Precipitable Water Vapor (PWV) is vital in climate research, monitoring in troposphere stability and weather disasters. This study investigates the detailed vertical variation of PWV in China, utilizing data from the 5th generation European Centre for Medium-Range Weather Forecasts (ECMWF). A PWV segmented vertical adjustment grid model (CPWV-H) was developed based on a sliding window algorithm, with a spatial resolution of 0.5° × 0.5° and a temporal resolution of one day. The performance of the CPWV-H model was evaluated using multi-source PWV data and compared with the conventional empirical model (EPWV-H) and the recently released C-PWVC1 model. Results show that the CPWV-H model has superior accuracy and stability. Using ERA5 PWV profiles as a reference, the CPWV-H model has a mean Bias of −0.45 mm and a mean RMSE of 1.24 mm, improving by 21.52 % over the EPWV-H model and 31.11 % over the C-PWVC1 model. With radiosonde profiles as a reference, it has a mean Bias of −0.10 mm and a mean RMSE of 2.86 mm, improving by 7.14 % and 13.86 % over the EPWV-H and C-PWVC1 models, respectively. Consequently, the CPWV-H model exhibits enhanced stability and vertical adjustment accuracy in China, offering significant utility for the fusion of multi-source water vapor data, comparative analysis, and climate research.
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