Variations In Relative Intensities Research Articles

Improved microwave dielectric properties of LaZn1/2Ti1/2O3 through Y3+ substitution

LaZn1/2Ti1/2O3 is a double perovskite with promising microwave dielectric properties for applications towards dielectric resonators and antennas. Its dielectric properties can be enhanced through the substitution of suitable ions in either A- or B-sites. In this paper, we report a significant improvement in the quality factor (Q) by substituting Y3+ in the La site with a marginal reduction in dielectric constant (εr). A single phase is confirmed in XRD indicating the formation of La1-xYxZn1/2Ti1/2O3 (0 ≤ x ≤ 0.25) solid solutions. The substitution results in an expansion of lattice along the b direction while there is a contraction in both a and c directions, leading to a reduction in unit cell volume. The dielectric constant, εr, is observed to reduce from 33.4 to 29.6 due to the polarizability of A-site atoms. The temperature coefficient of resonant frequency (τf) increases with an increase in x which does not appear to correlate with reducing tolerance factor (t). This non-conventional behaviour of τf in this perovskite based solid solutions brings bond valence of O site (VO) into picture. VO appears to show competing effect on τf. The non-monotonic behaviour is observed in Q×f with a maximum value of 41,400 GHz at x = 0.15 and a sharp decline for x > 0.15. This observation is correlated with variations in the A-site bond valence (VA) and a long-range ordering (LRO) of B-site ions. LRO is associated with Ag mode at 710 cm−1 in the Raman spectra. The low frequency (< 250 cm−1) Raman modes shift to a higher frequency with the increase in Y3+. Y3+ substitution also induces lattice distortion which is discussed in terms of variations in FWHM and relative intensity of the Raman modes.

On the Measurements of the Surface-Enhanced Raman Scattering Spectrum: Effective Enhancement Factor, Optical Configuration, Spectral Distortion, and Baseline Variation

In this paper, a comprehensive theoretical framework for understanding surface-enhanced Raman scattering (SERS) measurements in both solution and thin-film setups, focusing on electromagnetic enhancement principles, was presented. Two prevalent types of SERS substrates found in the literature were investigated: plasmonic colloidal particles, including spherical and spheroid nanoparticles, nanoparticle diameters, and thin-film-based SERS substrates, like ultra-thin substrates, bundled nanorods, plasmonic thin films, and porous thin films. The investigation explored the impact of analyte adsorption, orientation, and the polarization of the excitation laser on effective SERS enhancement factors. Notably, it considered the impact of analyte size on the SERS spectrum by examining scenarios where the analyte was significantly smaller or larger than the hot spot dimensions. The analysis also incorporated optical attenuations arising from the optical properties of the analyte and the SERS substrates. The findings provide possible explanations for many observations made in SERS measurements, such as variations in relative peak intensities during SERS assessments, reductions in SERS intensity at high analyte concentrations, and the occurrence of significant baseline fluctuations. This study offers valuable guidance for optimizing SERS substrate design, enhancing SERS measurements, and improving the quantification of SERS detection.

Thermal Effects on the Quality Parameters of Extra Virgin Olive Oil Using Fluorescence Spectroscopy.

Extra virgin olive oil is one of the superlative due to its health benefits. In this work, the Fluorescence spectra of extra virgin olive oil (EVOO) from different olive growing regions of Pakistan and Al-Jouf region from the Kingdom of Saudi Arabia (KSA) were obtained. The emission bands depicted relative intensity variations in all non-heated and heated EVOO samples. Prominent emission bands at 385, 400, 435 and 470nm represent oxidized products of fatty acids, bands at 520 and 673nm has been assigned to beta carotene and chlorophyll isomers respectively. All EVOO samples collected from Al-Jouf region, KSA and from Pakistan (Loralai Baluchistan, Barani Agricultural Research Institute, Chakwal and Morgha Biodiversity Park, Rawalpindi) regions showed thermal stability. Other EVOO samples from Chaman Baluchistan and one sample from wild specie (Baluchistan) bought directly from farmers showed denatured spectra even without heating. Chemical characteristics of all EVOO samples changed significantly at 200°C. Relatively, EVOO samples from Al-Jouf showed more thermal stability which might be due to geographical distribution, environmental effects, genetic background and processing or storage conditions. These results demonstrated fluorescence spectroscopy as a quick, cost-effective and reliable approach to assess the quality and thermal stability of EVOO. These characteristics of fluorescence spectroscopy may lead to the development of portable device for the onsite monitoring of EVOO.

