UV Band Research Articles

Turn-On Fluorescence Probe for Cancer-Related γ-Glutamyltranspeptidase Detection.

The design and development of fluorescent materials for detecting cancer-related enzymes are crucial for cancer diagnosis and treatment. Herein, we present a substituted rhodamine derivative for the chromogenic and fluorogenic detection of the cancer-relevant enzyme γ-glutamyltranspeptidase (GGT). Initially, the probe is non-chromic and non-emissive due to its spirolactam form, which hinders extensive electronic delocalization over broader pathway. However, selective enzymatic cleavage of the side-coupled group triggers spirolactam ring opening, resulting in electronic flow across the rhodamine skeleton, and reduces the band gap for low-energy electronic transitions. This transformation turns the reaction mixture from colorless to intense pink, with prominent UV and fluorescence bands. The sensor's selectivity was tested against various human enzymes, including urease, alkaline phosphatase, acetylcholinesterase, tyrosinase, and cyclooxygenase, and showed no response. Absorption and fluorescence titration analyses of the probe upon incremental addition of GGT into the probe solution revealed a consistent increase in both absorption and emission spectra, along with intensified pink coloration. The cellular toxicity of the receptor was evaluated using the MTT assay, and bioimaging analysis was performed on BHK-21 cells, which produced bright red fluorescence, demonstrating the probe's excellent cell penetration and digestion capabilities for intracellular analytical detection. Molecular docking results supported the fact that probe-4 made stable interactions with the GGT active site residues.

Multi-wavelength generation in UV and green bands through SRS and parametric processes in silica fibers.

We report on multi-wavelength generation through simultaneous second-order and third-order nonlinear parametric processes following cascaded stimulated Raman scattering (SRS) in silica fibers. The fiber system consists of a short standard step-index silica fiber and a microfiber tapered from it. When this system is pumped with a 130 ps laser at 1040 nm, multiple new wavelengths in the UV (340-370 nm) and green (507-547 nm) bands arise through four-wave mixing (FWM)/sum-frequency generation (SFG) from the pump and its Raman signals. The evolution of these wavelengths with pump power is demonstrated in detail. Matching of frequencies and propagation constants in the involved processes is verified. This work provides a compact and simple method of multi-wavelength generation with fibers.

Anatomy of the Star Formation in a Tidally Disturbed Disk Galaxy: NGC 3718

We present a UV, optical, and near-IR study of the star-forming complexes in the nearby peculiar galaxy NGC 3718, using Ultraviolet Imaging telescope, Galaxy Evolution Explorer, Spitzer, and DECam Legacy Survey imaging data. The galaxy has a disturbed optical morphology owing to the multiple tidal arms, the warped disk, and the prominent curved dust lanes, but in the near-IR it appears to be a bulge-dominated galaxy. Its disturbed morphology makes it an excellent case to study star formation in a tidally disturbed galaxy that may have undergone a recent minor merger. To study the distribution and properties of the star-forming clumps (SFCs), we divided the galaxy within the R 25 (B band) radius into three parts—the upper, central, and lower regions. Using the UV band images, we investigated the warped star-forming disk, the extended tidal arms, and the distribution and sizes of the 182 SFCs. Their distribution is 49, 60, and 73 in the galaxy’s upper, central, and lower regions, respectively. We determined the UV color, star formation rates (SFRs), star formation density (ΣSFR), and ages of the SFCs. The central disk of the galaxy has a larger mean ΣSFR that is ∼3.3 and ∼1.6 times higher than the upper and lower regions, respectively. We also find that the SFCs in the central disk are older than those in the tidal arms. Our study thus shows that minor mergers can trigger the inside-out growth of galaxy disks, where the younger SFCs are in outer tidal arms and not in the inner disk.

