Cr Values Research Articles

Source Apportionment and Influence Factors Analysis of Heavy Metals in Soils Around a Coal Gangue Heap Using the APCS-MLR Model and GeoDetector

To analyze the source apportionment and influence factors of heavy metals in soils surrounding a coal gangue heap in Chongqing, the absolute principal component scores-multiple linear regression （APCS-MLR） model and GeoDetector were used. The results showed that Cd was the primary pollutant and the average values of Cd, Hg, Pb, Cr, Cu, Zn, and Ni were 1.33, 0.29, 32.9, 142, 68.8, 118, and 54.6 mg·kg-1, respectively. Using the APCS-MLR model analysis, mining sources, which were mainly affected by long-term accumulation of the coal gangue heap, had a contribution rate of 37.1% and the main heavy metal pollutants were Cd, Hg, and Pb. Agriculture and transportation sources, mainly affected by pesticide and fertilizer application and vehicle emissions, had a contribution rate of 36.2%, with the main heavy metal pollutants being Cu, Zn, and Ni. Natural sources, which were mainly affected by geotechnical weathering processes of their parent materials, had a contribution rate of 26.7% and the main heavy metal pollutant was Cr. Using GeoDetector analysis, the "distance from coal gangue heap" had the strongest explanatory power for the contents of Cd, Hg, and Pb, whereas the "distance from rural settlements" had the strongest explanatory power for the contents of Cr, Cu, Zn, and Ni. However, the interaction of each influencing factor was enhanced, which indicated that the spatial distribution characteristics of heavy metals were influenced by multiple factors. The combined application of the APCS-MLR model and GeoDetector can make the results of source apportionment and influence factors more comprehensive, accurate, and reliable.

Enrichment Characteristics, Risk Evaluation, and Source Apportionment of Heavy Metals in Wabu Lake of Yangtze River to Huaihe River Water Diversion Project

Wabu Lake serves as a crucial junction within the Yangtze River to Huai River Water Diversion Project （Yangtze-Chao Lake-Wabu Lake-Huai River）, where clarifying the status and risk levels of heavy metal contamination in the lake is crucial for the aquatic ecological safety along the route of the project. Surface water and sediment samples from 24 locations in Wabu Lake were collected and analyzed for the contents of heavy metals （As, Zn, Pb, Ni, Cu, Cr, Fe, and Cd）. Risk evaluation and source apportionment of heavy metals in the lake were conducted using the human risk assessment （HRA） model, sediment quality guidelines （SQGs）, and positive matrix factorization （PMF） method. The results showed that the average concentrations of heavy metals （except for Cd and Pb） in the surface water were lower than the class III limits of the surface water quality standard （GB 3838-2002）. The average concentration of heavy metals （As, Zn, Pb, Ni, Cu, Cr, Fe, and Cd） in interstitial water were lower than the Criteria Continuous Concentration （CCC） of the National Recommended Water Quality Criteria. The average contents of As, Zn, Pb, Ni, Cu, Cr, and Cd in the sediment exceeded the background values by factors of 1.78, 1.85, 1.42, 1.77, 1.41, 1.38, and 3.46, respectively. In addition, the heavy metals Pb, Cd, and Cr in the Wabu Lake water posed severe risks to human health, with the cancer risk （CR） value for Cr reaching 6.14×10-5. The sediment quality guidelines （SQGs） indicated that the probability of adverse effects on lakes by As, Ni, and Cr was relatively high. The spatial distribution of risk areas showed that the risk control zones for As, Cr, and Ni in Wabu Lake covered almost the entire lake area. The PMF analysis indicated that the primary sources of heavy metals in Wabu Lake were exogenous inputs from industrial, agricultural, and residential activities in surrounding areas, followed by endogenous pollution caused by enclosed aquaculture. The subsequent focus should be on the pollution of heavy metals Cr, Cd, and Pb in the overlying water of Wabu Lake as well as the sediment ecological safety of As, Cr, and Ni in the sediment.

