Verwey Transition Temperature Research Articles

Magnetization process of cubic Fe3O4 submicron particles: First-order reversal curves and neutron diffraction studies

We have studied magnetization process of 260 nm sized cubic Fe3O4 particles below and above the Verwey transition temperature Tv∼ 110 K, by measurements of magnetic first-order reversal curves (FORCs) and high-resolution power neutron diffraction. The FORC diagram exhibits two distinct FORC distribution peaks below Tv, which shift towards the origin, merge into a single peak on heating, whereas only a single FORC peak appears above Tv. Neutron diffraction measurements under magnetic fields revealed a minimum of the magnetic intensity at a magnetic field of ∼−300 Oe, being close to the reversal field where the FORC peak is located. These results were interpreted as due to a reorientation and reversal of a spin vortex core, which accompany a large magnetic irreversibility.

Solid-State Schikorr Reaction from Ferrous Chloride to Magnetite with Hydrogen Evolution as the Kinetic Bottleneck.

The selective formation of meta-stable Fe3O4 from ferrous sources by suppressing its oxidative conversion to the most stable hematite (α-Fe2O3) is challenging under oxidative conditions for solid-state synthesis. In this work, we investigated the conversion of iron(II) chloride (FeCl2) to magnetite (Fe3O4) under inert atmosphere in the presence of steam, and the obtained oxides were analyzed by atomic-resolution TEM, 57Fe Mössbauer spectroscopy, and the Verwey transition temperature (Tv). The reaction proceeded in two steps, with H2O as the oxide source in the initial step and as an oxidant in the second step. The initial hydrolysis occurred at temperatures higher than 120 °C to release gaseous HCl, via substituting lattice chloride Cl- with oxide O2-, to give iron oxide intermediates. In the first step, the construction of the intermediate oxides was not topotactic. The second step as a kinetic bottleneck occurred at temperatures higher than 350 °C to generate gaseous H2 through the oxidation of FeII by H+. A substantially large kinetic isotope effect (KIE) was observed for the second step at 500 °C, and this indicates the rate-determining step is the hydrogen evolution. Quantitative analysis of evolved H2 revealed that full conversion of ferrous chloride to magnetite at 500 °C was followed by additional oxidation of the outer sphere of magnetite to give a Fe2O3 phase, as supported by X-ray photoelectron spectroscopy (XPS), and the outer phase confined the conductive magnetite phase within the insulating layers, enabling kinetic control of magnetite synthesis. As such, the reaction stopped at meta-stable magnetite with an excellent saturation magnetization (σs) of 86 emu g-1 and Tv > 120 K without affording the thermodynamically stable α-Fe2O3 as the major final product. The study also discusses the influence of parameters such as reaction temperature, initial grain size of FeCl2, the extent of hydration, and partial pressure of H2O.

Enhanced Magnetism and Anomalous Hall Transport through Two-Dimensional Tungsten Disulfide Interfaces

The magnetic proximity effect (MPE) has recently been explored to manipulate interfacial properties of two-dimensional (2D) transition metal dichalcogenide (TMD)/ferromagnet heterostructures for use in spintronics and valleytronics. However, a full understanding of the MPE and its temperature and magnetic field evolution in these systems is lacking. In this study, the MPE has been probed in Pt/WS2/BPIO (biphase iron oxide, Fe3O4 and α-Fe2O3) heterostructures through a comprehensive investigation of their magnetic and transport properties using magnetometry, four-probe resistivity, and anomalous Hall effect (AHE) measurements. Density functional theory (DFT) calculations are performed to complement the experimental findings. We found that the presence of monolayer WS2 flakes reduces the magnetization of BPIO and hence the total magnetization of Pt/WS2/BPIO at T > ~120 K-the Verwey transition temperature of Fe3O4 (TV). However, an enhanced magnetization is achieved at T < TV. In the latter case, a comparative analysis of the transport properties of Pt/WS2/BPIO and Pt/BPIO from AHE measurements reveals ferromagnetic coupling at the WS2/BPIO interface. Our study forms the foundation for understanding MPE-mediated interfacial properties and paves a new pathway for designing 2D TMD/magnet heterostructures for applications in spintronics, opto-spincaloritronics, and valleytronics.

