Cross-linked polyethylene (XLPE) insulated power cables are widely used in transmission and distribution networks. The enhanced localised electrical field/stress can result in surface discharges (SD), i.e. partial discharges on the surface of the dielectric. To measure discharges, very low frequency (VLF-0.1 Hz or lower) excitation has emerged as an attractive alternative to the conventional power frequency (PF- 50/60 Hz) testing as it significantly reduces the required reactive power from the test supply. As the discharge process mainly resulted from the enhanced electric stress; it is necessary to understand how the electric field distributes on the XLPE dielectric surface when it is exposed to a high voltage AC excitation. In this study, the distribution of surface electric field before, during and after a PD event at VLF and PF test voltage is investigated. Finite element analysis (FEA) based numerical simulation shows that the space charge dynamics cause the differences in the field distribution and supports the experimental results.