Valorization Of Products Research Articles

Fruit and vegetable waste as a raw material for obtaining functional antioxidants and their applications: A review of a sustainable strategy

AbstractThe growing concern about environmental sustainability and increasing fruit and vegetable waste (FVW) generation have stimulated research into their potential valorization. This paper explores using this type of waste to obtain beneficial antioxidants in various fields of study. It is imperative to delve into the problems associated with FVW, shedding light on the staggering amounts generated and the environmental and economic challenges of waste disposal. The biochemical composition of FVW reveals the diverse array of components present, such as carbohydrates, proteins, lipids, vitamins, minerals, and of course antioxidants, which can be obtained through different extraction methods, depending on the conditions, the efficiency and the purpose that is required during the process of separation of these compounds from the organic matter. Antioxidants are compounds that can neutralize free radicals, which contributes to combating various conditions and diseases to promote and preserve human health. Several groups of antioxidants have been described, such as polyphenolic compounds in significant amounts in plant biomass as FVW. These antioxidants demonstrate benefits, efficacy and potential applications in industries like medicine, cosmetics, pharmaceuticals and functional foods. The valorization of FVW as a source of antioxidants presents a promising avenue for sustainable waste management and the production of natural antioxidants. This approach contributes to environmental preservation and promotes circular economy principles by transforming waste into valuable resources. This paper provides valuable insights into the vast potential of FVW valorization for antioxidant production and its application across diverse industries.

Biomethane and Green Hydrogen Production Potential from Municipal Solid Waste in Cape Coast, Ghana.

Biomethane and hydrogen are promising elements in the transition towards sustainable energy, due to their capacity to mitigate greenhouse gas emissions. In Ghana, efforts to promote sustainable waste valorization for energy production are underway; however, organic waste conversion into biomethane and hydrogen still needs to be expanded. This study aims to evaluate the potential of producing biomethane and hydrogen from the municipal solid waste in Cape Coast, and their injection into the national gas grid. The upgrading biogas obtained from anaerobic digestion of food/organic wastes was used to generate biomethane. The modified Buswell Equation and data from literature were used to estimate the amount of biomethane and hydrogen. The environmental impact was assessed using the CO2 equivalent emissions. The findings reveal that Cape Coast generated approximately 6,400 tons of food waste in 2021, with a projection to 11,000 tons by 2050. Biomethane and hydrogen quantities was estimated at 3,700,000 m³ and 784,000 kg in 2021, respectively. Their projection reaches to 6,600,000 m³ and 1,400,000 kg by 2050. Converting waste into biomethane and hydrogen is an eco-friendly method of their management and use for renewable energy in Ghana. Strategies can be integrated into Ghana national energy policies to encourage waste-to-energy projects.

Coconut husk waste products valorization for fabrication of luminescent titanium dioxide NPs as powerful tool for photodecomposition and food born infection: A sustainable strategy.

Fabricating metal oxide nanoparticles has garnered much attention lately because creating safe chemicals, sustainable materials, economic processes, and renewable resources is becoming increasingly important. This research shows how TiO2 nanoparticles (NPs) could be generated in an ecologically responsible way using waste coconut husk with the help of tender coconut. This extract functions as both a reducing agent and a sealing agent. The investigation of TiO2 NPs exploited ultraviolet (UV), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and field-emission scanning electron microscopy (FE-SEM) with energy-dispersive X-ray (EDX) methods. The germicidal properties of TiO2 NPs against food-borne pathogenic strains were studied using the agar well method. Employing Congo red pigment, the photodecomposition behavior was investigated. The TiO2 NPs produced had a crystallite size measuring 16.2nm. The average grain size of the sample, as measured by FE-SEM inspection, falls within the range of 15 to 25 nm. Impressive anti-germ effects against food-borne germs like Gram-positive (Staphylococcus aureus and Listeria monocytogenes), Gram-negative (Salmonella typhimurium and Escherichia coli) bacteria, and fungi (Candida albicans and Aspergillus niger) have been proved by the sustainable fabrication of TiO2 NPs. The catalytic effectiveness of Congo red decreased by 88% after 90 min. The findings suggest that sustainable synthesis of TiO2 NPs is an effective tool for food-borne germicides and photodecomposition behaviors.

