Vein Mineralogy Research Articles

The Peña do Seo W-Sn deposit, NW Iberia: Petrology, fluid inclusions and O-H-S isotopes

The Peña do Seo W-Sn ore deposit in NW Iberia consists mainly of quartz veins hosted in schists. Vein mineralogy comprises wolframite, cassiterite and minor molybdenite. Peraluminous S-type granites and minor metaluminous granitoid breccias crop out in the same location. Whole rock geochemistry, mineral characterization, fluid inclusions and stable isotope geochemistry have been combined to infer hydrothermal mineralization conditions. A pre-ore stage (0) involving the alteration of host rocks, three stages of mineralization (I, II and III), and a supergene stage (IV) have been identified. Stage I (oxide-halide-sulfide stage) consisted of a cassiterite-pyrite-fluorite mineralization in granitoid breccias. Stage II (main oxide stage) involved wolframite-rich selvages and wolframite-cassiterite-(molybdenite) quartz veins. Stage III (main sulfide stage) consisted of a sulfide mineralization in quartz veins comprising pyrite and minor arsenopyrite and chalcopyrite. Three types of fluid inclusions were found in vein quartz: (1) aqueous two-phase inclusions, with homogenization temperatures (Th) between 445 °C and 280 °C and moderate salinities (9-14 wt.% NaCl eq.), (2) aqueous-carbonic three-phase fluid inclusions, with Th from 340 °C to 260 °C and low salinities (2-7 wt.% NaCl eq.), and (3) aqueous two-phase fluid inclusions, with Th from 270°C to 155 °C and low salinities (0-6 wt.% NaCl eq.). δ18O values in quartz from mineralized veins range from +11.2‰ to +13.4‰, and between +15.0‰ and +15.4% in quartz from mineralized granitoid breccias. δ34S values in sulfides (pyrite, arsenopyrite and chalcopyrite) range between +13.0 ‰ and +37.1 ‰, thus suggesting a marine source of sulfate and possible equilibration with host-rock sulfides. δD values in muscovite and chlorite from quartz veins range between -105.7 ‰ and -71.5 ‰ and between -69.4 ‰ and -67.1 ‰, respectively, indicating a transition from magmatic to magmatic-metamorphic conditions. An aqueous (H2O–NaCl) magmatic-hydrothermal fluid led to the W-Sn mineralization, as deduced from the studied fluid inclusions and isotopic signatures. High W and Sn contents in the peraluminous granites indicate that the W-Sn mineralization in Peña do Seo could partially be related to the granites and granitoid breccias. Whereas the Sn (± W) likely derived from hydrothermal fluids exsolving from the crystallizing magmas, host quartz schists would have supplied other elements required for wolframite deposition such as Fe and Mn. Sulfide mineralization in stage III was probably driven by fluid dilution.

Mineralogical and sample selection implications for geomechanical properties of intact heterogeneous and veined rocks from the Legacy skarn deposit

Abstract Predicting the geomechanical behaviour of rockmasses is key to the economic success and safety of rock engineering projects including surface and underground excavations. For these projects, unconfined compressive stress (UCS) laboratory testing provides fundamental geomechanical properties of intact rocks. It is currently standard practice for UCS testing to consider only homogeneous specimens that are free of defects and discard heterogeneous specimens such as those that contain intrablock structures (e.g. veins) or extra-granular defects (e.g. phenocrysts). Understanding the complexities of these heterogeneous rocks and rockmasses is critical for excavation projects such as deep cave mines where extensive tunnel networks, caves, and stopes are regularly excavated through heterogeneous rockmasses. This paper presents the test results and analyses of UCS tests conducted on 29 matrix-type and 21 veined drill core specimens from the Legacy Skarn deposit located in northern New Brunswick, Canada. These specimens are sorted into five lithological units: beige, red, and black varieties of quartz-plagioclase granodiorite, calcareous mudstone, and garnet-pyroxene skarn. Mineralogical compositions of these units are determined using field identification techniques and microscopic laboratory methods including petrographic thin section analysis, powdered X-Ray Diffraction, and micro-X-Ray Fluorescence. Significant effects of hydrothermal veining and phenocrysts on the UCS test results are discussed in this study to highlight the significant influence of mineralogy on the variability of geomechanical properties. For example, vein mineralogy dominated by calcite weakened the granodiorites but strengthened the calcareous mudstone. Vein mineralogy dominated by quartz in the skarn unit had a mixed influence on geomechanical properties. Vein thickness primarily influenced geomechanical properties of specimens with single veins, whereas vein density was more useful to characterize specimens that contained vein networks or stockwork. The effects of vein orientation only partially agree with the established Jaeger model for shear failure through critically oriented foliations. The disseminated alteration in the granodiorites (plagioclase phenocrysts) and skarn (garnet crystals) typically increased stiffness and strength as the large grains arrest crack propagation when under load. Lastly, the effects of sample selection on reported UCS test results using four sample selection methods are presented. The results demonstrate the importance of including heterogeneous veined specimens in UCS sample selection and testing programs to capture rock variability and improve the accuracy of numerical geomechanical design. Recommendations are made to improve geotechnical core logging and sample selection protocols when characterizing heterogeneous complex rockmasses.

Meta-rodingite dikes as recorders of subduction zone metamorphism and serpentinite dehydration: Voltri Ophiolite, Italy