Polarized neutron scattering study of hollow Fe3O4 submicron spherical particles

We report results of polarized small-angle and wide-angle neutron scattering experiments at T = 10 and 300 K for 420 nm-sized hollow Fe3O4 spherical particles. Each hollow particle is a mesocrystal, which is composed of small nanoparticles with nearly the same crystallographic orientation. Polarized neutron experiments allow us to evaluate magnetic correlations of parallel and perpendicular magnetization components with respect to magnetic field during magnetization process. Small-angle neutron scattering reveals that as the magnetic field decreases from a saturation field of 10 kOe, the perpendicular magnetization component maximizes around zero applied field, whereas the parallel component minimizes. This behavior was observed below and above Verwey transition temperature of ∼ 120 K. Calculations of neutron intensities for vortex structures suggest the reorientation of the vortex core towards the magnetocrystalline anisotropy axis from the magnetic field direction at low applied fields. Moreover, a magnetic domain length obtained from the wide-angle scattering is of the order of 30-40 nm and comparable to the size of the small nanoparticles forming a hollow sphere, suggesting that magnetic correlations within the small nanoparticles always retain during magnetization process.

Temperature dependence of the hyperfine parameters on Fe3O4(111) surfaces

The Verwey transition on Fe3O4(111) surface was investigated using nuclear resonant x-ray scattering (NRS). Measurements were conducted below (85 K) and above (297 and 500 K) the Verwey transition temperature. The internal magnetic field estimated from the NRS frequency spectra agreed with that of bulk Fe3O4 at all measured temperatures. A clear change in the intensity ratio of the two peaks in the frequency spectra was observed across the Verwey transition. The results indicate that despite the presence of the peculiar surface electronic states which makes the changes in the electronic properties across the Verwey transition temperature blurred, the hyperfine parameters of the (111) surface show a clear change across the Verwey transition temperature.

Frenkel pair formation energy for cubic Fe3O4 in DFT + U calculations

The cubic phase of magnetite is stabilized above the Verwey transition temperature of about 120 K via a complex electron–phonon interaction that is still not very well understood. In this work using the DFT + U method we describe our attempt to calculate point defect formation energies for this cubic phase in the static approximation. The electronic structure calculations and atomic relaxation peculiarities are discussed in this context. Only the cubic phase model with a small band gap and charge disproportionation (Fe2+/Fe3+) gives an adequate point defect formation energies, not the semi-metallic model. The relaxation of the local defect atomic structure and the relaxation of the surrounding crystal matrix are analyzed. Point defects cause only local perturbations of atomic positions and charge-orbital order. After analysis of the supercell size effects for up to 448 atoms, we justify the use of small supercells with 56 atoms to make calculations for the cubic phase. The extensive experimental results of Dieckmann et al on defects in magnetite at high temperature are deployed for comparison of our DFT + U results on Frenkel pair formation energies.

Temperature dependent transition of conduction mechanism from carrier injection to multistep tunneling in Fe3O4 (111)/Alq3/Co organic spin valve

We have presented experimental results addressing the origin of spin valve (SV) magneto-resistance (MR), in both injection and tunnel conduction regimes, in our fabricated Fe 3 O 4 (111)/Alq 3 /Co SV device. Experimental evidences have shown that any alternative MR process, such as ‘tunneling anisotropic MR’ is not at the origin of this SV MR. Spin resolved density of states of electrodes indicate that both the conduction mechanisms induce different spin dependent scattering which inturn modify the MR signal of the device. This modification helped in maintaining a non-monotonous quenching of MR signal with increase in temperature. We have also proposed a phenomenological model for device operation where the concept of charge gap modification at Fermi level across Verwey transition is envisaged to offer this unique scenario of tuning the conduction mode and hence MR in this ferrite based organic SV. The model is also supported by an established theoretical study which considers high temperature phonon assisted tunneling through defect states at electrode–organic interface of the device. • Conduction mechanism transition from carrier injection to multistep tunneling. • Transition due to Verwey transition of Fe 3 O 4 . • Spin flip scattering at Alq 3 spacer above Verwey transition temperature. • Non-monotonous MR quenching with temperature. • Room temperature MR signal of hybrid spin valve.