Biological Upcycling of Plastics Waste.

Plastic wastes accumulate in the environment, impacting wildlife and human health and representing a significant pool of inexpensive waste carbon that could form feedstock for the sustainable production of commodity chemicals, monomers, and specialty chemicals. Current mechanical recycling technologies are not economically attractive due to the lower-quality plastics that are produced in each iteration. Thus, the development of a plastics economy requires a solution that can deconstruct plastics and generate value from the deconstruction products. Biological systems can provide such value by allowing for the processing of mixed plastics waste streams via enzymatic specificity and using engineered metabolic pathways to produce upcycling targets. We focus on the use of biological systems for waste plastics deconstruction and upcycling. We highlight documented and predicted mechanisms through which plastics are biologically deconstructed and assimilated and provide examples of upcycled products from biological systems. Additionally, we detail current challenges in the field, including the discovery and development of microorganisms and enzymes for deconstructing non-polyethylene terephthalate plastics, the selection of appropriate target molecules to incentivize development of a plastic bioeconomy, and the selection of microbial chassis for the valorization of deconstruction products.

Innovative trends and strategies for the integral valorization of products in the beer supply chain

This review aims to explore the latest innovations in beer supply chain. Innovation is defined as the combined application of strategies that enhance intrinsic and extrinsic product characteristics while optimizing complementary aspects for a modern approach to the food market. The study is structured around key themes that define the overall quality of the beer supply chain: safety (wholesomeness and authenticity), biological quality (chemical composition, sensory profile, and nutritional quality), process quality, convenience, and commodities. The goal is to promote accurate dissemination of information within the beer community and dispel common misconceptions. These misconceptions often arise from flawed approaches, leading to the creation of urban legends and unfounded prejudices. Special attention is given to innovation and research in the craft beer sector, which is rapidly growing in Italy and the global market.

Sustainable duckweed biomass valorization for dark fermentative hydrogen production: Process evaluation under meso- and thermophilic operations

Aquatic plants are rich in biomass and contain good amounts of carbohydrates and proteins which are amenable for valorization to generate bioenergy. Duckweed is rich in proteins and carbohydrates that grow abundantly in contaminated waterbodies, which is now tested for as a substrate for biohydrogen production. Dark-fermentative hydrogen production was done by hydrothermal pretreatment of duckweed biomass under 15 lbs pressure, evaluated under three different operating temperatures that cover mesophilic (35 °C) and thermophilic conditions (50 and 55°C). The study resulted in the maximum hydrogen production rate of 0.97 mmol/day in batch culture (160 mL) from 55 °C that was found superior to 50 °C (0.84 mmol/day) and 35 °C (0.38 mmol/day) operations. From the 7 days of operation, under uncontrolled pH conditions, substrate (chemical oxygen demand, COD) utilization was 57.27 %, which is higher than in mesophilic conditions (50.67 %). Efficient hydrolysate conversion was noticed with thermophilic conditions, especially under operation at 55 °C (416 mL H2/g of biomass) than mesophilic conditions (144 mL H2/g of biomass) suggesting that duckweed can be dependable biomass for hydrogen production, and the dark-fermentation can be an appropriate solution of aquatic weed biomass management in a sustainable approach.

Improving waste management strategies in the food sector: case studies from Spain, Tunisia and Hong Kong

Appropriate waste generation and management is becoming increasingly important in making food systems more sustainable. It is, therefore, imperative to both reduce waste generation and sustainably manage the waste that cannot be reduced. However, this is challenging due to the heterogeneity of waste materials, the high economic costs of optimizing food systems and the low awareness of the issue in some societies. This article analyzes three case studies that explore improvements in waste management in the food sector in Europe, Africa and Asia. The case studies focus on a horticultural cooperative in Spain, a seafood company in Tunisia and municipal waste management in Hong Kong, highlighting different challenges and approaches. Key factors for horticultural waste management include a consistent regulatory framework, appropriate management systems and waste traceability. The article also highlights the potential for valorisation of waste products, such as blue crab by-products, which can be used to obtain polysaccharides, proteins, lipids, antioxidants, flavonoids, vitamins and minerals. A shift from landfill to anaerobic digestion is also recommended for a more sustainable waste management. By identifying and quantifying waste streams and problematic waste types, alternative solutions can be developed to improve the sustainability of the global food supply chain.