Roll‐to‐Roll Production of High‐Performance All‐Organic Polymer Nanocomposites for High‐Temperature Capacitive Energy Storage

AbstractDielectric materials with significant performance in high temperatures are highly desired, especially in harsh environments. However, the polymer‐based dielectric films have developed so far, the production scale remains at the state of the lab. Here, an all‐organic strategy is proposed by introducing phenyl‐acid‐based polymer nanodots (PAPD) into Polyetherimide (PEI), achieving high capacitive energy storage properties even at 200 °C and mass production by an industrial continuous roll‐to‐roll process. The abundant hydrogen bonding between PAPD and PEI chains ensures uniform distribution for the enhanced interaction between nanofillers and polymer matrix. Under UV irradiation, the electron‐affinity and band gap of the film are further extended, which impede charge transfer and reduction of conductive loss. A low loading (0.3 wt.%) of PAPD renders the membrane significant improvement in breakdown strength and charge–discharge efficiency. An ultrahigh energy storage density of 5.1 J cm−3 with a charge–discharge efficiency of over 90% and charge–discharge cycle stability up to 2 × 104 cycles at 150 °C is observed. Furthermore, a 1000 m long roll of polymeric film is roll‐to‐roll fabricated on an industrial solution‐casting production line and the low cost makes practical commercial scale application possible. Considering the low loading and low cost of nanofiller, this all‐organic design strategy sheds light on the industrial application of high‐temperature dielectric materials.

Spectral Control by Silver Nanoparticle-Based Metasurfaces for Mitigation of UV Degradation in Perovskite Solar Cells.

Perovskite solar cells are considered to be one of the most promising solar cell designs in terms of photovoltaic efficiency. However, their practical deployment is strongly affected by their short lifetimes, mostly caused by environmental conditions and UV degradation. In this contribution, we present a metasurface made of silver nanoparticles used as a UV filter on a perovskite solar cell. The UV-blocking layer was fabricated and morphologically and compositionally analyzed. Its optical response, in terms of optical transmission, was also experimentally measured. These results were compared with simulations made through the use of a well-proven computational electromagnetism model. After analyzing the discrepancies between the experimental and simulated results and checking those obtained from electron beam microscopy and electron dispersion spectroscopy, we could see that a residue from fabrication, sodium citrate, strongly modified the optical response of the system, generating a redshift of about 50 nm. Then, we proposed and simulated the optical behavior of core-shell nanoparticles made of silver and silica. The calculated spectral absorption at the active perovskite layer shows how the appropriate selection of the geometrical parameters of these core-shell particles is able to tune the absorption at the active layer by removing a significant portion of the UV band and reducing the absorption of the active layer from 90% to 5% at a resonance wavelength of 403 nm.

NIR-driven intense UV upconversion films for non-contact high-efficiency prevention of bacterial infections

Bacterial infections on wounds imposes a significant limitation to the wound healing. Although the conventional drug antibacterial dressing is employed for hindering bacterial infection, the inevitable microbial resistance and secondary damage severely limit the quality and speed of wound healing. Herein, the NIR-driven intense UV upconversion (UC) BaLu2F8:80%Yb3+/0.5%Tm3+ microcrystals are, for the first time, designed and fabricated into solid sterilization film to protect the wounds from infections. Equipped with excessive Yb3+ sensitizers, the emission of Yb3+/Tm3+ co-doped monoclinic BaLu2F8 matrix achieve a 175-fold enhancement at the UV band. The UV UC microcrystals was further fabricated into a NIR-to-UV sterilization film with a diameter of 1.5 cm and a thickness of 150 μm using solution casting method, which can efficiently destroy 97 % of E. coli with a NIR irradiation of 5 minutes. Due to the outstanding penetrability of NIR irradiation, the sterilization film under 4 layers gauze dressing can be activated to produce UV photons. The in-vivo mouse tests demonstrate the well-designed NIR-to-UV sterilization film can speed up the wound healing by high-efficient inhibiting E. coli infection under the irradiation of 980 nm NIR laser. The non-contact NIR-driven UV sterilization film require no more drugs and dressing exchange, thus entirely eliminating the effect of microbial resistance and secondary damage from conventional drug dressing. Our work provides a new alternative for constructing highly-efficiency sterilization dressing through the utilization of NIR-to-UV optical conversion materials.