Suppression of the nuclear forward scattering signal in GdBaFe2O5 and PrBaFe2O5

Antiferromagnetic double-cell perovskites GdBaFe2O5.004 and PrBaFe2O5.001 were studied with 14.4 keV 57Fe nuclear forward scattering (NFS). Both have charge- and orbital-ordered iron below a Verwey transition temperature TV and valence-mixed iron above a second transition at a higher Tp. At intermediate temperatures TV<T<Tp, only a partial charge separation remains and more than 75% of the NFS signal is suppressed. The breakdown of the coherent signal is due to broadening of the nuclear resonance by local disorder of the two partially charge-separated iron species at the single crystallographic Fe site.

Large spin-dependent tunneling magnetoresistance in Fe3O4/PET heterostructures developed at room temperature: A promising candidate for flexible and wearable spintronics

Half-metallic nanocrystalline magnetite (Fe3O4) thin films, with different thicknesses were developed on polyethylene-terephthalate (PET) substrates, by reactive sputtering at room temperature. Fe3O4 film (200-nm thick)/PET heterostructures possess superior electrical and magnetic characteristics, with a Verwey transition temperature (Tv) of ~122 K and a saturation magnetization (Ms) ~ 361 emu/cm3. Furthermore, the antiferromagnetic (AFM)-coupled antiphase boundaries (APBs) controlled the transport properties of the Fe3O4 thin films, due to the tunneling of spin-polarized electrons through the films. Very-high magnetoresistance (MR) value (−8.9%) were observed for H‖Film plane, constructed from Fe3O4 (200-nm thick)/PET when H values were below 60 kOe at 300 K. In addition, flexibility tests, to examine resistivity, M-H and MR, were performed using with 90° and 45° bent angles and cyclability experiments were implemented to validate the reproducibility of these characteristics. These outcomes demonstrated that Fe3O4/PET heterostructures may represent a promising candidate for flexible/wearable spintronics.

Biomineralization and Magnetism of Uncultured Magnetotactic Coccus Strain THC‐1 With Non‐chained Magnetosomal Magnetite Nanoparticles

AbstractMagnetotactic bacteria (MTB) have long fascinated geologists and biologists because they biomineralize intracellular single domain (SD) magnetite crystals within magnetosomes that are generally organized into single or multiple chains. MTB remains in the geological record (magnetofossils) are ideal magnetic carriers and are used to reconstruct paleomagnetic and paleoenvironmental information. Here we studied the biomineralization and magnetic properties of magnetosomal magnetite produced by uncultured magnetotactic coccus strain THC‐1, isolated from the Tanghe River, China, by combining transmission electron microscope (TEM) and rock magnetic approaches. Our results reveal that THC‐1 produces hexagonal prismatic magnetite single crystals that are elongated along the [111] crystallographic direction. Most of the magnetite crystals within THC‐1 are dispersed without obvious chain assembly. A whole‐cell THC‐1 sample yields a normal SD hysteresis loop and a Verwey transition temperature of ~112 K. In contrast to MTB cells with magnetosome chain(s), THC‐1 cells have a teardrop first‐order reversal curve distribution that is indicative of moderate interparticle interactions. Due to the absence of a magnetosome chain, THC‐1 has relatively high values of the difference between the saturation isothermal remanent magnetization (SIRM) below and above the Verwey transition temperature for field‐cooled and zero field‐cooled SIRM curves (δFC, δZFC) and a low δFC/δZFC value. Together with previous studies, our results demonstrate that some MTB species/strains can form magnetosomal magnetite without linear chain configurations. Magnetite produced by MTB has diverse magnetic properties, which are distinctive but not necessarily unique compared to other magnetite types. Therefore, combining bulk magnetic measurements and TEM observations remains necessary for identifying magnetofossils in the geological record.