On the modulation/energy competing of Tb(III)/Eu(III) emission in microporous MOF host for peroxide recognition

Being an important chemical reagent having moderate oxidizability, peracitic acid (PAA) has been applied in modern industries and processing, as well as public safety. These versatile applications make PAA an important analyte to be precisely and sensitively detected. The present work chose the combination of rare-earth-based probe and a microporous host bio-MOF-1 ([Zn8(ad)4(BPDC)6O·2(Me2NH2)+]·G, ad = adenine, BPDC = 4,4′-biphenyl dicarboxylic acid, G = N,N-dimetylformamide and water). Two β-diketone ligands, 1,3-di(pyridin-3-yl)propane-1,3-dione (DPY) and 1,3-diphenylpropane-1,3-dione (DPP), were coordinated to Tb(III) and Eu(III) ions to form probe [RE(DPY/DPP)2]Cl which was loaded into bio-MOF-1 micropores with different loading contents via an ionic exchange operation. The resulting composite samples were fully characterized, including synthesis, morphology, composition, sensing performance and mechanism. The protonation/oxidization of DPY and DPP ligands adjusted their triplet energy level (T1) and consequently affected their energy transfer (ET) efficiency to RE ions, resulting in the variation of RE emission relative intensity. A new pathway for PAA optical sensing was thus proposed. Linear fitting equations were observed for DPY-based samples, showing fluorescence intensity ratio value of 8.80, response time of 9 s, and LOD of 8.08 μM within working region of 0–140 μM.

O2-induced emission color changing/sensing via the combination of red-emitting COF and blue-emitting halogen-bridging Cu(I) phosphor: In-situ synthesis and performance

Covalent organic frameworks (COFs) have shown virtues of structural diversity and porous diversity, due to their versatile organic building blocks. These advantages make COFs a promising host for O2 gas sensors. In this work, a porous COF (denoted as COF-X, X = Br or Cl) having halogen ions (Br or Cl ions) in its micropores was firstly synthesized as host, then Cu clusters [Cu2(PPh3)3X2] were in-situ synthesized. The obtained composite structure was discussed in detail focusing on its photophysical parameters and optical oxygen sensing performance. Probe doping ratio was determined as 2:1 (C162H120N18O12X4@C54H45X2Cu2P3, X = Br or Cl). Host COF-X showed red emission around 628 nm, while probe Cu2(PPh3)3X2 exhibited blue emission around 436 nm with lifetime of 5.21 μs and quantum yield of 0.41 under pure N2 atmosphere. Upon pure O2 atmosphere, probe Cu2(PPh3)3Br2 lifetime and quantum yield were decreased to 1.16 μs and 0.09. Probe emission intensity followed a linear calibration curve with maximum sensitivity of 20.25 (a.u.) and response/recovery time of 9/41 s. This sensitivity was by far the highest one among phosphorescent Cu(I)-based sensors. The relative emission intensity variation between dopant blue emission and host red emission led to an emission color change between blue (under pure N2 atmosphere) and red (under pure O2 atmosphere).

Characterizing spatial variations of PAH emission in the reflection nebula NGC 1333

ABSTRACT Infrared emission features at 3.3, 6.2, 7.7, 8.6, and 11.2 µm, attributed to polycyclic aromatic hydrocarbons (PAHs), show variations in relative intensity, shape, and peak position. These variations depend on the physical conditions of the photodissociation region (PDR) in which strong PAH emission arises but their relationship has yet to be fully quantified. We aim to better calibrate the response of PAH species to their environment using observations with matching apertures and spatial resolution. We present observations from the Field-Imaging Far-Infrared Line Spectrometer onboard the Stratospheric Observatory for Infrared Astronomy of the gas cooling lines [O i] 63, 146 µm and [C ii] 158 µm in the reflection nebula NGC 1333 and use archival dust continuum observations from the Photodetector Array Camera and Spectrometer (PACS) onboard Herschel. We employ PDR modelling to derive the physical conditions and compare these with the characteristics of the PAH emission as observed with the Infrared Spectrometer onboard Spitzer. We find distinct spatial characteristics for the various PAH spectral components. We conclude that the ionic bands (6.2, 7.7, 8.6, and 11.0) and the 7–9 µm emission are due to multiple PAH subpopulations and that the plateaus are distinct from the features perched on top. The 6–9 µm PAH emission exhibits a significant change in behaviour between the irradiated PDR and diffuse outskirts, confirming these bands arise from multiple PAH subpopulations with different underlying molecular properties. We find multiple promising relationships between PAH ratios and the far-ultraviolet radiation field strength but no clear correlations with the PAH ionization parameter.

