Visible LED Lamps Research Articles

A comparative study of photo-Fenton process assisted by natural sunlight, UV-A, or visible LED light irradiation for degradation of real textile wastewater: factorial designs, kinetics, cost assessment, and phytotoxicity studies

The present work aims to evaluate the treatment of the effluent from the textile industry via advanced oxidative processes of photo-Fenton assisted by different sources (natural sunlight, UV-A or visible LED lamps). To identify the best operating conditions, a factorial design was carried out for each process. It was observed that after the optimization of the processes, chemical oxygen demand (COD) removals greater than 88% were achieved. In addition, it was observed that the use of the LED lamp required lower reagent concentrations compared to solar and UV-A sources. A kinetic study was carried out under the best conditions obtained and it was observed that the sources showed rapid evolution, reaching a COD removal equilibrium with 30 min of reaction. Reagent monitoring was also carried out, and it was observed that they were not limiting to the reaction. Phytotoxicity analysis was also satisfactory since the treated effluents allowed a higher relative growth and germination index of the cucumber roots compared to the raw effluent. Finally, the cost analysis indicated that the use of LED lamps resulted in a reduction in electrical consumption compared to the UV-A lamp, as well as a reduction in the cost of reagents due to the lower concentration of reagents required compared to processes assisted by natural sunlight and UV-A.

Effect of moving microalgae on underwater wireless optical links.

Underwater wireless optical communications is a promising technique for addressing short-range data networks, as it provides cost, performance, and complexity improvements as compared with other alternatives, such as acoustic communications or radio frequency links. It is a part of the optical wireless communications research area, since for these applications, broad optical sources such as visible LED lamps can be used. Unless those links are designed for short distances (about 1 m, as in data-muling services on internet-of-things submerged systems), they are still severely affected by channel perturbations, such as scattering due to the presence of particles. This effect is particularly important when considering sensing applications for algae or aquaculture farming, which are becoming a crucial economic resource in many maritime areas. In this work, the effects of moving microalgae on underwater short-range optical links are studied so as to estimate a model for this scattering under dynamic conditions. The statistical parameters over experimentally measured received signal level and signal-to-noise ratio (SNR) are calculated, and the experimental setup is described. Results show that in clear water (no-algae scenario), the water-pump-induced movement effect over the mean and variance of the received optical power can be neglected, while when microalgae are present, the average optical power value decreases and the variance increases with all measured wavelengths. Finally, the SNR penalty due to the movement of microalgae is statistically evaluated.

SPR effect of bismuth enhanced visible photoreactivity of Bi2WO6 for NO abatement

Bi2WO6 is a typical visible-light-responsive semiconductor photocatalyst with a layered structure. However, the relatively large bandgap (2.6–2.8 eV) and quick recombination of photo-generated carriers result in its low quantum efficiency. In this paper, Bi-nanospheres-modified flower-like Bi2WO6 was successfully prepared by solvothermal treatment of Bi2WO6 powders in Bi(NO3)3 solution using ethylene glycol as reductant. The photoreactivity of this photocatalyst was evaluated by the oxidation of NO in a continuous-flow reactor under irradiation by a visible LED lamp (λ > 400 nm). It was found that both Bi nanospheres and flower-like Bi2WO6 precursor exhibit very poor photocatalytic activity with NO removal rates of only 7.7% and 8.6%, respectively. The photoreactivity of Bi/Bi2WO6 was found to steadily increase from 12.3% to 53.1% with increase in the amount of Bi nanospheres from 0 to 10 wt%. However, with further increase in the loading amount of Bi nanospheres, the photoreactivity of Bi/Bi2WO6 hybridized photocatalyst begins to decrease, possibly due to the light filtering by the Bi nanospheres. The enhanced visible photoreactivity of Bi/Bi2WO6 towards NO abatement was attributed to surface plasmon resonance driven interfacial charge separation. The excellent stability of Bi/Bi2WO6 hybridized photocatalyst towards NO oxidation demonstrates its potential for applications such as air purification.

Improved Reactor Productivity for the Safe Photo‐Oxidation of Citronellol Under Visible Light LED Irradiation

AbstractA simple continuous flow photochemical reactor was optimized for the safe photo‐oxidation of citronellol into precursors of rose oxide, a flagrance of commercial value. The reactor productivity was increased by a factor of 4 compared to the current literature for a conversion above 99 % and in safe conditions (up to 0.72 mM min−1 mLreactor−1). The reactor was based on a classical design described by Booker‐Milburn et al., i. e. multiple loops of perfluoroalkoxy (PFA) tubing wrapped tightly around a visible LED lamp under slug flow conditions. The influence of the type of visible white LED light (6500 K vs. 3000 K), of photosensitizers (tetraphenylporphyrin vs. methylene blue), of solvent (CH2Cl2 vs. MeOH), concentration of citronellol (0.1 M vs. 2 M) and of mass efficiency of the reactors (PFA tubing of 0.75 mm to 0.25 mm) was paramount to increase the productivity of the reactor.

Treatment of textile wastewater under visible LED lamps using CuO/ZnO nanoparticles immobilized on scoria rocks

ZnO and CuO thin films were synthesized by a sol–gel and direct crystallization method on granular porous natural scoria respectively and CuO/ZnO/scoria was used for water treatment under visible light irradiation.

Feasibility of Light‐emitting Diode Uses for Annular Reactor Inner‐coated with TiO2 or Nitrogen‐doped TiO2 for Control of Dimethyl Sulfide

Limited environmental pollutants have only been investigated for the feasibility of light-emitting diodes (LED) uses in photocatalytic decomposition (PD). The present study investigated the applicability of LEDs for annular photocatalytic reactors by comparing PD efficiencies of dimethyl sulfide (DMS), which has not been investigated with any LED-PD system, between photocatalytic systems utilizing conventional and various LED lamps with different wavelengths. A conventional 8 W UV/TiO(2) system exhibited a higher DMS PD efficiency as compared with UV-LED/TiO(2) system. Similarly, a conventional 8 W visible-lamp/N-enhanced TiO(2) (NET) system exhibited a higher PD efficiency as compared with six visible-LED/NET systems. However, the ratios of PD efficiency to the electric power consumption were rather high for the photocatalytic systems using UV- or visible-LED lamps, except for two LED lamps (yellow- and red-LED lamps), compared to the photocatalytic systems using conventional lamps. For the photocatalytic systems using LEDs, lower flow rates and input concentrations and shorter hydraulic diameters exhibited higher DMS PD efficiencies. An Fourier-transformation infrared analysis suggested no significant absorption of byproducts on the catalyst surface. Consequently, it was suggested that LEDs can still be energy-efficiently utilized as alternative light sources for the PD of DMS, under the operational conditions used in this study.