Adhesion Values Research Articles

Evaluation of multifunctional marine coatings enriched with organometallic biocides supported on ZSM-5 zeolite for biofouling prevention

There is significant concern regarding the biocides commonly used in commercial antifouling protection systems because of their high concentrations in coastal areas and the potential harm they can cause to marine organisms. Thus, much research has been dedicated to replacing these biocides with environment-friendly alternatives. Particularly, the use of natural products that inhibit the settlement of fouling organisms is the key to antifouling coating technology. The purpose of this study was to develop antifouling paints by using eco-friendly compounds and implement a multifunctional coating factor. Natural-origin biocidal agents, such as capsaicin, and a copper-ion release system supported on synthetic zeolite ZSM-5 were used. The formulations resulted in viscosities and particle sizes similar to those of commercial antifouling paints. The capsaicin coatings exhibited less fracture damage and more resistance to deformation in the flexibility and cupping tests. In the adhesion tests, all formulations exceeded 3 MPa, thereby enhancing the adhesion values of conventional antifouling agents. However, the capsaicin coatings exhibited less abrasion resistance than those containing zeolite. Corrosion resistance tests using electrochemical impedance spectroscopy indicated good anti-corrosive properties, particularly in the coatings with 8 % and 10 % copper. All formulations proved to be bactericidal within 6 h, and some completely eliminated the cell density by 3 h, highlighting the effectiveness of the biocide against the marine strain Pseudoalteromonas sp. UCO92.

Exploring the probiotic potential of Lactiplantibacillus pentosus SM1: Resistance, anti-microbial activity, anti-biofilm, cytotoxic activity, and safety properties

Lactiplantibacillus pentosus SM1 displayed notable resistance to acidic environments, with over 76% survival after 3 h in low pH conditions, and demonstrated viability in simulated gastrointestinal fluids. The Lpb. pentosus SM1 exhibited surface hydrophobicity, auto-aggregation, co-aggregation, and adhesion values of 59.60%, 38.80%, 44.90%, and 13.10% respectively. The anti-adhesion capability of Lpb. pentosus SM1 against Listeria monocytogenes adhesion to Caco-2 cells was demonstrated by its ability to compete with, inhibit, and displace at rates of 54.10%, 48.80%, and 23.90%, respectively. The Lpb. pentosus SM1 exhibited broad-spectrum anti-microbial activity, particularly against Gram-positive bacteria, and inhibited biofilm formation. The strain also showcased antioxidant activity, effectively scavenging DPPH (57.60%) and ABTS (60.54%) radicals. Notably, it absorbed 51.60% of cholesterol, highlighting its potential for cholesterol-lowering benefits. The cytotoxicity values were measured at 36.57 mg/mL for HT-29 and 38.20 mg/mL for Hela cancer cell lines. Importantly, Lpb. pentosus SM1 was free of hemolytic activity and biogenic amines, demonstrating a favorable safety profile. Lpb. pentosus SM1 exhibited the strongest resistance to ampicillin, while its resistance to erythromycin was the weakest, with inhibition zones measuring 15.50 mm and 26.40 mm, respectively. These findings suggest that Lpb. pentosus SM1 has promising applications as a probiotic candidate for promoting gut health and preventing pathogenic infections.

Discontinuity-enhanced icephobic surfaces for low ice adhesion

HypothesisPassive low ice-adhesion surfaces are frequently composed of soft materials; however, soft materials potentially present durability issues, which could be overcome by fabricating composite surfaces with patterned rigid and soft areas. Here we propose the innovative concept of discontinuity-enhanced icephobic surfaces, where the stress concentration at the edge between rigid and soft areas, i.e. where discontinuities in elasticity are located, facilitates ice detachment. ExperimentsComposite model surfaces were fabricated with controlled rigid-soft ratios and discontinuity line lengths. The ice adhesion values were measured while recording the ice/substrate interface, to unravel the underpinning ice detachment mechanism. The experiments were complemented by numerical simulations that provided a better understanding of the ice detachment mechanism. FindingsIt was found that when a surface contains rigid and soft areas, stress is concentrated at the edge between soft and hard areas, i.e. at the discontinuity line, rather than all over the soft or rigid areas. An unexpected non-unidirectional crack propagation was observed for the first time and elucidated. When rigid and deformable materials are present, the crack occurs on the discontinuity line and propagates first on rigid and then on soft areas. Moreover, it was demonstrated that an increase in discontinuities promotes crack initiation and leads to a reduction of ice adhesion.

