Evaporation Behavior Research Articles

Antimony Vaporization and Condensation in Simulated Flash Smelting Off-Gas Train Conditions

AbstractAntimony is one of the most deleterious impurity elements in copper smelting and has a strong tendency to vaporize in the smelting furnace resulting in an enrichment of antimony in smelter flue dusts. The vaporization and condensation behavior of antimony species was studied in dust-free conditions simulating the off-gas train of a Flash Smelting Furnace at temperatures below 1273 K (1000 °C). The influences of the oxygen partial pressure and the condensate formation temperature on the characteristics of the precipitated antimony species were determined. It was found that practically all the vaporized antimony species precipitated between 853 K and 546 K (580 °C and 273 °C) and that a higher oxygen partial pressure favored precipitation at higher temperatures. The formation of antimony sulfate, which thermodynamically is the most stable antimony species in the studied conditions at temperatures below approximately 723 K (450 °C), was found to be kinetically constrained and the vaporized antimony species precipitated as oxides or sulfides depending on the oxygen partial pressure and the precipitate formation temperature.

The influence of impurities on the evaporation behavior of Po from liquid Pb–Bi eutectic at high temperatures

AbstractThis study presents an in-depth analysis of the polonium evaporation from high-energy and high-intensity proton-irradiated liquid lead-bismuth eutectic. The applied experimental conditions closely mimic those encountered within an accelerator-driven nuclear reactor, particularly focusing on the interaction of other impurities with polonium. Utilizing proton-irradiated lead-bismuth eutectic with an impurity spectrum similar to that of a real reactor, this research establishes reliable data for the polonium evaporation in the presence of said impurities, employing the transpiration method. The results agree well with those of prior model experiments using pure lead-bismuth eutectic. This indicates that the other coexisting impurities have a negligible impact on the polonium evaporation. The good agreement of the experimental values with literature data emphasizes the reliability of the applied methods and the robustness of the current understanding. These findings have significant implications for the operation and safety assessment of heavy metal-cooled nuclear reactors and support the advancement of Generation IV accelerator-driven systems.

Experimental Study on Evaporation and Ignition Behavior of RP-3 Fuel with Different Leakage Volumes on Hot Surface

ABSTRACT Fire accidents caused by fuel leakage to hot surfaces are of significant concern in the aerospace domain due to their potential for severe consequences. This paper investigates the evaporation and ignition characteristics of fuel leakage to a hot surface through a series of experiments with different volumes of RP-3 droplets. The evolution patterns of evaporation lifetime, ignition position, and ignition delay time are examined. The results show that within the surface temperature range of 500–700°C, the fuel droplets of all volumes almost immediately reach the film boiling state upon contact with the hot surface. The droplets move erratically across the surface, changing shape from irregular to elliptical and finally to spherical. The evaporation lifetime decreases with increasing hot surface temperature. The occurrence of ignition is stochastic, and the ignition probability rises with the hot surface temperature, while the minimum ignition temperature decreases with the increase of fuel volume. The movement of the fuel droplets in the film boiling state leads to the irregularity of the ignition position. Additionally, the ignition delay time decreases with an increase in the temperature of the hot surface. The relationship between ignition delay time and surface temperature in the film boiling state is discussed in the context of the vapor plume model and boiling heat transfer analysis.

Analysis of group evaporation characteristics of droplet clusters in an evaporating spray

Droplet clustering in sprays refers to the dynamic evolution of highly concentrated regions due to the preferential accumulation of the polydisperse droplets in the turbulent airflow entrained by the spray. In the current study, we aim to experimentally investigate the collective vaporization of the droplets in droplet clusters in an air-assisted acetone spray characterized by the Group number, $G$ . The magnitude of $G$ depends on the cluster length scale and interdroplet spacing, and it indicates the vaporization mode that may vary from the isolated mode ( $G \ll 1$ ) to external group mode ( $G \gg 1$ ). The droplet measurements were obtained under atmospheric conditions at different axial and radial locations within the spray. Application of the Voronoi analysis to particle image velocimetry images of the spray droplets facilitated the identification and characterization of the droplet clusters, which allowed the measurement of $G$ for each cluster. The results highlighted that multiscale clustering of the evaporating droplets leads to multimode group evaporation of the clusters (characterized by a wide range of $G$ : 0.001–10). The trend of interdroplet spacing versus cluster area allowed the classification of the droplet clusters into small-scale clusters (which are of the order of the Kolmogorov length scale) and large-scale clusters (that scale with the large-scale turbulent eddies), that are found to exhibit distinct group evaporation behaviour. A theoretical model is invoked to correlate $G$ with the droplet evaporation rate for individual clusters, and some interesting observations are identified, which are explained in the paper.

