Variation In Mineral Content Research Articles

Revealing chemistry-structure-function relationships in shark vertebrae across length scales

Shark cartilage presents a complex material composed of collagen, proteoglycans, and bioapatite. In the present study, we explored the link between microstructure, chemical composition, and biomechanical function of shark vertebral cartilage using Polarized Light Microscopy (PLM), Atomic Force Microscopy (AFM), Confocal Raman Microspectroscopy, and Nanoindentation. Our investigation focused on vertebrae from Blacktip and Shortfin Mako sharks. As typical representatives of the orders Carcharhiniformes and Lamniformes, these species differ in preferred habitat, ecological role, and swimming style. We observed structural variations in mineral organization and collagen fiber arrangement using PLM and AFM. In both sharks, the highly calcified corpus calcarea shows a ridged morphology, while a chain-like network is present in the less mineralized intermedialia. Raman spectromicroscopy demonstrates a relative increase of glucosaminocycans (GAGs) with respect to collagen and a decrease in mineral-rich zones, underlining the role of GAGs in modulating bioapatite mineralization. Region-specific testing confirmed that intravertebral variations in mineral content and arrangement result in distinct nanomechanical properties. Local Young's moduli from mineralized regions exceeded bulk values by a factor of 10. Overall, this work provides profound insights into a flexible yet strong biocomposite, which is crucial for the extraordinary speed of cartilaginous fish in the worlds’ oceans. Statement of significanceShark cartilage is a morphologically complex material composed of collagen, sulfated proteoglycans, and calcium phosphate minerals. This study explores the link between microstructure, chemical composition, and biological mechanical function of shark vertebral cartilage at the micro- and nanometer scale in typical Carcharhiniform and Lamniform shark species, which represent different vertebral mineralization morphologies, swimming styles and speeds. By studying the intricacies of shark vertebrae, we hope to lay the foundation for biomimetic composite materials that harness lamellar reinforcement and tailored stiffness gradients, capable of dynamic and localized adjustments during movement.

Pollinator Diversity and Phenological Interplay: Exploring Mineral, Hormonal, Sugar, and Vitamin Contents in Vitis vinifera L. cv Bozcaada Çavuşu.

Unraveling the intricate physiological and biochemical intricacies associated with female dominance in grape berries across diverse developmental stages is imperative for optimizing grape production and ensuring the attainment of high-quality yields. This study conducted a thorough analysis of grape berries across phenological stages (BBCH-79, BBCH-81, BBCH-89) and cultivars. At BBCH-89, Bozcaada Çavuşu*Vasilâki demonstrated the highest berry weight and total soluble solids (TSS) levels, emphasizing its enological potential. Acidity peaked at BBCH-79 (28.16) and declined at BBCH-89 (6.11), signaling a shift towards lower acidity in later stages. Bozcaada Çavuşu*Vasilâki consistently showed the highest maturity index (MI). Mineral content variations were observed across nitrogen (N), calcium (Ca), potassium (K), phosphorus (P), magnesium (Mg), sulfur (S), iron (Fe), manganese (Mn), boron (B), zinc (Zn), and copper (Cu), with Bozcaada Çavuşu*Vasilâki often having the highest concentrations, particularly in potassium, calcium, and boron. Hormonal analysis revealed a significant surge in concentrations at BBCH-89, with Bozcaada Çavuşu*Vasilâki standing out. Notably, Indole-3-acetic acid (IAA) concentrations increased by 106%, and abscisic acid (ABA) levels peaked at BBCH-79 with a 38% increase in Bozcaada Çavuşu*Kuntra. Sugar content analysis showed variations in fructose, glucose, sucrose, rhamnose, xylose, galactose, and arabinose levels across sampling times and cultivars. Bozcaada Çavuşu*Vasilâki consistently exhibited higher sugar levels, especially at BBCH-81 and BBCH-89. Vitamin concentrations varied temporally and among cultivars, with BBCH-89 displaying the highest vitamin A concentration (6.24 mg/100 g FW), and Bozcaada Çavuşu*Vasilâki often exhibiting maximum values for vitamin B1, B2, B6, and C. Further research and targeted cultivation practices focusing on the unique attributes of Bozcaada Çavuşu*Vasilâki could enhance grape production efficiency, emphasizing its potential contribution to achieving consistently high-quality yields across various phenological stages.