The effect of size concentration, lubricant and plasticizer agents contents on cold sizing process performance of cotton warp yarns: modelling and optimization studies

Cold sizing is the alternative to conventional hot sizing of cotton warp yarns due to this low-energy consuming character. This work aimed to evaluate the effects of size recipe ingredients on the cold sizing performance of cotton warp yarns. A three factors-three levels Box-Behnken experimental design and a response surface methodology were investigated to examine the effect of size concentration (40, 50, and 60 g/L), lubricant agent content (0%, 4%, and 8%), and plasticizer agent content (0%, 5%, and 10%) on sizing properties. In this work, the effect of experimental parameters was determined by using the analysis of variance (ANOVA) test. Therefore, a multi-objective optimization technique was used to optimize the output responses in terms of the maximum value of size cohesion power, the maximum value of size adhesion to cotton fibers, the maximum values of mechanical properties of sized cotton warp yarns, and the minimum value of hairiness of warp yarn after cold sizing. Finally, the experimental results are in good agreement with those obtained by SEM and FTIR analysis. In addition, desizing efficiencies and wettability results proved that the optimum size recipe was successfully removable from cotton fabrics by the desizing process in hot water.

Safety and effectiveness of a drug-loaded haemostatic sponge in chronic rhinosinusitis: a randomized, controlled, double-blind study

Some cases of chronic rhinosinusitis (CRS) require surgical treatment and postoperative nasal packing, but bleeding and adhesion are common complications after nasal surgery. Biodegradable drug-loaded implants hold great therapeutic options for the treatment of CRS, but little data are available regarding the safety and efficacy of a novel drug-loaded haemostatic sponge (DLHS) in the sinus. The aim of this study was to investigate the safety and efficacy of DLHS in the sinus. We conducted a prospective, randomized, controlled, double-blind clinical trial. In this clinical trial, 49 patients were enrolled and randomly divided into 2 groups: group A (n = 25) had the DLHS containing 1 mg budesonide and 0.67 mg sodium hyaluronate placed into the sinus, and group B (n = 24) had the Nasopore placed after ESS. Endoscopic follow-up was performed for 12 weeks, and the findings were classified using the discharge, inflammation, polyps/oedema (DIP) endoscopic appearance scores. All patients completed questionnaires to evaluate their sinonasal symptoms by using the sinonasal outcome test-22 (SNOT-22) Chinese version and visual analogue scale (VAS). Serum cortisol concentration in group A was measured prior to surgery and at days 1, 3, 7, and 14 after nasal surgery. Comparing group A and group B, at 2 weeks, no significant differences were observed in either objective or subjective parameters. The mean value of VAS for rhinorrhoea and DIP for oedema and the mean value of nasal adhesion were significantly lower in Group A than in Group B at 6 and 12 weeks, but a significant difference did not occur in SNOT-22 and VAS for dysosmia between the two groups at 6 and 12 weeks. The mean serum cortisol concentrations in group A at the follow-up were within normal limits without remarkable fluctuations. This study demonstrates the safety and efficacy of a novel biodegradable DLHS with the possibility of being used in CRS patients, and this sponge may reduce inflammation and minimize adhesions via controlled local drug delivery without measurable systemic exposure.