Tuning CO2 sensing properties of HPTS along with newly synthesized coordination polymers (CPs)

Coordination polymers (CPs), new functional hybrid materials, have received important attention due to their structural features and many different applications such as gas storage, catalysis, energy storage, small molecule adsorption, luminescence, and chemical sensors. In this study, two newly synthesized metal-organic frameworks (MOFs); [Mn2(µ4-dmg)-(µ4-dmg)(µ-bipy)]n (CP1) and [Mn2(µ4-dmg)(µ4-dmg)(µ-dpeten)]n (CP2); were used for sensing of gaseous carbon dioxide with a spectrofluorometric method with a dye, 8-hydroxypyrene-1, 3, 6-trisulfonic acid (HPTS) as matrix additive material for the first time. The ion-pair form of the HPTS was used in the polymethyl methacrylate matrix as a thin film form. When the HPTS based sensing slides along with the CPs, resulted in many advances such as high relative signal change and larger linear response range, improved sensor dynamics, and higher sensitivity with respect to the additive-free form. More specifically, in the presence of silver nanoparticles (AgNPs), the variation in relative signal intensities of CP1 and CP2 doped HPTS sensing agents were measured as 60 and 40% for the concentration range of 0–10% pCO2, respectively. The aim of this study is to enhance the CO2 response of HPTS with doped CPs due to their useful attributes and potential applications containing selective gas absorption.

Mixed siliciclastic-carbonate deposition and cyclical evolution of the Upper Shahejie Formation and its impact on reservoir development in the Eocene Huanghekou Sag, Bohai Bay Basin, East China

We have systematically investigated a typical lacustrine mixed siliciclastic-carbonate sedimentary system in this study, which primarily deposited in the Eocene Upper Shahejie Formation (Es1 formation) of the Huanghekou Sag, Bohai Bay Basin. Using synthetic lithologic data sets, we summarized eight lithofacies from mixed siliciclastic-carbonate rocks and classified them into siliciclastic- and carbonate-dominated groups, indicating the variation of relative intensity between fluvial/deltaic process and carbonate productivity. Combining petrological and mineral component analysis, most lithofacies are compositionally replaced by micrite dolomite and show vertically different scales of cyclicity. The high-level cyclicity suggests the alternation between siliciclastic- and carbonate-dominated mixed rocks, whereas the lower level indicates interbedding of different dolomite-dominated lithofacies. The controlling factors on both levels are different. The higher level is probably controlled by climate changes, which finally resulted in the relative variations of siliciclastic supply, although the lower level of cyclicity changes more frequently and is considered to have been controlled by fluctuating hydrodynamic conditions. Typical mixed rock depositing patterns are summarized as the “sandwich type,” which are mainly distributed at siliciclastic-dominated sections and the “interbedded type” at carbonate-dominated sections. Besides, reservoir physical properties among lithofacies display significant differences as well, and the grain-supported framework of carbonate-dominated lithofacies suggests most constructive in keeping intergranular pores. The investigated lacustrine cyclical sedimentation in mixed siliciclastic-carbonate rocks has been less concerned in previous studies and may serve as a useful reference for lacustrine mixed rocks analysis in other rifted basins.

Impact of N+ ion implantation on the properties of ZnSe thin films

Ion implantation in II–VI semiconducting nanostructures has proven to be an effective tool in tailoring the properties of nanostructures, thus making them a prominent candidate to be used in solar cells, gas sensing, optoelectronic, catalytic and many more applications. The present study is aimed at N+ ion implantation effects on various properties of ZnSe thin films. First, a two-step synthesis was employed to synthesize ZnSe nanoflakes by solvothermal technique which were then drop casted onto glass substrate. The impact of 80 keV N+ ions on ZnSe thin films was explored for structural, morphological, elemental, optical and electrical analysis using characterization tools. The X-ray diffraction study revealed peak intensity variation without any shift in the reflex positions. However, the texture analysis depicted a relative intensity variation along with change in preferred orientation of planes with fluence. The optical study demonstrated a decrement in band gap. The I–V characteristics exhibited an intensification in the current values with the exposed fluence. This decline in band gap and increment in conduction values may be because of decrease in charge carrier scattering by the grain boundaries along with generation of higher number of electron–hole pairs with increasing fluence. The effects of implantation on sample characteristics are described in this contribution along with feasible reasons for observed changes in properties.