Implications of husking process on the nutritional composition of sorghum grains: diverse varieties and regions

SummarySorghum, known for its nutritional value, health benefits and gluten‐free status, is now widely produced and suitable for human consumption in developed regions due to advancements in sorghum research and processing techniques. The research looked at how well the husking fraction time unit (HFTU) technique worked by examining its effects on the nutritional value of three varieties of sorghum grain. The efficiency of the husking process was assessed at 87% for concentrated and redistributed nutritional contents and 60% for variation of mineral contents based on bran/ endosperm. The technique reduced the T.K.W. compared to whole grain to the endosperm (grits). Moreover, the redistribution of the crude protein % showed the precision of the HFTU procedure by demonstrating an average of 26.6% as a variation ratio of the bran/endosperm in the data set. Contrary to the content of the total dietary fibre content, for example, the variation of TDF % attributed to bran/endosperm was 10.9%. On the other hand, the average ash % of whole grains (hummer) and husked products (TM05C) was increased by 33.2% based on averages of 1.5% and 2.1%, respectively. Accordingly, it was approved that the HFTU procedure effectively separated the endosperm (grits) and bran. This study also found that minerals such as Ca, Cu, Fe, K, Mg, Mn, Na, P, S and Zn changed over 30‐to‐80‐time units by 29%, 13%, 8%, 4%, 17%, 18%, 1%, 13%, 6% and 12% in the bran and endosperm. The HFTU process has influenced the colour attributes of variation sorghum varieties, particularly within a time scale of 80 (S) units. The research revealed that the husking technique substantially impacted the different sorghum grain varieties’ nutritional composition and colour properties. The method can be useful for developers in enhancing sorghum grain products’ nutritional properties attributed to various varieties and regions, allowing them to provide high nutritional quality sourced from sustainable products.

An Experimental Investigation of Interaction between CO2 Solution and Rock under Reservoir Conditions in the Jimsar Shale Oil Formation

Chemical sequestration is one important manner of CCUS. The injection of CO2 into an oil reservoir can not only sequestrate CO2 but also raise the oil recovery factor. The performance of chemical sequestration of CO2 depends on the interaction between CO2 solution and reservoir rock. In this paper, we have conducted three different scales of experiments, e.g., microscopic scale, core scale, and time scale, to fully investigate the interaction and resultant variation to mineral content, microscopic structure, porosity, and permeability under reservoir conditions (i.e., reservoir temperature of 90 °C) in Jimusar shale oil formation. The microscopic-scale experiment applied SEM and hyperspectral scanning to obtain microscopic pore throat structure and element distribution before and after soaking the rock in CO2 solution. The core-scale experiment employed XRD to evaluate mineral content variation caused by CO2 solution. Core flooding experiments were conducted to evaluate porosity and permeability variation caused by the dissolution of CO2 solution into the core samples. The third type of experiment was employed to investigate the effect of time sequence on the dissolution, in which the time ranged from 1 day to 14 days continuously. The experimental results indicate that, under Jimsar reservoir conditions, CO2 solution exhibits a relatively robust dissolution capability, causing significant alterations to the properties of the core samples. Specifically, the CO2 solution effectively dissolves carbonate upon contact. Calcite is the primary target for dissolution, followed by dolomite. In the presence of sufficient CO2, complete dissolution of all carbonates is achievable. On a microscopic scale, dissolution primarily occurs in the calcium-rich areas, leaving other regions unaffected. The typical pore size resulting from CO2 solution-induced dissolution ranges from several to dozens of micrometers. This dissolution process significantly enhances both porosity and permeability. For Jimsar shale core samples, porosity experienced an increase of over 20%, and permeability nearly doubled. Under Jimsar reservoir conditions at 90 °C, CO2 solution can consume all carbonates present in core samples within 8 days. The increase in porosity and permeability is rapid during the initial days and stabilizes around the 6th day. These research findings establish a theoretical foundation for CO2 chemical sequestration.

Forage yields and nutritive values of oat and triticale pastures for grazing sheep in early spring.

