Variability Of Water Fluxes Research Articles

Spatiotemporal Variability of Hyporheic Flow in a Losing River Section

AbstractCharacterizing the spatiotemporal variability of water fluxes at the stream‐groundwater interface is extremely challenging due to the lack of methods for estimating hyporheic flows at different scales. To address this, we demonstrate the potential of Active‐Distributed Temperature Sensing (DTS) methods for measuring and mapping hyporheic flow in a lowland stream. Experiments were conducted by burying a few hundred meters of heatable Fiber‐Optic cables within streambed sediments in a large meander, where permanent stream‐losing conditions are observed along the stream reach. We propose a new methodology to filter ambient temperature variations along the heated section of the DTS cable and to extend the application of Active‐DTS to losing streams. After data processing, the results show that, along lateral and longitudinal stream profiles, both thermal conductivity and water flux values follow normal distributions with relatively small standard deviations. Hyporheic fluxes vary by one order of magnitude. The absence of correlation between water fluxes within the hyporheic zone and streambed topography variations suggests that the variability is mainly controlled by local streambed heterogeneities. This means that the spatiotemporal variability of fluxes may be used as a marker of the variability of streambed hydraulic conductivities. The relatively low spatial variability (one order of magnitude) in hyporheic flow suggests a small variability of streambed properties. This is an important result for calibrating models assessing hyporheic processes, in which the hydraulic conductivity distribution is generally assumed. Additionally, measurements made over three years yield similar estimates showing the remarkable stability of hyporheic flows through time.

Numerical study of tidal effect on the water flux across the Korea/Tsushima Strait

Tremendous amounts of materials and energy are transported from the East China Sea (ECS) to the East/Japan Sea (EJS) through the Korea/Tsushima Strait (KTS). Tides undoubtedly play an important role in regulating ocean circulation on the broad continental shelf of the ECS, while the effects of tides on the water exchange between the ECS and EJS remain unclear. Using a three-dimensional Regional Oceanic Modeling System (ROMS) circulation model, we conducted numerical experiments with tides, without tides, and only barotropic tides. The results showed that the water flux across the KTS can increase by up to 13% (in summer) when excluding tides from the numerical simulation. To understand how tidal forcing regulates the KTS water flux, we performed a dynamic diagnostic analysis and revealed that the variation in sea surface height under tidal effect is the main reason for the water flux variation across the KTS. The tidal effect can adjust the sea surface height, weaken the pressure gradient and reduce the water flux across the KTS, which affect the intensity of water exchange between the ECS and EJS. The tidal effect can alter sea level difference between the Taiwan Strait and the KTS, which influences the KTS water flux. Tides can also influence the KTS water flux by altering the sea surface height through interaction with topography and stratification. We also found that tidal effect weakens the northward intrusion of the Yellow Sea Warm Current in winter and in turn enhances the water flux across the KTS according to volume conservation. These modeling results imply that tides must be considered when simulating the ocean environment of the northwestern Pacific Ocean.

Effect of etching and reduction time on the structure, performance, and stability of GO-based membrane for water purification

Holey graphene oxide (HGO) and reduced HGO membranes (rHGO) can overcome high tortuosity and poor stability of GO-based membranes, respectively. In this study, HGO and rHGO membranes were fabricated to try to quantitatively elucidate the etching and reduction time on structure, stability and rejection performance for slat and pharmaceuticals. Water flux of HGO membrane linearly increased (Jv=2.07t + 1.02, R2=0.9931) and Na2SO4 rejection linearly decreased (RNa2SO4=−4.37t + 88.26, R2=0.9511), while the membranes stability substantially increased with etching time from 1 to 5 h (water flux variation from 22% to 5% and rejection ratio variation from 17% to 7%) under long-term vibration . Subsequently, water flux of rHGO membranes exponentially decreased (Jv=exp(2.89–0.12t + 0.0039t2), R2= 0.9996) with reduction time, while slightly improved salt rejection (RNa2SO4=exp(2.89–0.12t + 0.0039t2), R2= 0.9971) were observed. Effective length of actual pathways for GO, HGO4 and rHGO4–5 membranes calculated by the mass transfer-based model was 7.37 ± 0.47, 4.48 ± 0.68 and 7.23 ± 1.29 µm, respectively, which were much higher than that geometric thickness of the GO membranes. These results indicated that d-spacing, tortuosity and porosity should be comprehensively considered for membrane design and fabrication. With a series of saccharides as probes, average pore size slightly decreased for HGO4 (rp=0.36 nm, Sp=0.34) and rHGO4–5 (rp=0.33 nm, Sp=0.28) membrane compared with GO membranes (rp=0.38 nm, Sp=0.3), demonstrating that etching and following reduction marginally affected the pore size distribution. H2O2 etching increased both water permeability (A) and its selectivity (A/B) for three pharmaceuticals, while the thermal reduction substantially decreased the water flux. Moderate and low rejection ratios for the three pharmaceuticals also demonstrated the importance of trade-off between etching and reduction time and the urgent need for narrowing pore-size distribution for GO-based membranes for water purification.

