Considerable variations in microscopic and industrial components (ash, moisture, volatile matter, etc.) have been reported within identical coal seams. These disparities in coal quality and pore structure within the same coal seam profoundly affect the drainage of deep coalbed methane (DCBM). This study focuses on 22 coal samples collected from two wells in the Benxi Formation of the central and eastern parts of the Ordos Basin. First, the coal facies were determined for all samples using submicroscopic components, and then, the adsorption pore and seepage pore structures were studied through CO2/N2 adsorption and mercury intrusive tests. Subsequently, the study delves into the correlation between coal rank, coal facies, and the distribution of the pore structures across various pore sizes, elucidating the primary controlling factors influenced by coal rank and coal phase. The results are as follows: (1) For a given coal seam, R o,max exhibits minimal variation among the samples, which suggests R o,max is not the primary factor affecting pore structure. Conversely, the ash content occupies the pore space, thereby revealing a negative correlation between the ash content and adsorption pore volume (PV). (2) On the basis of the texture preservation index (TPI) and gelatification index (GI), coal facies were classified into moist forest swamp facies (type A), moist herbaceous swamp facies (type B), and water-covered herbaceous swamp facies (type C). Type A is characterized by higher TPI, lower GI, and ash content, whereas type C exhibits lower TPI, higher GI, and ash content. (3) Type A samples, with the lowest ash content, display larger PV and specific surface area (SSA) compared with type B, while type C has the lowest values. Type C, with the highest vitrinite content, predominantly consists of semibright and bright coal, prone to microcracks, which results in a higher seepage PV compared with types A and B. (4) The coal facies represent variations in ash content and microscopic components, which significantly impacts both adsorption and seepage pores. Moist forest swamp facies samples are characterized by micropore development and the highest content of adsorbed gas. Herbaceous swamp facies samples display macropore development and the highest content of free gas.