Hydroflux Synthesis and Structural Phase Transition of Rare-Earth Borate Hydroxides Na2[RE(BO3)(OH)2] (RE = Y, Gd-Er).

Reacting RE2O3 and H3BO3 in an ultra-alkaline NaOH hydroflux at about 250 °C yielded pure, crystalline samples of Na2[RE(BO3)(OH)2] (RE = Y, Gd-Er). The compounds dehydrate to Na3RE(BO3)2 upon heating in air to about 500 °C. Na2[RE(BO3)(OH)2] (RE = Tb-Er) are photoluminescent under UV radiation. Their UV-Vis spectra show the typical absorptions associated with 4f-4f transitions and absorption edges in the UV (band gaps ≥ 5.7 eV). The RE3+ cation is coordinated by seven oxygen atoms, which define a distorted pentagonal bipyramid. The bipyramids share trans-edges of their base forming infinite chains. Triangular (BO3)3- groups connect the chains into layers. The crystal structure of Na2[Ho(BO3)(OH)2] was investigated at various temperatures in the range 100 K ≤ T ≤ 320 K. Above 310(2) K, the compound crystallizes in the orthorhombic space group Cmcm (β-phase), below, it undergoes a displacive phase transition of second order resulting in a monoclinic structure in space group C2/c (α-phase). The critical exponents derived from different structural parameters indicate a cooperative distortion of the borate layers, but a rather uncorrelated adaptation of the sodium cations to their local environment. The other compounds of the series also adopt the structure of the α-phase at 296 K.

NdxZn1-xO nanomaterial: Relating the effects of hydrazine-based synthesis to the improved structure, morphology and optical properties

The current paper reports a convenient method to obtain NdxZn1-xO (x = 0.05 and 0.1 % wt.) nanomaterial useful for optoelectronic applications. The material prepared from hydrazine-Nd/Zn-oxalate exhibited enhanced photoluminescence (PL) properties compared to their counterpart material prepared from Nd/Zn-oxalate precursor. The significant improvements in the microstructure and blue-light PL emissions of NdxZn1-xO were owed to the hydrazine-modified precursor. The XRD of materials confirmed the hexagonal wurtzite ZnO crystal structure. The microstructural analysis by SEM/TEM indicated spherically shaped nanosized crystal growth with narrow particle size distribution (10–70 nm). The HR-TEM revealed superior crystallinity with well-aligned lattice planes. EDAX, XPS and Raman confirmed the elemental composition (Zn2+, O2- and Nd3+) and their chemical bonding in the NdxZn1-xO. The band gap of materials were reduced due to the introduction of newly created mid-gap energy levels by Nd3+ dopant. The RT-PL spectra exhibited dual emission, the first UV band attributed to excitonic recombination while the second visible blue-green band assigned to deep-level emissions caused by intrinsic defects (O and Zn vacancies) and shallow Nd3+ and Zni levels. Improved PL intensities could be linked to the combined effect of Nd3+ doping and extra defects formed by the hydrazinate precursor. The blue-PL band (∼ λ = 468 nm) intensified 1.5 times with a narrow bandwidth of ̴ 15 nm. Hence, the current studies elucidated the optimistic use of hydrazine precursor for the production of Nd-doped ZnO nanomaterials with improved particle morphology, intrinsic defects and optical light emission properties.

Argon plasma-enhanced UV light emission from ZnO submicrowires grown by hydrothermal method