The metamorphic devolatilization of serpentinites during subduction represents the largest potential source of fluids from the subducting slab and influences a range of important processes from subduction zone seismicity to arc magmatism. Obtaining a record of metamorphic dehydration directly from serpentinites, however, is challenging, as serpentinite mineral assemblages are less conducive to extracting a detailed pressure-temperature-time (P-T-t) history. In this study, we use meta-rodingites (metasomatized gabbros) from the central portion of the Voltri Ophiolite in the Ligurian Alps (Italy), to investigate the P-T and geochronological record of subduction metamorphism and dehydration within the adjacent serpentinites. These meta-rodingites underwent eclogite-facies metamorphic recrystallization to a garnet-clinopyroxene-chlorite-ilmenite assemblage, and are cross-cut by several generations of garnet-bearing veins. A comparison of the Voltri meta-rodingites with un-subducted seafloor rodingites from the Apennines reveals textural and geochemical evidence of complete metamorphic recrystallization of the original seafloor metasomatic assemblage during Alpine subduction. Phase equilibria modeling of the Voltri meta-rodingite sample suggests that the peak metamorphic assemblage recorded was stable in the range of ~450–600 °C, which is consistent with previous P-T estimates for gabbroic and ultramafic lithologies from the Voltri Ophiolite. A late prograde to peak metamorphic age of 40.6 ± 2.9 Ma was obtained from the meta-rodingite using SmNd garnet geochronology, which closely matches the ages of late prograde to peak metamorphism estimated by companion studies of associated eclogites from the central part of the Voltri Ophiolite. The overlap in P-T conditions and timing of peak metamorphism for samples across the area suggests subduction and exhumation of the central part of the Voltri Ophiolite as a coherent lithospheric slice. Dating of a garnetite vein cross-cutting the main meta-rodingite body suggests an influx of fluid at 37.7 ± 1.4 Ma, at or near peak eclogite-facies conditions. Enrichment in the vein selvage of both compatible transition metals (Cr, Ni, Cu) and fluid-mobile elements (Li, Rb, Cs, Ba) suggests the fluid carried both serpentinite and sedimentary geochemical signatures and interacted with the main meta-rodingite body. We suggest that the most probable explanation for this fluid composition, and thus the source of the fluid, is the dehydration of the Voltri serpentinites. These serpentinites likely experienced an influx of sedimentary-derived, fluid-mobile-element-bearing fluids earlier in their history, either on the seafloor or most likely during the early stages of subduction. The presence of a sedimentary signature in this serpentinite-derived fluid emphasizes the importance of subducted serpentinites and their dehydration to the geochemical cycling of fluid-mobile elements in subduction zones. The widespread development of such vein systems within multiple meta-rodingites across the Voltri Ophiolite points to a large-scale fluid release event, likely resulting from the partial dehydration of brucite and antigorite within the surrounding serpentinite hosts. By utilizing direct dating of vein mineralogy formed during serpentinite dehydration, we provide one of the first geochronological records of serpentinite dehydration and fluid release occurring during subduction.

Vein Mineralogy and Hydrothermal Gold Mineralization at the Kyaw Soe Thu Prospect in the Wabo Deposit, Mandalay Region, Central Myanmar

The Kyaw Soe Thu Prospect is a part of the Wabo deposit which is situated along Mogok Metamorphic Belt (MMB) in Central Myanmar. Gold bearing veins are hosted in the banded garnet-biotite gneiss, calc-silicate, marble and granitoid of the Wabo area. The granitic rocks intruded into banded garnet-biotite gneiss. The MMB was intensely deformed and it is a highly fractured metamorphic terrain in which metamorphic facies ranges from amphibolite to granulite facies. Gold mineralization at the Kyaw Soe Thu Prospect in the Wabo deposit occurred in the forms of gold-quartz veins. The quartz veins are a few centimeters in width. The color of the quartz vein at the Kyaw Soe Thu Prospect is commonly smoky and milky. The quartz vein exhibits chalcedonic, saccharoidal and granular textures. Three mineralizations were indicated. Stage I is the thin layered crustiform chalcedonic quartz. Stage II is chalcedonic quartz vein and stage III is Ankerite-quartz-sericite vein. Stage II and stage III are gold rich hydrothermal stages, and Ankerite-quartz-sericite veins were formed with a small amount of sericites in the Kyaw Soe Thu Prospect. The Ankerite-quartz-sericite veinlets range from a centimeter up to three centimeter in width within the stage II chalcedonic quartz vein. Textures of mineralized quartz vein samples were petrographically examined. The textures include a feathery texture that is most closely associated with electrum in both stage II chalcedonic quartz veins and stage III Ankerite-quartz-sericite veins. Ankerite varies in color from pink, white to buff. Among them, pink color is more common in the Kyaw Soe Thu Prospect. Ankerite in the Kyaw Soe Thu Prospect exhibits rhombohedral idiomorphic, which exhibits growth patterns. Ore minerals of the veins are electrum, pyrite, galena, and trace amount of very fine-grained chalcopyrite. On the basis of textures of the chalcedonic quartz veins, the Kyaw Soe Thu Prospect is ascribed to be a low-sulfidation epithermal deposit.

Twenty million years of post-orogenic fluid production and hydrothermal mineralization across the external Araçuaí orogen and adjacent São Francisco craton, SE Brazil

The Araçuaí orogen (AO) is a hot orogenic system that is known for its widespread and long-lived magmatism (630–480 Ma). Within the last c. 20 million years of its evolution, the AO saw the widespread development of hydrothermal systems in its lower-grade external fold-and-thrust belt and its Foreland Domain (eastern margin of the adjoining São Francisco craton). UPb crystallization ages for hydrothermal monazite, rutile, and xenotime indicate that fluid circulation along the entire AO occurred between 515 to ca. 495 Ma, largely overlapping with UPb ages of hydrothermal systems and mineralized zones in the adjacent São Francisco craton. Titanium-in-quartz thermometry suggests that most hydrothermal systems closed at temperatures of ca. 360 °C. The SmNd isotope composition of the vein monazite samples ranges from εNd500Ma −16.8 to −17.8, and one less-evolved sample with εNd500Ma of −5.9. The SmNd isotope compositions overlap with the bulk rock SmNd data for the Espinhaço Supergroup, suggesting that the hydrothermal veins in this study are mainly related to metamorphic fluids derived from the prograde dehydration of low-grade metasedimentary rocks. The UPb ages, SmNd isotope composition, and vein mineralogy are all consistent with a 20 My period of channelized fluid flow, characterized by an oxidizing, low pH, REE-, P-, and Ti-bearing aqueous metamorphic fluid. The expression of supercritical fluid flow in the core of the AO is given by the emplacement of large volumes of bare/mineralized pegmatite bodies and regional resetting of monazite ages in host rocks. On a regional context, this widespread fluid flow is associated with a high-T, low-P metamorphism that marks the beginning of the post-collisional decompression of the orogeny, which is associated with lithospheric mantle delamination. The reorganization of mass and heat, due to extensional collapse, resulted in multi-sourced fluid production and mineralization from deep to shallow crustal levels that affected an area of over 400.000 km2 along the eastern border of the São Francisco Craton.