Separation of radioactive isotope 227Ac from LaBr3 via vacuum evaporation for low-background scintillating detectors

Both radioactive isotopes 138La and 227Ac in LaBr3:Ce crystal typically produce considerable intrinsic background signals, and thus hinder their applications with low count rates. Since the complete separation of 138La is almost impossible, the contamination of 138La is stubbornly present in all La-halide based scintillators. In this study, an efficient purification protocol based on vacuum distillation was developed to separate 227Ac from feedstock and reduce intrinsic background signal at 1.6–3 MeV introduced by 227Ac in LaBr3:Ce crystals. Through combined theoretical and experimental analysis, the alpha contamination from 227Ac in LaBr3: Ce was reduced exploiting the different evaporation behaviors of LaBr3 and AcBr3. Additional impurities were also reduced to lower levels, as confirmed by glow discharge mass spectrometry (GDMS). The purified material, distilled at various temperatures (1203 K, 1253 K, and 1303 K), was used to grow LaBr3:Ce single crystals for performance evaluation. The crystals distilled at 1203 K demonstrated enhanced scintillation performance, featuring lower background counts (0.0181 counts·s−1·cm−3 @1.6–3 MeV) by approximately 50%–60 % of untreated sample and excellent energy resolution (2.47 %@662 KeV). This study presents an effective approach for preparing low-background lanthanum bromide, so as to offer valuable insights for isotope separation in scintillation crystals by vacuum distillation.

Twin-free thermal laser epitaxy of Si on sapphire

The heteroepitaxial growth of silicon (Si) is essential for modern electronics. Our study investigates the potential of thermal laser epitaxy (TLE) for Si epitaxy. A systematic study on the evaporation behavior of Si during TLE identifies and addresses the causes of notable flux rate fluctuations, resulting in a Si flux with ±0.3% stability over time. We also demonstrate heteroepitaxy of Si on c-plane sapphire substrates via TLE. High-temperature substrate preparation combined with deposition at a substrate temperature of 1000 °C produced high-quality epitaxial Si (111) films without twin domains.

Drying Kinetics and Sorption Isotherms of Biocomposite Materials: Experimental Investigation and Modeling Analysis.

Modern materials science has made significant progress in creating new materials and processes for waste recovery. One such advancement involves the development of a new porous composite material made from clay and an environmentally sustainable eggshell powder. In this study, the dynamic behavior of water vapor during desorption and adsorption processes within this composite material was investigated. The moisture diffusivity coefficient was determined within the clay/eggshell powder composite material. The drying kinetic data were analyzed using various models such as Newton, Page, and Wan and Singh. The static gravimetric vapor adsorption/desorption experiments were conducted at different temperatures (30, 40, 50, 60, and 70 °C) to depict the material's capacity for absorbing and releasing moisture over time. The experimental isotherm data were fitted using different mathematical models (Guggenheim, Anderson, and De Boer, Peleg, Adam and Shove, Oswin, and Modified Henderson). The findings suggest that integrating eggshell powder with clay can significantly influence the behavior and characteristics of the resultant material. The combination of eggshell powder and clay reduces moisture sorption and accelerates the drying process. Consequently, this affects the porosity, permeability, and response to humidity changes.

