Water-vapor Interface Research Articles

Plausible Photomolecular Effect and Microwave in Phase Transition of Water as a New Dawn for Renewable Energy and Ensemble Holistic Approach to Health Management

Interaction among light and water molecules have baffled scientists for many decades, and even centuries. In this regards, photons in the visible spectrum, where bulk water normally doesn't absorb light, can surprisingly cleave off large water clusters from the water-vapor interface, according to a recent study by Tu and Chen [2]. This discovery, termed the "photomolecular effect," opens exciting possibilities for not only revolutionizing renewable energy but also paving the way for a more integrated-ensemble approach to health management [1-3]. In a sense, other than with green or red LED, we can also introduce low-intensity laser to alter water molecule, as we discussed earlier in this journal [6, 7].

Unsaturation triggers specific adsorption performance of water films in the clay nanopores

Soil is typically unsaturated, with water films covering the soil particles playing a crucial role in soil mechanics, structure, and element transport. However, the unusual behavior of these water films and the underlying mechanisms are not yet fully understood. This study, which used molecular dynamics methods, sheds light on the distinct interactions between water films and clay surfaces under unsaturation. At the water-mineral interface, water molecules formed a layered structure, while they rearranged as a meniscus as the unsaturation extent increased. On the other hand, unsaturation had a significant impact on the location of water molecules at the water-vapor interface, but only a limited effect at the water-mineral interface. The water’s orientational ordering and hydrogen bonding interactions were significantly affected by changes in relative humidity (RH). Based on the distance-dependent diffusion coefficient, the water molecules within the water film were classified into three types: WT1 (< 5 Å) had faster diffusivity at higher RH, WT2 (5–6 Å) had comparable diffusivity at any RH, and WT3 (> 6 Å) had faster diffusivity at intermediate RH. This classification was supported by the retention dynamics analysis. The specific behaviors mentioned above, which are associated with unsaturation, are closely linked to Na+ hydration. This is because the interaction between water and Na+ is more pronounced than the interaction between water and minerals or Cl−. The results indicate that unsaturation triggers specific adsorption behaviors of water films that cover the clay surfaces. These behaviors should be considered in interfacial processes and environmental engineering.

Spontaneous Appearance of Triiodide Covering the Topmost Layer of the Iodide Solution Interface Without Photo-Oxidation.

Ions containing iodine atoms at the vapor-aqueous solution interfaces critically affect aerosol growth and atmospheric chemistry due to their complex chemical nature and multivalency. While the surface propensity of iodide ions has been intensely discussed in the context of the Hofmeister series, the stability of various ions containing iodine atoms at the vapor-water interface has been debated. Here, we combine surface-specific sum-frequency generation (SFG) vibrational spectroscopy with ab initio molecular dynamics simulations to examine the extent to which iodide ions cover the aqueous surface. The SFG probe of the free O-D stretch mode of heavy water indicates that the free O-D group density decreases drastically at the interface when the bulk NaI concentration exceeds ∼2 M. The decrease in the free O-D group density is attributed to the spontaneous appearance of triiodide that covers the topmost interface rather than to the surface adsorption of iodide. This finding demonstrates that iodide is not surface-active, yet the highly surface-active triiodide is generated spontaneously at the water-air interface, even under dark and oxygen-free conditions. Our study provides an important first step toward clarifying iodine chemistry and pathways for aerosol formation.

Mechanistic Insights into the Adsorption of Monoclonal Antibodies at the Water/Vapor Interface.

Monoclonal antibodies (mAbs) are active components of therapeutic formulations that interact with the water-vapor interface during manufacturing, storage, and administration. Surface adsorption has been demonstrated to mediate antibody aggregation, which leads to a loss of therapeutic efficacy. Controlling mAb adsorption at interfaces requires a deep understanding of the microscopic processes that lead to adsorption and identification of the protein regions that drive mAb surface activity. Here, we report all-atom molecular dynamics (MD) simulations of the adsorption behavior of a full IgG1-type antibody at the water/vapor interface. We demonstrate that small local changes in the protein structure play a crucial role in promoting adsorption. Also, interfacial adsorption triggers structural changes in the antibody, potentially contributing to the further enhancement of surface activity. Moreover, we identify key amino acid sequences that determine the adsorption of antibodies at the water-air interface and outline strategies to control the surface activity of these important therapeutic proteins.