Late-stage anhydrite-gypsum-siderite-dolomite-calcite assemblages record the transition from a deep to a shallow hydrothermal system in the Schwarzwald mining district, SW Germany

The majority of hydrothermal vein systems of economic interest occur at relatively shallow crustal levels, although many of them formed at significantly greater depths. Their present position is a consequence of uplift and erosion. Although, many aspects of their formation are well constrained, the temporal chemical evolution of such systems during uplift and erosion is still poorly understood. These vein minerals comprise calcite, dolomite-ankerite, siderite-magnesite, anhydrite and gypsum forming the last gangue assemblages in Jurassic and Tertiary sulphide-fluorite-quartz-barite veins of the Schwarzwald mining district, SW Germany. Mineral textures of samples from nine localities reveal that in these sequences, mineral precipitation follows a recurring pattern: early calcite is followed by anhydrite or gypsum, siderite and/or dolomite. This succession may repeat up to three times.In-situ (LA-ICP-MS) U-Pb age dating of 15 carbonates from three subsequent generations of the late-stage vein assemblage yield robust ages between 20 and 0.6 Ma. Each mineral sequence forms in a distinctive period of about 2–5 Ma. These ages clearly relate these late-stage mineral phases to the youngest geological episode of the Schwarzwald, which is associated with the Cenozoic Rhine Graben rifting and basement uplift.Based on thermodynamic modelling, the formation of the observed mineral assemblages required an deeply sourced Mg-, Fe- and SO4-rich fluid (b), which was episodically mixed with a shallow crustal HCO3-rich fluid (a). As a consequence of fluid mixing, concentrations of Mg, Fe and SO4 temporarily increased and initiated the formation of the observed sulphate-carbonate mineral sequences.This discontinuous large-scale vertical fluid mixing was presumably directly related to episodes of active tectonics associated with the Cenozoic strike-slip regime of the Upper Rhine Graben. Analogously, episodic fluid mixing is a major key in the formation of older (Jurassic to early Tertiary) Pb-Zn-fluorite-quartz-barite assemblages in the same specific vein systems, albeit involving different fluid compositions.Late-stage hydrothermal (∼20–70 °C) vein assemblages reported in this study record the transition from deep (>2 km) to very shallow (0–1 km) crustal conditions. As a consequence of successive uplift, increasing proportions of shallower and cooler (∼50–70 °C) fluids could take part in such mixing processes. Associated changes in the fluid composition caused the vein mineralogy to change from sulphide-quartz-fluorite-barite to calcite-anhydrite/gypsum-siderite-dolomite, as the system passively ascended closer to the surface.

Quantifying the effects of vein mineralogy, thickness, and orientation on the strength of intact veined rock

The presence of veins in the rock matrix influences the behaviour of a rock. This results in a behaviour that is distinct from intact rock without any veins and structure and from jointed rock. In this context, intact veined rock is a rock containing mineral veins and no joints. This paper investigates the influence of vein mineralogy, thickness, and orientation on the strength of intact veined andesite from the El Teniente mine. This investigation has focused on a comprehensive vein characterization and analyses of the results of triaxial compression experiments.In a comprehensive laboratory investigation, it was demonstrated that the peak strength of intact veined rock specimens was strongly influenced by the orientations of individual veins, whereby vein mineralogy and thickness had a lesser role. A further analysis of the mineral composition of the intact veined rock specimens following a series of triaxial tests revealed a more dominant influence of the mineral composition of the veins. It was shown that rock specimens dominated by veins containing <30% of hard minerals, i.e. minerals with Moh's hardness>4, attained significantly lower peak strengths than specimens where the average content of hard minerals exceeded 60% of the vein infill. Analyses of the mobilised shear strength of individual veins demonstrated a strong correlation between the presence of hard minerals and the strength of individual veins in the rock specimens. This relationship was stronger when the vein volumetric content of hard minerals was <40–50%. For veins, in which the hard mineral content exceeded the 40–50% threshold, the estimated strength values were influenced by mineral content to a lesser degree.

Characterization of Gold Mineralization in the Northern Cariboo Gold District, British Columbia, Canada, Through Integration of Compositional Studies of Lode and Detrital Gold with Historical Placer Production: A Template for Evaluation of Orogenic Gold Districts

There is a strong association between regions containing orogenic gold mineralization and exploitation of placer gold, although, in many cases, the nature of the source mineralization for these placer deposits remains unclear. This study describes a novel approach to evaluating the economic potential of in situ orogenic gold mineralization through characterization of both lode and placer gold mineralogy, followed by synthesis of this information with records of both mineral occurrences and historical placer mining. The northern Cariboo Gold District in east-central British Columbia, Canada, was chosen as a location for the study because of the gold endowment of the area (1.2 million ounces [Moz] of lode gold and between 0.5 and 3 Moz. of placer gold) and the information available from both placer and lode gold mining. Compositional analysis of 533 gold grains from 21 lode localities and 1,914 gold grains from 30 placer localities from throughout the Cariboo Gold District has identified four main compositional types in terms of their alloy compositions and associated suite of mineral inclusions revealed in polished section. A distinctive low (4–7%)-Ag gold that exhibits a strong Bi association in the mineral inclusion suite is geographically limited to the Wells area, where it is recorded in both lode mineralization and its placer expression. Regionally pervasive mineralization yields gold of binary Au-Ag alloy and a simple inclusion suite of sulfides and sulfarsenides. Gold in most large placers in trunk drainages was derived from multiple (mostly small) occurrences of this type. The nature of compositional variation between gold grains liberated from hypogene ore has informed the history of episodic mineralization and suggests multiple stages of gold emplacement at some localities, while others are dominated by gold deposited in a single stage. The new information from gold grain analysis has been considered in the context of other information. Classification of a placer as either allocthonous or autocthonous both informs interpretation of compositional characteristics of the detrital gold grains and provides information on distance to the hypogene source. Mineral inclusion assemblages observed in sample populations of placer gold grains have been correlated with reports of hypogene vein mineralogy described in mineral occurrence records to clarify the geographical extent of specific mineralization types. The compositional range of alloys of different gold types has been compared to historical records of gold production and gold fineness (Au-Ag ratio) to reconstruct the size and distribution of hypogene sources prior to erosion. Synthesis of gold compositional studies with other publicly accessible data sets provides a new generic approach capable of evaluating the most attractive targets for future exploration and highlighting compositional signatures of placer gold which relate to undiscovered in situ sources.