Small-grain winter cereals can be utilized as early spring pastures in temperate climates to relieve grazing pressure and potentially mitigate feed shortages. This study was conducted to determine the effects of triticale and oat cereal pastures grazed by sheep during early spring on forage yields, nutritive values, and nutritional requirements of sheep. The research was carried out over three consecutive years, from 2015 to 2017, at the Sheep Research Institute in Bandırma-Balıkesir, located in the Marmara region of Türkiye. The treatments were arranged in a completely randomized block design, with the two forage species, triticale and oat, randomized within each of three blocks. The animal material for the study consisted of 24 Karacabey Merino sheep, each 2 years old, with an average live weight of 57.6±0.5 kg, all in the late lactation stage. In each replication, four sheep were included, resulting in a total of 12 sheep grazing in each of the triticale and oat pastures. The sheep grazed exclusively on the cereal pastures without any additional feed, and had unrestricted access to water throughout the entire period of the experiment. The dry matter yields (DMY), dry matter intakes (DMI), nutritive values, and mineral contents of the cereal species were determined. The DMY showed significant differences over the years (P<0.05). No differences in DMY were observed between pastures, with oats yielding 11.99tha-1 and triticale yielding 11.08 tha-1. During the grazing period, the change in DMY was significant in all years (P<0.05). The average DMI of the sheep was 2,003.5 g d-1 for triticale and 2,156.6 g d-1 for oat, respectively, and DMI exhibited no significant differences across pastures. Although there was no difference in DMI between 2015 and 2016, the lowest consumption occurred in 2017 (P<0.05). Additionally, while DMI showed different trends each year based on the periods, it generally decreased by the end of the grazing period. While both pastures provided similar nutritive values, significant differences were observed in the crude protein (CP), acid detergent fiber (ADF), in vitro true DM digestibility (DDM), and metabolisable energy (ME) values across the years. Over the years, as the grazing period progressed, CP levels decreased while neutral detergent fiber (NDF), ADF, and acid detergent lignin (ADL) increased, resulting in reduced DDM and ME values. The phosphorus (P) content in triticale was higher than in oats, but there were no differences in the content of other minerals between them. Between the years, significant differences were observed in the levels of phosphorus (P) and iron (Fe), while changes in other elements were insignificant. The variation in mineral content during the grazing process differed over the three years. Study results indicated that the nutritional values of triticale and oat pastures are similar, and both can effectively be used to provide sufficient feed to meet the early spring forage requirements for sheep.

Soilless cultivation systems to produce tailored microgreens for specific nutritional needs.

The awareness of the importance of following dietary recommendations that meet specific biological requirements related to an individual's health status has significantly increased interest in personalized nutrition. The aim of this research was to test agronomic protocols based on soilless cultivation for providing consumers with new dietary sources of iodine (I), as well as alternative vegetable products to limit dietary potassium (K) intake; proposed cultivation techniques were evaluated according to their suitability to obtain such products without compromising agronomic performance. Two independent experiments, focused on I and K respectively, were conducted in a commercial greenhouse specializing in soilless production. Four different species were cultivated using three distinct concentrations of I (0, 1.5 and 3 mg L-1 ) and K (0, 60 and 120 mg L-1 ). Microgreens grown in I-rich nutrient solution accumulate more I, and the increase is dose-dependent. Compared to unbiofortified microgreens, the treatments with 1.5 and 3 mg L-1 of I resulted in 4.5 and 14 times higher I levels, respectively. Swiss chard has the highest levels of K (14 096 mg kg-1 of FW), followed by rocket, pea and radish. In radish, rocket and Swiss chard, a total reduction of K content in the nutrient solution (0 mg L-1 ) resulted in an average reduction of 45% in K content. It is possible to produce I-biofortified microgreens to address I deficiency, and K-reduced microgreens for chronic kidney disease-affected people. Species selection is crucial to customize nutritional profiles according to specific dietary requirements due to substantial mineral content variations across different species. © 2023 The Authors. Journal of The Science of Food and Agriculture published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.