THE PREPARATION OF NANOPARTICLE FILMS BASED ON LIGHT WELDING TECHNOLOGY

Continuous improvements in scientific research methods have led to increasingly in-depth technological applications of nanomaterials. Currently, research on nanomaterials is no longer limited to analyzing their physical properties, but also focuses on ways to achieve efficient and low-cost nanomaterial synthesis. Nanoparticle films (NFs) are a type of nanomaterial that can be applied in multiple fields. In this study, we investigated ways to improve the self-assembly technology at the water-vapor interface using light welding (LW) technology in order to enhance the mechanical strength and achieve low-cost nanomaterial preparation of high conductivity and flexible metal NFs. The results showed that the resistance of NFs significantly decreased after improving the self-assembly technology at the water-vapor interface using the LW technology. After 60 minutes of light treatment, the resistance of silver NFs decreased by about 53 &amp;#937; and the resistance of the gold NFs decreased by about 9 &amp;#937;. After photo-welding treatment, the catalytic activity of the self-supporting porous gold film was the highest with a peak current density of 24.6 &amp;mu;A/cm&lt;sup&gt;2&lt;/sup&gt;. The results obtained in this research study can be employed to improve the preparation technology of fluid self-assembled nanomaterials. LW technology can be utilized to achieve low-cost manufacturing of nanomaterials with high strength and expand the application field of NFs.

Energetic description of the liquid-vapor interface of water with organic coating molecules

In situ measurements revealed the presence of a myriad of organic chemical compounds in cloud droplets. Among them, a significant fraction is composed of polar or amphiphilic compounds and these...

Dynamics of large cavity induced by valve closure in an undulating pipeline

The dynamics of large cavity and the accompanied water column separation and rejoining induced by fast closing of a butterfly valve in an undulating pipeline system are investigated in this study. The three-dimensional computational fluid dynamics numerical simulations are performed using a newly developed interfacial surface tension-based model (ISTM) that accounts for the surface tension effect on large cavities. The applicability of the ISTM model is validated with the experimental data, showing better accuracy in predicting pressure fluctuations and cavity evolutions than three typical cavitation models. Differences in cavitation characteristics are observed between upstream and downstream of the valve. Upstream the valve, cavitation primarily appears at the pipe top, with the vapor volume fraction varying sharply due to the rarefaction pressure waves (maximum value of 0.0073). Downstream the valve, the complete water-column separation occurs, and vapor volume fraction changes slowly correspond with the growth and collapse of the large cavity (maximum value of 0.647). The maximum length of the large cavity can reach about six times the pipe diameter, with a minimum water vapor interface angle of 16°. The cavitation evolution displays a transition from a clustered inception to a sheet-like growth and collapse pattern. These findings contribute to the design and operation guidance for complex hydraulic systems during transient processes.

Adsorption of Mixed Dispersions of Silica Nanoparticles and an Amphiphilic Triblock Copolymer at the Water–Vapor Interface

This study investigates the surface modification of hydrophilic silica nanoparticles by non-chemical adsorption of an amphiphilic triblock copolymer, Pluronic F-127, and elucidates its influence on the interfacial dispersion properties. The interaction between Pluronic F-127 and silica nanoparticles drives the formation of copolymer-decorated particles with increased hydrodynamic diameter and reduced effective charge as the copolymer concentration increases, while the opposite effect occurs as the particle concentration increases at a fixed polymer concentration. This indicates that increasing the copolymer concentration leads to an increase in the coating density, whereas increasing the particle concentration leads to a decrease. This is of paramount importance for modulating the reorganization of the Pluronic F-127 shell upon adsorption at fluid–fluid interfaces and, thus, the adsorption of the decorated nanoparticles at the interface and the rheological properties of the obtained layers. In fact, the relationship between copolymer concentration and interfacial tension, as well as the mechanical response of the interface, mirrors the patterns observed in Pluronic F-127 solutions, and only a shift mediated by the Pluronic F-127 concentration is found. This suggests that the presence of particles limits the space available for Pluronic F-127 molecules to reorganize at the interface but does not significantly affect the interfacial behavior of the particle-laden interface.