Heavy metals in roadside soil along an expressway connecting two megacities in China: Accumulation characteristics, sources and influencing factors

Transportation is widely recognized as a significant contributor to heavy metal (HM) pollution in roadside soils. A better understanding of HM pollution in soils near expressways is crucial, particularly given the rapid expansion of expressway transportation in China in recent years. In this study, 329 roadside topsoil samples were collected along the Beijing-Tianjin Expressway, which connects two megacities in China. Chemical analysis showed that HM concentrations in the soil samples were generally below national limits. The mean pollution index (Pi) values for As, Cr, Cu, Ni, Pb, and Zn ranged from 0.94 to 1.01, while Cd and Hg exhibited slightly higher mean Pi values of 1.19 and 1.13, respectively. The Nemerow integrated pollution index values for all samples ranged from 0.71 to 4.97, with a mean of 1.26. This suggests a slight enrichment of HM above natural background levels, especially for Cd and Hg. Source apportionment using positive matrix factorization revealed that natural sources contributed the most to soil HMs (64.51 %), followed by agricultural sources (19.15 %), traffic sources (9.77 %), and industrial sources (6.57 %). The Shapley additive explanation analysis, based on the random forest model, identified soil organic carbon, deep soil HM content, altitude, total soil K2O, urbanization composite impact index, and total soil P as primary influencing factors. This indicates that the impact of transportation on roadside soils along the Beijing-Tianjin Expressway is currently relatively limited. The prominent influence of soil properties and altitude underscored the importance of “transport” and “receptor” in the soil HMs accumulation process at the local scale. These findings provide critical data and a scientific basis for decision-makers to develop policies for expressway design and roadside soil protection.

Pollution analysis of metals in the sediments of lagoon lakes in Türkiye: Toxicological risk assessment and source insights

This study addresses gaps in understanding the distribution, sources, and health risks of potentially toxic elements (PTEs) in the sediments of lagoon lakes Akgöl and Simenit in Türkiye. Sediment samples from 16 locations were analyzed for Fe, Cu, Mn, Zn, Cr, Ni, As, Pb, Cd, and Hg. Findings indicate higher concentrations of Fe and Mn in Simenit Lake and elevated levels of Cr and Ni in both lakes. The Enrichment Factor (EF), Contamination Factor (CF), and Pollution Load Index (PLI) were used to evaluate contamination levels in sediments, while sediment quality guidelines and the Potential Ecological Risk Index (PERI) assessed ecotoxicological risks. Results reveal moderate to high pollution in Simenit Lake, particularly for Cr and Ni, with Cd posing a significant ecological risk. Health risk assessments showed non-carcinogenic risks (Hazard Index, HI > 1) for children, especially in Simenit Lake (HI = 1.10). Carcinogenic risks from Cr and Ni were within acceptable limits; however, Simenit Lake exhibited higher Total Cancer Risk (TCR) values for Cr (5.40E-05) and Ni (1.37E-04), indicating a low but notable risk. Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA) identified industrial discharge and agricultural runoff as primary contamination sources. These findings highlight the need for targeted management strategies to mitigate health and ecological risks in these vulnerable aquatic systems.

The partitioning of chalcophile and siderophile elements (CSEs) between sulfide liquid and carbonated melt

Carbonated melts play a significant role in mobilizing lithophile and volatile elements in the Earth’s mantle and mantle metasomatism. However, there has been limited investigation into their potential for mobilizing chalcophile and siderophile elements(CSEs). In this study, we experimentally determine the sulfide liquid–carbonated melt partition coefficients of CSEs (DCSESul/C_melt) for a range of elements, including Co, Ni, Cu, Zn, Se, Mo, Ag, Cd, In, Sn, Re, and Pb, at 1300–1600 °C, 1.0–3.0 GPa, andoxygen fugacity (fO2) close to the graphite-CO2 fluid buffer. Furthermore, the DSul/C_melt values for lithophile elements Cr, Mn, Rb, Sr, Y, Zr, Nb, Cs, Ba, Hf, and Ta (DLithoESul/C_melt) are also determined. The obtained DCSESul/C_melt values are 34–1230 for Co, 380–75200 for Ni, 200–14900 for Cu and Ag, 0.5–28 for Zn and Mo, 42–98 for Se, 24–640 for Cd, 5–52 for In and Sn, 650–15200 for Re, and 22–2470 for Pb. The obtained DLithoESul/C_melt values are below 1–10. The variations of DCSESul/C_melt and DLithoESul/C_melt are primarily influenced by the FeOtot content in the carbonated melts. A partitioning model was developed to parameterize DCSESul/C_melt and DLithoESul/C_melt as a multi-function of pressure, temperature, composition of the carbonated melt (mainly the FeOtot content), and composition of the sulfide liquid. Our parameterization can explain the observed large variations of DCSESul/C_melt and DLithoESul/C_melt for most of the trace elements studied. Using our DCSESul/C_melt parameterization, we model the CSE and U–Th contents of low-degree partial melts of carbonated mantle peridotite and slab eclogite with sulfur concentrations ranging from 50 to 500 µg/g. The modeling results can generally explain the trace element patterns observed in natural kimberlites and carbonatites; however, the peridotite- or slab-derived carbonated melts have a low capability in mobilizing CSEs, which can extract less than 3 % of Cu, Ni, Co, Re, and Os, 3–30 % of Mo, Pb, and Se, but up to 30–50 % U and Th from the source lithology. Consequently, the influence of carbonatite metasomatism on the Cu, Ni, Co, Re, and Os systematics of the Earth’s mantle is minimal, although local enrichments of CSEs may occur when sulfides precipitate from carbonated melts. Because of the elevated concentrations of U and Th and the corresponding U/Pb and Th/Pb ratios in the carbonated melts, the mantle lithology that has undergone metasomatism by these melts can become a geochemical reservoir with high 208Pb/206Pb ratios. However, the effect of carbonatite metasomatism on Re–Os isotopic systems of the mantle is minimal due to the low Re concentrations in the carbonated melts. Accordingly, the radiogenic Pb–Os isotopic signatures of HIMU ocean island basalts cannot be explained solely by carbonatite metasomatism in the mantle.