Seasonal variation in mineral concentrations of four marine fish species retained by fishers in Vanga and Msambweni, Kenya

Marine fish is a rich source of minerals in the diet of humans, but seasonal variation in fish mineral concentrations is relatively unstudied. We investigated seasonal mineral concentrations among four marine fish species retained by small scale fishers in Msambweni and Vanga fishing villages in Kenya. The fish species were Siganus sutor (rabbitfish) in Msambweni and Decapterus macarellus (mackerel scad), Sphraena forsteri (bigeye barracuda) and Sphyraena obtusata (obtuse barracuda) in Vanga. Mineral concentrations were quantified in 120 fish specimens (60/season) and their mineral supplementation potential evaluated. The concentrations of Potassium (K), Magnesium (Mg), Zinc (Zn), Iron (Fe) and Iodine (I) were determined using Inductively Coupled Plasma Optical Emission Spectrometry. K, Mg, Zn and I levels in fish samples varied between seasons with higher concentrations during the wet and cool southeast monsoon (SEM) season (April to October). However, Fe concentration was significantly higher during the dry and warm northeast monsoon (NEM) (November to March). S. fosteri recorded the highest concentrations of Mg (72.29 mg/100g in SEM) and Fe (3.63 mg/100g in NEM). S. sutor was the richest source of K (410.21 mg/100g in SEM). These two species also recorded the highest concentration of I (57.6 μg/100g in SEM) while D. macarellus had the highest Zn concentration (5.84 mg/100g in SEM). Mineral concentrations were dependent on fish species as well as season, influencing the mineral intake in Msambweni and Vanga villages.

Upper cervical spine bone mineral content variations in elderly females

The purpose of the study was to determine the bone mineral densities (BMDs) of the C1 and C2 vertebrae and discuss their implications for autonomous vehicle environments and vulnerable road users. Using quantitated computed tomography (QCT), the BMDs were obtained at eight regions for the C1 vertebra and seven regions for the C2 vertebra. The spine surgeon author outlined the boundaries of each region, and nine elderly female human cadaver specimens were used. The regions were based on potential stabilization locations for fracture fixation. In the C1 vertebra, the BMD was greatest at the anterior tubercle, followed by the posterior tubercle, the posterior arch, and the lateral and anterior lateral masses. In the C2 vertebra, the distal odontoid had the greatest BMD, followed by the spinous process, the C2-lateral mass, the odontoid-body interface, and the anterior inferior aspect of the body. Use of these data in female-specific finite element models may lead to a better understanding of load paths, injuries, mechanisms, and tolerance.

Variation in enamel and dentine mineral concentration and density in primate molars

ObjectiveVariation in enamel and dentine mineral concentration and total effective density can be reliably collected using Micro-CT scans. Both variables are suggested to reflect mechanical properties such as hardness and elastic modulus in dental tissues, meaning Micro-CT methods allow relative composition and mechanical properties to be collected non-destructively. Design16 lower molars from 16 Catarrhine primates were Micro-CT scanned alongside hydroxyapatite phantoms using standardized settings and methods to calculate mineral concentration and total effective density. Mineral concentration, total effective density and thickness of dentine and enamel were calculated for four cusps, representing each 'corner' of the tooth and four lateral crown positions (i.e., mesial, buccal, lingual and distal). ResultsThe results show mean mineral concentration and total effective density values were higher in areas of thicker enamel, while the opposite was observed for dentine. Buccal positions had significantly higher mineral concentration and total effective density values than lingual areas. Cuspal positions had higher mean values than lateral enamel, for both dentine (mineral concentration cuspal: 1.26 g/cm3; lateral: 1.20 g/cm3) and enamel (mineral concentration cuspal: 2.31 g/cm3; lateral: 2.25 g/cm3). Mesial enamel had significantly lower values than other locations. ConclusionsThese common patterns across Catarrhine taxa may be linked to functional adaptations related to optimization of mastication and tooth protection. Variation in mineral concentration and total effective density may also be associated with wear and fracture patterns, and can be used as baseline information to investigate the effect of diet, pathological changes and aging on teeth through time.

Variation in macrominerals and trace elements in cows’ retail milk and implications for consumers nutrition

Based on previous farm-level studies, this study hypothesised that production system (conventional, CON; organic, ORG; channel island, CHA) and season would cause variation in the concentrations of macrominerals and trace elements in retail milk. On average, milk retained its status as an excellent source of Ca, P, I, and Mo across different demographics, and a very good source of K, Mg, and Zn for children. Compared with CON and ORG, CHA milk contained higher concentrations of Ca, Mg, P, Cu, Mn, and Zn; and lower concentrations of K and I. Macrominerals did not show a clear seasonal pattern but trace elements were all at lower concentrations during the typical grazing season. Variation in mineral concentrations can have implications to Ca and P supply in children, and I and Zn supply across different consumer demographics; while the seasonal variation was more pronounced than that associated with production system.