Grain boundary effect on structural, optical, and electrical properties of sol–gel synthesized Fe-doped SnO2 nanoparticles

Tin oxide (SnO2) and iron-doped tin oxide (Sn1 – x Fe x O2, x = 0.05 wt%, 0.10 wt%) nanoparticles are synthesized by the simple sol–gel method. The structural characterization using x-ray diffraction (XRD) confirms tetragonal rutile phases of the nanoparticles. The variations in lattice parameters and relative intensity with Fe-doping concentration validate the incorporation of iron into the lattice. The compressive strain present in the lattice estimated by using peak profile analysis through using Williamson–Hall plot also exhibits the influence of grain boundary formation in the lattice. The radiative recombination and quenching observed in optical characterization by using photoluminescence spectrum (PL) and the shift in the band gap estimated from UV-visible diffused reflectance spectrum corroborate the grain boundary influence. Raman spectrum and the morphological analysis by using a field emission scanning electron microscope (FESEM) also indicate the formation of grain boundaries. The compositional analysis by using energy dispersive x-ray spectrum (EDAX) confirms Fe in the SnO2 lattice. The conductivity studies exhibit that the impendence increases with doping concentration increasing and the loss factor decreases at high frequencies with doping concentration increasing, which makes the Sn1 – x Fe x O2 a potential candidate for device applications.

Tuning CO2 sensitivity of HPTS by ZnO and ZnO@Ag nanoparticles

Carbon dioxide sensing ability of 8-hydroxypyrene-1,3,6-trisulfonic acid trisodium (HPTS) has been improved by using nano-scale zinc oxide (ZnO) and silver coated zinc oxide (ZnO@Ag) particles. Sol-gel synthesized particles were characterized by XRD, XPS, SEM, FTIR and UV–vis spectroscopy. When the ion pair form of the HPTS embedded in ethyl-cellulose thin film along with the additives, resulted in many advances such as high relative signal change (I0/I100 = 116) and larger response range, improved sensor dynamics and higher sensitivity with respect to the additive-free form. More specifically, in the presence of the ZnO and ZnO@Ag nanoparticles, 80.0 and 97.0 % variation in relative signal intensity was observed for the concentration range of 0–20 % [CO2], respectively. The observed enhancement in the CO2 induced sensitivity of the HPTS can be attributed to the absorption-emission abilities of the ZnO and silver-coated-ZnO nanoparticles as well as their hygroscopic characteristics.

Evaluation of performance and validity limits of gas chromatography electron ionisation with Orbitrap detection for fatty acid methyl ester analyses.

While the GC-Orbitrap, marketed in 2015, represents a technological breakthrough in terms of sensitivity, resolution and mass stability, many studies have reported ion ratio modification in mass spectra using the standard 70 eV electron ionisation. We studied the influence of the acquisition and sample parameters leading to these modifications on fatty acid methyl esters (FAMEs). FAMEs showed that these variations in relative intensities of ions were related to the acquisition parameters such as the mass range and the offset values of the C-TRAP, but also directly related to the column concentration of the sample, and especially that it was molecule-dependent. Advantageously, it is possible to use this feature to promote the molecular ions of FAMEs sometimes not present in a spectrum under electron ionisation at 70 eV. The 70 eV electron ionisation mass spectra from the GC-Orbitrap were clearly molecule-dependent and could be due to metastable ions during storage states in the C-TRAP.

Charge Transfer, Complexes Formation and Furan Fragmentation Induced by Collisions with Low-Energy Helium Cations.

