Vacuum Ultraviolet Spectrometer Research Articles

Absolute measurement of vacuum ultraviolet fluxes from inductively coupled plasmas via metal surface photoemission currents

Quantifying vacuum-ultraviolet (VUV) fluxes typically requires vacuum-compatible spectrometers and is often associated with significant cost and effort. A simple technique for the absolute measurement of local VUV fluxes from plasmas using the photoemission from a set of coated metal plates, is described. The radiant power from a 13.56 MHz hydrogen plasma operating at 40–87 mTorr and with an radio frequency (RF) input power from 100 to 120 W was investigated by irradiating a set of 2 cm diameter Au, Ag and Cu plates. The variation in photoemission currents was compared with the photoelectric yield curves to estimate the absolute flux incident on the surfaces in the 113–190 nm range. The measured fluxes were found to have an uncertainty of 5%–30% when compared with the VUV spectrometer measurements. The VUV output power was found to have a maximum at a pressure of 70–80 mTorr and to increase with RF power. In all cases, the VUV output power was measured to be approximately 12%–16% of the RF input power to the matching network, in good agreement with spectroscopy results.

Vacuum-Ultraviolet spectrometer system for impurity emission measurement on a Compact Torus Injection System of EAST

Recently, a compact torus injection (CTI) system was developed for central fueling on experimental advanced superconducting tokamak (EAST). As impurity generated by the interaction between CTI plasma and the electrode material can dilute the fuel particle, it is important to measure impurity content in CTI and evaluate the effect of impurity on the plasma before the application of CTI to EAST. A vacuum-ultraviolet (VUV) spectrometer that utilizes a concave holographic grating with 1200 groove mm-1 was developed and installed on EAST-CTI for impurity emission measurement and transport study. The mainly parts of the spectrometer are an entrance slit, a concave holographic grating with 1200 groove mm-1 and a charge coupled device (CCD). The spectrometer is designed to image the spectra of 50–460 nm by turning the grating. Preliminary experimental results were obtained from the recent EAST-CTI campaign. Impurity line spectra from 50 to 460 nm wavelength range were measured and identified for several impurity species, such as iron, copper, chromium, oxygen, carbon and fluorine. For example, spectra in the intervals of 150 nm to 300 nm contained strong Fe lines. Helium spectra are also measured in the form of He I and He II spectral lines as helium is the main component of the plasma. The results show that the VUV spectrometer is capable of measuring impurity radiations on EAST-CTI and will be a useful tool for impurity behavior study.

Role of pinch in Argon impurity transport in ohmic discharges of Aditya-U Tokamak

We present experimental results of the trace argon impurity puffing in the ohmic plasmas of Aditya-U tokamak performed to study the argon transport behaviour. Argon line emissions in visible and Vacuum Ultra Violet (VUV) spectral ranges arising from the plasma edge and core respectively are measured simultaneously. During the experiments, space resolved brightness profile of Ar1+ line emissions at 472.69 nm (3p44s 2P3/2–3p44p 2D3/2), 473.59 nm (3p44s 4P5/2–3p44p 4P3/2), 476.49 nm (3p44s 2P1/2–3p44p 2P3/2), 480.60 nm (3p44s 4P5/2–3p44p 4P5/2) are recorded using a high resolution visible spectrometer. Also, a VUV spectrometer has been used to simultaneously observe Ar13+ line emission at 18.79 nm (2s22p 2P3/2–2s2p22P3/2) and Ar14+ line emission at 22.11 nm (2s21S0–2s2p 1P1). The diffusivity and convective velocity of Ar are obtained by comparing the measured radial emissivity profile of Ar1+ emission and the line intensity ratio of Ar13+ and Ar14+ ions, with those simulated using the impurity transport code, STRAHL. Argon diffusivities ~ 12 m2/s and ~ 0.3 m2/s have been observed in the edge (ρ > 0.85) and core region of the Aditya-U, respectively. The diffusivity values both in the edge and core region are found to be higher than the neo-classical values suggesting that the argon impurity transport is mainly anomalous in the Aditya-U tokamak. Also, an inward pinch of ~ 10 m/s mainly driven by Ware pinch is required to match the measured and simulated data. The measured peaked profile of Ar density suggests impurity accumulation in these discharges.