Tracing fluid migration pathways in the root zone below unconformity-related hydrothermal veins: Insights from trace element systematics of individual fluid inclusions

The temporal evolution of fracture networks below hydrothermal veins (root zones) and their impact on fluid chemistry, vein mineralogy and ore formation is insufficiently understood for unconformity-related hydrothermal veins in regions of extension, such as the common epithermal sediment-, unconformity- and basement-hosted Pb–Zn deposits. As metals and other trace elements are presumably mobilized during water–rock interaction of highly saline brines with igneous and metamorphic basement rocks, the evolution of these fracture zones seems to play a major role for hydrothermal ore formation. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICPMS) microanalysis of individual, texturally well-characterized fluid inclusions, hosted in fluorite and quartz of the Jurassic–Cretaceous Brandenberg fluorite–barite–quartz–galena–sphalerite vein near Todtnau, Schwarzwald, SW Germany, was carried out. Fluid mobile elements (Rb, Cs, Li, W, Ba, Zn, Pb, Sr), preferentially released by the alteration of primary rock-forming minerals (process tracer) were analysed as well as the Cl/Br ratio (source tracer) of fluid inclusions in genetically early fluorite and later quartz. A distinct decrease of trace elements within the fluid inclusions with time indicates successive alteration of primary minerals at the fracture wall to clay minerals with consecutive fluid pulses. A maximum concentration of trace elements in the fluid and consequent ore precipitation is associated with the initial phase of formation of a fracture root. Later fluid pulses migrate along pre-existing fractures so that the amount of fresh reactive rock material decreases with each fluid pulse. As a consequence, multiple generations of ore minerals require the formation of new fracture branches in the root zone of hydrothermal veins. Therefore, it seems that cataclastic zones below hydrothermal veins essentially control ore formation, and their tectonically induced dynamics might be one key parameter that governs the temporal interval of ore precipitation.

Multiple Gold Mineralizing Styles in the Northern Pataz District, Peru

Gold production from the northern Pataz district in the eastern Andean Cordillera of Peru has been sourced mainly from mesothermal quartz-carbonate-sulfide veins hosted by the Mississippian Pataz batholith. Gold is also found in basement-hosted veins underlying the batholith, in the Vijus-Santa Filomena area of the district. Both are located within a central horst; similar vein mineralogy and proximal phengitic white mica alteration are common to both. However, comb-textured quartz, the chemical compositions of bulk ore and sulfide minerals, and the presence of barite and siderite veins suggest that the basement-hosted veins formed at a shallower crustal level. Similar expressions of hydrothermal alteration associated with anomalous gold, As, Sb, and Tl are also present in the adjacent Lavasen graben, where alteration is intimately associated with volcanic processes that deposited the Mississippian Lavasen Volcanics. K-Ar and 40 Ar- 39 Ar ages for hydrothermal illite from all three locations range between Mississippian and Late Triassic but are consistent with a single Mississippian hydrothermal event, if the data record a minimum age for original illite formation. The geologic setting, mineralization styles, and chemical data suggest a range of crustal depths, ranging from mesothermal batholith-hosted veins through shallow to intermediate depths for the Vijus-Santa Filomena area to a near-surface epithermal setting for the Misquichilca area. Telescoping of this 10- to 13-km crustal range into a 3-km topographic section of the Andes is attributed to syn- and postmineralization uplift and erosion. Sulfide-rich high-grade ore shoots and moderately saline fluid inclusions in the batholith-hosted veins are inconsistent with the original orogenic gold model and suggest a magmatic source component for the ore fluid, consistent with stable isotope (O, H, C, and S) compositions of quartz, illite, carbonates, and sulfides. The isotopic data suggest a mixed magmatic-meteoric ore fluid in the basement-hosted deposits of the Vijus-Santa Filomena area and the volcanic-hosted Misquichilca area. Both the Pataz batholith and the Esperanza Subvolcanic Complex are of the same Mississippian age as the hydrothermal alteration and mineralization. The Esperanza Subvolcanic Complex, comagmatic with the Lavasen Volcanics, contains cognate mineral clots from which a subjacent magma chamber can be inferred. It exhibits potassic, calc-silicate, and argillic alteration, and evidence for the evolution of an Fe-rich volatile phase. The Lavasen-Esperanza magma suite is ferroan and weakly alkaline, with A-type affinities. These features provide a conceptual genetic link with hydrothermal alteration associated with gold mineralization, including Fe (±As) sulfides, phengitic white mica, celadonite, Fe-rich carbonates, and less common Fe oxides. An oxidized intrusion-related model is proposed for gold and hydrothermal alteration in the northern Pataz district.

Geomechanical characterization of Newberry Tuff

In this paper we present the results of a petrophysical and geomechanical characterization program focusing on the rock mechanical properties of welded tuffs from Newberry volcano, Oregon. The rock samples are from drill cores obtained from three wells in the vicinity of the Newberry EGS namely, GEO N-2, GEO N-1, and OXY 72–3. As part of the rock characterization process, petrographic thin sections were prepared and used to describe rock texture and mineralogy. High resolution X-ray CT scanner was also used to provide 3D images of the rock pore structure. Rock porosity and permeability were measured using the gas expansion method and a pulse permeameter, respectively. Triaxial compression tests were performed on the specimens extracted from whole core to determine their Young's modulus, Poisson's ratio, and failure envelopes. In particular, multistage triaxial compression tests were carried out to determine deformation and failure properties, and to establish relationships between petrophysical and mechanical/failure properties. In addition, multistage triaxial shear tests were performed to determine the mechanical properties and shear strengths of the fractures developed in triaxial compression tests. Joint roughness coefficient (JRC) and Joint Wall Compressive Strength (JCS) were obtained through analysis of the shear tests. Joint normal stiffness and shear stiffness were also estimated and it was observed that a higher confining pressure results in higher joint shear stiffness. These studies provide insight into the effects of mineralogy and texture and structure on the strength and deformation properties of the tuff samples tested. Mineral composition and the presence of phenocrysts, argillitic materials, and natural fracture were noted to impact rock mechanical properties. Natural fracture and vein mineralogy also influence fracture development in the samples as well as frictional and shear strength properties of the joints tested. Rock samples with higher clay mineral content were found to be relatively more ductile with minimal increase, or even decrease, in permeability under failure in compression tests. The data set obtained in this study is very useful for stimulation design and interpretation of observed micro-seismicity in relation to permeability enhancement.