The present work focuses on unraveling the collisional processes leading to the fragmentation of the gas-phase furan molecules under the He+ and He2+ cations impact in the energy range 5–2000 eV. The presence of different mechanisms was identified by the analysis of the optical fragmentation spectra measured using the collision-induced emission spectroscopy (CIES) in conjunction with the ab initio calculations. The measurements of the fragmentation spectra of furan were performed at the different kinetic energies of both cations. In consequence, several excited products were identified by their luminescence. Among them, the emission of helium atoms excited to the 1s4d 1D2, 3D1,2,3 states was recorded. The structure of the furan molecule lacks an He atom. Therefore, observation of its emission lines is spectroscopic evidence of an impact reaction occurring via relocation of the electronic charge between interacting entities. Moreover, the recorded spectra revealed significant variations of relative band intensities of the products along with the change of the projectile charge and its velocity. In particular, at lower velocities of He+, the relative cross-sections of dissociation products have prominent resonance-like maxima. In order to elucidate the experimental results, the calculations have been performed by using a high level of quantum chemistry methods. The calculations showed that in both impact systems two collisional processes preceded fragmentation. The first one is an electron transfer from furan molecules to cations that leads to the neutralization and further excitation of the cations. The second mechanism starts from the formation of the He−C4H4O+/2+ temporary clusters before decomposition, and it is responsible for the appearance of the narrow resonances in the relative cross-section curves.

Indexing electron backscatter diffraction patterns with a refined template matching approach

Electron backscatter diffraction (EBSD) is a well-established method of characterisation for crystalline materials. Using this technique, we can rapidly acquire and index diffraction patterns to provide phase and orientation information about the crystals on the material surface. The conventional analysis method uses signal processing based on a Hough/Radon transform to index each diffraction pattern. This method is limited to the analysis of simple geometric features and ignores subtle characteristics of diffraction patterns, such as variations in relative band intensities. A second method, developed to address the shortcomings of the Hough/Radon transform, is based on template matching of a test experimental pattern with a large library of potential patterns. In the present work, the template matching approach has been refined with a new cross correlation function that allows for a smaller library and enables a dramatic speed up in pattern indexing. Refinement of the indexed orientation is performed with a follow-up step to allow for small alterations to the best match from the library search. The refined template matching approach is shown to be comparable in accuracy, precision and sensitivity to the Hough based method, even exceeding it in some cases, via the use of simulations and experimental data collected from a silicon single crystal and a deformed α-iron sample. The speed up and pattern refinement approaches should increase the widespread utility of pattern matching approaches.

Non-Boltzmann Luminescence inNaYF4:Eu3+: Implications for Luminescence Thermometry

Luminescence (nano)thermometry is an important technique for remote temperature sensing. The recent development of lanthanide-doped nanoparticles with temperature-dependent emission has expanded the field of applications, especially for ratiometric methods relying on the temperature variation of relative emission intensities from thermally coupled energy levels. Analysis and calibration of the temperature dependence is based on a Boltzmann equilibrium for the coupled levels. To investigate the validity of this assumption, we analyze and model thermal equilibration for Eu3+ D15 and D05 emission in NaYF4. The results show that for low Eu3+ concentrations, temperature-dependent multiphonon relaxation can accurately explain both the intensity ratio and emission decay dynamics. The analysis also reveals that a Boltzmann equilibrium is not realized in the temperature regime investigated (300-900 K). By increasing the Eu3+ concentration, cross relaxation between neighboring Eu3+ ions enhances D15-D05 relaxation rates and extends the temperature range in which emission intensity ratios can be used for temperature sensing (500-900+ K). The results obtained are important for recognizing, understanding, and controlling deviations from Boltzmann behavior in luminescence (nano)thermometry. By varying the dopant concentration, the range for accurate temperature sensing can be adjusted. These insights are crucial in the development and understanding of reliable temperature sensors.

Edge preserving suppression for depth estimation via comparative variation

Most applications in computer vision manage to suppress textures and noise while maintaining meaningful structure based on colour intensity variation, but it is intractable due to texture patterns or error. This study presents an edge-preserving suppression method for depth estimation. The authors formulate a functional energy function based on the relative total intensity and space variation, and they minimise the energy function via iteratively reweighted least squares. Assuming that textural edges most likely correspond to depth discontinuities, they exploit the comparative variations of the colour image to produce a more accurate depth map. The experimental results demonstrate the usefulness of the proposed approach, and show that texture patterns are suppressed while meaningful edges are preserved. According to the results of the depth acquisition methods, the proposed depth estimation methods generate the accurate and robust results.