EUV/VUV Spectroscopy for the Study of Carbon Impurity Transport in Hydrogen and Deuterium Plasmas in the Edge Stochastic Magnetic Field Layer of Large Helical Device

The ergodic layer in the Large Helical Device (LHD) consists of stochastic magnetic fields exhibiting a three-dimensional structure that is intrinsically formed by helical coils. Spectroscopic diagnostics was employed in the extreme ultraviolet (EUV) and vacuum ultraviolet (VUV) wavelength ranges to investigate emission lines of carbon impurities in both hydrogen (H) and deuterium (D) plasmas, aiming to elucidate the impact of distinct bulk ions on impurity generation and transport in the edge plasmas of the LHD. The emission intensity of carbon CIII, CIV, CV, and CVI lines is significantly higher in the D plasma compared to the H plasma, indicating a greater sputtering rate of carbon materials in the D plasma, resulting in a higher quantity of carbon impurities originating from the divertor plates. A Doppler profile measurement of the second order of CIV line emission (1548.20 × 2 Å) was attempted using a 3 m normal-incidence VUV spectrometer in the edge plasma at a horizontally elongated plasma position. The flow velocity reaches its maximum value close to the outermost region of the ergodic layer, and the observed flow direction aligns with the friction force in the parallel momentum balance. The flow velocity increases with the electron density in H plasmas, suggesting that the friction force becomes more dominant in the force balance at higher density regimes. This leads to an increase in the impurity flow, which can contribute to the impurity screening. In contrast, the flow velocity in the D plasma is smaller than that in the H plasma. The difference in flow values between D and H plasmas, when the friction force term dominates in the momentum balance, could be attributed to the mass dependence of the thermal velocity of the bulk ions.

Experimental study on synchrotron radiation photoionization of secondary organic aerosol derived from styrene ozonolysis

Experimental study on synchrotron radiation photoionization of secondary organic aerosol derived from styrene ozonolysis

A portable diagnostic system for the quantification of VUV fluxes emitted from low-temperature plasmas

Vacuum-ultraviolet (VUV) spectroscopy is linked to a huge effort, in particular if absolute numbers are required. To overcome this, a flexible device is developed based on a photodiode and optical filters for wavelength selection. Characterization of the diagnostic is performed against a VUV spectrometer that is radiometrically calibrated down to 46 nm. In the first instance, the latter is used for an analysis of VUV spectra of inductively coupled low-temperature plasmas for a variety of discharge gases and mixtures. The measured photon fluxes can easily have comparable magnitude as the occurring ion flux, and it is demonstrated that the photonic energy distribution can change drastically with varying external parameters (pressure, RF power). This highlights the need for energy resolution for VUV flux detection and a set of ten optical filters was selected for the VUV diode system according to the respective prominent emission ranges of typical discharge gases for plasma processing. Recommended filter combinations for each of the discharge gases and mixtures are given. The developed diagnostic is calibrated in-house against the VUV spectrometer, which makes energy-resolved absolute VUV flux measurements up to photon energies of 27 eV possible. The calibration is performed individually for all the investigated discharge gases and the corresponding filter combinations, and an accuracy of better than 25% compared to the VUV spectrometer is attested for the investigated parameter space (0.3–10 Pa, 200–1100 W RF power). Its applicability is demonstrated by measuring VUV fluxes at two further low-temperature plasma setups.