Effect of the mechanical densification process in wood material on the surface adhesion strength of varnishes

This research aimed to determine the impact of the mechanical densifying process of wood material on the varnish surface adhesion strength. Specimens from black pine (Pinus nigra) and Uludag fir (Abies bornmuelleriana Mattf.) were subjected to densification in a hydraulic press at 140 °C to the extent of 25% and 50% in the radial direction. While densification increased the surface adhesion strength of the varnish layer in black pine, the value decreased in fir. Regarding the interaction between densification ratio, surface treatment, and wood type, the highest surface adhesion strength of the varnish layer was found in black pine + unsanded surface + 25% densification, and the lowest was in Uludag fir + unsanded surface + 50% densification. It can be stated that the densification process creates high adhesion values for the polyurethane varnish in the black pine wood type. The sanding process has an intensifying effect on these values, and the products that were obtained from the polyurethane varnished samples do not require sanding. Considering these situations can provide significant advantages in projects with wood materials subjected to the densification process.

Influence of Bond Coat Roughness on Adhesion of Thermal Barrier Coatings Deposited by the Electron Beam–Physical Vapour Deposition Process

Thermal barrier coatings (TBCs) are effective protective and insulative coatings on hot section components of turbine engines. The quality and subsequent performance of the TBCs are strongly dependent on the adhesion between the coating and the metal substrate. The adhesion strength of TBCs varies depending on the substrate materials and coating, the coating technique used, the coating application parameters, the substrate surface treatments, and environmental conditions. Therefore, the roughness of the substrate surface has a significant effect on the performance of the TBC system. In this work, the roughness and microstructure of the 7YSZ (7 wt.% yttria-stabilised zirconia) top coat under different bond coat roughness treatments were studied. The purpose of this paper was to investigate the influence of the roughness of the bond coat on the adhesion of 7YSZ TBCs prepared by the electron beam–physical vapour deposition (EB-PVD) process. The VPA (vapour phase aluminium) bond coat was deposited on Inconel 718 nickel superalloy substrate using the above-the-pack technique. The ceramic top coat was applied to the bond coat using the EB-PVD process. The dependence between the TBC coating roughness and the bond coat roughness was determined. Adhesion strength measurements were performed according to the ASTM C 633 standard test method. The highest adhesion value observed in the tensile adhesion tests was 105 MPa. However, it was not determined whether the surface roughness of the bond coat affects the adhesion of the 7YSZ top coat.

Formulation and investigation of differently charged β-cyclodextrin-based meloxicam potassium containing nasal powders

Nasal systemic drug delivery may provide an easy way to substitute parenteral or oral dosing, however, the excipients have an important role in nasal formulations to increase the permeability of the mucosa and prolong the residence time of the drug. In this work, we aimed to produce meloxicam potassium monohydrate (MXP) containing nasal powders by a nano spray drier with the use of a neutral, an anionic and a cationic β-cyclodextrin as permeation enhancers, and (polyvinyl)alcohol (PVA) as a water soluble polymer. The following examinations were performed in order to study the effect of the applied excipients on the nasal applicability of the formulations: laser scattering, scanning electron microscope measurement, XRPD, DSC and FTIR measurements, adhesivity, in vitro drug release and permeability tests through an artificial membrane and RPMI 2650 cells. Based on our results, spherical particles were prepared with a size of 1.89–2.21 µm in which MXP was present in an amorphous state. Secondary interactions were formed between the excipients and the drug. The charged cyclodextrin-based formulations showed significantly higher adhesive force values regardless of the presence of PVA. The drug release was fast and complete. The passive diffusion of MXP was influenced not only by the charge of the cyclodextrin, but the presence of PVA, too. The permeation of the drug was enhanced in the presence of the anionic cyclodextrin testing it on RPMI 2650 cell model.

Multibraided Fixed Retainers with Different Diameters after Magnetic Resonance Imaging (MRI): In Vitro Study Investigating Temperature Changes and Bonding Efficacy.