In this work, the optical, morphological, and structural improvements of vertically aligned, hydrothermally grown ZnO submicrowires (SMWs) treated with a 250 W, 250 V RF argon plasma (Ar) during different exposure times were investigated by scanning and transmission electrons microscopy, X-ray diffraction, and micro-Raman and photoluminescence (PL) spectroscopies. In two steps, the SMWs were synthesized in an aqueous medium at low temperatures. The plasma-treated samples showed significantly improved room-temperature PL compared to untreated samples. All the treated samples exhibited a substantial increase of the near band edge UV emission intensity and a decrease of the deep level emission in the visible. The samples treated for 4 minutes presented the best UV/vis intensity ratio of ∼ 1568 (an increase of ⁓174-fold with respect to the untreated sample). The analysis of the UV band in terms of the first and second phonon replica of the excitonic emission indicated that the Ar plasma treatment favors the multiple phonon-exciton coupling, with partial correlation with the observed overall increase of the UV/visible intensity ratio. From the PL measurements at low temperatures, the presence of excitons bound to H donors in the ZnO structure was inferred. The possible reasons for the Ar plasma-induced enhancement of the UV emission from the treated SMWs are discussed in terms of previous work, the observed morphology and changes expected to occur at the SMW surfaces due to Ar ion impacts from the plasma.

Investigation of QSO spectra having measured Lα from GALEX FUV

Active Galactic Nuclei, especially quasars, have not been thoroughly investigated in far UV range. There are few observations in this range, and most of this range is available for objects with high redshifts, whose UV range is shifted to the optical one. But on the other hand, there is GALAXY Evolution Explorer (GALEX) space UV telescope catalog, where 82,992,086 near-UV (NUV, 1750–2800 ˚A) and far-UV (FUV, 1350–1750 ˚A) flux measurements in UV bands are available. In order to find a connection between the fluxes of two of the most important emission lines, λ5007 ([OIII]) and λ1216 (Lα) in the spectra of quasars, we created a sample of quasars with measured Lα. For this, we took the Milliquas 2023 catalog, which contains 1,021,800 objects. From these objects, we selected those having redshifts lying between 0.15 < z < 0.40, so that Lα spectral line is located in GALEX FUV window. As a result, we have 42,150 objects. These sources were identified with SDSS DR16 and GALEX DR6+DR7, and as a result we have 11,697 identifications which have data from both SDSS and GALEX. Using a pilot survey (for 177 objects), we found a preliminary connection between Lα and [OIII] lines.

The radio properties of z>3.5 quasars: Are most high-redshift radio-loud active galactic nuclei obscured?

We explore the radio properties of powerful (rest-frame luminosity $ at 500 MHz) high-redshift ($z 3.5$) quasars. The aim of this study is to gain a better understanding of radio-loud sources at the epoch when they reach the highest space density. We selected 29 radio-loud quasars at low radio frequencies (76 MHz). Their radio spectra, covering the range from 76 MHz to 5 GHz, are generally well reproduced by a single power law. We created samples that were matched in radio luminosity at lower redshift (from $z to $z to investigate any spectral evolution. We find that the fraction of flat-spectrum radio quasars (FSRQs) strongly increases with redshift (from $ 8<!PCT!>$ at z=1.2 to $ 45<!PCT!>$ at z$>$3.5). This effect is also observed in quasars with lower luminosities (down to $ The increase in the fraction of FSRQs with redshift corresponds to a decrease in the steep- spectrum radio quasars. This result can be explained when we assume that the beaming factor and the slope of the luminosity function do not change with redshift and if high-redshift radio-loud sources can be recognized as quasars only when they are seen at a small viewing angle ($ but most of them, about 90<!PCT!> are obscured in the UV and optical bands. We also found a trend for the size of radio sources to decrease with increasing redshift. Because projection effects are insufficient to cause this trend, we suggest that the large amount of gas causing the nuclear obscuration also hampers the growth of the more distant sources.

