reveal that the density of the hybrid PFs–Al2O3 composites decreased for increasing volume fractions of PFs: from 2.173 g cm−3 of SFA to 1.042 g cm−3 of SFE. The highest values of tensile strength (i.e. 49.085 MPa), tensile elastic modulus (i.e. 1.431 GPa) and impact strength (24 kJ m−2) were obtained for the SFD composite material with 30% volume fraction of PFs and 10% volume fraction of Al2O3: this happened because interface bonds between PFs, Al2O3 and epoxy phases achieved their optimal configuration. Overall, mechanical properties of the hybrid PFs–Al2O3‐reinforced epoxy composites were superior to those of composites reinforced only by PF fibers or only by Al2O3. Water absorption and swellability reached their maximum values at the steady state occurring after tested samples remained immersed in water for 820 h. The SFE composite reinforced only by PFs presented the highest water absorption and swelling (i.e. 6.034% and 5.81%, respectively) while for all other hybrid composites (SFD, SFC and SFB) these two quantities remained below 5%. Density and volume fraction of voids of hybrid PFs–Al2O3‐reinforced composites were consistent with the corresponding properties of the composites reinforced only by Al2O3 or PFs. SFD was also the most thermally stable material. Scanning electron microscopy observations of fractured surfaces indicated that the microstructure of the PFs–Al2O3‐reinforced epoxy composites presents several voids, fiber pullouts and transverse fibers, which together optimize the mechanical response of the composite material. Remarkably, the SFD composite material was highly competitive with the most recently developed hybrid composites employing natural reinforcements. © 2024 Society of Industrial Chemistry.

The effect of silica nanoparticles on the shock adiabatic relation and tensile strength in polyurethane

This work exploded the effect of silica nanoparticles on shock adiabatic relation and tensile fracture in polyurethane based on atomistic simulations. It is found that the non-uniform interface structures introduced by nanoparticles can increase the shock impedance, which also leading to increased twisting of polyurethane chains and the generation of local hotspots near the nanoparticles. The interface structures near the nanoparticle consists of polyurethane chains with a high gyration radius, and the average gyration radius increases approximately linearly with the increase in nanoparticle content. At lower shock velocity, the potential energy increment initially increases and then decreases with the increase in nanoparticle content. Bond analysis reveal that flexible segments dominate the bending and twisting deformations of polyurethane, while nanoparticles enhance the corresponding deformation degrees. Furthermore, nanoparticles can serve as void nucleation sites for early-stage tensile damage, resulting in a decrease in fracture strength. Differing from metals, the relationship between tensile strength and fracture temperature follows a more linear law. Nanoparticles inhibit the later growth and coalescence of voids by increasing the temperature and steric hindrance. The density and size distribution characteristics of voids are consistent with the changes in potential energy during the shock compression process. Unlike classical spallation, the curled polyurethane chains in the tensile region gradually orient along the shock direction, evolving into a void-fiber structure.

Effect of Carbon Nanotube Reinforcement on Creep and Recovery Behavior of Additively Manufactured Polymers: An Experimental and Prediction Study

In this study, one of the most frequently used polymeric materials in fused deposition modeling (FDM) acrylonitrile butadiene styrene (ABS) is reinforced with different amount of carbon nanotubes (CNTs). Thermogravimetric analysis and differential scanning calorimetry analysis are applied to examine thermal degradation behavior of produced nanocomposite filaments. Specimens are manufactured by fused deposition modeling by using produced nanocomposite filaments. Tensile, creep and viscoelastic-viscoplastic behaviors of FDM-printed nanocomposite samples are investigated by conducting tensile, creep and loading–unloading tests under different strain rates and strain levels. Morphology of 3D printed samples is examined through scanning electron microscopy. Void densities which plays important role in mechanical behavior of additively manufactured samples are determined via ImageJ and CNT reinforcement on void densities are investigated. Data obtained from tests are used in system identification process, and multi-input–single-output model structures are proposed for the prediction of tensile, creep and recovery behaviors of 3D printed nanocomposite materials.

Nanovoid formation mechanism in nanotwinned Cu

Nanotwinned metals have been intensely investigated due to their unique microstructures and superior properties. This work aims to investigate the nanovoid formation mechanism in sputter-deposited nanotwinned Cu. Three different types of epitaxial or polycrystalline Cu films are fabricated by magnetron sputtering deposition technique. In the epitaxial Cu (111) films deposited on Si (110) substrates, high fractions of nanovoids and nanotwins are formed. The void size and density can be tailored by varying deposition parameters, including argon pressure, deposition rate, and film thickness. Interestingly, nanovoids become absent in the polycrystalline Cu film deposited on Si (111) substrate, but they can be regained in the epitaxial nanotwinned Cu (111) when deposited on Si (111) substrate with an Ag seed layer. The nanovoid formation seems to be closely associated with twin nucleation and film texture. Based on the comparative studies between void-free polycrystalline Cu films and epitaxial nanotwinned Cu films with nanovoids, the underlying mechanisms for the formation of nanovoids are discussed within the framework of island coalescence model.Graphical abstract

Finite element modelling of ultrasonic backscattered waves for improving creep void detection

ABSTRACT Ultra-supercritical coal-fired power plants in Japan and globally experience creep damage in the welded parts of their high-chromium steel assets. As the creep damage advances, voids develop at depth by preference and become dense and cause accidents. The voids cannot be detected using existing non-destructive methods, causing the unreasonable and uneconomic management of plants. To establish a non-destructive examination method that can be used for practical and economic maintenance, a detection method for dense creep voids using ultrasonic backscattered waves is proposed herein. The creep-damaged structures are modelled using a transducer and the transmission and reception characteristics are discussed. These characteristics are considered using the finite element method, as they cannot be measured through normal experiments. The results show that without a focusing process at the time of reception, changes in the amplitude of backscattered waves cannot be confirmed; thus, the contribution of transmission focus to creep void detection is limited. Conversely, it is confirmed that when the received backscattered waves in the direction normal to the transducer are integrated and the phase matching is reflected, the amplitude of the scattered waves increases with creep void density. The reception focus considerably contributes towards dense creep void detection.