Formulation and nutritional properties of qualea-bird-meat-based complementary foods for children (6–23 months) in Tanzania using a linear programming technique

BackgroundLong-standing mitigation strategies have been used to address the issue of malnutrition in children, especially undernutrition in developing countries including Tanzania, however, the problem still exists. Development of instant complementary formulae based on readily available local foods using robust mathematical models, to fight malnutrition seems to be one of the best options. PurposeThe purpose of this study was to develop and evaluate the nutritional content of instant supplemental food formulations based on qualea bird's meat for infants between the ages of 6 and 23 months using a linear programming model. Basic procedureFour complementary meal formulations based on bird meat were developed using a linear programming model: control, only bird meat (CtrQM); green banana mixed with bird meat (BanQ); Irish potato mixed with bird meat (PotQ); and rice mixed with the meat (RicQ). The formulations were cooked separately at 98 °C for 45–55 min and extruded to create instant dry products and analyzed using standard methods for proximate composition, minerals, and vitamin A. Main findingThe proximate composition parameters, minerals and vitamin A contents (in DM) were substantially enhanced and differed significantly (p < 0.05) between the formulations. PotQ had a higher moisture content (8.9 g/100 g), protein (16.7 g/100 g), crude fat (1.8 g/100 g), ash (5.4 g/100 g) and crude fibre (2.9 g/100 g) than lower values in other formulations. Furthermore, calcium was the most abundant mineral (832.5 mg/kg) whereas zinc was the least abundant mineral (38.5 mg/100 g). The variation in mineral contents among formulations was also significant (p < 0.05). Additionally, RicQ had significantly (p < 0.05) highest retinol (26.5 mg/kg) and beta-carotene (4.9 μg/g) while the lowest values were observed in the control sample with values of 3.3 mg/kg and 1.6 μg/g respectively. ConclusionIn a view of the findings, a linear programming model optimized and enhanced the proximate composition, mineral, and vitamin A qualities of the qualea birds' meat-based instant complementary formulation that seems to meet the RDAs for infants aged 6 to 23 months. Therefore, the application of the model in product formulation to combat malnutrition in the country is highly recommended.

SSR and GBS based GWAS study for identification of QTLs associated with nutritional elemental in common bean (Phaseolus vulgaris L.)

Common bean is one of the important staple food legumes, and is a potential source of minerals with high content of P, K, B and S and is being targeted for nutritional improvement to overcome mineral malnutrition and hidden hunger problem globally. In the present study, we used Genome Wide Association approach (GWAS) for P, K, B and S using a core set of 96 genotypes of common bean representing landrace diversity of Western Himalayas. Significant variation in mineral content among the genotypes was observed and an inventory of nutrients for the available germplasm was established. Four genotypes (R9, WB1680, WB923 and N13) were found with highest content of P, K, B and S respectively. Moreover, we also categorized germplasm in 10 highest and lowest genotypes for utilization in breeding program. Further, the germplasm was genotyped using SSR's and SNP's (genotyping by sequencing; GBS) for studying genetic diversity and population structure. 22 SSRs selected from the linkage map that were distributed on 11 chromosomes of common bean were used. Moreover, GBS approach was also used for dense genome wide marker coverage. Based on SSRs, germplasm was divided into 2 subpopulations whereas SNPs divided the germplasm into 5 subpopulations. GWAS was also done for both the markers systems. Our study concluded with the establishment of nutrient inventory in the available germplasm and identification of 9 significant SSR markers and 35 significant SNP markers associated with these traits, out of which 4 SSR markers were located on chromosome 2 and 7. Most of the SNP markers were located on chromosome 10 which suggest that maximum genes responsible for nutrient accumulation might be present on chromosome 10 of common bean. Further 58 candidate genes near to the vicinity of significant SNPs were identified. The significant markers associated with the traits of interest after validation can prove an asset for plant breeders to enhance the nutrient status (biofortification) of common bean which can help in tackling the malnutrition and can solve the hunger related problems majorly in the developing countries as it forms the cheap but widely used energy source in these countries.