Influence of the Drying Process on the Volatile Profile of Different Capsicum Species.

Chili is a globally significant spice used fresh or dried for culinary, condiment, and medicinal purposes. Growing concerns about food safety have increased the demand for high-quality products and non-invasive tools for quality control like origin tracing and safety assurance. Volatile analysis offers a rapid, comprehensive, and safe method for characterizing various food products. Thus, this study aims to assess the impact of the drying process on the aromatic composition of various Capsicum species and to identify key compounds driving the aromatic complexity of each genetic makeup. To accomplish these objectives, the aroma was examined in fruits collected from 19 different pepper accessions (Capsicum sp.) belonging to four species: one ancestral (C. chacoense) and three domesticated pepper species (C. annuum, C. baccatum and C. chinense). Fresh and dried samples were analyzed using a headspace PTR-TOF-MS platform. Our findings reveal significant changes in the composition and concentration of volatile organic compounds (VOCs) from fresh to dried Capsicum. Notably, chili peppers of the species C. chinense consistently exhibited higher emission intensity and a more complex aroma compared to other species (both fresh and dried). Overall, the data clearly demonstrate that the drying process generally leads to a reduction in the intensity and complexity of the aromatic compounds emitted. Specifically, fresh peppers showed higher volatile organic compounds content compared to dried ones, except for the two sweet peppers studied, which exhibited the opposite behavior. Our analysis underscores the variability in the effect of drying on volatile compound composition among different pepper species and even among different cultivars, highlighting key compounds that could facilitate species classification in dried powder. This research serves as a preliminary guide for promoting the utilization of various pepper species and cultivars as powder, enhancing product valorization.

Valorization of Peach Fruit and Wine Lees through the Production of a Functional Peach and Grape Juice.

The valorization of agri-food products not only represents important economic and environmental benefits but can also be a source of potentially profitable, functional, and safe ingredients. This study aimed to valorize peach fruit and wine lees (WL) by producing functional juice. WL were incorporated at different concentrations (1.5 and 2%; w:w) in unpasteurized peach and grape juice and subsequently stored under refrigeration (5 °C). The antimicrobial activity of WL in peach and grape juices was assessed against Listeria monocytogenes and Saccharomyces cerevisiae as well as physicochemical, nutritional microbiological, and sensory acceptability. The maximum addition of WL to the juice (2%) showed a significant inhibitory effect against L. monocytogenes (4-log reduction) and increased the content of total soluble solids (TSS) (10%), total polyphenol content (TPC) (75%), and total antioxidant activity (AOX) (86%). During storage, AOX, TPC, TSS, pH, and titratable acidity (TA) remained stable. A significant correlation was observed between TPC and AOX. Total mesophilic aerobic bacteria and yeast counts increased during storage. Fifty-seven percent of tasters (n = 26) rated the functional juice positively. Thus, these agri-food products could be useful for producing functional juices with a longer shelf life, contributing to their valorization.

VALORIZATION OF AGROPASTORAL PRODUCTS AND BY-PRODUCTS. CASE OF THE WILAYA OF NÂAMA (WESTERN ALGERIA)

The present work aims to design an approach of valorization of agropastoral products and by-products in the wilaya of Naâma (West Algeria). The analysis of the surveys carried out on 364 breeders reveals that lamb production is characterized by a high economic value with a share 85 % of sold products in total production, followed by «Milk» with a rate of 24%. The rate of wool shows that this resource is classified as a low-value by-product since 77% of producers are unable to sold their fleeces. The skin is classified as a by-product without significant value, since only about 03% of breeders sold their product. Our approach of valorization of this production is initiated in a broad conception that integrates several actors. The SWOT matrix for the valorization of agro-pastoral products highlights the internal strengths and strengths and external opportunities offered, identifying internal weaknesses to resolve them while limiting external threats.