Specific Ion Effects at the Vapor-Formamide Interface: A Reverse Hofmeister Series in Ion Concentration Depth Profiles.

Employing neutral impact collision ion scattering spectroscopy (NICISS), we have directly measured the concentration depth profiles (CDPs) of various monovalent ions at the vapor-formamide interface. NICISS provides CDPs of individual ions by measuring the energy loss of neutral helium atoms backscattered from the solution interface. CDPs at the vapor-formamide interface of Cl-, Br-, I-, Na+, K+, and Cs+ are measured and compared to elucidate the interfacial specific ion trends. We report a reverse Hofmeister series in the presence of inorganic ions (anion and cation) at the vapor-formamide interface relative to the water-vapor interface, and the CDPs are found to be independent of the counterion for most ions studied. Thus, ions at the surface of formamide follow a "Hofmeister paradigm" where the counterion does not impact the ion series. These specific ion trends are complemented with surface tension and X-ray absorption near-edge structure (XANES) measurements on formamide electrolyte solutions.

Early monitoring of pore wetting in membrane distillation using ultrasonic time-domain reflectometry (UTDR)

Pore wetting induced by surfactants and salt scaling is a major obstacle to the industrial application of membrane distillation (MD). Identifying the transition of wetting stages and achieving early monitoring of pore wetting are crucial for wetting control. Herein, we made a pioneering attempt to use ultrasonic time-domain reflectometry (UTDR) technique to non-invasively detect the pore wetting in a direct contact MD, and explain the UTDR waveform with the help of optical coherence tomography (OCT) imaging. The results showed that the water–vapor interface had a strong reflection to ultrasound (reflection coefficient = 0.9995), while the water-membrane and water-scaling layer interfaces showed relatively weak reflection. Therefore, UTDR could effectively detect the movement of water–vapor interface with the low interference from the signals generated by the membrane and scaling layer. For the surfactant-induced wetting, the occurrence of wetting could be successfully detected by the right-shift in phase and the reduction in amplitude of the UTDR waveform. Moreover, the wetting depth could be accurately calculated by the time of flight (ToF) and ultrasonic velocity. For scaling-induced wetting, the waveform slightly shifted to the left at the beginning due to the growth of scaling layer, then to the right because the left-shift was surpassed by the right-shift of the waveform caused by pore wetting. Both for the surfactant- and scaling-induced wetting, the variation of the UTDR waveform was sensitive to wetting dynamics, and the right-shift of phase and the reduction in amplitude of the waveform could act as early monitoring signals to the occurrence of wetting.

Relevance of Surface Adsorption and Aqueous Complexation for the Separation of Co(II), Ni(II), and Fe(III)