A comparative study of oxidation of pure ammonia and ammonia/dimethyl ether mixtures in a jet-stirred reactor using SVUV-PIMS

Oxidation of pure ammonia or ammonia/dimethyl ether (NH3/DME) mixtures in O2/Ar in a jet-stirred reactor (JSR) at atmospheric pressure was experimentally studied using a synchrotron vacuum ultraviolet photoionization mass spectrometer (SVUV-PIMS) and a gas chromatograph (GC) to analyse the reaction intermediates and product species. Particular attention was given to the effect of DME addition on NH3 → NH2, a critical step that initiates NH3 oxidation and subsequent formation of nitrogen oxides. The initial mole fraction of NH3 was set to 0.01, and for the NH3/DME mixture, the NH3/DME molar ratio was set to 1. The experiments were performed at two equivalence ratios of ϕ = 1.0 and 0.2 in the temperature range of 500 – 1100 K. A kinetic model for NH3/DME oxidation was developed and kinetic analysis was performed. It was found that the addition of DME significantly promotes the NH3 to NH2 pathway and the mechanisms of this promotion effect are different at low and high temperatures. At a low temperature (∼ 600 K), NH3 → NH2 is mainly promoted by OH radicals produced from the DME low-temperature chain-branching reactions, while at a high temperature (∼ 1000 K), mainly by OH radicals produced from the reactions consuming HO2 and H radicals, which were formed from DME high temperature oxidation. At T > 800 K with ϕ = 0.2, the addition of DME promotes the formation of nitrogen oxides, however, at a low temperature of 600 K, the addition of DME only promotes the formation of N2O and NO2 but not NO. A reaction pathway analysis indicates that the oxidation of NO into NO2 at low temperature is promoted by HO2 and CH3OCH2O2, the intermediate products from the low temperature oxidation of DME.

A wide range experimental study and further development of a kinetic model describing propane oxidation

This work presents an experimental and kinetic modeling study of propane oxidation. Ignition delay times of propane were measured in a high-pressure shock tube and in rapid compression machines in the temperature range 689 – 1700 K at equivalence ratios of 0.5, 1.0 and 2.0 in ‘air’, for a wide range of pressures from 20 to 90 bar. CO and H2O mole fraction profiles for propane oxidation were measured in a shock tube behind reflected shock waves in the temperature range 1370–1840 K at equivalence ratios of 0.5, 1.0 and 2.0 and at a pressure of approximately 1.3 atm. Moreover, propane oxidation was studied using a jet-stirred reactor coupled to a synchrotron vacuum ultraviolet photoionization mass spectrometer at low temperatures in the range 565 – 690 K and at a pressure of 1 atm. This wide range of experimental datasets for propane oxidation was used to reoptimize and update our previous kinetic mechanisms, AramcoMech3.0 and NUIGMech1.1. In the current mechanism, NUIGMech1.3, the thermochemical parameters of all species relevant to low-temperature propane oxidation chemistry, including propyl-peroxyl, hydroperoxyl-propyl, hydroperoxyl-propyl-peroxyl, and carbonyl-hydroperoxide radicals, are updated based on newly calculated values at the CCSD(T)-F12/TZ-F12//B2PLYPD3/TZ///B2PLYP-D3/TZ level of theory. The improvements made in the thermochemical values and in the kinetic parameters for the low-temperature propane oxidation reactions in NUIGMech1.3 result in better model agreement with the new IDTs and speciation data, including carbon monoxide, formaldehyde, propene, acetaldehyde and various minor products such as ethylene, acetic acid, acrolein as well as various hydroperoxide and cyclic ether species.

An experimental and modeling study of tetramethyl ethylene pyrolysis with polycyclic aromatic hydrocarbon formation