Revealing the influence of ring-shaped beam profiles in high-speed laser beam microwelding by synchrotron x-ray imaging

Laser beam microwelding is a precise technique for joining miniature metal components with high feed rates, which is crucial for productivity. However, high feed rates provoke humping formation—periodic beadlike protuberances along the weld seam—that compromise weld integrity. While humping has been associated with the keyhole transition from a narrow to an elongated shape using standard laser intensity distributions (e.g., Gaussian, top-hat), the impact of complex beam profiles, like ring-shaped intensity distributions, remains less understood. In this work, the influence of core-only, ring-only, and superimposed core-ring intensity distributions on humping formation during laser beam microwelding is investigated by means of synchrotron x-ray imaging. Single-track experiments on stainless steel (1.4404) at 1000 mm/s reveal that the keyhole geometry shifts from deep and narrow with core-only power input to shallow and elongated with ring-only power input. Using a superimposed core-ring intensity distribution (Pc = 300 W, Pr = 600 W) results in a U-shaped capillary and the reduction of the humping amplitude by nearly 80% (from 45.61 μm with core-only to 10.29 μm). The additional laser power comes with the tripling of the melt pool width (from 81 μm with core-only to 263 μm) likely decreasing the melt flow velocity. The reduced variability of the capillary length present for the superimposed intensity distribution further indicates a stabilized evaporation behavior. This work provides valuable insights into mitigating humping formation during laser beam microwelding of stainless steel at elevated feed rates using core-ring intensity distributions.

Evaporation of stable microemulsion droplets

Emulsion fuels have the potential to reduce both particulate matter and NOx emissions and can potentially improve the efficiency of combustion engines. However, their limited stability remains a critical barrier to practical use as an alternative fuel. In this study, we explore the evaporation behavior of thermodynamically stable water-in-oil microemulsions. The water-in-oil microemulsion droplets prepared from different types of oil were acoustically levitated and heated using a continuous laser at different irradiation intensities. We show that the evaporation characteristics of these microemulsions can be controlled by varying water-to-surfactant molar ratio (ω) and volume fraction of the dispersed phase (ϕ). The emulsion droplets undergo three distinct stages of evaporation, namely preheating, steady evaporation, and unsteady evaporation. During the steady evaporation phase, increasing ϕ reduces the evaporation rate for a fixed ω. It is observed that the evaporation of microemulsion is governed by the complex interplay between its constituents and their properties. We propose a parameter (η) denoting the volume fraction ratio between volatile and nonvolatile components, which indicates the cumulative influence of various factors affecting the evaporation process. The evaporation of microemulsions eventually leads to the formation of solid spherical shells, which may undergo buckling. The distinction in the morphology of these shells is explored in detail using scanning electron microscopy imaging.

Ablation and molten layer flow simulation for plate model of SiO2f/SiO2 composite material using particle method

In this paper, the moving particle semi-implicit method (MPS) is extended from calculating free mobility to simulating the extremely viscous and temperature-dependent molten layer flow of SiO2f/SiO2 composite material under aerodynamic heating conditions, which includes strong heating and shear of incoming flow. A method for applying heat flux and airflow shear, based on the conceptual particle approach, has been established. Heat transfer, melting, solidification, and evaporation behaviors are considered, with temperature-dependent viscosity variations also accounted for. The ablative regression of the plate model is verified using experimental results of the SiO2f/SiO2 composite material, and results from convergence analysis demonstrate the accuracy of the space step size selection. Surface morphology analysis through three-dimensional computation indicates that the extended particle method also accurately describes the surface morphology of SiO2f/SiO2 composite material under aerodynamic heating conditions. Thus, the extended particle method accurately simulates both the ablation process and the surface morphology of the SiO2f/SiO2 composite material. The influences of acceleration and surface tension are discussed. Ablative recession, when subject to acceleration, is smaller than that observed in its absence. When exposed to surface tension, the liquid layer tends to form a spherical shape, and the particles behave as a cohesive unit, resulting in smaller ablative recession than in the absence of surface tension.

Continuous Homogeneous Thin Liquid Film on a Single Cross-Shaped Profiled Fiber with High Off-Circularity: Toward Quick-Drying Fabrics.