Regional and Seasonal Variability of Mineral Patterns in Some Organs of Slaughtered One-Humped Camels [Camelus dromedarius] from Saudi Arabia

Camel products are receiving great interest worldwide because of their high functional properties and nutritive values. Therefore, this study was focused on the variation of copper [Cu], zinc [Zn], manganese [Mn], selenium [Se], iron [Fe], iodine [I], and some heavy metals, cobalt [Co], lead [Pb], and cadmium [Cd], in the blood and tissues of slaughtered camels from five regions in Saudi Arabia [SA] during the summer and winter seasons, because environmental factors vary from region to region. Whole blood, meat, liver, rumen fluid, and rumen tissues were collected from the slaughterhouse in each region during the two seasons. Moreover, samples were prepared and analyzed for trace mineral and heavy metal concentrations using ICP-MS. The data were statistically analyzed as part of a complete randomized design and correlation analysis for season and location using SAS. The findings revealed a pattern in the minerals, with Ca being the only mineral that was unrelated to other minerals in the liver. For lead and cadmium, our mean value in liver [0.40 µg/g] was below the limit of the EU standard for cadmium [0.50 µg/g], while in meat and liver, lead contents [1.62 µg/g and 2.57 µg/g, respectively] were above the limit of the EU standard [0.10 and 0.20 µg/g, respectively]. For meat, the significantly highest positive correlations were observed between P and Mg [R2 = 0.928], Fe and Mn [R2 = 0.860], and Co and Mn [R2 = 0.821]. For rumen tissues, P and Mg were highly correlated [R2 = 0.958] as well as Zn and Mg [R2 = 0.857], Zn and P [R2 = 0.836], and Fe and Ca [R2 = 0.802]. As a result, a region and season reflect variations in mineral concentrations in SA during the summer and winter seasons. Further intensive research is needed to investigate the minerals' biological mechanisms in camels under different environmental conditions.

Effects of CO2 intrusion on pore structure characteristics of mineral-bearing coal: Implication for CO2 injection pressure

CO2 intrusion has a crucial effect on the pore structure of mineral-bearing coal. In this study, we selected long flame coal, lean coal, and anthracite after CO2 adsorption at different pressures and tested the coal samples using X-ray diffraction, mercury intrusion porosimetry, and N2 (77 K) adsorption methods. The tests were conducted to determine the variations in mineral content, pore structure, and fractal characteristics. The results showed that supercritical CO2 had a greater ability to dissolve minerals in coal than that of subcritical CO2. Although the total pore volume and BET specific surface area gradually increased with the increase in CO2 intrusion pressure in coal, the transformation of different pores and partial new pores caused by the dissolution of minerals and the adsorption swelling of coal matrix caused the micro-macropores in the three coal samples to exhibit different trends. The pore surface roughness and pore structure complexity of seepage pore in the long-flame coal after CO2 adsorption increased while those of the lean coal and anthracite decreased. Meanwhile, CO2 intrusion caused the surface of the adsorption pore in coal to become smooth, and the pore structure was more regular, except for the lean coal. A conceptual model of the mineral-bearing coal was developed to describe the relationship between the mineral composition and pore structure induced by CO2 intrusion. These findings help to understand the transformation effect of CO2 on coal seams. Thus, a higher CO2 injection pressure should be used to obtain a larger injection volume and shorter injection time during CO2 storage implementation.

Variation in Tap Water Mineral Content in the United Kingdom: Is It Relevant for Kidney Stone Disease?

Introduction: The dissolved mineral content of drinking water can modify a number of excreted urinary parameters, with potential implications for kidney stone disease (KSD). The aim of this study is to investigate the variation in the mineral content of tap drinking water in the United Kingdom and discuss its implications for KSD. Methods: The mineral composition of tap water from cities across the United Kingdom was ascertained from publicly available water quality reports issued by local water supply companies using civic centre postcodes during 2021. Water variables, reported as 12-monthly average values, included total water hardness and concentrations of calcium, magnesium, sodium and sulphate. An unpaired t-test was undertaken to assess for regional differences in water composition across the United Kingdom. Results: Water composition data were available for 66 out of 76 cities in the United Kingdom: 45 in England, 8 in Scotland, 7 in Wales and 6 in Northern Ireland. The median water hardness in the United Kingdom was 120.59 mg/L CaCO3 equivalent (range 16.02–331.50), while the median concentrations of calcium, magnesium, sodium and sulphate were 30.46 mg/L (range 5.35–128.0), 3.62 mg/L (range 0.59–31.80), 14.72 mg/L (range 2.98–57.80) and 25.36 mg/L (range 2.86–112.43), respectively. Tap water in England was markedly harder than in Scotland (192.90 mg/L vs. 32.87 mg/L as CaCO3 equivalent; p < 0.001), which overall had the softest tap water with the lowest mineral content in the United Kingdom. Within England, the North West had the softest tap water, while the South East had the hardest water (70.00 mg/L vs. 285.75 mg/L as CaCO3 equivalent). Conclusions: Tap water mineral content varies significantly across the United Kingdom. Depending on where one lives, drinking 2–3 L of tap water can contribute over one-third of recommended daily calcium and magnesium requirements, with possible implications for KSD incidence and recurrence.