On the distribution of Verwey transition temperatures in natural magnetites

SUMMARYThe Verwey transition in magnetite is a crystallographic phase transition occurring in the temperature range 80–125 K and depends on stoichiometry and cation substitution, which may in turn serve as an indicator of the conditions under which magnetite was formed or altered in nature. We have analysed the distribution of Verwey transition temperatures (TV) in a large set of samples (N = 1110) from a wide variety of rocks, sediments, and other natural and synthetic materials containing magnetite, mined from the database of the Institute for Rock Magnetism and from published studies. The analysis is restricted to measurements of remanence while warming through the transition from which TV was determined by the derivative method. Our analysis showed that the TV distribution exhibited a generally bimodal distribution of Verwey transition temperatures, both for the entire data set and for almost all of the lithological subsets. There is a sharp peak for values in the range 118–120 K, and a broad, relatively flat or polymodal distribution from about 98 to 118 K. The upper end of the distribution was sharp, with only a few values exceeding 124 K, and the tail on the lower end extended down to about 80 K. Virtually all of the sample types exhibited polymodal distributions, almost always with one peak near 120 K, and with one or more additional peaks at lower temperatures. Biogenic magnetites produced by magnetotactic bacteria had the lowest modal value of TV (100 K). Loesses (103.5 K) and igneous extrusives (102.5 K) also had low modal transition temperatures and distributions with dominant low-TV peaks. Lithological groups with the highest modal transition temperatures were modern soils (119.5 K), silicate minerals with exsolved magnetite (119 K) and sedimentary rocks (119 K). Numerical experiments confirmed that the derivative method for the determination of TV was reasonably robust and that the observed distributions cannot be explained as an artefact related to the determination of TV from individual thermomagnetic runs but rather is a general characteristic of natural magnetites. The results provide context for studies that interpret TV in particular samples in terms of natural processes or conditions during formation or alteration of magnetite.

Unveiling the role of Fe3O4 in polymer spin valve near Verwey transition

The spinterface formed between ferromagnetic (FM) electrode and organic materials is vital for performance optimization in organic spin valve (OSV). Half-metallic Fe3O4 with drastic change in structure, conductivity and magnetic property near Verwey transition can serve as an intrinsic spinterface regulator. However, such modulating effect of Fe3O4 in OSV has not been comprehensively investigated, especially below the Verwey transition temperature (Tv). Here, we highlight the important role of Fe3O4 electrode in reliable-working and controllable Fe3O4/P3HT/Co polymer spin valves by investigating the magnetoresistance (MR) above and below Tv. In order to distinguish between different contributions to charge transport and related MR responses, the systematic electronic and magnetic characterizations were carried out in full temperature range. Particularly, the first-order metal-insulator transition in Fe3O4 has a dramatic effect on the MR enhancement of polymer spin valves at Tv. Moreover, both the conducting mode transformation and MR line shape modulation could be accomplished across Tv. This research renders unique scenario to multimodal storage by external thermodynamic parameters, and further reveals the importance of spin-dependent interfacial modification in polymer spin valves.

Ferromagnetic Resonance Study of the Verwey Phase Transition of Magnetite Thin Film on MgGa₂O₄(001) Substrate

We report on temperature-dependent broadband ferromagnetic resonance studies of magnetite (Fe <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</sub> ) film of thickness 30 nm grown on magnesium gallate [MgGa <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</sub> (001)] single crystal substrate by pulsed laser deposition. The isotropic point, i.e., the temperature at which magnetocrystalline anisotropy vanishes, is found to be approximately 120 K, which is 10 K lower than the bulk value. The Verwey transition is close to 110 K, again about 10 K lower than the bulk crystal value. Below the Verwey transition temperature, the uniaxial anisotropy of the monoclinic phase increases gradually and asymptotically approaches a constant value indicating a smooth structural transition rather than a sudden change. Resonance linewidth and effective damping increase abruptly below 110 K. The effective damping constant is determined to be ~0.01 and is independent of temperature from 300 K to 120 K.

Tuning the shape, size, phase composition and stoichiometry of iron oxide nanoparticles: The role of phosphate anions

This work describes a microwave synthetic approach for the controlled assembly of α-Fe2O3 nanosystems with defined morphologies, such as hollow nanotubes (NTs), solid nanorods (NRs) and nanodisks (NDs). The morphological control is aided during the crystallization processes by using phosphate anions as key surfactants in solution. Furthermore, the thermal reduction under H2 atmosphere of these NTs, NRs and NDs α-Fe2O3 systems to the correspondent Fe3O4 nanomaterials preserved their initial morphologies. It was observed that the concentration of phosphate anions and volume of solvent had significant impact not only on controlling the shapes and sizes, but also phase composition and stoichiometry of the NTs, NRs and NDs nanoparticles. X-ray Rietveld refinement analysis of the NTs, NRs and NDs systems, after reduction in H2, revealed the presence of zero-valent iron (Fe0) in the final materials, with Fe0 fractions that decreased gradually in % from NTs (∼16%), NRs (∼11%) to NDs (∼0%) upon increasing amount of phosphate anions. Bulk magnetic susceptibility measurements showed clear alterations of the Verwey transition temperatures (TV) and the development of unusual magnetic phenomena, such as magnetic vortex states in NDs, which was subsequently verified by micro-magnetic simulations. From the combination of XRD analysis, bulk magnetic susceptibility and Mössbauer results, we provide herein a detailed mechanistic description of the chemical processes that gated the development of shape-controlled synthesis of NTs, NRs and NDs and give a detailed correlation between specific morphology and magneto-electronic behaviors.