Human health risk assessment of heavy metals in beer brands from Tanzania market

Heavy metal contamination in the environment, often resulting from industrial activities, mining, and improper waste disposal, leads to the accumulation of heavy metals in soil, water, air, drinks and food. Prolonged exposure to these metals can cause serious health issues in humans, including neurological damage, kidney failure, respiratory problems, and an increased risk of cancer. High levels of heavy metals in food are hazardous to human health. Heavy metals can find their way into beer at different stages, including through raw materials, the brewing process, equipment, bottling, and storage. This study examined the presence of Cu, Cd, Pb, Cr, Fe, and Zn in ten of the most consumed beer brands in Tanzania using an atomic absorption spectrometer (AAS). The results showed that the concentration of heavy metals in the beer samples increased in the order of Zn < Cu < Fe < Cr. Cd and Pb were not detected in any beer samples. Compared to WHO guidelines, the levels of Zn and Cu were below the limit, while Fe and Cr exceeded it. Estimated daily intake (CDI), hazard quotient (HQ), hazard index (HI), and incremental lifetime cancer risk (ILCR) were used to evaluate the potential human health risks. The EDI values of Fe and Zn were lower than the provisional maximum tolerable daily intake (PMTDI) set by the FAO/WHO. However, the mean EDI for Cr surpassed the recommended value, posing a potential risk for moderate and high beer consumers. The HQ and HI values for Zn and Fe were below 1, signifying no non-carcinogenic health concerns. In contrast, Cr had HQ and HI values greater than 1, indicating a notable non-carcinogenic health risk through beers consumption. ILCR due to Cr ranged from 0.029 to 0.695. These ILCR values for Cr in all beer samples are above range of 10−6−10−4 recommended by USEPA, suggesting a potential carcinogenic risk linked to this toxic metal and, consequently, a possible cancer risk for beer consumers. Therefore, beer manufacturers should continuously work to minimize public health risks. Additionally, further research involving a larger variety of beer brands and the implementation of policy interventions is needed.

How Do Teachers Survive? Turkish Adaptation of Selection, Optimization, and Compensation Strategies Scale

The continuous development of professional competencies and active retention of teachers in the field, stemming from alterations in their professional life cycles, are intrinsically connected to the necessity of lifelong learning for teachers. The model of selection, optimization, and compensation (SOC) strategies can be used to gain insight into the ways in which teachers manage their resources to remain in the profession, how they adapt to their professional lives in the context of lifelong learning, and how to develop effective policies to support the professional development of teachers. Although previous research has emphasized the primary factors that influence teachers' professional development and motivation, there is a scarcity of research on the strategies that teachers use to maintain their employment. In order to fill this gap, this study aims to adapt the Selection, Optimization, and Compensation Scale (SOCQ) (Zacher &amp; Frese, 2011), which emphasizes the strategies that teachers use to remain effective in their professional lives, into Turkish. The sample of the study consisted of 299 teachers working in schools in Çekmeköy district of Istanbul province. In the adaptation process of the scale, Turkish translation, back translation, cross-checking, and Turkish face validity stages were followed. Confirmatory Factor Analysis (CFA) was conducted to evaluate the construct validity of the scale. The CFA revealed excellent fit indices for the scale. Consisting of 12 items and three dimensions, the reliability of the scale was evaluated using Cronbach Alpha internal consistency coefficient and composite reliability coefficient (CR). The internal consistency coefficient was 0.81, while the CR value was 0.902. The study's findings demonstrate that the Turkish version of the SOCQ is a valid and reliable tool for assessing teachers' use of SOC strategies.