Governance of the circular economy in the canned fish industry: A case study from Spain

Spain is the leading country in production, 305,403 tons in 2022, of canned fish in Europe. Part of its success is because this industry is one of the leading sectors in innovation and technology transfer within the agri-food chain in Spain. At the beginning of the 21st century, its research center created a line of product valorization, the seed of current research on circular economy. This article aims to analyze, from the New Institutional Economics (NIE) approach, the process of institutional change and the evolution of the Spanish canned fish sector. The evolution of the legal framework, as well as the internal organization of the sector and its strategies, have modified the governance relationships, altering the incentives and transaction costs of the industry actors. The results show the existence of two distinct stages, 2007–2015 and 2016–2022. In the first stage, most of the research projects were regional in nature and institutional relations were more limited. In the second stage, the creation of a solid legal framework together with the inauguration of a new research center, the incorporation of new equipment, the increase in the number of partners and the increase in relations with agents in the sector reinforced the implementation of the circular economy in the canning industry. In both periods, the high degree of associationism in the Spanish canned fish industry is key to creating economies of scale, increasing public and private collaborations and participating in research projects.

Gastronomic Identity and the Role of the Confraternities in the Valorisation of Local Products. The Confraternity of Bucho Raiano in the Promotion of Culture and Inland Tourism

Abstract Considering gastronomy as a source of expression of local culture, its use in tourism can contribute to enhancing and adding value to the destination, as well as encourage the pride of the local community, stimulating its production and consumption, and its dissemination outside the region. Bucho Raiano is a gastronomic product of identity and representativeness for the inland border region of Portugal (Riba Côa), for which its confraternity seeks the dissemination, the promotion of its consumption, and enhancement as a cultural resource. In this context, we seek to frame the Bucho Raiano gastronomic product, its identity, and the role of the confreres in its promotion and dissemination. Thus, this research aims to contextualize the Confraria do Bucho Raiano as a case study, evaluate the confreres’ perception of the confraternity’s mission, its strategies and contributions to the promotion and enhancement of this gastronomic product. The aim is to find out whether Bucho can be an important tourist product for this region and, consequently, strengthen the link between traditional local gastronomy and the tourist destination, according to the confreres’ perception.

Reinforcement learning-based control for waste biorefining processes under uncertainty

Waste biorefining processes face significant challenges related to the variability of feedstocks. The supply and composition of multiple feedstocks in these processes can be uncertain, making it difficult to achieve economically feasible and sustainable waste valorization for large-scale production. Here, we introduce a reinforcement learning-based framework that aims to control these uncertainties and improve the efficiency of the process. The framework is tested on an anaerobic digestion process and is found to perform better than traditional control strategies. In the short term, it achieves faster target tracking with increased precision and accuracy, while in the long term, it shows adaptive and robust behavior even under additional seasonal supply variability, meeting downstream demand with high probability. This reinforcement learning-based framework offers a promising and scalable solution to address uncertainty issues in real-world biorefining processes. If implemented, this framework could contribute to sustainable waste management practices globally, making waste biorefining processes more economically viable and environmentally friendly.

Microwave co-pyrolysis of industrial sludge and waste biomass: Product valorization and synergistic mechanisms

Microwave co-pyrolysis of textile dyeing sludge (TS) and furfural residue (FR) was investigated in this study. Comprehensive pyrolysis index (CPI) was employed to investigate pyrolysis performance and FR addition significantly improved co-pyrolysis. Product distribution showed that increasing FR ratio enhanced the bio-oil and gas with significant reduction in biochar. For bio-oil, FR addition neutralized the strong alkalinity and inhibited the formation of nitrogen compounds. Moreover, bio-oil maintained a very low oxygenates content (0.97–5.97%). For biochar, co-pyrolysis was favorable for the enrichment of C and H and mitigated the potential contamination. FR addition increased the calorific value and contributed to pore development of biochar. Online inspection displayed that co-pyrolysis drastically restrained the release of sulfur-compounds and nitrogenates in volatile, while enhanced the production of alkanes, aldehydes, and ketones. Moreover, the interaction between TS and FR was influenced by their major components. For heavy metals (HMs), Er was at low risk for most HMs and FR addition ratios of 40 and 80 wt% appeared to be more favorable. Principal component analysis (PCA) showed that FR addition changed the decomposition behavior and affected co-pyrolysis process. This study also evaluated the co-pyrolysis synergistic mechanisms of TS and FR. Overall, microwave co-pyrolysis is a novel and effective method to reduce environmental pollution and produce high-quality products, providing new insights for the low consumption and efficient utilization of industrial solid waste.