Orthodontists are often asked to remove fixed retainers before patients undergo magnetic resonance imaging (MRI). The present in vitro study was designed to analyze the heating and bonding efficacy of stainless steel multibraided fixed retainers after 1.5- and 3-tesla (T) MRI. A total of 180 human mandibular incisors were used to create 45 specimens of four teeth each, divided into nine groups. Handmade multibraided fixed retainers of three different sizes, defined by the diameter of the initial wire used (0.008″, 0.010″ and 0.012″), were tested. Three groups underwent MRI at 1.5 T, another three groups underwent MRI at 3 T and the last three groups did not undergo MRI. Temperature was assessed before and after MRI. Shear bond strength (SBS) and adhesive remnant index (ARI) were assessed after MRI for all groups. Data were statistically analyzed (p < 0.05). After 1.5 T exposure, no significant temperature increase from T0 to T1 was observed in any of the groups (p > 0.05). Regarding the 3 T groups, a significant difference from T0 to T1 was found for all the groups (p < 0.05). Temperature changes were not clinically relevant, as they were less than 1 °C for all groups except for group 3 (ΔT0-T1: 1.18 ± 0.3 °C) and group 6 (ΔT0-T1: 1.12 ± 0.37 °C). Furthermore, there were no significant differences between the temperature variations associated with different wire diameters (p > 0.05). No significant changes in SBS or ARI were found (p > 0.05). Since overheating was irrelevant and adhesion values did not change, the tested devices were concluded to be safe for MRI examinations at 1.5 T and 3 T.

Determining friction properties of ABS plastic in contact with loamy soil

The paper explores the feasibility of substituting steel working bodies with polymer ones in soil-cultivating units. (Research purpose) The research aims to investigate how the friction parameters of acrylonitrile butadiene styrene (ABS plastic) are affected by variations in absolute soil moisture and speed of the unit during the interaction of its working body with loamy soil. (Materials and methods) A laboratory unit was developed to examine the friction characteristics of the polymer in contact with loamy soil. The study measures the friction and adhesion properties by altering the absolute moisture of loamy soil. (Results and discussion) Graphs were constructed to illustrate the relationship between of the friction parameters of acrylonitrile butadiene styrene (ABS plastic) on absolute soil moisture. It was determined that at absolute soil moistures of 18, 20 and 26 percent, the friction coefficients of acrylonitrile butadiene styrene are 0.45, 0.5 and 0.6, respectively. The adhesion values were recorded at 100, 145 and 700 pascals for absolute soil moistures of 18, 20 and 28 percent, respectively. A decrease in both friction and adhesion was observed when the soil moisture reached between 26% and 28%. (Conclusions) The friction properties of acrylonitrile butadiene styrene (ABS plastic) are lower than those of steel, yet significantly higher than those of fluoroplastic. Further research in this area is expected to significantly increase the effi ciency of selecting materials for the manufacturing of working parts in soil-cultivating units, while also reducing energy costs.

Improved quantification of tumor adhesion in meningiomas using MR elastography-based slip interface imaging.

Meningiomas, the most prevalent primary benign intracranial tumors, often exhibit complicated levels of adhesion to adjacent normal tissues, significantly influencing resection and causing postoperative complications. Surgery remains the primary therapeutic approach, and when combined with adjuvant radiotherapy, it effectively controls residual tumors and reduces tumor recurrence when complete removal may cause a neurologic deficit. Previous studies have indicated that slip interface imaging (SII) techniques based on MR elastography (MRE) have promise as a method for sensitively determining the presence of tumor-brain adhesion. In this study, we developed and tested an improved algorithm for assessing tumor-brain adhesion, based on recognition of patterns in MRE-derived normalized octahedral shear strain (NOSS) images. The primary goal was to quantify the tumor interfaces at higher risk for adhesion, offering a precise and objective method to assess meningioma adhesions in 52 meningioma patients. We also investigated the predictive value of MRE-assessed tumor adhesion in meningioma recurrence. Our findings highlight the effectiveness of the improved SII technique in distinguishing the adhesion degrees, particularly complete adhesion. Statistical analysis revealed significant differences in adhesion percentages between complete and partial adherent tumors (p = 0.005), and complete and non-adherent tumors (p<0.001). The improved technique demonstrated superior discriminatory ability in identifying tumor adhesion patterns compared to the previously described algorithm, with an AUC of 0.86 vs. 0.72 for distinguishing complete adhesion from others (p = 0.037), and an AUC of 0.72 vs. 0.67 for non-adherent and others. Aggressive tumors exhibiting atypical features showed significantly higher adhesion percentages in recurrence group compared to non-recurrence group (p = 0.042). This study validates the efficacy of the improved SII technique in quantifying meningioma adhesions and demonstrates its potential to affect clinical decision-making. The reliability of the technique, coupled with potential to help predict meningioma recurrence, particularly in aggressive tumor subsets, highlights its promise in guiding treatment strategies.