Mineralogy, fluid inclusion and stable isotope constraints on the genesis of the Namseong Au-Ag deposit, Republic of Korea

The Namseong gold and silver deposit is located in the Seolcheon metallogenic province, one of the most important gold production areas in the Republic of Korea. It consists of three gold and silver-bearing quartz veins that fill fractures oriented NW along fault zones in Triassic porphyritic granite. The gold and silver-bearing quartz veins are simple and consist of only one mineralization stage on basis of vein mineralogy and paragenesis. Coarse-grained quartz is found in mainly comb, and partially cockade and cavity-filling textures throughout most of the veins. Wall-rock alteration minerals include sericite, minor pyrite and chlorite. Ore minerals deposited along with electrum include pyrite, sphalerite, chalcopyrite, galena, pyrargyrite, argentite and native silver. Its mineralization age (78.2 ± 1.7 Ma) determined on sericite from wall-rock alteration indicates that the gold and silver mineralization was synchronous with Cretaceous igneous activity. Petrographic examination of textural relationships among sulfides, fluid inclusions, and quartz from one stage shows the genetic relationships between Au–Ag deposition and fluid entrapment. Early wall-rock alteration in one stage was produced and sulfides were deposited from H 2 O–NaCl–CO2 fluids (260–1,700 bar, average 1,000 bar) with Th total values of 250°C to 380°C and salinities less than about 4 wt.% NaCl. The late sulfides and electrum in one stage were deposited from H 2 O–NaCl fluids (100 bar) with Th total values of 195°C to 331°C and salinities less than about 7 wt.% NaCl. The H 2 O–NaCl fluids either evolved through unmixing of H 2 O–NaCl–CO 2 fluids or through mixing with circulating meteoric waters as a result of uplift or unloading during mineralization, or both. The deposition of electrum and silver minerals was caused by a decrease in sulfur fugacity/aH 2 S/aCl, oxygen fugacity and temperature during wallrock alteration, cooling and dilution produced by mixing of the saline aqueous fluids with meteoric water. The calculated sulfur isotope compositions of hydrothermal fluids from the Namseong deposit (δ 34 S H2S = 3.7‰ to 7.2‰) indicate that ore sulfur was derived mainly from a magmatic source but also in part from sulfur contained in the host rocks. The calculated and measured oxygen and hydrogen isotope compositions of the ore-forming fluids (δ 18 O H2O = –2.2‰ to 1.6‰, δD = –83‰ to –64‰) indicate that the fluids were derived from meteoric water and evolved by mixing with local meteoric water and by limited water-rock exchange during mineralization in uplift zones.

Structural genesis of the Eunsan and Moisan low-sulphidation epithermal Au–Ag deposits, Seongsan district, Southwest Korea

The Seongsan district in the Jindo–Haenam basin of southwest Korea comprises Precambrian gneissic basement, overlain and intruded by Cretaceous volcanic (98–71 Ma) and plutonic (86–68 Ma) rocks, respectively. Haenam Formation volcanic and volcaniclastic rocks are the dominant rock type exposed in the district and are the main host to high-sulphidation (82–77 Ma) and low-sulphidation (79–73 Ma) epithermal deposits. The Eunsan and Moisan low-sulphidation epithermal deposits have similar vein mineralogy, zoned hydrothermal alteration mineral assemblages, structural framework and interpreted deformation events. These similarities suggest that they formed by district-scale hydrothermal fluid flow at about 77.5 Ma. At this time, ore fluid movement along subvertical WNW-trending faults was particularly focussed in dilatant fault bends, jogs, and at intersections with N-trending splays. At Eunsan, Au–Ag ore shoots coincide with these areas of structural complexity, whereas at Moisan, narrower ore zones correspond with several parallel, poorly connected veins. A secondary control on the location of ore zones is the intersection between mineralised WNW-striking structures and rocks of the Haenam Formation. The higher permeability and porosity of these rocks, in comparison with mudstones and siltstones of the underlying Uhangri Formation, resulted in the more efficient lateral migration of ore fluids away from subvertical faults and into wall rocks. The intersection between subvertical WNW-striking faults and the gently dipping Haenam Formation imparts a low angle SW plunge to both ore bodies. WNW-striking post-mineralisation faults displace ore zones up to 100 m and complicate the along-strike exploration and mining of WNW-trending ore zones. Future exploration strategies in the district involve the systematic testing of WNW-trending mineralised structures along strike from known deposits, with a particular emphasis on identifying structurally complex areas that experienced local dilation during the mineralisation event. Poorly exposed regions have historically been under-explored. However, based on the proposed exploration model for the Eunsan and Moisan deposits, these areas of poor outcrop are now considered important target areas for hidden ore bodies using ground-based geophysical exploration tools, such as seismic surveys.

Post-Variscan hydrothermal vein mineralization, Taunus, Rhenish Massif (Germany): Constraints from stable and radiogenic isotope data