During the solvent extraction of metal ions from an aqueous to an organic phase, organic-soluble extractants selectively target aqueous-soluble ions for transport into the organic phase. In the case of extractants that are also soluble in the aqueous phase, our recent studies of lanthanide ion-extractant complexes at the surface of aqueous solutions suggested that ion-extractant complexation in the aqueous phase can hinder the solvent extraction process. Here, we investigate a similar phenomenon relevant to the separation of Co(II), Ni(II), and Fe(III). X-ray fluorescence near total reflection and tensiometry are used to characterize ion adsorption behavior at the surface of aqueous solutions containing water-soluble extractants, either bis(2-ethylhexyl) phosphoric acid (HDEHP) or 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEHEHP), as well as adsorption to a monolayer of water-insoluble extractant dihexadecyl phosphoric acid (DHDP) at the aqueous-vapor interface. Competitive adsorption of Ni(II) and Fe(III) utilizing either HDEHP or DHDP illustrates the essential feature of the recent lanthanide studies that the ion, which is preferentially extracted in liquid-liquid extraction, Fe(III), is found preferentially adsorbed to the water-vapor interface only in the presence of the water-insoluble extractant DHDP. A more subtle competition produces comparable adsorption behavior of Co(II) and Ni(II) at the surfaces of both HDEHP- and HEHEHP-aqueous solutions in spite of the known preference for Co(II) under solvent extraction conditions. Comparison experiments with a monolayer of DHDP reveal that Co(II) is preferentially adsorbed to the surface. This preference for Co(II) is also supported by molecular dynamics simulations of the potential of mean force of ions interacting with the soluble extractants in water. These results highlight the possibility that complexation of extractants and ions in the aqueous phase can alter selectivity in the solvent extraction of critical elements.

Intermolecular forces at ice and water interfaces: Premelting, surface freezing, and regelation.

Using Lifshitz theory, we assess the role of van der Waals forces at interfaces of ice and water. The results are combined with measured structural forces from computer simulations to develop a quantitative model of the surface free energy of premelting films. This input is employed within the framework of wetting theory and allows us to predict qualitatively the behavior of quasi-liquid layer thickness as a function of ambient conditions. Our results emphasize the significance of vapor pressure. The ice-vapor interface is shown to exhibit only incomplete premelting, but the situation can shift to a state of complete surface melting above water saturation. The results obtained serve also to assess the role of subsurface freezing at the water-vapor interface, and we show that intermolecular forces favor subsurface ice nucleation only in conditions of water undersaturation. We show that ice regelation at ambient pressure may be explained as a process of capillary freezing, without the need to invoke the action of bulk pressure melting. Our results for van der Waals forces are exploited in order to gauge dispersion interactions in empirical point charge models of water.

Comment on "Liquid-Gas Interface of Iron Aqueous Solutions and Fenton Reagents".

A recent Letter in this Journal (Gladich et al. J. Phys. Chem. Lett. 13, 2994-3001) reported that photoelectron spectroscopy could not detect any products on the surface of aqueous Fe2+ jets dosed with gaseous hydrogen peroxide. The Letter however concluded that Fe(aq)2+ ions react with H2O2(g) at the water-vapor interface to produce the same Fe3+ + HO• products as their reaction with H2O2(aq) in bulk water. We argue that this conclusion is untenable because nothing can be asserted about undetected species.

Hierarchical liquid marbles formed using floating hydrophobic powder and levitating water droplets

HypothesisLiquid marbles i.e. droplets coated by hydrophobic particles may be formed not only on the solid substrates but also on the floating layers of hydrophobic powders such as fluorinated fumed silica or polytetrafluoroethylene. ExperimentsFormation and growth of liquid marbles on fluorinated fumed silica or polytetrafluoroethylene powder floating on a heated water-vapor interface is reported. Marbles emerge from condensation of water droplets levitating above the powder layer. FindingsThe kinetics of the growth of droplets is reported. Growth of droplets results from three main mechanisms: water condensation, absorption of small droplets and merging of droplets with neighboring ones. Growing droplets are coated with the hydrophobic powder, eventually giving rise to the formation of stable liquid marbles. Formation of hierarchical liquid marbles is reported. Growth of liquid marbles emerging from water condensation follows the linear temporal dependence. A phenomenological model of the liquid marble growth is suggested.

Tuning Contact Angles of Aqueous Droplets on Hydrophilic and Hydrophobic Surfaces by Surfactants.