Humidity related magnetite alteration in an experimental setup

SUMMARY Low-temperature oxidation (LTO) of magnetite is an alteration process which occurs under normal atmospheric conditions, causing maghemitization. The use of magnetic properties as palaeoclimate proxies requires improved understanding of how humidity and temperature affect such processes. We exposed natural magnetite, with grain size ranging from &amp;lt;1 to ∼30 μm, to different humidity conditions at room temperature and 70 °C for 1 yr. Changes in room temperature setups were very minor, but in all 70 °C setups alteration was detected by magnetic and mineralogical properties. Lowering of the Verwey transition temperature (Tv) turned out to be the most sensitive indicator of LTO, and also lattice constants correlate well with the shift of Tv. Thermomagnetic curves and XRD-results indicate that LTO affects the entire volume of the particles rather than only surface layers. The sample exposed to high relative humidity (rH) &amp;gt;90 per cent at 70 °C showed the strongest degree of LTO with an increase of the oxidation degree by ∼3 per cent according to Tv, and it was the only setup where partial alteration to hematite was indicated by Mössbauer analysis. The sample with extremely dry conditions (rH of ∼5 per cent) at 70 °C, and the sample that was exposed to cycles of high and low humidity in 2-weeks alternation at 70 °C, both revealed a smaller degree of LTO. The smallest change of the high temperature setups was observed for the sample with intermediate rH of ∼13 per cent. The results suggest a non-linear sensitivity of magnetite alteration to humidity conditions, high humidity strongly favours alteration, but alteration is strongly reduced when extreme humidity alternates with dry conditions, suggesting an importance of seasonality in natural weathering.

Magnetic field induced structural changes in magnetite observed by resonant x-ray diffraction and Mössbauer spectroscopy

When a magnetic field is applied to a single crystal of magnetite at $124\phantom{\rule{0.16em}{0ex}}\mathrm{K}gTg50\phantom{\rule{0.16em}{0ex}}\mathrm{K}$, the monoclinic ${c}_{M}$ axis, which is the easy magnetization axis, switches to one of the ⟨100⟩ cubic directions, nearest to the direction of the magnetic field, and the phenomenon known as an axis switching (AS) occurs. A global symmetry probe, resonant x-ray scattering, and a local probe, M\ossbauer spectroscopy, are used to better understand the mechanism of axis switching. The behavior of three subsystems ordered below the Verwey transition temperature ${T}_{V}$, i.e., lattice distortion, an orbital, and charge orderings, was observed via resonant x-ray scattering as a function of an external magnetic field. This was preceded by calculation of selected peak intensities using the fdmnes code. The M\ossbauer spectroscopy studies confirmed that the magnetic field triggers electronic rearrangements and atomic displacements. The structure observed after the process of axis switching is very similar to the one obtained after cooling below ${T}_{V}$ with the magnetic field applied along one of the initial ⟨100⟩ cubic directions and distinct from the cooling in the absence of a magnetic field. From all the experimental observations of the phenomenon done so far, it is clear that AS starts from the fluctuations between octahedral iron orbitals that ultimately lead to the Verwey transition, but also to the higher-temperature trimeron dynamics. Therefore, further observation of the axis switching may be a key point to the understanding of a majority of strongly correlated electronic behavior in magnetite as well as in other transition metal oxides.

