Bio-cellulose derived carbon microcoils (BCMC) are renowned for their distinctive helical structure, sustainability, and renewability, making them highly versatile for applications such as microwave absorption, water purification, and energy storage. Despite extensive research on carbon microcoils or nanocoils, the luminescent properties of BCMC remain largely unexplored. This study delves into the luminescence characteristics of BCMC extracted from recycled tea leaves, revealing a broad spectrum of multicolor emissions including ultraviolet (355 nm, 396 nm), blue (467 nm), and near-infrared (764 nm). These emissions are attributed to BCMC's distinctive three-dimensional helical configuration and its rich array of oxygen-containing functional groups. Incorporating europium further tailors the photoluminescent properties of BCMC, significantly amplifying UV and blue light emissions. Additionally, annealing improves UV emission, showcasing the potential for enhanced luminescence performance. This research not only deepens our understanding of sustainable luminescent materials but also paves the way for developing advanced UV luminophores with diverse applications.