Robust In Situ Fouling Control toward Thin-Film Composite Reverse Osmosis Membrane via One-Step Deposition of a Ternary Homogeneous Metal–Organic Hybrid Layer

Membrane fouling is one of the persistent headaches for water desalination because of the significant detriment to membrane performance and operating cost control. It is a great challenge to overcome such crisis in a facile and robust manner. This work was dedicated to customizing an antifouling thin-film composite (TFC) reverse osmosis (RO) membrane with a polydopamine (PDA)/β-alanine (βAla)/Cu2+ ternary homogeneous metal-organic hybrid coating. The metal ions were evenly distributed in a continuous organic network via polydentate coordination. The incorporation of βAla enabled a substantial promotion of the Cu2+ loading capacity on the membrane surface. The involved one-step codeposition protocol made the surface engineering practically accessible. The deposition time was optimized to afford an uncompromising permselectivity of the membrane. This novel trinity was a smart blend of anti-adhesive and bactericidal factors, and each component in the all-in-one layer performed its own function. The hydrophilic PDA/βAla phase induced weak deposition propensity of organic foulant and bacteria onto the modified membrane, as elucidated by water flux variation, foulants adhesion profile, and interfacial interaction energy. Meanwhile, the Cu2+-loaded surface strongly inactivated the attached bacteria to further alleviate biofouling. Excellent sustainability and stability implied the reliable performance of such trinity-coated membrane in practical service. Given the simplicity and robustness, this work opened a promising avenue for in situ fouling control of TFC RO membranes during water desalination.

Simulation of site‐scale water fluxes in desert and natural oasis ecosystems of the arid region in Northwest China

AbstractThe study of water fluxes is important to better understand hydrological cycles in arid regions. Data‐driven machine learning models have been recently applied to water flux simulation. Previous studies have built site‐scale simulation models of water fluxes for individual sites separately, requiring a large amount of data from each site and significant computation time. For arid areas, there is no consensus as to the optimal model and variable selection method to simulate water fluxes. Using data from seven flux observation sites in the arid region of Northwest China, this study compared the performance of random forest (RF), support vector machine (SVM), back propagation neural network (BPNN), and multiple linear regression (MLR) models in simulating water fluxes. Additionally, the study investigated inter‐annual and seasonal variation in water fluxes and the dominant drivers of this variation at different sites. A universal simulation model for water flux was built using the RF approach and key variables as determined by MLR, incorporating data from all sites. Model performance of the SVM algorithm (R2 = 0.25–0.90) was slightly worse than that of the RF algorithm (R2 = 0.41–0.91); the BPNN algorithm performed poorly in most cases (R2 = 0.15–0.88). Similarly, the MLR results were limited and unreliable (R2 = 0.00–0.66). Using the universal RF model, annual water fluxes were found to be much higher than the precipitation received at each site, and natural oases showed higher fluxes than desert ecosystems. Water fluxes were highest during the growing season (May–September) and lowest during the non‐growing season (October–April). Furthermore, the dominant drivers of water flux variation were various among different sites, but the normalized difference vegetation index (NDVI), soil moisture and soil temperature were important at most sites. This study provides useful insights for simulating water fluxes in desert and oasis ecosystems, understanding patterns of variation and the underlying mechanisms. Besides, these results can make a contribution as the decision‐making basis to the water management in desert and oasis ecosystems.