Iso-olefins, in the C5–C8 range can potentially be blended with renewable gasoline fuels to increase their research octane number (RON) and octane sensitivity (S). RON and S increase with the degree of branching in iso-olefins and this is a desirable fuel anti-knock quality in modern spark-ignited direct-injection engines. However, these iso-olefins tend to form larger concentrations of aromatic species leading to the formation of polycyclic aromatic hydrocarbons (PAHs). Thus, it is important to understand the pyrolysis chemistry of these iso-olefins. In this study, a new detailed chemical kinetic mechanism is developed to describe the pyrolysis of tetramethyl ethylene (TME), a symmetric iso-olefin. The mechanism, which includes the formation of PAHs, is validated against species versus temperature (700–1160 K) measurements in a jet-stirred reactor at atmospheric pressure and in a single-pulse shock tube at a pressure of 5 bar in the temperature range 1150–1600 K. Synchrotron vacuum ultraviolet photoionization mass spectrometer (SVUV-PIMS) and gas chromatography (GC) systems were used to quantify the species in the jet-stirred reactor and in the single-pulse shock tube, respectively. The mechanism derives its base and PAH chemistry from the LLNL PAH sub-mechanism. The predictions are accurate for most of the species measured in both facilities. However, there is scope for mechanism improvement by understanding the consumption pathways for some of the intermediate species such as isoprene. The formation of 1, 2, and 3-ring aromatic species such as benzene, toluene, naphthalene and phenanthrene measured experimentally is analyzed using the chemical kinetic mechanism. It is found that the PAH formation chemistry for TME under pyrolysis conditions is driven by both propargyl addition reactions and the HACA mechanism.

Real-time VUV radiation monitoring in low-pressure hydrogen plasma based on fluorescence of sodium salicylate

Recently, vacuum ultra-violet (VUV) radiation emitted from plasmas has been of particular interest in semiconductor device fabrication because of the effects of its high-energy photons, such as induced damage or curing on low-k materials. Due to the difficulty of implementing conventional spectroscopic methods to monitor VUV radiation with high accuracy and time resolution in current plasma processing equipment, novel monitoring methods must be investigated. Therefore, in this work, we developed a compact VUV radiation monitoring system based on a scintillator, i.e. sodium salicylate (NaSal), for real-time VUV measurements. Compared to conventional VUV spectrometers, the system shows considerable implementation potential thanks to its compact size, higher detection accuracy and high time resolution. VUV radiation emitted by continuous and pulsed hydrogen plasmas generated at low pressure was investigated using the developed system. Using various filters, we were able to compare the VUV photon intensity in different wavelength ranges. It was found that the VUV photon intensity between 115 and 250 nm was about 2.5 times higher than in the region below 115 nm due to intense Lyman-α and molecular radiation, such as Lyman and Werner bands observed in low-pressure hydrogen plasmas.

Evaluation of self-absorption effect of He I resonance line by measurement of forbidden emission in helium arc jet plasma

We have proposed a new method to estimate the optical escape factor (OEF) in high-density helium (He) plasma. Plasma with an electron temperature of ca. 3 eV and density of 5 × 1013 cm−3 was generated by a cascaded arc discharge and rapidly cooled by the introduction of additional He gas, which resulted in a transition from ionizing to recombining plasma. With an increase in the gas pressure, the plasma became optically thick, and the He I forbidden line (spin-exchange intercombination line, 1 1S-2 3P: 59.1 nm) with resonance lines were simultaneously observed using a vacuum ultraviolet spectrometer. Comparison of the intensity ratio of the He I 58.4 nm resonance line to the forbidden emission with those by determined from the collisional-radiative model considering the self-absorption enabled the successful estimation of the OEF. The OEF was decreased with the ambient He gas pressure and was 6.6 × 10−4 and 3.5 × 10−5 for He gas pressures of 1.59 and 20.22 Pa, respectively.

Quantification of n-heptane low temperature oxidation products by proton-transfer-reaction mass spectrometry

While studies on the low temperature oxidation of organic compounds have been in depth, fast and accurate quantitative analysis of oxidation products, especially for those without standard samples, remains challenging and requires analytical developments. This work studied n-heptane low temperature oxidation in a jet-stirred reactor (JSR) using proton-transfer-reaction mass spectrometry (PTR-MS). The oxidation products were also analyzed by a synchrotron vacuum ultraviolet radiation photoionization mass spectrometer (SVUV-PIMS) for comparison. The results showed that PTR-MS was able to measure most oxygenated intermediates compared to SVUV-PIMS. Furthermore, the method for the quantification of low temperature oxidation products was studied. By employing a series of calibration gases, the sensitivities of PTR-MS were confirmed to be linearly related to proton-transfer reaction rates, which were calculated using the trajectory parameterization theory. Mole fraction profiles of oxidation products measured by PTR-MS were compared to SVUV-PIMS and literature gas chromatography data, and in most cases, the results showed good consistency. Special attention is needed for some molecules, such as carboxylic acids, formaldehyde, and peroxides. The effect of the humidity of the reaction environment and the fragment on the quantification need to be considered. Overall, PTR-MS is a promising instrument for the quantitative analysis of combustion products and has the potential to measure the total mole fraction of complex isomers (could not distinguish isomers) and to predict the mole fraction of products without a standard sample.