High dose gamma ray exposure effect on the properties of CdSe nanowires

We report high dose gamma-ray (γ-ray) induced modifications incurred by polycrystalline cadmium selenide (CdSe) nanowires of 80nm diameter. The nanowires have been synthesized using polycarbonate template assisted electro-deposition technique. The samples were irradiated with 60Co γ-radiation at a dose rate of 4.533kGy/h for different time intervals with doses varying from 0 to 400kGy. The effects of γ rays on the structural, morphological, optical and electrical properties of nanowires are discussed. XRD patterns of as-synthesized and gamma irradiated CdSe nanowires did not show any phase transformations but the variation in relative intensity was observed. The crystallite size evaluated using Scherrer's formula was found to vary. The optical parameters were obtained using UV–vis spectrometer measurements of absorption. Band gap was found to decrease with γ irradiation up to a dose of 300kGy after which it was seen to increase. Refractive index and optical dielectric constants were also evaluated. Subjection of γ-radiation also brings about key changes in the electrical properties of CdSe nanowires. The attained data shows that the electrical conductivity varies with absorbed dose. The variations in the properties of CdSe nanowires can be considered as a consequence of ionization process, defect production and its annihilation.

Measurement of angular distributions of K x-ray intensity of Ti and Cu thick targets following impact of 10–25 keV electrons

We present new results on angular distributions of the relative intensity of Kα and Kβ x-ray lines of thick targets of Ti (Z=22) and Cu (Z=29) pure elements following impact of 10–25keV electrons. The angular measurements of the K x-radiations were accomplished by rotating the target surface with respect to the electron beam direction. The x-rays emerging from the target surface in reflection mode were detected by an energy dispersive Si P-I-N photodiode detector. The resulting variation of the relative intensity of the characteristic lines as a function of angle of detection and impact energy has been found to be anisotropic and it is considered to arise due to change in path lengths at a given incidence angle α for the photons generated by direct as well as by indirect K shell ionization processes. The measured angular variations of relative intensity of Kα and Kβ x-ray lines of both targets are found to increase by about 60–70% in going from θ=1050 to 1650 at a given impact energy; however there is a slight indication of impact energy dependence of Cu Kα x-ray line as also noted by the earlier workers. We compare the experimental results with those obtained by Monte Carlo simulations using PENELOPE calculations; the agreement between experiment and theory is found to be satisfactory within uncertainties involved in the measurements and the theoretical results.

Effect of structure, size and copper doping on the luminescence properties of ZnS

Luminescence properties of wurtzite and cubic forms of bulk ZnS have been investigated in detail and compared with that of ZnS nanoparticles. Blue emission observed in both hexagonal and cubic forms of undoped bulk ZnS is explained based on electron–hole recombination involving electron in conduction band and hole trapped in Zn2+ vacancies where as green emission arises due to electron hole recombination from Zn2+ and S2− vacancies. Conversion of wurtzite form to cubic form is associated with relative increase in intensity of green emission due to increased defect concentration brought about by high temperature heat treatment. Copper doping in ZnS, initially leads to formation of both CuZn and Cui (interstitial copper) centers, and latter to mainly CuZn centers as revealed by variation in relative intensities of blue and green emission from the samples.

Er3+-Tm3+-Yb3+:Gd2O3 upconverting phosphors for sensing and laser induced heating applications

This paper explores the near infrared (NIR) to visible frequency upconversion emissions in the Er3+−Tm3+−Yb3+ tri-doped Gd2O3 phosphors prepared by the combustion technique. The cubic phase formation and crystalline structure of the prepared materials has been examined with the help of X-ray diffraction study. The multicolour upconversion emission capability of the prepared materials has been confirmed under the excitation with 980-nm NIR laser source. The relative intensity variation corresponding to the transitions from the thermally coupled energy levels ( $^{2}\text{H}_{11/2}$ , $^{4}\text{S}_{3/2}$ ) to the ground level ( $^{4}\text{I}_{15/2}$ ) of Er3+ ions with pump power and temperature has been studied to investigate the optical temperature sensing ability of the prepared material. The maximum sensor sensitivity of the synthesized material reaches the value 0.0073 $\text{K}^{-1}$ at 443 K. The laser-induced heating capacity of the prepared material caused by laser excitation at different pump powers has been analyzed. The observed results support the utility of the prepared materials in optical temperature sensing and laser-induced heating along with additional capability for being used in making NIR to visible upconverter.