Variation of free volume and thickness by high pressure applied on thin film composite reverse osmosis membrane

Analytical technologies for polymeric membranes, including positron annihilation lifetime spectroscopy (PALS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS), were employed to understand the origin and harmful effects of thin film composite (TFC) reverse osmosis (RO) membrane compaction. Although no variation in water flux exceeding 10% from the initial flux was observed under all compaction pressures, the hydraulic pressure induced by the high-pressure pump caused a rapid contraction of the free volume and thickness of the TFC RO membrane. In particular, due to the viscoelastic polymer properties of the active layer, a reduction of approximately 15% free volume and 48% thickness was observed at a compaction pressure of 60 bar. Consequently, the analytical procedures can provide a better understanding of membrane compaction during pressurized membrane processes and strategic development to reduce the harmful effects of membrane compaction.

Water storage, mixing, and fluxes in tile-drained agricultural fields inferred from stable water isotopes

Quantifying hydrological processes that control the upper critical zone water balance and contaminant transport in drained landscapes is needed, especially as precipitation patterns driving water balance dynamics continue to shift due to climate change. Here, hydrometric data are integrated with stable isotope signatures to quantify water storage, mixing, and fluxes to subsurface tile drainage at an agricultural field located in Indiana, USA. Over a 2-yr period, precipitation, soil water sampled with suction lysimeters (10–80 cm depth), groundwater (below tile depth; >1 m), and subsurface tile discharge were sampled 97 times. Results showed that isotopic variability in near-surface soil water (10–20 cm) reflected the seasonality of the precipitation input signal, while groundwater values were relatively consistent indicating that water stored below tile drain depth was recharged during winter. Soil water between 20 and 80 cm depth was a mixture of near-surface water and groundwater that varied seasonally depending upon groundwater hydrodynamics. Mean transit time of water ranged from 12 to 20 d for 10-cm soil water to 225–334 d for groundwater, with tile drainage exhibiting a mean transit time of 245 d. Both two- and three-component hydrograph separation indicated that groundwater was the primary source of water to the tile drain followed by soil water. Tile drain hydrograph response (i.e., celerity) was largely controlled by antecedent wetness. Comparison of tile drain celerities and velocities revealed however varying mechanisms controlling hydrograph response across a range of environmental conditions. Data sets of both water and tracer flux were, thus, useful to track the spatiotemporal variability of water fluxes within and from the critical zone. Such data provide valuable information to improve the representation of critical zone processes in these landscapes within spatially distributed hydrological models.

Is the annual maximum leaf area index an important driver of water fluxes simulated by a land surface model in temperate forests?

In land surface models, vegetation is often described using plant functional types (PFTs), a classification that aggregates plant species into a few groups based on similar characteristics. Within-PFT variability of these characteristics can introduce considerable uncertainty in the simulation of water fluxes in forests. Our objectives were to (i) compare the variability of the annual maximum leaf area index (LAImax) within and between PFTs and (ii) assess whether this variability leads to significant differences in simulated water fluxes at a regional scale. We classified our study region in southwestern Quebec (Canada) into three PFTs (evergreen needleleaf, deciduous broadleaf, and mixed forests) and characterized LAImax using remotely sensed MODIS-LAI data. We simulated water fluxes with the Canadian Land Surface Scheme (CLASS) and performed a sensitivity analysis. We found that within-PFT variability of LAImax was 1.7 times more important than variability between PFTs, with similar mean values for the two dominant PFTs, deciduous broadleaf forests (6.6 m2·m−2) and mixed forests (6.3 m2·m−2). In CLASS, varying LAImax within the observed range of values (4.0–7.5 m2·m−2) led to changes of less than 2% in mean evapotranspiration. Overall, LAImax is likely not an important driver of the spatial variability of water fluxes at the regional level.

Simultaneous water and vapour transfer in an unsaturated mudstone in badlands terrain, southwestern Taiwan