Comparison of thrombogenicity in different types of drug-eluting stents during transition from DAPT to SAPT.

During the transition from dual antiplatelet therapy (DAPT) to single antiplatelet therapy (SAPT), previous studies have raised concerns about a rebound effect. We compared platelet and inflammatory cell adhesion on different types of stents in the setting of clopidogrel presence and withdrawal. In Experiment 1, three pigs were administered with DAPT, that is, clopidogrel and acetylsalicylic acid (ASA), for 7 days. Each animal underwent an extracorporeal carotid arteriovenous shunt model implanted with fluoropolymer-coated everolimus-eluting stent (FP-EES), biodegradable-polymer sirolimus-eluting stent (BP-SES), and biodegradable-polymer everolimus-eluting stents (BP-EES). In Experiment 2, two pigs were administered DAPT, clopidogrel was then withdrawn at day 7, and SAPT with ASA was continued for next 21 days. Then flow-loop experiments with the drawn blood from each time point were performed for FP-EES, BioLinx-polymer zotarolimus-eluting stents (BL-ZES), and BP-EES. The rebound effect was defined as the statistical increase of inflammation and platelet adhesion assessed with immunohistochemistry on the stent-strut level basis from baseline to day-14 or 28. Both experiments showed platelet adhesion value was highest in BP-EES, while the least in FP-EES during DAPT therapy. There was no increase in platelet or inflammatory cell adhesion above baseline values (i.e., no therapy) due to the cessation of clopidogrel on the stent-strut level. Monocyte adhesion was the least for FP-EES with the same trend observed for neutrophil adhesion. No evidence of rebound effect was seen after the transition from DAPT to SAPT. FP-EES demonstrated the most favorable antithrombotic and anti-inflammatory profile regardless of the different experimental designs.

Phosphate Esters: New Coating Materials for a Sustainable Release Paper.

AbstractPaper manufacturers have long used silicone as the coating agent for release liners. However, silicone‐based release paper is very difficult to recycle due to covalent bonds between silicone and fibers. The most suitable solution to overcome this problem is to use alternative coating materials with adequate release properties, provided that they can be easily repulped in typical paper recycling facilities. We proposed a coating agent composed of phosphate esters and dimethylacetamide in order to manufacture a recyclable and efficient release paper. Analyses carried out on coated sheets showed that phosphate esters allowed the formation of a surface with adequate release properties (low peeling force and surface free energy). In addition, the residual adhesion values obtained with phosphate esters confirmed that they are well anchored on the backing paper surface, thus limiting the mass transfer to the adhesive tape.

Surface engineering of aerospace aluminium alloys: Understanding alloying effects on chemical pre-treatment and sol-gel coating adhesion

The sol–gel process is a chemical surface preparation method based on hydrolysis and polycondensation reactions for enhanced adhesion for metallic substrates in adhesive bonding and coating applications. This paper describes an investigation into the effect of the microstructural complexity of two commonly used aerospace aluminium alloys (AAs) 2024-T3 and 7075-T6, on the response to different surface pre-treatments before deposition of the sol-gel coating and subsequent adhesive bonding.Different surface pre-treatments, including two abrasive treatments and three chemical surface pre-treatments were used, and their effect on surface chemistry, wettability and roughness was assessed. Surfaces were characterized by scanning electron microscopy, X-ray photoelectron spectroscopy, profilometry and static contact angles. A hybrid silane sol-gel film was deposited on the differently pre-treated aluminium alloys, an epoxy adhesive was applied and the adhesion properties were evaluated using pull-off testing. The role of the altered physicochemical properties of the pre-treated surfaces was related to the adhesion strength of the sol–gel reinforced epoxy/aluminium interfaces.The microstructural complexity of the aerospace alloys caused non-uniform responses to the pre-treatments, proving the importance of compatibility between material and treatment conditions. Statistical analysis revealed that, despite that overall higher adhesion values were obtained on rougher surfaces, only a strong correlation exists between the surface hydroxyl fraction and adhesion strength. The relation of roughness and water contact angle to interfacial adhesion was found to be non-significant.The findings of this study underscore the critical role of surface pre-treatments and their impact on adhesion strength in aerospace aluminium alloys, providing valuable insights for the effective utilization of sol-gel coatings in adhesive bonding and coating processes.