On the Nature of the Radio Calibrator and Gamma-Ray Emitting NLS1 Galaxy 3C 286 and Its Multiwavelength Variability

The quasar 3C 286, a well-known calibrator source in radio astronomy, was found to exhibit exceptional multiwavelength properties. Its rich and complex optical emission-line spectrum revealed its narrow-line Seyfert 1 (NLS1) nature. Given its strong radio emission, this makes 3C 286 one of the radio-loudest NLS1 galaxies known to date. 3C 286 is also one of very few known compact steep-spectrum (CSS) sources detected in the gamma-ray regime. Observations in the X-ray regime, rarely carried out so far, revealed evidence for variability, raising the question whether it is driven by the accretion disk or jet. 3C 286 is also well known for its damped Lyman alpha system from an intervening absorber at z = 0.692, triggering a search for the corresponding X-ray absorption along the line-of-sight. Here, we present new observations in the radio, X-ray, optical, and UV bands. The nature of the X-ray variability is addressed. Spectral evidence suggests that it is primarily driven by the accretion disk (not the jet), and the X-ray spectrum is well fit by a powerlaw plus soft excess model. The radio flux density and polarization remain constant at the Effelsberg telescope resolution, reconfirming the use of 3C 286 as radio calibrator. The amount of reddening/absorption along the line-of-sight intrinsic to 3C 286 is rigorously assessed. None is found, validating the derivation of a high Eddington ratio (L/LEdd ∼ 1) and of the very high radio-loudness index of 3C 286. Based on the first deep Chandra image of 3C 286, tentative evidence for hard X-ray emission from the SW radio lobe is reported. A large variety of models for the gamma-ray emission of 3C 286 are briefly discussed.

Examining the dual effect of copper nanoparticles and nitrogen doping on Cu@N-TiO2

Abstract The study of six compositions of Cu@N-TiO2 with different amounts of copper and nitrogen synthesized using a sol–gel method is reported. X-ray diffraction patterns and Raman spectra indicated the formation of a single anatase TiO2 phase in all materials without evidence of secondary phases including copper or nitrogen. Electron microscopy images showed a homogeneous distribution of the copper particles around a TiO2 matrix, just as that the insertion of nitrogen did not have a significant effect on the morphology of the particles. X-ray photoelectron spectroscopy analysis confirmed that nitrogen was inserted in the atomic arrangement of titanium dioxide, while copper was presented mainly as metallic element on the TiO2 surface. Characterization of the optical properties and photoactivity test confirm that band gap strongly depends on the copper and nitrogen content phenomenon attributed to the combined presence of modifiers over the TiO2 surface and the promotion of a plasmonic effect, which displaced the absorption UV bands to higher wavelengths with respect to un-doped TiO2. The catalytic test performed using rhodamine-B as probe molecule, confirm that TiCuN2 and TiCuN3 samples exhibit the best decomposition percentages of 38 and 36 % respectively. Such results confirm the surface plasmon resonance effect associated to Cu particles on the TiO2 as main cause in the increase in current along synthesized samples and the use of cyclic voltammetry technique to identify these effects between 0.0 and 1.5 V.

The outflowing ionised gas of I Zw 1 observed by HST COS

Aims. We present an analysis of the Hubble Space Telescope Cosmic Origins Spectrograph spectrum of I Zw 1 aiming to probe the absorbing medium associated with the active galactic nucleus (AGN). Methods. We fitted the emission spectrum and performed spectral analysis of the identified absorption features to derive the corresponding ionic column densities and covering fractions of the associated outflows. We employed photoionisation modelling to constrain the total column density and the ionisation parameter of four detected kinematic components. By investigating the implications of the results together with the observed kinematic properties of both emission and absorption features, we derived constraints on the structure and geometry of the absorbing medium in the AGN environment. Results. We find and characterise absorption line systems from outflowing ionised gas in four distinct kinematic components, located at −60, −280, −1950, and −2900 km s−1 with respect to the source rest frame. While the two slower outflows are consistent with a full covering of the underlying radiation source, the well-constrained doublet line ratios of the faster two, higher column density, outflows suggest partial covering, with a covering fraction of Cf ∼ 0.4. The faster outflows show also line-locking in the N V doublet, a signature of acceleration via line absorption. This makes I Zw 1 possibly the closest object that shows evidence for hosting line-driven winds. The observed −1950 km s−1 absorption is likely due to the same gas as an X-ray warm absorber. Furthermore, the behaviour in UV and X-ray bands implies that this outflow has a clumpy structure. We find that the highly asymmetric broad emission lines in I Zw 1, indicative of a collimated, outflowing broad line region, are covered by the absorbing gas. Finally, the strongest UV–X-ray absorber may be connected to some of the blueshifted line emission, indicative of a more spatially extended structure of this ionised medium.