Quick-drying fabrics, renowned for their rapid sweat evaporation, have witnessed various applications in strenuous exercise. Profiled fiber textiles exhibit enhanced quick-drying performance, which is attributed to the excellent wicking effect within fibrous bundles, facilitating the rapid transport of sweat. However, the evaporation process is not solely influenced by macroscopic liquid transport but also by microscopic liquid spreading on the fibers where periodic liquid knots induced by spontaneous fluidic instability significantly reduce the evaporation area. Here, a cross-shaped profiled fiber with high off-circularity, featured as multiple concavities along the fibrous longitude-axis, which enables the formation of a homogeneous thin liquid film on a single fiber without any periodic liquid knots, is developed. The high off-circularity cross-sections help overcoming Plateau-Rayleigh instability by tuning the Laplace pressure difference, further facilitated by capillary flow along the concave surface. The homogeneous thin liquid film on a single fiber is responsible for maximizing the evaporation area, resulting in excellent overall evaporation capacity. Consequently, fabrics made from such fibers exhibit rapid evaporation behavior, with evaporation rates ≈50% higher than those of cylindrical fabrics. It is envisioned that profiled fibers may provide inspiration for the manipulating homogeneous liquid films for applications in fluid coatings and functional textiles.

Towards Establishing Best Practice in the Analysis of Hydrogen and Deuterium by Atom Probe Tomography.

As hydrogen is touted as a key player in the decarbonization of modern society, it is critical to enable quantitative hydrogen (H) analysis at high spatial resolution and, if possible, at the atomic scale. H has a known deleterious impact on the mechanical properties (strength, ductility, toughness) of most materials that can hinder their use as part of the infrastructure of a hydrogen-based economy. Enabling H mapping including local hydrogen concentration analyses at specific microstructural features is essential for understanding the multiple ways that H affect the properties of materials including embrittlement mechanisms and their synergies. In addition, spatial mapping and quantification of hydrogen isotopes is essential to accurately predict tritium inventory of future fusion power plants thus ensuring their safe and efficient operation. Atom probe tomography (APT) has the intrinsic capability to detect H and deuterium (D), and in principle the capacity for performing quantitative mapping of H within a material's microstructure. Yet, the accuracy and precision of H analysis by APT remain affected by complex field evaporation behavior and the influence of residual hydrogen from the ultrahigh vacuum chamber that can obscure the signal of H from within the material. The present article reports a summary of discussions at a focused workshop held at the Max-Planck Institute for Sustainable Materials in April 2024. The workshop was organized to pave the way to establishing best practices in reporting APT data for the analysis of H. We first summarize the key aspects of the intricacies of H analysis by APT and then propose a path for better reporting of the relevant data to support interpretation of APT-based H analysis in materials.

Cannabis Use and Associated Risk Behavior Factors among High School Students in Mississippi: Youth Risk Behavior Surveillance System 2021.

Cannabis is the most used illicit drug among youths in the United States. The objectives of this study were to identify the association between cannabis use and other risk behaviors, including suicidality, among high school students. This is a cross-sectional study using the 2021 Mississippi Youth Risk Behavior Surveillance System (YRBS). The 2021 YRBS data sets were combined for this study. The crude odds ratio (OR) and adjusted odds ratio (AOR) with a 95% confidence interval were generated using the survey packages in R to account for weights and the complex sampling design of the YRBS data. Univariate analysis identified seven risky behaviors that were significantly associated with current cannabis use, including carrying weapons on school campuses, suicidal attempts, electronic vapor use, current smoking, current drinking, sexual behaviors, and unsupervised children. In multivariable analysis, after adjusting for gender, race, students' grades, and other risky behaviors, statistically significant variables for cannabis use included current use of electronic vapor, current smoking, current drinking, and sexual behaviors. Cannabis use is evenly burdened between males and females and between all race categories among Mississippi high school students. The identified associations seem to indicate that electronic vapor, tobacco products, and alcohol use could be the forerunners for drug use and should be treated accordingly in drug use prevention programs.