Dinitriles and nitriles are common intermediates of pyrrole pyrolysis

Pyrrole is a typical fuel nitrogen model compound of coal and it is the precursor of fuel-NOx. The mechanism and kinetics of pyrrole pyrolysis were studied in a jet-stirred reactor coupled with a synchrotron vacuum ultraviolet molecular beam mass spectrometer and a gas chromometer over the temperature range of 940–1240 K at atmospheric pressure. Two sets of new data of pyrrole pyrolysis were provided. Based on the photoionization efficiency analysis, nitrogenous products are mainly produced in the form of nitriles and dinitriles. Of the pyrrole pyrolysis products, six nitriles were newly identified including methyl isocyanide (C2H3N), cyanogen (NCCN), isocyanogen (CNCN), propionitrile (C3H5N), propanedinitrile (C3H2N2), butanedinitrile (C4H4N2). Mole fractions of pyridine (C5H5N), C3H2N2, cyanovinylacetylene (C5H3N), and benzonitrile (C7H5N) were also quantified. HCN is the dominant nitrogenous product of pyrrole pyrolysis. C2H2 and CH4 are the major carbonaceous products. An updated pyrrole kinetic model was proposed comprising 196 species and 2939 reactions. The production of pyridine and several nitriles during pyrrole pyrolysis could be reasonably predicted using the current model. C3H2N2 is mainly produced by the reaction between CH2CN and other nitriles, and it is converted into CH2CN and CH3CN. The reaction between CH3 and C3H2N2 is the most sensitive reaction for promoting the consumption of C3H2N2. Results of this work confirm the importance of dinitriles and nitriles during the pyrolysis of pyrrole as an important fuel-NOx model compound of coal and other nitrogen-containing fuels.

Vacuum Ultraviolet Fourier-transform Spectroscopy of 16O and 18O

A spectroscopic study of atomic oxygen (O i) is performed using the Fourier-transform vacuum ultraviolet (VUV) spectrometer at the Dichroïsme Et Spectroscopie par Interaction avec le Rayonnement Synchrotron beamline of the SOLEIL synchrotron. Transition frequencies of O i lines in the range between 76,000 and 151,000 cm−1, corresponding to wavelengths between 665 and 1306 Å, are presented. In the wavelength window a data set of 208 lines is obtained for which line centers were determined at an accuracy of ≤0.035 cm−1, verified through a comparison with previous VUV-laser spectroscopy at an accuracy of 0.008 cm−1. Transitions to upper states belonging to several ns and nd Rydberg series that converge to the 4S3/2, 2D, and 2P ionization limits are presented. Besides studies on the main 16O isotope, measurements of the 18O isotope are also performed, for which an enriched sample of 18O2 gas is used. A least-squares optimization analysis is performed after merging the present new data set with some relevant accurate literature data to extract a list of level energies at high accuracy. When comparing with the database of the National Institute of Standards and Technology, good agreement is found for levels with low principal quantum numbers n ≤ 7 or below excitation energies of 108,000 cm−1; however, significant deviations were found for levels with n > 7. The main result of the present study is the realization of an improved data set of transition frequencies and level energies for O i, with its usefulness demonstrated in a comparison with high-resolution astronomical spectra showing absorption in the line of sight to distant quasars.