Absence of nebular He ii λ4686 constrains the UV emission from the Ultraluminous X-ray pulsar NGC 1313 X–2

Abstract While much has been learned in recent decades about the X-ray emission of the extragalactic Ultraluminous X-ray sources (ULXs), their radiative output in the UV band remains poorly constrained. Understanding of the full ULX spectral energy distribution (SED) is imperative to constrain the accretion flow geometry powering them, as well as their radiative power. Here we present constraints on the UV emission of the pulsating ULX (PULX) NGC 1313 X–2 based on the absence of nebular He ii λ4686 emission in its immediate environment. To this end, we first perform multi-band spectroscopy of the ULX to derive three realistic extrapolations of the SED into the unaccessible UV, each predicting varying levels of UV luminosity. We then perform photo-ionization modelling of the bubble nebula and predict the He ii λ4686 fluxes that should have been observed based on each of the derived SEDs. We then compare these predictions with the derived upper limit on He ii λ4686 from MUSE data, which allows us to infer a UV luminosity LUV ≲ 1 × 1039 erg/s in the PULX NGC 1313 X–2. Comparing the UV luminosity inferred with other ULXs, our work suggests there may be an intrinsic difference between hard and soft ULXs, either related to different mass-transfer rates and/or the nature of the accretor. However, a statistical sample of ULXs with inferred UV luminosities is needed to fully determine the distinguishing features between hard and soft ULXs. Finally, we discuss ULXs ionising role in the context of the nebular He ii λ4686 line observed in star-forming, metal-poor galaxies.

Unveiling the periodic variability patterns of the X-ray emission from the blazar PG 1553+113

The search for periodicity in the multiwavelength, highly variable emission of blazars is a key feature to understanding dynamical processes at work in this class of active galactic nuclei. The blazar is an attractive target due to the evidence of periodic oscillations observed at different wavelengths, with a solid proof of a 2.2-year modulation detected in the gamma -ray, UV, and optical bands. We aim to investigate the variability pattern of the X-ray emission using a more than 10-year-long light curve in order to robustly assess the presence or lack of a periodic behavior, evidence of which is only marginal so far. We conducted detailed statistical analyses, studying in particular the variability properties of the X-ray emission of by computing the Lomb-Scargle periodograms, which are suited for the analyses of unevenly sampled time series, and adopting epoch-folding techniques. We find a modulation pattern in the X-ray light curve of PG 1553+113 with a period of sim 1.4 years, which is about 35<!PCT!> shorter than the one observed in the gamma -ray domain. Our finding is in agreement with the recent spectro-polarimetric analyses and supports the presence of more dynamical phenomena simultaneously at work in the central engine of this quasar.

UV to NIR Broadband Flexible Photodetector Based on Solution‐Processed MoS2/PDPP3T Inorganic–Organic Hybrid Heterostructures

AbstractMolybdenum disulfide (MoS2) is a 2D material with excellent electrical and optical properties, and developing a universal technology for the preparation of high‐performance MoS2‐based photodetector is extremely desirable. Here, a UV to NIR broadband flexible photodetector based on MoS2/(PDPP3T) inorganic–organic hybrid heterostructures is reported. In the experiment, high crystalline 2H‐phase few‐layer MoS2 nanoflakes are first prepared by optimized electrochemical intercalation of tetraheptylammonium cation (THA+) and ultrasound‐assisted exfoliation strategy. Thereafter, a narrow bandgap organic semiconductor PDPP3T is introduced to construct the MoS2/Poly(diketopyrrolopyrrolothiophrn) (PDPP3T) heterojunction. Experimental results reveal that the photodetector can have broadband photo response from 380 to 980 nm. Meanwhile, excellent responsivities and detectivity of 12.4 mA W−1, 2.2 × 1010 Jones at 380 nm and 0.1 mA W−1 and 5 × 108 Jones at 980 nm are achieved, which are ≈10 (UV band)/100 (NIR band) times high than that obtained on the pure MoS2‐based detector. Moreover, the flexibility of the device is investigated by conformal covering the device on a curved surface (R = 5 and 2.5 mm), it shows that the photo response remains almost the same as that measured on the planar substrate, indicating the possible application in the wearable electronics.