Detecting normal and cancer skin cells via glycosylation and adhesion signatures: A path to enhanced microfluidic phenotyping

Recruiting circulating cells based on interactions between surface receptors and corresponding ligands holds promise for capturing cells with specific adhesive properties. Our study investigates the adhesion of skin cells to specific lectins, particularly focusing on advancements in lectin-based biosensors with diagnostic potential. We explore whether we can successfully capture normal skin (melanocytes and keratinocytes) and melanoma (WM35, WM115, WM266-4) cells in a low-shear flow environment by coating surfaces with lectins. Specifically, we coated surfaces with Dolichos biflorus (DBA) and Maackia Amurensis (MAL) lectins, which were used to detect and capture specific skin cells from the flow of cell mixture. Alterations in glycan expression (confirmed by fluorescent microscopy) demonstrated that DBA binds predominantly to normal skin cells, while MAL interacts strongly with melanoma cells. Assessing adhesion under static and dynamic low-shear stress conditions (up to 30 mPa) underscores the reliability of DBA and MAL as markers for discriminating specific cell type. Melanocytes and keratinocytes adhere to DBA-coated surfaces, while melanoma cells prefer MAL-coated surfaces. A comprehensive analysis encompassing cell shape, cytoskeleton, and focal adhesions shows the independence of our approach from the inherent characteristics of cells, thus demonstrating its robustness. Our results carry practical implications for lectin-biosensor designs, emphasizing the significance of glycan-based discrimination of pathologically altered cells. Combined with microfluidics, it demonstrates the value of cell adhesion as a discriminant of cancer-related changes, with potential applications spanning diagnostics, therapeutic interventions, and advanced biomedical technologies.

A facile strategy to fabricate low viscosity and high cold tack soy protein-based adhesive for particleboard production

The utilization of soy protein as a wood adhesive has been successfully implemented in the industrial production of plywood. However, it is still a significant challenge to directly utilize soy protein-based adhesive for the fabrication of particleboard owing to its high viscosity and low cold tack. In this study, polyvinyl acetate (PVAc) emulsion was used to modify soy protein-based adhesive to reduce its viscosity and enhance its cold tack. By incorporating a content of 30% PVAc emulsion, the viscosity of the adhesive was reduced to 880 mPa·s, which was much lower than the pure soy protein-based adhesive value. Simultaneously, the cold tack was significantly increased by nearly 500 times after the addition of PVAc. The obtained adhesives met the requirements for particleboard production. In addition, the internal bonding strength of the produced particleboard reached 0.7 MPa, significantly exceeding the requirements for P6-grade particleboards (≥ 0.40 MPa, GB/T4897–2015). Moreover, it exhibited no formaldehyde emissions, making it a high-quality particleboard suitable for furniture applications. This study successfully presents a soy protein-based adhesive suitable for particleboard production using a simple blending modification approach, thereby expanding the application scope of soy protein-based adhesives.