Technological possibilities for adding value on defective skins: Practical valorization of leather products with chromium and dyeing spots

In this study, decolorization via a bleaching operation was carried out on chrome and dye spotted skins with several bleaches to valorize the defective leather materials. Sodium perborate, hydrogen peroxide, sodium thiosulfate, sodium percarbonate, and oxalic acid were applied as bleaching agents in production. Sodium perborate by itself was applied and combined with other bleaching agents. Combined processes were also supported with an emulsifier agent for uniform distribution and deeper penetration of bleaching agents into the fibers. Color changes and differences on leather products were determined by Konica Minolta CM-3600d test apparatus spectrophotometrically before and after the applications. Bleached leathers were processed again, re-dyed, and finished after the bleaching operations. Then, bleaching performances of the single and combination applications were also evaluated for the leather strength indicators by analyzing tensile and tear strength of the final products as well as chromium (VI) oxidation of basic chromium (III) salts used in tanning. Antibacterial properties of the final bleached products were also investigated. As a result, sodium perborate was found to provide the most effective and safe bleaching without any physical and chemical deformation by creating antibacterial activity on leather.

Valorization of wheat production in marginal areas: farmer-centric experimentation for variety choice and evolutionary population development

In Italy, from 2000 to 2010, 58% of farms in mountain areas were abandoned leading to a 33% decrease in available land for agriculture. This research aimed to restore value and competitiveness to the Apennine area, by proposing a balanced and sustainable agriculture model. Following the needs of farmers, underutilised cereals were selected as the ideal genetic material for the study and development of short local food supply chains. The field experiments were carried out in two organic farms located in the Emilia-Romagna Region (Italy). During two growing seasons, seven wheat genotypes, two wheat evolutionary populations and one einkorn mixture were cultivated under organic farming management. Results related to functional traits are presented along with the main agronomic and technological parameters that were determined. Several nutritional properties are included. Mean yield and stability performance over environments for each genotype were explored using the “Genotype and Genotype by Environment biplot” elaboration. Considering yield performances, “Benco” was closer to the ‘ideal’ genotype. All the results were evaluated with the farmers, who expressed their own preferences from field observations. The right coupling between environment and genotypes can discourage the abandonment of hilly and mountainous farms by enhancing the economic competitiveness of agriculture in these regions.

Life Cycle Assessment of Hydrothermal Carbonization: A Review of Product Valorization Pathways

Hydrothermal carbonization (HTC) has the potential to be a sustainable and environmentally beneficial approach for organic waste treatment. It is likely that HTC product use will dictate the viability of large-scale HTC facilities; therefore, understanding the viability and environmental implications associated with HTC product valorization pathways is critical. The overall goal of this review is to gain an understanding of how HTC product valorization is currently being modeled in life cycle assessment studies, and to use such information to assess current research and/or data needs associated with product valorization. To accomplish this, a review of existing HTC literature was conducted and used to assess the current state of knowledge surrounding the environmental implications of HTC product use. From this review of the literature, it is clear that potential exists for HTC product valorization. To realize this potential in a full-scale application, research gaps and data needs were identified that included a system-level integration to evaluate location-specific information as well as more extensive characterization of the impact of HTC product properties on valorization impacts.

Leaching of Phytochemicals from Beans during Hydration, Kinetics, and Modeling.