Mineral Content Variation in Leaves, Stalks, and Seeds of Celery (Apium graveolens L.) Genotypes.

Celery is an important nutritionally rich crop in the family Apiaceae. It is cultivated worldwide for food as well as for use in pharmaceutics. It is an excellent source of minerals, vitamins, and phytochemicals. Identification of superior genotypes with improved nutritional content is the requirement to develop cultivars for commercial cultivation. For mineral analysis of celery, an experiment was carried out taking 20 diverse genotypes. These genotypes were analysed for macro- and micronutrients which include nitrogen (N), phosphorus (P), potassium (K), calcium (Ca), iron (Fe), zinc (Zn), manganese (Mn), copper (Cu), and sodium (Na). The study revealed high content of K (20.3-26.1 mg/g dry weight (DW)) and Zn (0.09-0.14 mg/g DW) in leaves while the stalks were rich in Ca (41.5-51.3 mg/g DW) and Na (5.2-8.0 mg/g DW). High contents of P (5.2-6.8 mg/g DW), Fe (0.41-0.56 mg/g DW), Cu (0.015-0.026 mg/g DW), and Mn (0.020-0.029 mg/g DW) were observed in seeds. Based on the mineral content, three genotypes, viz., PAU2, PAU4, and PAU7, were found to be superior in terms of mineral composition in leaves, stalks, and seeds. Cluster analysis divided the genotypes into two major groups. These genotypes can be used in crosses as they showed great potential for use in biofortification. This study opens newer avenues for future research, encouraging researchers to enhance the product quality and production efficiency of the leaves, stalks, and seeds valuable for human consumption.

Elevated temperature and carbon dioxide levels alter growth rates and shell composition in the fluted giant clam, Tridacna squamosa

Giant clams produce massive calcified shells with important biological (e.g., defensive) and ecological (e.g., habitat-forming) properties. Whereas elevated seawater temperature is known to alter giant clam shell structure, no study has examined the effects of a simultaneous increase in seawater temperature and partial pressure of carbon dioxide (pCO2) on shell mineralogical composition in these species. We investigated the effects of 60-days exposure to end-of-the-century projections for seawater temperature (+ 3 °C) and pCO2 (+ 500 µatm) on growth, mineralogy, and organic content of shells and scutes in juvenile Tridacna squamosa giant clams. Elevated temperature had no effect on growth rates or organic content, but did increase shell [24Mg]/[40Ca] as well as [40Ca] in newly-formed scutes. Elevated pCO2 increased shell growth and whole animal mass gain. In addition, we report the first evidence of an effect of elevated pCO2 on element/Ca ratios in giant clam shells, with significantly increased [137Ba]/[40Ca] in newly-formed shells. Simultaneous exposure to both drivers greatly increased inter-individual variation in mineral concentrations and resulted in reduced shell N-content which may signal the onset of physiological stress. Overall, our results indicate a greater influence of pCO2 on shell mineralogy in giant clams than previously recognized.

Mineral content variations between Australian tap and bottled water in the context of urolithiasis.