Development of Microparticle Implanted PVDF-HF Polymer Coating on Building Material for Daytime Radiative Cooling.

A passive cooling method with great potential to lower space-cooling costs, counteract the urban heat island effect, and slow down worldwide warming is radiant cooling. The solutions available frequently require complex layered structures, costly products, or a reflective layer of metal to accomplish daytime radiative cooling, which restricts their applications in many avenues. Furthermore, single-layer paints have been used in attempts to accomplish passive daytime radiative cooling, but these usually require a compact coating or only exhibit limited cooling in daytime. In our study, we investigated and evaluated in daytime the surrounding cooling outcome with aid of one layer coating composed of BaSO4/TiO2 microparticles in various concentrations implanted in the PVDF-HF polymers on a concrete substrate. The 30% BaSO4/TiO2 microparticle in the PVDF-HF coating shows less solar absorbance and excessive emissivity. The value of solar reflectance is improved by employing micro-pores in the structure of PVDF polymers without noticeable effect on thermal emissivity. The 30% BaSO4/TiO2/PVDF coating is accountable for the hydrophobicity and proportionate solar reflection in the UV band, resulting in efficient solar reflectivity of about 95.0%, with emissivity of 95.1% and hydrophobicity exhibiting a 117.1° water contact angle. Also, the developed coating could cool to about 5.1 °C and 3.9 °C below the surrounding temperature beneath the average solar irradiance of 900 W/m-2. Finally, the results demonstrate that the 30% BaSO4/TiO2/PVDF-HF microparticle coating illustrates a typical figure of merit of 0.60 and is also capable of delivering outstanding dependability and harmony with the manufacturing process.

Effect of doping TiO2 with Fe on the loading of a natural extract

This study explores the relationship between Fe doping in TiO2 nanoparticles and their capacity to load a natural citrus extract. Synthesized TiO2 (T) and TiO2-Fe (TF) nanoparticles were characterized using XRD patterns, N2 physisorption, UV–Vis and FTIR spectroscopy, and electron microscopy. Fe doping induced shifts in X-ray diffraction patterns and broadened absorption bands in UV–Vis spectra, reflecting changes in crystal structure and electronic transitions. BET analysis revealed increased surface area with Fe doping. Loading of the natural citrus extract was confirmed by FTIR. SEM and TEM images displayed slight morphological changes and a reduced nanoparticle size after Fe doping. Finally, Fe doped TiO2 demonstrated an improvement in loading ability with loading values up to 82.4%.

High reflectivity, ultraflat-spectrum chirped fiber Bragg grating written using low energy UV femtosecond pulses

Chirped fiber Bragg gratings (CFBGs) have been extensively used in applications such as ultrafast lasers, fiber sensors, and fiber communications. This work presents a comprehensive investigation of CFBG written using a 257 nm femtosecond laser and a linear chirped phase mask. The CFBG, written on a hydrogen-loaded polarization-maintaining fiber, exhibited a center wavelength of 1031.7 nm and a bandwidth of 11.97 nm. The CFBG achieved an average reflectivity of 98.2 % within its bandwidth, demonstrating an ultrahigh flatness of the reflection spectrum with a low spectral reflectivity variance of 0.00003 (σ2). The high group velocity dispersion (GVD) of 60.7 ps2 signifies its potential in fiber chirped pulse amplification systems and dispersion compensation system. Meanwhile, the fs-laser + PM writing method shows advantages of high efficiency and low energy consumption (as low as 2 nJ), owing to the high photosensitivity of the fiber to the UV band, which holds significant promise in fiber grating inscription.