Effect of fat on physicochemical, rheological, textural and sensory properties of Ricotta cheese spreads

SummaryThe effect of different fat contents of milk and cheese whey mixture (20:80) on physicochemical, rheological and sensory properties of Ricotta cheese spread (RCS) was evaluated. Four types of product such as no‐fat milk (NFM)‐RCS, low‐fat milk (LFM)‐RCS, medium‐fat milk (MFM)‐RCS and full‐fat milk (FFM)‐RCS were prepared from Ricotta cheese curd added with salt (1.5%) and guar gum (0.4%). The NFM‐RCS had higher (P &lt; 0.05) protein, ash, acidity, dynamic modulus (G' and G"), critical stress, firmness, work of shear, stickiness, work of adhesion values and lower fat, and pH, L*, a*, b* values when compared with LFM‐, MFM‐ and FFM‐RCS. Except spreadability, highest sensory scores for all other attributes were found in MFM‐RCS when compared with other experimental samples. This study indicated that increase in fat content or decrease in protein content of RCS samples produced lower viscoelastic modulus values, firmness, stickiness, adhesiveness and higher spreadability, yield, solids recovery and highly acceptable sensory characteristics.

Atomic Force Microscopy beyond Topography: Chemical Sensing of 2D Material Surfaces through Adhesion Measurements.

Developing new functionalities of two-dimensional materials (2Dms) can be achieved by their chemical modification with a broad spectrum of molecules. This functionalization is commonly studied by using spectroscopies such as Raman, IR, or XPS, but the detection limit is a common problem. In addition, these methods lack detailed spatial resolution and cannot provide information about the homogeneity of the coating. Atomic force microscopy (AFM), on the other hand, allows the study of 2Dms on the nanoscale with excellent lateral resolution. AFM has been extensively used for topographic analysis; however, it is also a powerful tool for evaluating other properties far beyond topography such as mechanical ones. Therefore, herein, we show how AFM adhesion mapping of transition metal chalcogenide 2Dms (i.e., MnPS3 and MoS2) permits a close inspection of the surface chemical properties. Moreover, the analysis of adhesion as relative values allows a simple and robust strategy to distinguish between bare and functionalized layers and significantly improves the reproducibility between measurements. Remarkably, it is also confirmed by statistical analysis that adhesion values do not depend on the thickness of the layers, proving that they are related only to the most superficial part of the materials. In addition, we have implemented an unsupervised classification method using k-means clustering, an artificial intelligence-based algorithm, to automatically classify samples based on adhesion values. These results demonstrate the potential of simple adhesion AFM measurements to inspect the chemical nature of 2Dms and may have implications for the broad scientific community working in the field.

Structure and Physical Properties of High Entropy Coatings on Surfaces of Weapons and Military Equipment Parts

The method of spraying CGDN coatings we propose is universal for repairing military equipment in the field. We carried out the method using a Dimet-425 installation and an IPG Photonics laser. The increase in heat resistance and adhesion of the coated sample relative to the uncoated sample is explained by the fact that the modified surface layer of the sample is a transition layer that has a sharp boundary with the base material or transition zone, consisting of a diffusion zone and a thermal-affected zone. The characteristic adhesion value obtained for CGDN coatings is 20 - 80 MPa, and the powder utilization rate reaches 50 - 80%

Cold rolling pass design and process based on controlling the distribution of material strain energy density

To address the problem of excessive grain boundaries and difficulty in eliminating defects on the inner surface of a pipe under a cold rolling pass, a method to control the distribution of material strain energy density is proposed, and a reasonable reduction in wall thickness is designed. An analysis model for inner surface defects was established using the inner wall adhesion value as the main criterion to quantitatively analyze the degree of defects on the pipe's inner surface. A systematic analysis of the rolling process of three different pass-opening shapes revealed that the opening shape dramatically affects the deformation and flow of the metal. During the rolling process, because of the unreasonable distribution of metal deformation caused by the existing pass design, the pipe is prone to high or concentrated stress, resulting in a low adhesion value for the inner wall and a greater degree of defects on the inner surface. Therefore, we propose a new opening shape and reasonably allocate the wall thickness reduction of the pipe to obtain a new pass. Numerical simulation reveals that, after rolling with the new pass, the inner wall adhesion value becomes relatively high, and the mechanics parameters have also been improved. The experimental results show that, under the new pass design, grain boundaries on the inner surface of the pipe are reduced and the smoothness is significantly improved, proving the feasibility of a cold rolling pass design based on controlling the distribution of material strain energy density.