In the current era, there is a growing emphasis on the circular economy and the valorization of waste products. Bean processing industries generate substantial nutrient-rich waste laden with valuable phytochemicals. Understanding the leaching patterns and kinetics of major phytochemicals is key to designing better processes leading to increased sustainability. This review investigates phytochemical leaching mechanisms and kinetic modeling methods. Firstly we lay the foundation with a broad theoretical framework, and later deal with kinetic modeling approaches and promising areas for future research. Currently, the composition of industrial-scale bean wastewater remains undocumented in the open literature. Nonetheless, drawing from existing studies and general bean composition knowledge, we proposed a multi-phase leaching process. We hypothesize three distinct phases: initial leaching of phytochemicals from the outer seed coat, followed by a second phase involving polysaccharides, and concluding with a third phase wherein phenolic acids within the cotyledons leach into the hydration water. This review aims to shed light on the complex process of phytochemical leaching from common beans during hydration. By combining theoretical insights and practical modeling strategies, this work seeks to enhance our understanding of this phenomenon and ultimately contribute to the optimization of food processing methods with reduced environmental impact.

GEOGRAPHICAL INDICATIONS THROUGH THE PERSPECTIVE OF SUSTAINABLE DEVELOPMENT

While globalization promotes the homogenization of consumption, it is possible to observe during the last years a change in consumers' behavior towards a valorization of local products produced traditionally. In this context are the Geographical Indications (GIs), responsible for identifying the origin of a given product or service when its place of origin has become known for its production or when certain product quality is linked to its demographic origin. The GIs also preserve local traditions and the natural environment, as well as foster farmers’ market access, which makes these labels be seen as a development tool. Therefore, this work verifies the potential of GIs to contribute to the dimensions of sustainable development (SD), which are economic, social, and environmental. A bibliographic literature review was carried out. Results show that a GI can contribute to the three dimensions of sustainability, which are social, economic, and environmental.

Whole genome structural predictions reveal hidden diversity in putative oxidative enzymes of the lignocellulose-degrading ascomycete Parascedosporium putredinis NO1.

Economic valorization of lignocellulose is paramount to realizing a true circular bioeconomy; however, this requires the development of systems and processes to expand the repertoire of bioproducts beyond current renewable fuels, chemicals, and sustainable materials. Parascedosporium putredinis NO1 is an ascomycete that thrived at the later stages of a wheat-straw composting community culture, indicating a propensity to degrade recalcitrant lignin-enriched biomass, but exists within an underrepresented and underexplored fungal lineage. This strain has been proven to be an exciting candidate for the identification of new enzymes targeting recalcitrant components of lignocellulose following the recent discovery of a new lignin β-ether linkage cleaving enzyme. The first genome for the genus Parascedosporium for P. putredinis NO1 genome was sequenced, assembled, and annotated. The genome is 39 Mb in size, consisting of 21 contigs annotated to contain 9.998 protein-coding sequences. The carbohydrate-active enzyme (CAZyme) repertoire was compared to 2570 ascomycete genomes and in detail with Trichoderma reesei, Fusarium oxysporum, and sister taxa Scedosporium boydii. Significant expansion in the oxidative auxiliary activity class of CAZymes was observed in the P. putredinis NO1 genome, resulting from increased sequences encoding putative lytic polysaccharide monooxygenases (LPMOs), oxidative enzymes acting within LPMO redox systems, and lignin-degrading laccases. P. putredinis NO1 scored above the 95th percentile for AA gene density across the ascomycete phylum, suggesting a primarily oxidative strategy for lignocellulose breakdown. Novel structure-based searching approaches were employed, revealing 17 new sequences with structural similarity to LPMO, laccase, and peroxidase sequences and which are potentially new lignocellulose-degrading enzymes.IMPORTANCEAn annotated reference genome has revealed P. putredinis NO1 as a useful resource for the identification of new lignocellulose-degrading enzymes for biorefining of woody plant biomass. Utilizing a "structure-omics"-based searching strategy, we identified new potentially lignocellulose-active sequences that would have been missed by traditional sequence searching methods. These new identifications, alongside the discovery of novel enzymatic functions from this underexplored lineage with the recent discovery of a new phenol oxidase that cleaves the main structural β-O-4 linkage in lignin from P. putredinis NO1, highlight the underexplored and poorly represented family Microascaceae as a particularly interesting candidate worthy of further exploration toward the valorization of high value biorenewable products.