Ecological Health Hazards and Multivariate Assessment of Contamination Sources of Potentially Toxic Elements from Al-Lith Coastal Sediments, Saudi Arabia

To assess the contamination levels, sources, and ecological health risks of potentially toxic elements (PTEs) in the sediments of Al Lith on the Saudi Red Sea coast, 25 samples were collected and analyzed for Zn, V, Cr, Cu, Ni, As, Pb, and Fe using inductively coupled plasma-atomic emission spectrometry. The average concentrations of PTEs (μg/g) were obtained in the following order: Fe (14,259) &gt; V (28.30) &gt; Zn (22.74) &gt; Cr (16.81) &gt; Cu (12.41) &gt; Ni (10.63) &gt; As (2.66) &gt; Pb (2.46). The average values of enrichment factor were in the following order: As (1.12) &gt; Zn (0.75) &gt; V (0.70) &gt; Cr (0.69) &gt; Cu (0.69) &gt; Pb (0.67) &gt; Ni (0.46). This indicated that the Al Lith sediments exhibited either no or minimal enrichment of PTEs, with concentrations below the low effect range. This suggests that the primary source of these PTEs is the minerals associated with the basement rocks of the Arabian Shield (sphalerite, vanadiferous magnetite, chromite, pentlandite, arsenopyrite, and galena) and that they are unlikely to pose a substantial risk to benthic communities. The hazard index (HI) values for the PTEs in both adults and children were below 1.0, indicating no significant non-carcinogenic risk. The lifetime cancer risk (LCR) values for Pb, As, and Cr in both adults and children were within acceptable or tolerable levels, posing no significant health threats. However, a few samples showed LCR values exceeding 1 × 10−4, which may indicate potential risks.

Characteristics, Sources, and Health Risk Changes of Heavy Metal Pollution Carried by PM2.5 in Beijing and Evaluation of Policy Effectiveness

To evaluate the effectiveness of air pollution prevention and control measures in Beijing, this study measured the content of 13 metal elements, including seven heavy metal elements [As, Cd, Co, Cr（Ⅵ）, Ni, Pb, and V], through daily PM2.5 sampling （n = 934） in the urban area of Beijing for four years. We analyzed the interannual changes in the concentration levels of various metals and the differences between heating and non-heating seasons, used a positive definite matrix factorization （PMF） model for quantitative source analysis, and used health risk assessment methods to evaluate the health risks of six metals. The results showed that, except for a few metal elements such as Cr（Ⅵ） and Ni, which showed an increase in concentration in individual years, the overall concentration of each element showed a downward trend. The concentrations of ten metals, including V, Co, Pb, and Mn, during the heating season were significantly higher than those during the non-heating season （P&lt;0.05）. There were five main types of atmospheric heavy metal pollution sources in Beijing： dust sources, transportation sources, coal sources, industrial sources, and fuel oil combustion sources. Among them, the proportion of coal sources was generally decreasing. The HQ values of each metal were all less than 1, indicating no non-carcinogenic health risk. The carcinogenic risk of Ni and Cd could be ignored, while the R values of As, Co, and Cr（Ⅵ） in each year were between 10-6 and 10-4, indicating a certain carcinogenic risk. The interannual trends in atmospheric concentration, sources, and health risks indicate that the relevant measures for air pollution prevention and control in Beijing have achieved positive results.

Evaluating health risks of PM2.5-bound heavy elements in Faridabad, Haryana (India): an industrial perspective.

The present study isfocused on investigating the heavy/toxic metals (Al, Ni, Cr, Pb, Cu, As,Mn, and Zn) of PM2.5 and assessing their associated human health risks. During the study period (July 2022 to July 2023), the PM2.5 samples were collected from two distinct sites in Faridabad (92 samples from site 1 and 85 samples from site 2). In this study, the US EPA's Risk Assessment Guidance for Superfund (RAGS) was followed to evaluate the human health risk associated with PM2.5-bound heavy elements. The annual average of PM2.5 concentrations was 108 ± 16µgm⁻3 at site 1 and 154 ± 11µgm⁻3 at site 2, approximately three to fourtimes higher than the national ambient air quality standards (annual, 40µgm-3). The analysis of enrichment factors (EFs) for the elements Cr, As, Zn, Cu, Mn, Pb, and Ni indicates that the heavy elements associated with PM2.5 primarily originate from anthropogenic sources. The application of the conditional bivariate probability function (CBPF) model for Faridabad revealed local pollution sources contributing to elevated mass concentrations at the receptor site from the southern (S), northwestern (NW), northeastern (NE), southwestern (SW), and southeastern (SE) regions. Furthermore, positive matrix factorization (PMF) analysis identified the predominant sources of PM2.5-bound heavy elements as industrial emissions (41%), vehicular emissions (34%), and combustion processes (25%). After a thorough assessment of health hazards, Cr appeared as a significant carcinogenic risk factor. Children with elevated hazard quotient (HQ) values for Mn and Cr indicated non-carcinogenic health problems. Ultimately, this analysis reinforces the necessity for rigorous monitoring and intervention to safeguard public health from the potentially harmful effects of heavy elements.