Water vapor condensation behavior on different wetting surfaces via molecular dynamics simulation

Understanding water vapor condensation behavior at molecular level provides critical insights and useful guidance towards applications such as atmospheric water harvesting. In this work, condensation behavior of water vapor with a range of concentrations is investigated by molecular dynamics simulation on surfaces with different wetting states, viz. hydrophilic, hydrophobic, superhydrophilic, and superhydrophobic under five levels of water vapor content. The effect of water vapor content on condensation morphology, condensation beginning time, number of water molecules condensed over time, and accumulation rate are quantitatively examined. The results demonstrate that water condensation mass increases linearly with time on hydrophilic and superhydrophilic surfaces, while displaying a two-stage behavior on hydrophobic and superhydrophobic surfaces. The increase at the first stage is slower than the second stage. Higher water vapor content enables earlier nucleation and shortens the duration of the slow increase stage for hydrophobic and superhydrophobic surfaces. Quantitatively, water condensation mass increases linearly with the relative humidity of the vapor, and the coefficient with relative humidity on the hydrophilic, hydrophobic, superhydrophilic and superhydrophobic surfaces is 25.74 × 10–19, 8.31 × 10–19, 27.63 × 10–19, and 1.34 × 10–19, respectively. Our results show that increasing water vapor content has more significant impact on hydrophilic and superhydrophilic surfaces than hydrophobic and superhydrophobic surfaces. In addition, increasing water vapor content has minor effect on condensation rate in the slow increase stage on hydrophobic and superhydrophobic surfaces, but significantly increase the condensation rate on the rapid increase stage.

Climatic Effects on Vapor Flow and Behavior in the Vadose Zone

AbstractThe concentrations and transport of volatile organic compounds (VOCs) and other vapors in the vadose zone may exhibit some degree of temporal variability due to the effect of various climatic factors, including (1) Air temperature; (2) Barometric pressure; (3) Surface winds; and (4) Soil moisture, including the effects of any water infiltration and/or changes in groundwater level. These variables may directly affect the rates of gas transport through the vadose zone or may indirectly affect transport by changing the soil‐gas concentrations at a given location and depth. To understand the potential effect of these factors due to climate change, it is first necessary to understand their effect over typical time periods of one to several days, seasonally, and annually. In this paper, the effects of the above variables over various time periods are presented and the long‐term effects due to climate change are discussed. Standard approaches for soil‐gas measurement attempt to account for these variables, either to negate their potential influence or to capture data under reasonably worst‐case conditions. The appropriateness and adequacy of typical soil vapor measurement approaches are discussed.

Impact of wrinkle orientation on the nanotribological properties of chemical vapor deposited TMD monolayers using AFM

Structural defects in two-dimensional (2D) materials are ubiquitous and can influence their physical and chemical properties. The presence of structural defects in single atom thick 2D materials such as graphene is detrimental to the tribological properties and is well documented; however, their effects on various other 2D materials such as transition metal dichalcogenides (TMDs) remain largely unexplored. Here, we report the role of wrinkles’ orientation on the nanoscale tribological behavior of the chemical vapor deposited (CVD) tungsten disulfide (WS2) monolayers. Our molecular dynamics (MD) simulations reveal the underlying atomistic mechanism which indicates the presence of wrinkles exhibiting various orientations, and maximum damage occurred when the tip moved at a 45-degree angle to the wrinkle. This underscores the significant influence of wrinkles’ orientation on the wear behavior of WS2 monolayers.

Effects of B2O3 on melting characteristic temperature and evaporation of CaF2-CaO-Al2O3 based ESR slag

The evaporation behaviors of ESR slag (CaF2-CaO-Al2O3-MgO-(B2O3)) for B-containing rack steel was laboratorially investigated to improve the stability of ESR process and the quality of ESR ingots. The thermogravimetric measurement, FactSage 8.3, kinetic analysis and molecular dynamics simulation methods were applied in this study. Additionally, the melting characteristic temperatures of the slag was tested by the hemisphere method. The results showed that B2O3 reduced the melting characteristic temperatures and mass loss of slag. Increasing the B2O3 content increased the vapor pressure of AlF3, OBF, and BF3, consequently promoting their evaporation. The main evaporating product in the slag was found to be CaF2, followed by minor amounts of MgF2, AlF3, OBF, AlOF, and BF3. Notably, the apparent activation energy for fluoride evaporation was calculated to fall within the range of 189.43–388.24 kJ mol−1, with the evaporation process following a nucleation and growth mechanism. The order of the self-diffusion coefficients of ions in the slag was determined to be F− > Mg2+>Ca2+>O2− ≈ B3+>Al3+. With the increase of B2O3 content in the slag, the self-diffusion coefficient of each ion underwent an initial decrease followed by a significant increase, illustrating that diffusion did not serve as the controlling step of the evaporation reaction.