Adsorption of small amphiphilic molecules occurs in various biological and technological processes, sometimes desired while other times unwanted (e.g., contamination). Surface-active molecules preferentially bind to interfaces and affect their wetting properties. We use molecular dynamics simulations to study the adsorption of short-chained alcohols (simple surfactants) to the water–vapor interface and solid surfaces of various polarities. With a theoretical analysis, we derive an equation for the adsorption coefficient, which scales exponentially with the molecular surface area and the surface wetting coefficient and is in good agreement with the simulation results. We apply the outcomes to aqueous sessile droplets containing surfactants, where the competition of surfactant adsorptions to both interfaces alters the contact angle in a nontrivial way. The influence of surfactants is the strongest on very hydrophilic and hydrophobic surfaces, whereas droplets on moderately hydrophilic surfaces are less affected.

A New Turbulent Viscosity Correction Model With URANS Solver for Unsteady Turbulent Cavitation Flow Computations

Abstract Due to the ignorance of the effect of the water–vapor interface on the cavitation flow field, the standard k–ε turbulence model (ST model) may overestimate the turbulent viscosity. It is unable to simulate cavitation shedding, especially at small attack angles of a hydrofoil. In the present investigation, a turbulent viscosity correction model is proposed to dampen the turbulent viscosity at the water–vapor interface. Cavitation flow around a NACA0009 truncated hydrofoil with a 2.5 deg angle of attack is used to demonstrate the effect of correction. The results show that the interface effect-based correction model (IE model) can both predict the pressure distribution on the suction surface of the hydrofoil with experimental data and the re-entrance jet in the leading-edge cavitation shedding. The region of the IE model influenced concentrates on the water–vapor interface and intensifies the vortex strength, which directly enhances the formation of a horseshoe vortex. The reduction of turbulent viscosity by the IE model reduces the resistance to the development of a re-entrance jet. The shear stress plays an important role in the shedding of the attached cavity bubble. The increase of shear force in the leading-edge cavitation occurs with the re-entrance of water and the main shear flow concentrates on the middle of the cavity bubble. This paper therefore presents a new method of numerical simulation of cavitation flow in engineering applications.

Flexible MXene-based Janus porous fibrous membranes for sustainable solar-driven desalination and emulsions separation

Sustainable solar energy driven seawater desalination technology is currently deemed as a promising pathway to overcome the shortage of freshwater resources, but solar water evaporation material suffers from serious salt-fouling, low freshwater yield, and poor long-term performance in seawater. Herein, a Janus photothermal porous fibrous membrane, composed of hydrophobic MXene/Poly(dimethylsiloxane) coatings and a hydrophilic polylactic acid/TiO2 nanofluids porous fibrous membrane, was prepared. During the solar-driven seawater desalination process, the hydrophilic fibrous membrane, functioned as salt-rejection barrier, induced by TiO2 nanofluids and transport seawater to the surface through its microporous channels; the MXene/PDMS coatings acted as a photothermal layer and generated localized heat at the water-vapor interface upon light irradiation. The solar-thermal test results show that, the Janus porous fibrous membrane displays stable solar-thermal conversion efficiency of 60%, freshwater yield of 1 kg m-2 h-1 and low ion concentration (≤1 ppm) under 1 sun irradiation in direct contact mode, which is superior to other literatures reported. With synergistic effect of TiO2 nanofluids and MXene, the Janus fibrous membrane exhibits a high salt rejection rate of 99.95%, and antibacterial activity as high as of 100%. Notably, benefiting from opposite wettability of Janus porous fibrous membrane, the as-prepared membranes also display excellent separation flux and high separation accuracy (>99.95%) in various surfactant-stabilized oil/water emulsions. It is anticipated that this versatility of Janus porous fibrous membrane has excellent photothermal conversion capability and separation properties, making it have great application potential in using sustainable solar energy to collect freshwater from seawater, medical service wastewater and other application in environmental protection.

Unraveling the Kinetics and Mechanism of Surfactant-Induced Wetting in Membrane Distillation: An In Situ Observation with Optical Coherence Tomography.