Heavy metal contamination and potential health risks in upland rice-producing soils of rotational shifting cultivation in northern Thailand

Rotational shifting cultivation (RSC) is commonly practiced in northern Thailand for upland rice cultivation, primarily for household consumption. However, the potential health risks from heavy metal contamination in these soils have not been thoroughly explored. This study aimed to evaluate the contamination of six heavy metals (Arsenic (As), Mercury (Hg), Cadmium (Cd), Lead (Pb), Copper (Cu), and Chromium (Cr)) in upland rice across RSC fields with varying fallow periods and assess the associated health risks from rice consumption. Four RSC fields with 5, 6, 10, and 12-year fallow periods were examined. The RSC-6Y and RSC-12Y fields were used for upland rice cultivation in 2022, while the RSC-5Y and RSC-10Y fields were cultivated in 2023. The geo-accumulation index (Igeo) was calculated, and translocation factors (TF) were assessed for the transfer of heavy metals from soil to straw (TFStraw/Soil), straw to grain (TFGrain/Straw), and soil to grain (TFGrain/Soil). The results indicated that after burning vegetation in the RSC fields, the highest concentrations of Pb, Cr, and Hg were found in the ash. In RSC soils, Cu, Cr, As, Pb, and Hg levels were below reference standards, with Cd undetected. In rice grains, the order of concentration was Pb > Cu > Cr > As, with Hg and Cd undetected. Pb levels in rice grains exceeded the safety threshold. Igeo values indicated no contamination to moderate contamination across sites, with negative Igeo values for Cr and Cu, and zero values for Cd. The TF results showed limited transfer of As, Hg, and Cd from soil to rice plants (TFStraw/Soil < 0.1), but notable transfer for Pb, Cr, and Cu. Pb was readily transferred from soil to grain (TFGrain/Soil), posing a potential health risk. The study highlights potential non-carcinogenic and carcinogenic risks from heavy metal exposure, particularly Pb, and underscores the need for further research to determine contamination sources and mitigation strategies.

Hamstring-to-Quadriceps Strength Ratios in Women Team Sport Athletes: A Systematic Review

ABSTRACT Women experience a higher rate of anterior cruciate ligament (ACL) injuries than men. Muscle imbalance, in particular hamstring-to-quadriceps (H:Q) strength ratio, is considered a risk factor for ACL injury. The purpose of this systematic review was to identify isokinetic H:Q strength ratios in women team sport athletes and determine whether cutoff values, determined from research with predominantly males, of &gt;0.6 for conventional ratio (Hamstringconcentric:Quadricepsconcentric [CR]) and &gt;1.0 for functional ratio (Hamstringeccentric:Quadricepsconcentric [FR]) were met. The CR (0.6) was not met for team ([mean ± SD: 0.56 ± 0.08]), field (0.57 ± 0.08), and court (0.56 ± 0.08) sports. Handball presented the highest (0.58 ± 0.07), and softball presented the lowest CRs (0.47 ± 0.06). The FR (1.0) was not met for team (0.69 ± 0.14), field (0.85 ± 0.14), and court (0.65 ± 0.14) sports. Soccer presented the highest (0.85 ± 0.14) and handball the lowest (0.66 ± 0.13) FRs. When assessing hamstring and quadriceps strength balance, women team sport athletes did not meet CR or FR values, which may contribute to increased ACL injury risk. H:Q ratios below cutoff values may indicate compromised hamstring strength. It is recommended practitioners implement strength exercises aimed to improve H:Q ratios.

Assessing metals and metalloids impact of roadside dust on human health in Osogbo, Osun state, Nigeria