Post-Variscan hydrothermal base-metal mineralization of the Taunus ore district, SE Rhenish Massif (Germany), has been studied through combination of stable (S, C, O) and radiogenic (Pb) isotope geochemistry. Based on field and textural observations, five hydrothermal mineralization types can be distinguished. These are (1) tetrahedrite–tennantite bearing quartz–ankerite veins, (2) quartz veins with Pb–Zn–Cu ores, (3) giant quartz veins, (4) metasomatic dolomite in Devonian reef complexes, and (5) calcite–(quartz) mineralization in Devonian reefs. The δ18OV-SMOW quartz values of base-metal veins are in the range of 18.0–21.5‰, whereas those of giant quartz veins have lower values of 15.9–18.6‰. This difference reflects the higher fluid fluxes and smaller extent of rock-buffering for the giant quartz veins. Hydrothermal carbonates from the tetrahedrite and Pb–Zn–Cu veins have variable but distinctly negative δ13CV-PDB values. They can be explained by contributions from fluids that had picked up low δ13CV-PDB carbon via oxidation of organic matter and from fluids that interacted with Devonian reef carbonate having positive δ13CV-PDB. Metasomatic dolomite has positive δ13CV-PDB values that closely reflect those of the precursor limestone. By contrast, carbonates of calcite–(quartz) mineralization have negative δ13CV-PDB values which are negatively correlated with the δ18O values. This pattern is explained by fluid mixing processes where contributions from descending cooler fluids with rather low salinity were dominant. The isotope data suggest that tetrahedrite veins, Pb–Zn–Cu veins, and giant quartz veins formed from fluid mixing involving two end-members with contrasting chemical features. This is supported by fluid inclusion data (Adeyemi, 1982) that show repeated alternation between two different types of fluid inclusions, which are hotter intermediate- to high-salinity NaCl–CaCl2 fluids and cooler low-salinity NaCl-dominated fluids. The metal-rich saline fluids were likely generated at the boundary between the pre-Devonian basement and the overlying Devonian–Carboniferous nappe pile. Fault activation resulted in strong fluid focusing and upward migration of large volumes of hot Na–Ca brines, which mixed with cooler and more dilute fluids at shallower crustal levels. Variable contributions from both fluid types, local fluid fluxes, temperature variations, and variations in pH and oxidation state have then controlled the vein mineralogy and metal inventory.

Geochemical indicators of gold-rich zones in the La Josefina epithermal deposit, Deseado Massif, Argentina

The gold deposit at La Josefina, in the Deseado Massif of Argentina, is a low-sulfidation epithermal deposit with some features of the intermediate sulfidation style; the Au occurs in quartz veins and hydrothermal breccias hosted by acid pyroclastic rocks produced by Jurassic bimodal volcanism. Exploration for this deposit type uses geochemical data for vectoring to mineralized rocks. Although a general suite of elements with anomalous concentrations around low-sulfidation deposits is known, that suite varies amongst individual deposits, which should be studied individually. The aim of this study was to determine, in the La Josefina deposit, geochemical indicators of Au-rich rocks at different scales and to assess the effects of weathering on those indicators. To reach these objectives, a mineralized zone (hosting Au-rich veins) and a non-mineralized zone (hosting barren veins) were compared in terms of vein mineralogy, alteration minerals and geochemistry. These zones were also compared with estimated element concentrations of the protolith. Element concentrations in the mineralized zone were then plotted against distance to the Au-rich veins, separating the dataset into two subsets: one from strongly oxidized rocks and the other from weakly oxidized rocks, considering the degree of oxidation as indicative of relative degree of weathering. Based on alteration and vein mineralogy, we interpret that the mineralized zone was hydrothermally active before, during and after Au-mineralization, while the non-mineralized zone was active only before Au-mineralization. Therefore, differences in element concentrations between the estimated protolith and the non-mineralized zone represent geochemical changes produced before mineralization, whereas differences between mineralized and non-mineralized zones represent changes produced during and after mineralization. We conclude that in rhyolitic to rhyodacitic pyroclastic rocks of the study area, affected by predominantly argillic and silicic hydrothermal alterations, high concentrations of Au, Cu, Hg, V, Co and P, and low concentrations of Ba are probably the best deposit-scale geochemical indicators to distinguish Au-mineralized zones from non-mineralized zones. High concentrations of As, Mn, Fe, Pb, Cr, Ni, MgO and Zn (as well as high values of chlorite-carbonate-pyrite index), and low concentrations of Be and CaO can also distinguish mineralized from non-mineralized zones. High concentrations of Au, Cu, Pb, As, Hg, and Co indicate Au-rich zones, independently of lithology and alteration, because they were introduced into the veins and host rocks together with Au. At detailed-scale, the concentrations of 15 elements vary with distance to Au-rich veins; therefore, those elements are considered potential indicators of proximity to Au-rich veins. Of those elements, Au, P, Cu, Pb, Hg, Ba and MgO are the strongest indicators of proximity to the Au-rich veins. In strongly oxidized rocks, some indicators of mineralized zones (Co, Mn, Pb, Zn and MgO) and some indicators of proximity to Au-rich veins (P, Au, Cu, Hg and Ba) should be used with caution or be avoided because weathering modifies their quality as indicators.

Mineral Chemistry and In Situ Dating of Allanite, and Geochemistry of Its Host Rocks in the Bagjata Uranium Mine, Singhbhum Shear Zone, India--Implications for the Chemical Evolution of REE Mineralization and Mobilization

The present study combines textures, compositions, and in situ dating of allanite and whole-rock geochemistry from the Bagjata uranium deposit in the Singhbhum shear zone, the most important uranium-producing belt in India, to investigate the chemical evolution of rare earth element (REE) mineralization. Allanite, volumetrically the most important sink of light rare earth elements (LREEs) in this deposit, occurs as disseminated grains, pockets, veins, and stringers in biotite schist and chlorite schist. Metasomatic addition of LREEs in the rock was associated with Ca-K-Fe ± B metasomatism, as evident from the vein mineralogy. The allanite-bearing metasomatized rocks are locally extremely enriched in REEs, reaching up to ~4.8 wt percent ∑REEs. The textures and compositions of allanite demonstrate that early REE-rich allanite was replaced by later, relatively less REE bearing allanite-epidote, and this alteration followed a substitution scheme of REE +3 + (Fe +2 , Mg +2 ) → Ca +2 + (Al, Fe +3 ). The presence of halite-bearing fluid inclusions in associated tourmaline, high Cl content of biotite, and other circumstantial evidence indicate that a high-salinity, Cl-rich fluid was likely responsible for initial LREE metasomatism. A later hydrothermal event altered preexisting allanite and removed REEs. The more oxidized nature of altered allanite and the presence of unidentified secondary REE minerals in association with sulfide might indicate the involvement of oxidized, sulfate-rich fluid in the alteration of allanite and the removal of REEs. Alternatively, fluoride complexing of REEs and selective removal of HREEs during this alteration are possible. In situ laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb dating of allanite and monazite indicates that LREE metasomatism took place at ~1.88 Ga. The next hydrothermal event, which altered existing allanite, removed some REEs, and perhaps was associated with U (+HREE) addition, is dated at ~1.66 Ga. The youngest age determined from the thin rim of allanite is ~1.02 Ga. These three different ages, determined from allanite, overlap with the known thermotectonic events in and around the Singhbhum shear zone. Comparison between the calculated ∑REE content of allanite-rich rock prior to allanite alteration and whole-rock ∑REE composition of the same rock suggests that the addition of a large quantity of REEs was followed by significant REE removal. Strong variations in the modal abundances of the constituent minerals and in whole-rock compositions, including REEs, indicate open-system behavior. The whole-rock REE pattern suggests that decoupling between LREEs and HREEs might be possible during superimposed alteration. Therefore, petrogenetic modeling using an REE-based discrimination diagram and REE patterns should be done with caution for rocks that underwent multiple events of hydrothermal fluid flux.