AbstractThe simultaneous transfer of pore fluid and vapour was studied in the unsaturated shallow subsurface of a Plio‐Pleistocene marine mudstone badland slope in southwestern Taiwan during the dry season using field monitoring data and numerical simulations. Data from field monitoring show mass‐basis water contents of ~0.05 to ~0.10 that decrease towards the unsaturated ground surface and were invariant during the middle part of the dry season, except for daily fluctuations. In addition, the observed daily fluctuations in water content correlate with fluctuations in bedrock temperature, especially at depths of 2.5–5.0 cm. Periodic increases in water content occurred most notably during the day, when the bedrock temperature showed the greatest increase. Water contents then decreased to the previous state as bedrock temperature decreased during the night. Calculated vapour fluxes within the mudstone during the day increased up to 6 × 10−6–1 × 10−5 kg m−2 s−1, deriving a 0.01–0.02 increase in mass‐basis water content at 2.5 cm depth for a 12‐h period. This agrees with field monitoring data, suggesting that increases in water content occurred due to vapour intrusions into the bedrock. Pore water electrical conductivity (EC) showed periodic variations due to vapour intrusion, and gradually increased between the ground surface and depths of 2.5–5.0 cm. In contrast, pore water EC gradually decreased between 15 and 40 cm depth. Calculated water fluxes at depths of 2.5–40.0 cm varied from −4 × 10−6 to −2 × 10−9 kg m−2 s−1. These fluxes generated an increase in solute concentrations at the ground surface, with negative values of water flux indicating an upwards movement of water towards the surface. We show that the increase in solute content due to solute transfer from depth is highly dependent on variations in water flux with depth. © 2020 John Wiley & Sons, Ltd.

Temperature and electrical conductivity of water in Lake Nyos transmitted by an automatic observation buoy

An automatic observation buoy (AOB) was installed at Lake Nyos in March 2014. The temperature and electrical conductivity (EC) of lake water were continuously observed from March 10, 2014 to April 15, 2016. The thermocline and chemocline located deeper than −90 m subsided 15 m in the observation period due to the bottom water removal by the CO2 degassing pipes. The velocity of subsidence was estimated quantitatively by correlating the time variation of EC obtained by AOB and the depth profile of EC. The velocity of subsidence was not constant, namely, it was fast in dry season and slow in rainy season. The time variation in the velocity of subsidence can be attributed to the seasonal variation of water flux in the degassing pipes. Considering the water balance in the deep part of lake, the flux of ground water supplied to lake was estimated to be 6.5*106 (m3/year), which is comparable to the recharge rate of ground water within the catchment area surrounding Lake Nyos. Abrupt drops in temperature and conductivity were observed at −120 m in January 2016, when the temperature at -4 m reached 21.8 °C as the lowest value. The abrupt drops are due to the sinking of surface cold water.

Influence of hydrodynamic operating conditions on organic fouling of spiral-wound forward osmosis membranes: Fouling-induced performance deterioration in FO-RO hybrid system

The forward osmosis-reverse osmosis (FO-RO) hybrid process has been extensively researched as part of attempts to reduce the high energy consumption of conventional seawater reverse osmosis in recent years. FO operating conditions play a substantial role in the hybrid process, dictating not only the performance of the entire system but also the propensity for fouling, which deteriorates performance in long-term field operations. Therefore, determining the optimal FO operating conditions with regard to membrane fouling may promote sustainable operation through efficient fouling control. This study thus evaluated the influence of each hydrodynamic operating condition (feed flowrate, draw flowrate, and hydraulic pressure difference) and their synergistic effects on fouling propensity in a pilot-scale FO operation under seawater and municipal wastewater conditions. Fouling-induced variation in water flux, channel pressure drop, diluted concentration, and the resulting specific energy consumption (SEC) were comparatively analyzed and utilized to project performance variation in a full-scale FO-RO system. Fouling-induced performance reduction significantly varied depending on hydrodynamic operating conditions and the resultant fouling propensity during 15 days of continuous operation. A high feed flowrate demonstrated a clear ability to mitigate fouling-induced performance deterioration in all conditions. A high draw flowrate turned out to be detrimental for fouling propensity since its high reverse solute flux accelerated fouling growth. Applying additional hydraulic pressure during FO operation caused a faster reduction of water flux, and thus feed recovery and water production; however, these drawbacks could be compensated for by a 10% reduction in the required FO membrane area and an additional reduction in RO SEC.