Evaporation characteristics of single free-falling liquefied natural gas droplet under different ambient conditions based on the VOF method

The evaporation characteristics of droplets is a fundamental issue for accurate depictions of moving liquefied natural gas (LNG) droplets and constantly changing ambient environment owing to intense heat, mass transfer, and momentum exchanges. In this study, a modified droplet evaporation model is developed to investigate the evaporation behavior of a single free-falling LNG droplet under various ambient conditions. The proposed model captures the droplet interface and calculates the mass transfer rate through the vapor concentration gradient using the volume of fluid method integrated with a smooth function. Evaporation experiments were conducted on a single free-falling LNG droplet to capture the evaporation process. The results indicate that it is acceptable to ignore the effect of the Stefan flow of a single free-falling LNG droplet. This study also examined the impact of different ambient conditions on evaporation characteristics. The results indicate that the evolution of the droplet diameter is mainly influenced by the ambient temperature because it affects the thermal properties of the surrounding gas and the distribution of the boundary layer. The temporal characteristics of the Nu and Sh numbers generally stabilize after a period of rapid decline. This study provides a theoretical basis for understanding the evaporation mechanisms of LNG droplets.

Large Ozone Hole in 2023 and the Hunga Tonga Volcanic Eruption

AbstractPolar stratospheric chemistry is highly sensitive to changes in water vapor content and temperature. We identified an unusual behavior of water vapor and temperature in the southern polar winter stratosphere in 2023. The relationships between the Hunga-Tonga eruption injection of water vapor (detected in the tropics) and its transport to SH high latitudes, temperature changes and ozone anomalies at southern high latitudes are discussed, as well as the roles of zonal wind and the meridional flux of zonal mean zonal momentum. These parameters exhibit a consistent pattern in anomalous year 2023. In the winter of 2023 in the Southern Hemisphere, an unexpected decrease in ozone levels and the emergence of an excessive ozone hole were observed. This event marked one of the deepest Antarctic ozone holes with the largest area since 2011. This appears to be associated with the Hunga Tonga eruption anomalous water vapor injection. This study highlights importance of water vapor for evolution of the Antarctic stratosphere.

Drying time of plaster within in-fill plasterboard walls and evaporation theory for water within gypsum: methodology, numerical simulation and application

ABSTRACT The desulphurisation-gypsum-filling-wall (DSG-FW) formed by pouring into plasterboard partitions with desulphurisation gypsum slurry can utilise low-quality desulphurisation gypsum and also improve the acoustic insulation issues arising from the use of hollow partitions. The construction schedule of this wall is unable to be controlled because the moisture transfer characteristics in DSG-FW are unclear. Therefore, it is important to determine the drying time and the moisture-transfer behaviour during the construction process. By using different thicknesses of gypsum samples, adding different amounts of perlite and adjusting the relative humidity, whether the gypsum board is covered, the drying and evaporating process of gypsum was compared and analysed. The evaporative characteristics of the desulphurisation gypsum core wall at different relative humidities were determined through experiments. In addition, an evaporation model was introduced for simplification and verification. The experimental results show that the drying of gypsum is correlated with relative humidity and gypsum thickness: the higher the relative humidity, the lower the evaporation rate; the thicker the gypsum, the longer the drying time; perlite and gypsum board have no effect on gypsum drying. The rate of evaporation of DSG-FW increases non-linearly with the decrease in relative humidity under which the DSG-FW is conditioned; the simplified Hertz-Knudsen-Langmuir (HKL-S) model can only be used to predict the evaporation behaviour within the higher relative humidity range (more than 55% RH), while the simplified statistical rate theory (SRT-S) model was verified as being able to predict the rate of evaporation across almost the whole relative humidity range. The SRT-S model can be used to predict and control the construction of DSG-FW in actual engineering work.