Space-resolved vacuum-ultraviolet spectroscopy for measuring impurity emission from divertor region of EAST tokamak

The measurement of impurity distribution in the divertor region of tokamaks is key to studying edge impurity transport. Therefore, a space-resolved vacuum-ultraviolet (VUV) spectrometer is designed to measure impurity emission in the divertor region on EAST. For good spectral resolution, an eagle-type VUV spectrometer with 1 m long focal length with spherical holograph grating is used in the system. For light collection, a collimating mirror is installed between the EAST plasma and the VUV spectrometer to extend the observing range to cover the upper divertor region. Two types of detectors, i.e. a back-illuminated charge-coupled device detector and a photomultiplier-tube detector, are adopted for the spectral measurement and high-frequency intensity measurement for feedback control, respectively. The angle between the entrance and exit optical axis is fixed at 15°. The detector can be moved along the exit axis to maintain a good focusing position when the wavelength is scanned by rotating the grating. The profile of impurity emissions is projected through the space-resolved slit, which is set horizontally. The spectrometer is equipped with two gratings with 2400 grooves/mm and 2160 grooves/mm, respectively. The overall aberration of the system is reduced by accurate detector positioning. As a result, the total spectral broadening can be reduced to about 0.013 nm. The simulated performance of the system is found to satisfy the requirement of measurement of impurity emissions from the divertor area of the EAST tokamak.

Direct observation of the particle-phase bicyclic products from OH-initiated oxidation of 1,3,5-trimethylbenzene under NOx-free conditions

The OH initiated oxidation of 1,3,5-trimethylbenzene (1,3,5-TMB) under NOx-free conditions has been investigated by using a home-made vacuum ultraviolet (VUV) photoionization aerosol mass spectrometer complemented by high-level theoretical computations. The chemical composition of the nascent particles from the oxidation reaction is measured on-line and the high mass O2-bridged bicyclic compounds in the particle phase are directly observed and determined, with the aid of the deuterated 1,3,5-TMB experiments to confirm the species’ assignment. To illuminate the formation of the O2-bridged bicyclic compounds, the potential energy surfaces of the reaction of the bicyclic peroxy radical (BPR) with the hydroperoxy radical (HO2), and of the self-reaction of the BPR radical, have been theoretically calculated and then their reaction mechanisms are discussed in detail. This study provides direct evidence to support the essential role of the O2-bridged bicyclic compounds in the particle formation from the OH initiated oxidation of 1,3,5-TMB.

Predictive estimation of vacuum ultraviolet emission intensity in a low-pressure inductively coupled hydrogen plasma based on the branching ratio technique

Vacuum ultraviolet (VUV) emission has recently attracted attention in low pressure processing plasmas because of the possibility of high-energy photon damages on the substrates. To quantify the VUV induced damages during the plasma processes, it is need to use of a VUV spectrometer equipped with vacuum systems not readily available in industries. In this work, therefore, we report a simple method to estimate the VUV emission intensity of hydrogen plasmas utilizing a conventional visible spectrometer widely used in plasma processes. From the measurement of hydrogen emission spectra in the visible wavelength region, the VUV emission line (Lyman-β) was calculated using the branching ratio technique and enabled the estimation of Lyman-α emission intensity based on the Boltzmann relation with given plasma parameters. In addition, it was found that the method could also predict the VUV emission intensity for high density hydrogen plasma cases by considering the self-absorption effect by hydrogen atoms. • VUV emission intensity measurement and predictive estimation. • Calculation of VUV Lyman-α (121 nm) emission based on Branching ratio technique. • Correlation between predicted and measured VUV Lyman-α (121 nm) emission intensity. • Self-absorption effect of hydrogen atoms on VUV emission intensity estimation.