A comparison of three models used to determine water fluxes over the Albany Thicket, Eastern Cape, South Africa

The Albany Thicket (AT) biome contains outstanding global biodiversity as well as the potential to achieve carbon credits associated with water-efficient Crasslucean acid metabolism (CAM). Understanding the water fluxes in the AT is crucial to determining carbon (C) sequestration rates and water-use efficiency. Despite large variation in water fluxes across the AT, only a few studies have been conducted in this region with their results validated against short periods of observed data. This study aims to evaluate three models of water fluxes over AT against data from an eddy covariance (EC) system active from October 2015 to May 2018. ET was modelled using the BioGeoChemistry Management (BGC-MAN) model, a biophysical model (Penman-Monteith-Leuning (PML)) and a remotely-sensed product (MOD16), and their results compared with that from the EC system. More than three decades of rainfall data from Climate Hazards Group InfraRed Precipitation with Station Data (CHIRPS) was used to assess some rainfall characteristics of the region. The mean annual rainfall is 404 mm and mean monthly rainfall ranges from 16.0–50.7 mm, with minima likely to occur in winter period (between May and July) and monthly maxima in the summer period (between October and March). Among the three hydrological years in this study, total ET for 2016-2017 exceeded rainfall received by about 7% which shows that AT is likely to be supported by groundwater at some point but this requires further investigations. Generally, the three models applied in this study performed reasonably well when compared with the measured ET. The cumulative ET from BGC-MAN was slightly higher than that from EC by 16% and 8% in 2015-2016 and 2017-2018 hydrological years respectively while PML was slightly lower by 3% and 17% in 2016-2017 and 2017-2018; additionally, MODIS was slightly lower by 14% and 7% in 2016-2017 and 2017-2018, respectively. However, the correlation between the ET from EC and simulated ET from the three models was significant at p < 0.01.

Pressure retarded osmosis coupled with activated sludge process for wastewater treatment: Performance and fouling behaviors

A novel hybrid technology integrating pressure retarded osmosis with activated sludge process (denoted as PRO-MBR) was proposed in this study for wastewater treatment. Here, performance and fouling behaviors of PRO-MBR were investigated. Excellent contaminants removal and power production were simultaneously achieved in the PRO-MBR. A significant drop of water flux in the PRO-MBR was mainly due to the severe fouling of the support layer in forward osmosis (FO) membrane including internal fouling and external fouling. Although the external fouling was identified to be the major type of fouling, the internal fouling dominated the overall decline of water flux. In addition, organic foulants and biofoulants were the dominant foulants for the external fouling while inorganic foulants were equal to organic foulants and biofoulants for the internal fouling. According to the variations of water flux in the PRO-MBR, the development of support layer fouling was divided into three stages.

Long-term performance and initial fouling evaluation of an open-loop plate and frame forward osmosis element using wastewater treatment plant secondary effluent as a feed solution

In this study, the long-term performance of a plate and frame forward osmosis (PFFO) process was systematically assessed through an element-scale system using secondary effluent from a full-scale wastewater treatment plant. To the best of our knowledge, this represents the first time long-term operation of an element-scale PFFO process has been performed with relatively stable operation, water flux, and contaminant rejection rates without physical or chemical cleaning. Seasonal variations in water flux, inlet pressure, and contaminants in the element-scale PFFO process were monitored during the 10 months of operation. The results showed that at the end of the operating period, there was a 52 % reduction in water flux compared to the initial value due to the effects of initial membrane fouling, while the transmembrane inlet pressure increased by approximately 0.2 bar. High DOC removal of over 90.7 % was obtained with the presence of humic-like and protein-like substances in the diluted draw solution. In addition, the hydrophilicity of the diluted draw solution increased by 40.8 %. After the process, the hydrophobicity of the membrane surface (contact angle) increased by 16°, and a large amount of multivalent ions were detected on fouled membrane surface (i.e., Al, Ca, Fe, and Si). The results of this element-scale PFFO process demonstrate that sustainable long-term operation can be achieved compared with spiral wound type FO elements owing to the low water flux reduction and high rejection rate of contaminants.

Modeling the impact of agricultural crops on the spatial and seasonal variability of water balance components in the Lake Tana basin, Ethiopia

AbstractThe Lake Tana basin hosts more than three million people and it is well known for its water resource potential by the Ethiopian government. The major economic activity in the region is agriculture, but the effect of agricultural crops on water resources is poorly understood. Understanding the crop water interaction is important to design proper water management plans. Therefore, the primary objective of this research is to investigate the effect of different agricultural crops on the spatial and seasonal variability of water balance components of Gilgelabay, Gumara, and Ribb catchment areas of Lake Tana basin, Ethiopia. To this end, the hydrologic model SWAT (Soil and Water Assessment Tool) was used to simulate the water fluxes between 1980 and 2014. The water balance components, which were mapped for each hydrologic response unit, indicated the spatial variations of water fluxes in the study. Cereal crops like teff and millet had significant effect in enhancing groundwater recharge, whereas leguminous crops like peas had significant impact in increasing runoff generation. Moreover, the model outputs showed that the total streamflow is dominated by baseflow and about 13%, 9%, and 7% of the annual rainfall goes to the deep aquifer system of Gilgelabay, Gumara, and Ribb catchment areas, respectively.