BackgroundMetals and metalloids in roadside dust pose considerable threats to both human health and the environment. ObjectivesThis study assesses human health risks of metal exposure to roadside dust by conducting a health risk assessment (HRA) for metals and metalloids uptake rates for children and adults via exposure pathways. MethodsSettled dust samples were collected from the major roads in Osogbo, Osun state. These samples were subjected to standard laboratory procedures for metals and metalloids analysis using Atomic Absorption Spectroscopy (AAS). ResultsAll the metals and metalloids except Cd had their concentration below the WHO limit. The average concentration of Cd was 1.54 mg kg-1, significantly above the WHO guideline of 0.80 mg kg-1, indicating a possible health concern. A strong positive correlation exits between Ni and Cd (0.774⁎⁎) (p < 0.01), Pb (0.662⁎⁎) (p < 0.01), Zn (0.606⁎⁎) (p < 0.01), and as (0.549*) (p < 0.05), showing that greater Ni concentrations are associated with higher concentrations of Cd, Pb, Zn, and As. Two principal components were identified, accounting for 80 % of the overall variation. PC1 has an eigenvalue of 60.834; however, PC2 has a higher eigenvalue of 74.952, implying that PC2 explains more of the variation in the data than PC1. Non-carcinogenic risk evaluations identify possible health risks linked with Cu, Cd, Cr, and As exposure, primarily through inhalation routes. Carcinogenic risk showed that Cd demonstrated high CR values ranging from 3740 to 1.30×1012 for adults and children throughout the study's various exposure paths. ConclusionThis study offered significant insight into the metals and metalloids pollution status in Osogbo, Nigeria, employing data and statistics, highlighting the need for evidence-based actions for environmental preservation to safeguarding people's health.

Differential evolution with multi-strategies for UAV trajectory planning and point cloud registration

The present study introduces a novel adaptive algorithm, MELSHADE-cnEpSin, which aims to enhance the performance of LSHADE-cnEpSin, which is not only stands out as one of the most competitive versions of differential evolution but also holds the distinction of being one of the CEC winner algorithms. Compared to the original methodology, four main distinctions are presented. To begin with, we adopt an adaptive selection mechanism (ASM) of crossover rate Cr value based on the external archive to rechoose a suitable value. In the next place, a nonlinear population reduction strategy using Sigmoid function is employed to improve population distribution. Additionally, a restart strategy is implemented to mitigate the risk of algorithmic convergence towards suboptimal solutions. Furthermore, the performance of MELSHADE-cnEpSin was evaluated using standard CEC2017 and CEC2022 test suites in conjunction with nine CEC-winning algorithms (L-SHADE, EBOwithCMAR, AGSK, LSHADE-SPACMA, LSHADE-cnEpSin, ELSHADE-SPACMA, EA4eig, MadDE and APGSK-IMODE) as well as two novel algorithms (ACD-DE and MIDE). Furthermore, MELSHADE-cnEpSin was effectively employed to address the challenge of UAV trajectory planning in intricate mountainous terrain and underwent simulation with point cloud registration cases utilizing a rapid global registration dataset, thereby showcasing the potential of MELSHADE-cnEpSin in tackling real-world optimization problems.

An Investigation into the Viability of Portable Proximal Sensor X-Ray Fluorescence Data for Assessing Heavy Metal Contamination in Urban Soils: A Case Study in Changchun, China.

In order to validate the applicability of pXRF for rapid in situ detection of heavy metals in urban soils and to accurately obtain an assessment of soil quality in Changchun, a city in northeast China, 164 soil samples from within the main urban area of Changchun were collected for pXRF analysis. The main stable elements Si and Ti were used to establish a matrix effect correction model, and the values of Cr (64.2 mg⋅kg-1), Cu (43.8 mg⋅kg-1), Zn (96.2 mg⋅kg-1), As (20.9 mg⋅kg-1), and Pb (57.4 mg⋅kg-1) were predicted. The empirical findings indicate that the quality of soil data from the pXRF was improved to different degrees under the correction model, and it became a relatively reliable dataset; the order of improvement was Cu > Pb > Cr > Zn > As. A comprehensive assessment indicated that Changchun City is primarily contaminated by the heavy metals As, Pb, and Cu, with the main sources being automobile manufacturing and pharmaceutical chemical production. These findings align with previous studies and have produced favorable outcomes in practical applications. This rapid, non-destructive and economical detection method is very applicable and economical for the sustainable monitoring and control of heavy metals in large cities. This study provides a basis for rapid large-scale prediction of urban soil safety and protection of local human health.

Contamination and health risk assessment of potentially toxic elements in rice (Oryza sativa) and soil from Ashanti Region.

