Sugarcane agroindustry sustainability is the result of interaction of technology, land suitability, environment, management practices, by-products utilization, socioeconomic and geographic constraints of stakeholders. Nevertheless, as competitiveness factor is measured by three self-dependent indicators: sugarcane, sucrose and factory yield by statistically analysis, without consider multiple interrelated and interdependent socioeconomics and ecological factors. This paper presented a method for development of composite sustainability index, based on the Multicriteria evaluation Analytic Hierarchy Process (AHP) in a GIS, as a technique for supporting the decision making, which integrates in the analysis 14 sector-specific criteria ranked along all the three aspect of value chain, raw material production, processing and markets at the Mexican sugarcane agroindustry, as case study. These criteria were integrated in a hierarchic structure, pair-wise comparisons matrix and after obtaining the relative importance of each criterion, an integrated sustainability assessment tool was developed. Results show that the construction of sustainability index, provides a framework for assessing and zoning the sustainability, and the variables Sugarcane yield, Sugarcane Agroindustry final products, Sugar mill Yield and Productivity Index (Ratio Harvested area/sugar production), as socio-economic factors and Agro-climatic suitability for sugar cane cultivation are highly relevant with a overall weight of 69.5% and represent the key point of decision making by stakeholders.