Modeling Investigation of Diurnal Variations in Water Flux and Its Components with Stable Isotopic Tracers

The isotopic compositions of water fluxes provide valuable insights into the hydrological cycle and are widely used to quantify biosphere–atmosphere exchange processes. However, the combination of water isotope approaches with water flux components remains challenging. The Iso-SPAC (coupled heat, water with isotopic tracer in soil–plant–atmosphere-continuum) model is a useful framework for simulating the dynamics of water flux and its components, and for coupling with isotopic fractionation and mixing processes. Here, we traced the isotopic fractionation processes with separate soil evaporation (Ev) and transpiration (Tr), as well as their mixing in evapotranspiration (E) for simulating diurnal variations of isotope compositions in E flux (δE). Three sub modules, namely isotopic steady state (ISS), non-steady-state (NSS), and NSS Péclet, were tested to determine the true value for the isotope compositions of plant transpiration (δTr) and δE. In situ measurements of isotopic water vapor with the Keeling-plot approach for δE and robust eddy covariance data for E agreed with the model output (R2 = 0.52 and 0.98, RMSD = 2.72‰, and 39 W m−2), illustrating the robustness of the Iso-SPAC model. The results illustrate that NSS is a better approximation for estimating diurnal variations in δTr and δE, specifically during the alternating periods of day and night. Leaf stomata conductance regulated by solar radiation controlled the diurnal variations in transpiration fraction (Tr/E). The study emphasized that transpiration and evaporation, respectively, acted to increase and decrease the δ18O of water vapor that was affected by the diurnal trade-off between them.

Use of remote sensing and long-term in-situ time-series data in an integrated hydrological model of the Central Kalahari Basin, Southern Africa

Distributed numerical models, considered as optimal tools for groundwater resources management, have always been constrained by availability of spatio-temporal input data. This problem is particularly distinct in arid and semi-arid developing countries, characterized by large spatio-temporal variability of water fluxes but scarce ground-based monitoring networks. That problem can be mitigated by remote sensing (RS) methods, which nowadays are applicable for modelling not only surface-water but also groundwater resources, through rapidly increasing applications of integrated hydrological models (IHMs). This study shows implementation of various RS products in the IHM of the Central Kalahari Basin (~200 Mm2) multi-layered aquifer system, characterized by semi-arid climate and thick unsaturated zone, both enhancing evapotranspiration. The MODFLOW-NWT model with UZF1 package, accounting for variably saturated flow, was set up and calibrated in transient conditions throughout 13.5 years using borehole hydraulic heads as state variables and RS-based daily rainfall and potential evapotranspiration as driving forces. Other RS input data included: digital-elevation-model, land-use/land-cover and soils datasets. The model characterized spatio-temporal water flux dynamics, providing 13-year (2002–2014) daily and annual water balances, thereby evaluating groundwater-resource dynamics and replenishment. The balances showed the dominant role of evapotranspiration in restricting gross recharge to only a few mm yr−1 and typically negative net recharge (median, −1.5 mm yr−1), varying from −3.6 (2013) to +3.0 (2006) mm yr−1 (rainfall of 287 and 664 mm yr−1 respectively) and implying systematic water-table decline. The rainfall, surface morphology, unsaturated zone thickness and vegetation type/density were primary determinants of the spatio-temporal net recharge distribution.