ObjectivesThe objective of this study is to investigate the variations in mineral content of tap drinking water across major Australian cities, compared with bottled still and sparkling water, and discuss the possible implications on kidney stone disease (KSD).Materials and MethodsThe mineral composition of public tap water from 10 metropolitan and regional Australian cities was compared using the drinking water quality reports published from 2019 to 2021 by the respective water service utilities providers. Specifically, average levels of calcium, bicarbonate, magnesium, sodium, potassium, and sulphates were compared with published mineral content data from bottled still and sparkling drinking water in Australia.ResultsThe median or mean (depending on report output) mineral composition was highly variable for calcium (range 1.3 to 20.33 mg/L), magnesium (range 1.1 to 11.2 mg/L), bicarbonate (range 12 to 79 mg/L), sodium (range 3 to 47.1 mg/L), potassium (range 0.4 to 3.23 mg/L) and (sulphates range <1 to 37.4 mg/L). Calcium, magnesium and bicarbonate levels in tap water were lower than in bottled sparkling water. Consumption of 3 L/day of the most calcium rich tap water would fulfil 4.7% of the RDI, compared with 8.7% with bottled sparkling water. Consumption of 3 L of the most magnesium rich tap water would fulfil 8% of the RDI, compared with 13.6% with bottled sparkling water.ConclusionThe mineral content of tap drinking water varied substantially across major Australian city centres. Bottled sparkling water on average provided higher levels of calcium, bicarbonate and magnesium and may be preferred for prevention of calcium oxalate stones. These findings may assist counselling of patients with KSD depending on geographic location in the context of other modifiable risk factors and 24‐h urine analysis results.

Mineralogy and pore characteristics of marine gas hydrate-bearing sediments in the northern South China Sea

Properties of host sediments are critical to understanding the formation and occurrence of gas hydrates in nature. This study investigates the mineralogy and pore characteristics of marine gas hydrate-bearing sediments (GHBS) within and below two high-saturation zones cored in drilling site W01 in the Qiongdongnan Basin in the South China Sea. The study involves an original application of high-resolution SEM imaging and automated mineralogy to fields-of-view (FOVs) large enough to undertake quantitative analyses at micro- to nano-scales. The samples are mainly fine-grained (<63 μm) and mineralogically dominated by illite, montmorillonite and quartz, significantly higher in clay mineral content than GHBS cored elsewhere in the South China Sea. Porosities determined from thin sections are from 27.6% to 33.0% and the pores are dominated by diameters of 0.1–1 μm. A sample from the upper high-saturation GHBS is rich in clay minerals and clay-sized grains with pores mainly 0.1–1 μm in size, while a sample from the lower zone of high-saturation GHBS has less clay minerals, more sands, and pore diameters of >1 μm are as important as those 0.1–1 μm in size. A third sample from an underlying zone has similar mineral compositions, grain-size and pore-size distributions to those in the uppermost high-saturation hydrate bearing zone. The largest pores are due to microfossil cavities, but their contribution to total porosity is <5%, suggesting their role in fine-grained sediments should not be overestimated. It is inferred that grain size and pore size, affected by variations in mineral content, are important factors influencing differences in hydrate accumulation. The geological source of gas and its migration are also factors determining the distribution of gas hydrate in the study area. Our approach using large FOVs to obtain quantitative micro- and nano-scale data from SEM images facilitates correlation to centimeter- and meter-scale information from well logs and seismic data, and offers opportunities to obtain new insights into the in-situ occurrence and accumulation of gas hydrate and its effects on physical properties of gas hydrate reservoirs.

Grain size variation in sand column along Chhatrapur coast, Ganjam district, Odisha – A clue to the depositional environment

The concentration of heavy mineral placer deposits along the coastal tracts are function of various favourable factors i.e. hinterland geological formations, prevalence of favourable climatic condition, their transportation through intricate drainage systems and various coastal processes, which operated during the geological past. Textural analysis of the available unconsolidated sediments from the present deposits is of vital importance to decode the prevailing depositional environment while grain size analysis is the major parameter used. Present study highlights the grain size analysis of the identified sand column from Chhatrapur Mineral Sand Deposit along the coastal tract of Odisha to infer the environment of deposition of heavy mineral bearing sand and their heavy mineral content variation. Standard procedure of sampling, data analysis and interpretation techniques were adopted. Result shows that, sands from frontal and rear dune are characterized by distinct bi-modal distribution, medium to fine, moderately to well sorted with good positive skewness, whereas, sand from Inter-dunal region shows dominant unimodal, medium to coarse grain, moderately poorly sorted nature and slightly positive skewness. The better heavy mineral concentration (10 to 25 % grade) in frontal and rear dunes is attributed to prevalence of aeolian dune deposition accompanied by good sorting. In contrast, the low concentration of heavy mineral (3 to 6 %) in inter dune region is due to occasional fluvial regime and poor sorting of sediments. Thus, grain size analysis can be an effective tool to decipher local prevailing depositional environment, which has a bearing on heavy mineral concentration as well.