Epithermal gold mineralization at Wadi Abu Khushayba, southwestern Jordan

The Wadi Abu Khushayba area in southwestern Jordan hosts an auriferous, quartz-veined shear zone with features of an epithermal low-sulfidation gold system. The quartz-lode and quartz-carbonate mineralization is characterized by open-space textures, typically with sharp-walled veins and multi-stage brecciation of the late Neoproterozoic (~ 560 Ma) rhyolitic and granophyric host rocks. Silicic alteration by cryptocrystalline quartz is abundant; potassic alteration is expressed by muscovite and K-feldspar blastesis, commonly with dispersed hematite laths. Sulfide content is low. Relict pyrite and chalcopyrite occur in comb and cockade quartz. Gold occurs disseminated in the volcanic and subvolcanic wall rocks and as late vein infill. The coexistence of vapor-rich and liquid-rich fluid inclusions in quartz, quartz textures, and the presence of adularia and calcite in the vein mineralogy suggest boiling concomitant with gold deposition in a structural setting favoring high fluid flow. Fluid inclusions in quartz define a temperature range of 350–380 °C and low salinity (~ 1.5–7 wt.% NaC1 equiv.) for the ore system. Pressure is estimated at 200–250 bars, indicating a maximum paleo-depth of 2500 m (hydrostatic). It appears likely that the Wadi Abu Khushayba system represents the near-surface epithermal expression of a larger unexposed mesothermal system. Such mesothermal systems are typical elsewhere in the Arabian–Nubian Shield, but are not exposed in southwestern Jordan where the present-day erosional level is close to the unconformity of the transgressive Early Cambrian platform sedimentation.

Potassic and ultrapotassic magmatism in the circum-Tyrrhenian region: Significance of carbonated pelitic vs. pelitic sediment recycling at destructive plate margins

The central-western Mediterranean is one of the most important areas on Earth for studying subduction-related potassic and ultrapotassic magmatism. In the circum-Tyrrhenian area leucite-free (i.e., lamproite) and leucite-bearing (i.e., kamafugite, leucitite, and plagioleucitite) ultrapotassic rocks have been emplaced and are associated with shoshonites and high-K calc-alkaline volcanic rocks. Four different magmatic provinces are recognised from this area. Eastward and then south-eastward migration of magmatism with time occurred following roll-back of the subducting plate. Leucite-free silica-rich lamproites are restricted to the early stages of magmatism, associated with shoshonites and high-K calc-alkaline volcanic rocks. Present day volcanic activity is restricted to the Neapolitan district where ultrapotassic rocks with variable geochemical and isotopic characteristics occur. Ultrapotassic rocks are strongly enriched in incompatible trace elements with variable fractionation of Ta, Nb, and Ti with respect to Th and large ion lithophile elements. Mafic ultrapotassic rocks are also variably enriched in radiogenic Sr and Pb and unradiogenic Nd. The main geochemical and isotopic signatures result from sediment recycling within the upper mantle via subduction. Selected trace element ratios suggest that high temperatures are required to generate sediment-derived melts. Recycling of carbonated pelites play an important role in the Roman province controlling the genesis of leucite-bearing magmas. Large volumes of metasomatic components are predicted to be accommodated within a vein network in the sub-continental lithospheric mantle. Partial melting of the pure vein mineralogy is likely to generate ultrapotassic magmas of either lamproitic or kamafugitic nature. Over time, increased interaction between the metasomatic vein lithology and the surrounding mantle dilutes the alkaline component producing shoshonites and high-K calc–alkaline rocks. The addition of a further subduction-related component shortly before magma generation is required to explain the isotopic composition of rocks from the Neapolitan district. In the last phases of circum-Tyrrhenian evolution, a within-plate component appears within south-eastern Italy. This component is evident at Vulture volcano, in the Lucanian Magmatic province (SE Italy).

Gold-Bearing Mesothermal Veins from the Gubong Mine, Cheongyang Gold District, Republic of Korea: Fluid Inclusion and Stable Isotope Studies