Magnetite thin films grown on different flexible polymer substrates at room temperature: Role of antiphase boundaries in electrical and magnetic properties

Currently, there is an enormous need for flexible electronic devices given their astonishing competencies. In this view, we investigated the structural, electrical, and magnetic characterstics of magnetite (Fe3O4) thin films with a thickness of 100 nm prepared using a reactive RF sputtering technique at 300 K on polycarbonate (PC), polymethyl methacrylate (PMMA), and polythene terephthalate (PET) flexible substrates. The structural properties showed that the films grown on PC, PMMA, and PET substrates exhibited the pure form of Fe3O4 nanostructures by flowing oxygen with a flow rate of 3.5 sccm. The Verwey transition temperatures (Tv) of ∼123 K, ∼124 K, and ∼126 K; saturation magnetization (Ms) values of ∼220 emu/cm3, ∼235 emu/cm3, and ∼261 emu/cm3; and magnetoresistance (MR) values of −7.1%, −7.3%, and −7.8% under the H∥Film plane below 60 kOe at 300 K for 100-nm-thick Fe3O4 film on PC, PMMA, and PET substrates respectively were observed. These remarkable results were interpreted and the effect of antiferromagnetically (AFM) coupled antiphase boundaries (APBs) was explained, which suggested that Fe3O4/PET heterostructure can be a most promising component for flexible spintronics.

Magnetic vortex formation in hollow Fe3O4 submicron particles studied using first-order reversal curves

We report results of first-order reversal curves (FORCs) measurements for hollow Fe3O4 submicron spherical particles, varying particle size from 400 to 700 nm. For all the samples, the FORC diagrams exhibit a butterfly-like feature of distribution peaks, being characteristic to the vortex formation. With increasing temperature from 10 K nucleation and annihilation fields of a vortex sharply increase and become almost constant above the Verwey transition temperature (Tv∼115 K). This reflects temperature-dependent magnetocrystalline anisotropy, associated with a structural transition at Tv. Above Tv the field range at which a vortex state is stable increases with increasing particle size, indicating that an increasing contribution of demagnetizing fields dominates a vortex stability for larger hollow particles.

Slow magnetic relaxation in well crystallized, monodispersed, octahedral and spherical magnetite nanoparticles

Thermally activated relaxation over energy barriers concurrently related to local properties and interparticle interactions constitutes a major contribution to both the coercivity and the applied field frequency dependence of that quantity. We have measured the slow magnetic relaxation of magnetite nanoparticles (NPs), synthetized by using the oxidative precipitation technique, having spherical and octahedral shapes, monodispersed size distributions and similar transverse dimensions. From our relaxation data we evaluated the temperature dependencies of a) the irreversible demagnetization susceptibility, b) the fluctuation field (associated to the thermally induced demagnetization occurring during the measuring time range) and c) the activation volume (corresponding to the demagnetization produced by the fluctuation field). We conclude that i) the irreversible susceptibility peaks in both samples at ca. 135 K (Verwey transition temperature) and ii) the monotonically increasing temperature variation of the activation volume shows the same values in both samples for temperatures below ca. 135 K and at 290 K reaches values corresponding to 10 and 30 times the average particle volume of the spherical and octahedral NPs, respectively. Those large increases of the activation volume are compatible with a transition from local to collective of the thermally activated processes.

Room temperature growth of half-metallic Fe3O4 thin films on polycarbonate by reactive sputtering: Heterostructures for flexible spintronics

Nowadays, there is a huge demand of bendable/stretchable electronic devices because of their remarkable capabilities. With such an aim and inclination towards flexible spintronics devices, half-metallic nanocrystalline Fe3O4 thin films with various thicknesses are grown on flexible polycarbonate (PC) substrates by reactive sputtering at room temperature. The structural analysis reveals that as the deposition time increases from ∼165 s to ∼1335 s, the thickness of the film also increases from 50 nm to 400 nm with the size of the grain from ∼12 nm to ∼32 nm, respectively. The X-ray photoelectron spectroscopy (XPS) shows that the films grown on PC substrates are the pure form of Fe3O4 nanostructures. The electrical and magnetic characteristics are studied to illustrate the furtherance of the original belongings of Fe3O4. The Verwey transition temperature (Tv) of ∼127 K, Ms value of ∼317 emu/cm3 and MR -8.3% under H ∥ Film plane below 60 kOe at 300 K for 200 nm thick Fe3O4 film on PC substrate were observed. Additionally, several bending experiments are executed to confirm the retention and adjustability of these properties for such heterostructures. These remarkable results show that Fe3O4/PC heterostructures can be a promising applicant for flexible spintronics.