In this study, we performed a direct contact membrane distillation and successfully demonstrated the non-invasive imaging of surfactant-induced wetting using optical coherence tomography. This method enabled us to investigate the wetting kinetics, which was found to follow a "three-region" relationship between the wetting rate and surfactant concentration: the (i) nonwetted region, (ii) concentration-dependent region, and (iii) concentration-independent region at low, intermediate, and high surfactant concentrations, respectively. This wetting behavior was explained by the "autophilic effect", i.e., the wetting was caused by the transfer of surfactants from the water-vapor interface to the unwetted membrane and rendered this membrane hydrophilic, and then the wetting frontier moved forward under capillary forces. At region-(i), the surfactant concentration in the water-vapor interface (Clv) was too low to make the unwetted membrane sufficiently hydrophilic; thereby, the membrane could not be wetted. At region-(ii), due to the fast adsorption of the surfactant on the newly wetted membrane, the wetting rate was determined by the advection/diffusion of surfactants from the feed stream. Consequently, the wetting rate increased with the increases in the water flux and surfactant concentration. At region-(iii), the advection/diffusion provided excess surfactants for adsorption, and thus Clv reached its upper limit (maximum surface excess) and the wetting rate leveled off.

Adsorption of Single and Multiple Graphene-Oxide Nanoparticles at a Water-Vapor Interface.

The adsorption of graphene-oxide (GO) nanoparticles at the interface between water and vapor was analyzed using all-atom molecular simulations for single and multiple particles. For a single GO particle, our results indicate that the adsorption energy does not scale linearly with the surface coverage of oxygen groups, unlike typically assumed for Janus colloids. Our results also show that the surface activity of the particle depends on the number of surface oxygen groups as well as on their distribution: for a given number of oxygen groups, a GO particle with a patched surface was found to be more surface active than a particle with evenly distributed groups. Then, to understand what sets the thickness of GO layers at interfaces, the adsorption energy of a test GO particle was measured in the presence of multiple GO particles already adsorbed at the interface. Our results indicate that in the case of high degree of oxidation, particle-particle interactions at the water-vapor interface hinder the adsorption of the test particle. In the case of a low degree of oxidation, however, clustering and stacking of GO particles dominate the adsorption behavior, and particle-particle interactions favor the adsorption of the test particle. These results highlight the complexity of multiple particle adsorption and the limitations of single-particle adsorption models when applied to GO at a relatively high surface concentration.

Heterogeneous assembly of water from the vapor phase-Physical experiments and simulations with binding trifunctional organosilanes at the vapor/solid interface.

A trace amount of interfacial water is required to initiate hydrosilation reactions of trifunctional organosilanes to form surface assemblies. In recent studies, we have learned that water also has a critical role in directing molecular placement on surfaces because water can react with silicon to provide oxygenated sites for surface binding. Consequently, the wettability nature of substrates influences the placement and density of organosilane films formed by vapor-phase reactions. Nanopatterning protocols were designed using vapor-phase organosilanes and colloidal lithography to compare the wettability differences of hydrophilic mica(0001) compared to relatively hydrophobic Si(100) as a strategy for tracking the location of water on surfaces. The competition between hydrophobic and hydrophilic domains for the adsorption and coalescence of water condensed from vapor can be mapped indirectly by mapping the organosilanes, which bind to water at the solid interface, using atomic force microscopy. Trifunctional octadecyltrichlorosilane (OTS) was used as a marker molecule to map out the areas of the surface where water was deposited. The effect of systematic changes in film thickness and surface coverage of OTS was evaluated at the vapor/solid interface by adding an incremental amount of water to sealed reaction vessels to wet the surface and assessing the outcome after reaction with vapor-phase trichlorosilane. Reactive molecular dynamics simulations of the silicon-water vapor interface combined with electronic structure calculations of oxygenated silicon clusters with methyltrichlorosilane provided insight of the mechanism for surface binding, toward understanding the nature of the interface and wettability factors, which influence the association and placement of silane molecules on surfaces.