Anthropogenic activities release potentially toxic elements into the environment, which contaminate the food chain. The main objective of this research was to analyze the concentrations of As, Cd, Cr, Hg, and Pb in rice grains and soils, establish their correlation and transfer factors between soil and rice grains as well as evaluate their human health risk from consumption of rice cultivated in the Asante Akim area. The levels of As, Cd, Cr, Hg, and Pb in soil and rice samples were assayed using an Agilent 7700 Series inductively coupled plasma-mass spectrophotometer. The mean heavy metal content in soil was 7.5, 0.52, 0.47, 1.30, and 8.69mg/kg for As, Cd, Cr, Hg, and Pb, respectively. Mean levels of the potentially toxic elements in rice were 0.082, 0.27, 0.48, 0.028, and 0.14mg/kg for As, Cd, Cr, Hg, and Pb, respectively. Soil pollution indices showed that the soils were unpolluted with the potentially toxic elements studied. The concentrations of the potentially toxic elements in rice were below the maximum allowable concentration (MAC) recommended by the Codex Alimentary Commission except Cd which was marginally higher than the MAC. Dietary exposure to the elements to consumers was assessed by comparing the estimated daily intake (EDI) to the provisional tolerable daily intake (PTDI). The estimated daily intake values for As, Cd, Cr, Hg, and Pb were 1.45 × 10-4, 4.8 × 10-4, 8.5 × 10-4, 4.95 × 10-5, and 2.4 × 10-4, respectively. The HQ for all the potentially toxic elements was less than the permissible value of 1, suggesting that the consumption of rice from the study area constitutes no potential non-carcinogenic health risk to the population. This study is unique because the risk is evaluated from rice that is directly consumed, and this gives a clearer picture of the risk to humans. Regular monitoring studies should be conducted to ascertain the levels of heavy metals in rice cultivated in the area since heavy metals can accumulate and the concentrations could increase to toxic levels with time.

Fluid Force Reduction and Flow Structure at a Coastal Building with Different Outer Frame Openings Following Primary Defensive Alternatives: An Experiment-Based Review

A well-constructed tsunami evacuation facility can be crucial in a disaster. Understanding a tsunami’s force and the flow structure variation across various building configurations are essential to engineering designs. Hence, this study assessed the steady-state flow structure at building models (BM) incorporating outer frame openings, including piloti-type designs with a different width-to-spacing ratio of piloti-type columns following an embankment model (EM) with a vegetation model (VM). The experiments also demonstrated the outer frame opening percentage’s impact and orientation toward the overtopping tsunami flow at the BM. The results show that the arrangement of an opening on the outer frame and the piloti-type columns are critical in reducing the tsunami force concerning the experimental setup. Moreover, allowing a free surface flow beneath the BM implies that the correct piloti-pillar arrangement is crucial for resilient structure design. In addition, the three-dimensional numerical simulation was utilized to explain the turbulence intensity of the overtopping flow around the critical BM type. The derived resistance coefficient (CR) defined the drag and the hydrostatic characteristics at the BM due to the overtopping tsunami flow. Furthermore, for the impervious BM, the value CR was consistent with the previous studies, while the CR value for the BMs with an outer frame opening was directly coincident with the percentage of porosity.

Predictors of Acute Kidney Injury Resolution and Associated Clinical Outcomes Among Hospitalized Patients with Cirrhosis.

Background: Acute kidney injury (AKI) is one of the common complications of liver cirrhosis. It occurs in nearly 20% of patients with cirrhosis who are hospitalized. Prior literature demonstrated that the AKI occurrence in patients with cirrhosis is independently associated with higher mortality. However, there are data assessing predictors and outcomes of AKI resolution in hospitalized patients with cirrhosis. Therefore, the aim of the current study was to identify clinical predictors of AKI resolution among inpatients with cirrhosis that are easily obtained and to evaluate the clinical outcomes of those patients. Methods: The current study is a retrospective cohort of patients with cirrhosis who were hospitalized and had AKI between 2012 and 2020 at a tertiary referral center. Patients included in this study were identified using the International Classification of Diseases 9 codes and then they were manually verified by two independent chart reviewers. AKI was classified according to the AKI Network (AKIN) serum creatinine (Cr) criteria, with AKIN resolution defined as AKIN stage 1 or lower at the time of discharge, while unresolved AKIN was defined as AKIN stage 2 or 3 at the time of discharge. For univariate analysis, Fisher's exact and the two-sample T-test were utilized. For multivariable analysis, stepwise logistic regression was performed to evaluate variables associated with AKIN resolution. Survival curves were estimated and compared using the Kaplan-Meier method and Log-Rank Test. A p-value cutoff of 0.05 was used for statistical significance. Results: Between 2012 and 2020, there were 140 patients who were included (59% males). The majority of patients had viral hepatitis (54%) as the cirrhosis etiology with 80% of them having hepatitis C virus. Most patients had fluid-responsive AKI (49%), and stage 1 AKIN (69%). In terms of outcomes, the majority of patients (117 patients; 84%) had AKIN resolution at the time of discharge. In the multivariable analysis, after adjusting for clinical meaningful variables, our study shows that higher albumin value at the time of admission (adjusted Odds Ratio "aOR" = 3.28; p = 0.01) and non-metabolic dysfunction-associated steatotic liver disease (non-MASLD) cirrhosis (aOR = 9.43; p < 0.01) were variables associated with higher odds of AKIN resolution at the time of discharge. Conversely, we show that a higher Cr value at the time of admission was associated with lower odds of AKIN resolution at the time of discharge (aOR = 0.31; p < 0.01). When evaluating mortality, patients with unresolved AKIN at the time of discharge had higher rates of in-hospital mortality (p < 0.01) compared to those with resolved AKIN. Survival curve analyses using the Kaplan-Meier method indicated that patients with resolved AKIN experienced higher 90-day survival rates (p < 0.01). Additionally, those with resolved AKIN demonstrated greater transplant-free survival compared to patients with unresolved AKIN at both the 1-year (p = 0.04) and 3-year (p < 0.01) follow-ups. Conclusions: When evaluating clinical predictors of AKIN resolution in admitted patients with cirrhosis, our study showed that a higher admission albumin value and non-MASLD etiology of cirrhosis were associated with higher odds of AKIN resolution at the time of discharge. Conversely, a higher admission Cr value was associated with lower odds of AKIN resolution at the time of discharge. We also demonstrate that AKIN resolution during index admission was associated with improved short- and long-term transplant-free survival (up to 3 years). Our findings warrant external validation in larger cohorts to further evaluate the impact of inpatient AKI resolution on cirrhosis outcomes. Our findings can help clinicians predict AKIN outcomes and encourage more aggressive management of AKI, especially in high-risk patients, which can improve mortality.