The Gubong deposit consists of five massive, gold-bearing mesothermal quartz veins that fill fractures oriented northeast and northwest along fault shear zones over an area of 14 km2 in Precambrian metasedimentary rocks of the Gyeonggi massif. The veins are divided into three groups, based on their orientation and location. They have a ribbon texture that is interpreted to result from repeated hydraulic fracturing events. Mineral deposition was associated with hydrothermal fluid overpressuring within and below the active fault shear zones. The vein mineralogy and paragenesis of the veins allow two separate discrete mineralization episodes to be recognized, separated by a major faulting event. The ore minerals are contained within quartz and calcite associated with fracturing and healing of veins that occurred during both mineralization episodes. Wall-rock alteration minerals during stage I, the main ore stage, include sericite, chlorite, and minor pyrite and carbonates. Sulfide minerals deposited along with electrum during this stage include arsenopyrite, pyrite, pyrrhotite, sphalerite, marcasite, chalcopyrite, galena, and argentite. Electrum also was deposited during stage II mineralization in the one group of veins, along with pyrite, sphalerite, chalcopyrite, and galena, but the second stage of deposition in other veins was barren. Petrographic examination of textural relationships among sulfides, fluid inclusions, microfracturing, and quartz shows chronological and genetic relationships between gold deposition and fluid entrapment. Systematic studies of fluid inclusions in stage I vein indicate two contrasting events: a relatively high temperature (203°–432°C) and pressure (943–2,098 bars) event related to early sulfide deposition and associated with H2O-CO2-CH4-NaCl ± N2 fluids (less than about 13.4 wt % NaCl), and a lower temperature (202°–399°C) and pressure (670–850 bars) late sulfide depositional event involving H2O-NaCl fluids (3.9–17.3 wt % NaCl). The H2O-NaCl fluid involved in ore-related stage II mineralization had a salinity of 0.4 to 4.2 wt percent NaCl and a homogenization temperature of 201° to 378°C. The calculated sulfur isotope compositions of hydrothermal fluids from the stage I veins (δ34SH2S = 3.5–10.5‰) indicate that ore sulfur was derived mainly from a magmatic source but also in part from sulfur contained in the host rocks. The calculated and measured oxygen and hydrogen isotope compositions of the ore-forming fluids (stage I: δ18OH2O = 1.1–9.0‰, δD = −92 to −21‰; stage II: δ18OH2O = −0.1 to +0.3‰, δD = −95 to −93‰) indicate that the fluids were derived from magmatic and/or deep-seated metasedimentary rocks (stage I) and evolved by mixing with local meteoric water (stage II), by limited water-rock exchange and by degassing during mineralization in uplift zones. The H2O-NaCl fluids involved in the stage I development of these veins represent fluids that evolved either through unmixing of H2O-CO2-CH4-NaCl ± N2 fluids following a decrease in fluid pressure or through mixing with deeply circulating meteoric waters, possibly as a result of uplift and/or unloading during mineralization. The H2O-NaCl fluid involved in stage II was derived from meteoric water. Early deposition of gold in stage I was caused by a decrease in sulfur fugacity (H2S loss) that accompanied the immiscible separation of carbonic vapor from H2O-CO2-CH4-NaCl ± N2 fluids. Gold in late stage I and stage II veins was precipitated from H2O-NaCl fluids by cooling and by dilution caused by mixing with meteoric water.

Formation of the Auriferous and Barren North Dipper Veins in the Sigma Mine, Val d'Or, Canada: Constraints from Structural, Mineralogical, Fluid Inclusion, and Isotopic Data

The Sigma-Lamaque mine (>100 metric tons (t) of gold) is an example of an Archean greenstone belt gold deposit formed by processes related to multistage hydrothermal fluid circulation. The earliest recognized vein systems are steeply to moderately dipping fault-fill veins within shear zones and contemporaneous subhorizontal veins, which were overprinted by the late North Dipper vein system. The latter strikes east-west, dips moderately to the north, and exhibits complex internal geometry with features similar to fault-fill and extensional veins, and therefore is interpreted as extensional shear veins. This late vein system was considered one of the major sources of gold in the shallow underground and open-pit ore reserve estimations. These late North Dipper veins were studied in detail in the Sigma pit where they contain ore-grade gold and are hosted by the calc-alkaline tuffs of the Val d’Or Formation and in the North zone where they are barren and hosted by the tholeiitic volcanic rocks of the Jacola Formation. In the Sigma pit, these veins have apparent thicknesses of 0.8 to 3 m and very irregular contacts with the vein walls. They comprise irregular zones of milky quartz filling, disrupted blocks of layered quartz and tourmaline and slabs of foliated pyrite-rich wall rock. Layers with tourmaline and quartz crystals oriented perpendicular to the vein walls are observed close to the vein walls. The veins contain minor amounts of calcite, pyrite, rutile, and traces of chlorite, muscovite, pyrrhotite, chalcopyrite, galena, bismuth tellurides, and gold. Locally, the sulfide content can attain 10 modal percent of the vein mineralogy. In the veins, native gold (with 6 wt % Ag) occurs rarely associated with the main vein-filling minerals, commonly as inclusions in pyrite (main vein-filling stage), and most commonly filling fractures in pyrite, tourmaline, and quartz, where it is alloyed with 8 to 17 wt percent Ag and is associated with calcite and Bi tellurides (late auriferous stage). The proximal wall-rock alteration related to the auriferous North Dipper veins overprints the metamorphic assemblage and is characterized by abundant fine-grained plagioclase, calcite, quartz and minor chlorite, tourmaline, and pyrite in the tuffs and more abundant muscovite in the intrusive feldspar porphyry. In the wall rock, gold with 6 to 28 wt percent Ag is found locally filling fractures in pyrite, where it is associated with a late generation of calcite. The barren North Dipper vein also comprises mainly quartz and tourmaline but lacks calcite and gold, has a very low content of sulfides ( Aqueous-carbonic fluid inclusions with salinities less than 8 wt percent (NaCl equiv) and homogenization temperatures between 228° and 440°C, and carbonic fluid inclusions with less than 0.2 mol percent CH 4 coexisting in the same healed fractures, are common in the auriferous North Dipper veins but very rare in the barren vein where aqueous fluid inclusions have lower temperatures (dominantly 125°–225°C). Crush leaching and laser ablation time-of-flight inductively coupled mass spectrometry (LA-TOF-ICPMS) of fluids in the inclusions indicate elevated concentrations of Ni, Cu, Sb, Pb, and Ag in the fluids in the auriferous veins compared to the aqueous fluids in the barren veins. This suggests different sources for the metals in the fluids associated with the gold, possibly including both igneous and sedimentary rocks. Calculated oxygen isotope equilibration temperatures for quartz-tourmaline pairs from the auriferous main vein-filling stage are 323° to 370°C. This is within the range documented in fluid inclusions related to the late auriferous stage, indicating that the temperature of the auriferous hydrothermal fluids did not change appreciably during the evolution of the system. Calculated δ 18 O H 2 O values for the mineralizing fluids are 9.5 per mil, consistent with either low water/rock ratio systems associated with high-grade metamorphism or a magmatic origin for the fluids. Gold included in pyrite may have precipitated during the main vein-filling stage due to the decrease of H 2 Sconcentration in the hydrothermal fluid following the deposition of sulfides. However, gold in fractures in the main vein-filling minerals precipitated later, due probably to dilution of the auriferous aqueous-carbonic fluids by mixing with aqueous fluids. The absence of ore-grade gold in the barren North zone vein is probably due to the lack of circulation of auriferous aqueous-carbonic fluids in the North zone, located distal to the first-order Larder-Lake Cadillac fault, which may have served as the main regional conduit for the auriferous aqueous carbonic fluids.