This article describes the development and characterization of an optical fiber humidity sensor employing intensity modulation via the evanescent wave (EW) absorption technique. For the development of the sensor, SiO2-capped ZnO quantum dot (QDs) thin film is synthesized over the decladded portion of plastic cladding silica (PCS) fiber via the sol-gel method. A thorough experimental investigation was conducted by varying the thickness of the sensing film to optimize the sensor’s response. The sensing probe with optimized film thickness of 891 nm demonstrates a linear response over 30.5%–92.5%RH with an enhanced sensitivity of 46.2 mV/%RH (0.0138RH−1). Very fast response and recovery times of 2 s and 2.5 s are observed during humidification and dehumidification for the optimized sensing probe. The maximum resolution recorded during the short stability test is ±0.12%RH. Additionally, the proposed sensor demonstrates a very high degree of repeatability, reversibility, and stability. The proposed sensor has also been tested for human breath monitoring and voice print recognition. The result shows the sensor is able to detect minute humidity fluctuations in exhaled air during breathing and speaking.