Line identification of boron and nitrogen emissions in extreme- and vacuum-ultraviolet wavelength ranges in the impurity powder dropping experiments of the Large Helical Device and its application to spectroscopic diagnostics

An impurity powder dropper was installed in the 21st campaign of the Large Helical Device experiment (Oct. 2019–Feb. 2020) under a collaboration between the National Institute for Fusion Science and the Princeton Plasma Physics Laboratory for the purposes of real-time wall conditioning and edge plasma control. In order to assess the effective injection of the impurity powders, spectroscopic diagnostics were applied to observe line emission from the injected impurity. Thus, extreme-ultraviolet (EUV) and vacuum-ultraviolet (VUV) emission spectra were analyzed to summarize observable impurity lines with B and BN powder injection. Emission lines released from B and N ions were identified in the EUV wavelength range of 5–300 Å measured using two grazing incidence flat-field EUV spectrometers and in the VUV wavelength range of 300–2400 Å measured using three normal incidence 20 cm VUV spectrometers. BI–BV and NIII–NVII emission lines were identified in the discharges with the B and BN powder injection, respectively. Useful B and N emission lines which have large intensities and are isolated from other lines were successfully identified as follows: BI (1825.89, 1826.40) Å (blended), BII 1362.46 Å, BIII (677.00, 677.14, 677.16) Å (blended), BIV 60.31 Å, BV 48.59 Å, NIII (989.79, 991.51, 991.58) Å (blended), NIV 765.15 Å, NV (209.27, 209.31) Å (blended), NVI 1896.80 Å, and NVII 24.78 Å. Applications of the line identifications to the advanced spectroscopic diagnostics were demonstrated, such as the vertical profile measurements for the BV and NVII lines using a space-resolved EUV spectrometer and the ion temperature measurement for the BII line using a normal incidence 3 m VUV spectrometer.

Development and preliminary test of a space-resolved vacuum-ultraviolet spectroscopy in EAST.

The impurity radiation from the divertor region of the EAST tokamak is dominantly in the wavelength range of vacuum ultraviolet (VUV) due to the elevated edge electron temperature. A space-resolved VUV spectroscopy is developed to measure impurity radiation in the divertor region. An eagle-type VUV spectrometer with a focal length of 1m is adopted in this system, equipped with a spherical grating and a charged-coupled device (CCD) detector. The performance of the VUV spectrometer is preliminarily tested on a synchrotron radiation facility. The wavelength calibration is conducted near 65nm. It is found that the wavelength range observed by the CCD detector is about 11.07nm around the central wavelength of about 65nm. With a linear dispersion of 0.0053 nm/pixel, it is possible to measure the ion temperature lower than 20eV at the edge region by analyzing the Doppler broadening of a carbon line. These test results show that the performance of the VUV spectrometer is capable of measuring divertor radiation and analyzing the ion temperature of edge impurity ions.

Absolute calibration of the Lyman-α measurement apparatus at DIII-D.

The LLAMA (Lyman-Alpha Measurement Apparatus) diagnostic was recently installed on the DIII-D tokamak [Rosenthal et al., Rev. Sci. Instrum. (submitted) (2020)]. LLAMA is a pinhole camera system with a narrow band Bragg mirror, a bandpass interference filter, and an absolute extreme ultraviolet photodiode detector array, which measures the Ly-α brightness in the toroidal direction on the inboard, high field side (HFS) and outboard, low field side (LFS). This contribution presents a setup and a procedure for an absolute calibration near the Ly-α line at 121.6nm. The LLAMA in-vacuum components are designed as a compact, transferable setup that can be mounted in an ex situ vacuum enclosure that is equipped with an absolutely calibrated Ly-α source. The spectral purity and stability of the Ly-α source are characterized using a vacuum ultraviolet spectrometer, while the Ly-α source brightness is measured by a NIST-calibrated photodiode. The non-uniform nature of the Ly-α source emission was overcome by performing a calibration procedure that scans the Ly-α source position and employs a numerical optimization to determine the emission pattern. Nominal and measured calibration factors are determined and compared, showing agreement within their uncertainties. A first conversion of the measured signal obtained from DIII-D indicates that the Ly-α brightness on the HFS and LFS is on the order of 1020 Ph sr-1m-2s-1. The established calibration setup and procedure will be regularly used to re-calibrate the LLAMA during DIII-D vents to monitor possible degradation of optical components and detectors.