Response of soybean Cd to soil Cd and pH and its associated health risk in a high geological background area in Guizhou Province, Southwest China.

This study comprehensively examined the accumulation of cadmium (Cd) in soybeans grown in low- and high-Cd soils around the high geological background areas in Guizhou province. The aim was to analyze the relationship between soybean Cd and soil pH and soil Cd, alongside assessing the potential carcinogenic and non-carcinogenic risks associated with Cd in soybeans. Cd content of soybeans cultivated in the high-Cd area (0.430 mg/kg) was significantly higher than that in low-Cd areas (0.156 mg/kg) (P < 0.05). Biological concentration factors (BCFs) of soybean for Cd in low- and high-Cd areas were 0.282 and 0.314, respectively, with no significant differences (P > 0.05). Multiple linear regression results indicated that soil pH was a determining factor for Cd accumulation in soybeans in both areas. Furthermore, soil pH and soil Cd could accurately predict Cd accumulation in soybeans according to the neural network model. These findings suggest that regulating soil pH could reduce Cd accumulation in soybeans in areas with high geological background. In both areas, there was no significant non-carcinogenic risk for the adult population (HQ value < 1) through soybean consumption. However, according to the Monte Carlo model, the percentage of Cd in soybeans exceeding the acceptable range (CR value > 1.00 × 10 -04) in areas was 99.18%, indicating an unacceptable carcinogenic risk for the adult population. Our discussion revealed that reducing the soybean intake and increasing soil pH did not effectively lower the carcinogenic risk of Cd in soybeans to an acceptable range (CR value ≤ 1.00 × 10 -04). These findings necessitate further exploration of alternative remediation strategies to ensure the safe production of soybeans, such as screening for low-Cd accumulation soybean varieties and implementing the combined remediation strategies.

Internal structure validation of a teacher autonomy scale through confirmatory factor analysis

Purpose: Teacher autonomy is defined as the freedom of teachers to organize the learning and teaching process at school. The teaching autonomy scale measures teacher autonomy (Pearson &amp; Hall, 1993). This study was conducted to identify whether the measuring instrument of teacher autonomy meets the validity and reliability requirements of a measuring instrument. Method: The number of respondents in this study was obtained using a proportional sampling technique involving 170 respondents. The teacher autonomy measuring instrument produced from this study consists of 17 items that measure two dimensions; curriculum autonomy and general teaching autonomy. The quantitative data analysis techniques used were content-based validity tests through CVR and readability tests, validity evidence based on internal structure through CFA, and reliability tests based on homogeneity (internal consistency) through CR and AVE. Result: Shows CVR value with a minimum value of 0.78; loading factor ≥ 0.4, except for item 7 and item 8, as well as fit model fit with RMSEA = 0,077; RMR = 0,030; GFI = 0,847; CFI = 0,858; TLI = 0,797; NFI = 0,805; and p-value &lt; 0.05. reliability test through CR value (0.944) &gt; 0.7 and AVE (0.544) &gt; 0.4. Conclusion: The adaptation of the teacher autonomy measurement tool for female junior high school teachers met good validity and reliability values.