Storage, mixing, and fluxes of water in the critical zone across northern environments inferred by stable isotopes of soil water

AbstractQuantifying soil water storage, mixing, and release via recharge, transpiration, and evaporation is essential for a better understanding of critical zone processes. Here, we integrate stable isotope (2H and 18O of soil water, precipitation, and groundwater) and hydrometric (soil moisture) data from 5 long‐term experimental catchments along a hydroclimatic gradient across northern latitudes: Dry Creek (USA), Bruntland Burn (Scotland), Dorset (Canada), Krycklan (Sweden), and Wolf Creek (Canada). Within each catchment, 6 to 11 isotope sampling campaigns occurred at 2 to 4 sampling locations over at least 1 year. Analysis for 2H and 18O in the bulk pore water was done for &gt;2,500 soil samples either by cryogenic extraction (Dry Creek) or by direct equilibration (other sites). The results showed a similar general pattern that soil water isotope variability reflected the seasonality of the precipitation input signal. However, pronounced differences among sampling locations occurred regarding the isotopic fractionation due to evaporation. We found that antecedent precipitation volumes mainly governed the fractionation signal, temperature and evaporation rates were of secondary importance, and soil moisture played only a minor role in the variability of soil water evaporation fractionation across the hydroclimatic gradient. We further observed that soil waters beneath conifer trees were more fractionated than beneath heather shrubs or red oak trees, indicating higher soil evaporation rates in coniferous forests. Sampling locations closer to streams were more damped and depleted in their stable isotopic composition than hillslope sites, revealing increased subsurface mixing towards the saturated zone and a preferential recharge of winter precipitation. Bulk soil waters generally comprised a high share of waters older than 14 days, which indicates that the water in soil pores are usually not fully replaced by recent infiltration events. The presented stable isotope data of soil water were, thus, a useful tool to track the spatial variability of water fluxes within and from the critical zone. Such data provide invaluable information to improve the representation of critical zone processes in spatially distributed hydrological models.

Changes in streamflow contributions with increasing spatial scale in Thukela basin, South Africa

Sustainable management of river basins requires precise understanding of the origin and variability of water fluxes. Water samples were collected in Thukela Basin (30,000 km2), South Africa, over the 2012 rainy season, from fifteen 1 m2 runoff microplots (for OF), a 5-m deep piezometer (SW) and 20-m deep borehole (GW), in the basin headwater and nested catchment outlets (microcatchment, 0.23 km2; subcatchment, 1.20 km2; catchment, 9.75 km2; sub-basin, 253 km2). The water samples were analysed for Sodium (Na) and Silica (Si) concentrations using an inductively coupled-plasma emission spectrophotometry. End Member Mixing Analysis (EMMA), with Na and Si as tracers, was then used to quantify the water compartment contributions to river flow. The results showed a general decrease of unit-area runoff in downslope direction from 5.7 to 1.2 L m−2 day−1 at microplot and microcatchment level, respectively, to 1.4 L m−2 day−1 at the basin outlet. OF contributions averaged 61% at microcatchment, 79% at subcatchment, 40% at catchment, 78% at sub-basin and 67% at the basin outlet, which corresponded to 0.82, 0.26, 5 × 10−5, 2 × 10−3 and 9 × 10−5 L m−2 day−1, respectively. The respective SW contributions were 39% (0.38 L m−2 day−1), 18% (0.10 L m−2 day−1), 49% (5 × 10−5 L m−2 day−1), 15% (4 × 10−4 L m−2 day−1) and 33% (5 × 10−5 L m−2 day−1). GW contributions were much lower at all spatial scales, but showed a general increase with increasing contributing surface area from microcatchment to sub-basin outlet followed by a decrease to the basin outlet. The end-member contributions showed large spatial variations, hence longer-term research integrating more observation points is recommended to generate adequate data for development of prediction models for this important river basin. More research linking carbon, nutrient and pollutant fluxes to water dynamics is also recommended.

Detailed study of temperature-responsive composite membranes prepared by dip coating poly (2-ethyl-2-oxazoline) onto a ceramic membrane

Here, we report a reversible, thermo-responsive polymer-ceramic composite membrane that achieves opening and closing of pores by itself. This novel composite membrane was prepared by coating the polymer poly (2-ethyl-2-oxazoline) on ceramic membrane using the dip coating technique. Different parameters such as polymer concentration and dip coating time were considered while preparing the membrane. Special emphasis has been laid down on an extensive study of the physical and chemical properties of the membrane. Temperature responsiveness was utilized for studying the variation in water flux and protein rejection. It was found that at temperatures above LCST the flux achieved was highest at about 5.58 × 103L/hm2 than at temperatures below LCST.