Use Of Ultrashort Laser Pulses Research Articles

Morphological study of depth-controlled high quality holes and lines fabricated on a metal substrate with a thin metal film by picosecond laser pulses

Laser micromachining is a convenient technique to structure and/or functionalize the surfaces of various materials. The use of ultrashort laser pulses has an obvious advantage to minimize the heat effect, which results in the formation of a hole without rims. Nevertheless, it is still difficult to fabricate a line without rims even with ultrashort laser pulses, because multiple irradiation of ultrashort laser pulses with a sufficient spatial overlap promotes the formation of rims and undesired structures. In this work we employ a metal substrate with a thin metal film, and demonstrate the fabrication of depth-controlled high quality lines, not to mention holes, through the selective removal of the film by picosecond laser pulses without forming rims and undesired structures. Morphological study of the target surface reveals that the fabricated structures have unprecedentedly flat bottoms with nearly vertical sidewalls to the surface.

High throughput wide field second harmonic imaging of giant unilamellar vesicles.

Cell-sized giant unilamellar vesicles (GUVs) are an ideal tool for understanding lipid membrane structure and properties. Label-free spatiotemporal images of their membrane potential and structure would greatly aid the quantitative understanding of membrane properties. In principle, second harmonic imaging is a great tool to do so, but the low degree of spatial anisotropy that arises from a single membrane limits its application. Here, we advance the use of wide-field high throughput SH imaging by SH imaging with the use of ultrashort laser pulses. We achieve a throughput improvement of 78% of the maximum theoretical value and demonstrate subsecond image acquisition times. We show how the interfacial water intensity can be converted into a quantitative membrane potential map. Finally, for GUV imaging, we compare this type of nonresonant SH imaging to resonant SH imaging and two photon imaging using fluorophores.

Reaction nanoscopy of ion emission from sub-wavelength propanediol droplets

Abstract Droplets provide unique opportunities for the investigation of laser-induced surface chemistry. Chemical reactions on the surface of charged droplets are ubiquitous in nature and can provide critical insight into more efficient processes for industrial chemical production. Here, we demonstrate the application of the reaction nanoscopy technique to strong-field ionized nanodroplets of propanediol (PDO). The technique’s sensitivity to the near-field around the droplet allows for the in-situ characterization of the average droplet size and charge. The use of ultrashort laser pulses enables control of the amount of surface charge by the laser intensity. Moreover, we demonstrate the surface chemical sensitivity of reaction nanoscopy by comparing droplets of the isomers 1,2-PDO and 1,3-PDO in their ion emission and fragmentation channels. Referencing the ion yields to gas-phase data, we find an enhanced production of methyl cations from droplets of the 1,2-PDO isomer. Density functional theory simulations support that this enhancement is due to the alignment of 1,2-PDO molecules on the surface. The results pave the way towards spatio-temporal observations of charge dynamics and surface reactions on droplets.

Raman Red‐Shift Compressor: A Simple Approach for Scaling the High Harmonic Generation Cut‐Off

The use of ultrashort laser pulses with long wavelengths as drivers is a relevant strategy for scaling high harmonic generation (HHG) to higher photon energies. Here, stimulated Raman scattering enhanced by the formation of multidimensional solitary states in a molecular gas‐filled hollow‐core fiber as the mechanism to produce a versatile HHG driver is reported on. This recently discovered method allows to red shift and to compress conventional subpicosecond laser pulses with a simple experimental apparatus, ultimately increasing the generated photon energy, while assuring a high photon flux. The adaptability, simplicity, and stability of this method make it attractive for tailoring HHG sources to individual applications at specific photon energies. Measurements of resonant magnetic scattering in a cobalt/platinum multilayer sample are presented as a demonstration of the relevance of this approach for photon‐hungry applications in the extreme ultraviolet.

Organic Nanocrystal Fabrication Using the Process of Resonant Second-Harmonic Generation of Light.

Laser ablation with the use of ultra-short laser pulses is a widely used technique for the fabrication of nanoparticles of metals, inorganic and hybrid materials. However, fabrication of fragile organic nanocrystals via laser ablation is rarely used due to easy photodegradation of molecules. The method employing laser irradiation of the target material is beneficial as no other chemicals are used in the production of nanoparticles, except for a given material and a solvent. In this work, we test the concept of formation of nonlinear optical (NLO) organic nanocrystals dispersion in water by irradiation of the microcrystals of the NLO material with nonabsorbed infrared nanosecond light pulses. These pulses, due to a nonlinear optical process active in a noncentrosymmetric organic crystal, such as those studied in this work, DCNP dye (3-(1,1-dicyanoethenyl)-1-phenyl-4,5-dihydro-1H-pyrazole), produce nanosecond pulses of second-harmonic (SH) light. Due to doubling of photon energy, they are reabsorbed in the volume of DCNP microcrystals and thermal shocks fracture them into nanometer size crystals. To the best of our knowledge, such process and its interpretation have not been described yet in the literature.

New Techniques Based on Ultrashort Laser Microsurgery for Use in Assisted Reproductive Technologies

Two noncontact techniques based on the use of ultrashort laser pulses are presented for assisted reproductive technologies. The first creates a unique alphanumeric code on an embryo’s envelope to simplify its identification during the period of preimplantation development. The second ensures the embryo will start to hatch at a prescribed site via laser-assisted drilling of its shell at the early blastocyst stage, where the inner cell mass and trophectoderm cells can be distinguished clearly.

Using an alpha magnet to compress the electron bunches from a photocathode RF gun

We report here the design, simulation, and characterization of a compact electron injector for the formation of high-current, femtosecond electron bunches from a photocathode RF gun without mandatory use of ultra-short laser pulses and a high power RF supply. The proposed injector consists of a 1.6-cell S-band photocathode RF gun to produce the electron beam and a small bunch compressor to increase the peak current. The RF gun is designed to operate at a 65 MV/m accelerating field gradient, and the bunch compressor is a small α-magnet with a maximum magnetic field gradient of 340 G/cm. The output beam from the gun has 100 pC charge per-bunch that is equivalent to a beam current of ∼15 A, and output beam from the injector has an RMS bunch length of ∼ 439 fs, a peak current of 0∼ 12 A and an RMS normalized horizontal emittance of 1.21 mm-mrad.

Measurement of Ultrashort Vector Pulses From Polarization Gates by In-Line, Single-Channel Spectral Interferometry

The growing use of ultrashort laser pulses exhibiting time-varying polarization (vector pulses) demands simple and robust characterization techniques capable to perform measurements in a broad range of experimental and environmental conditions. Here, we present in-line, single-channel setup based on spectral interferometry to characterize ultrashort vector pulses. The use of a bulk interferometer based on birefringence is key for the stability and sensitivity of the technique, thus being simple and highly robust. The technique is used to measure vector pulses corresponding to polarization gates, which are used in many applications. Those results are validated by simulations. The technique here presented has a number of potential applications in nonlinear effects (e.g., transient birefringence and nonlinear phenomena with vector pulses).

An ab-initio approach to describe coherent and non-coherent exciton dynamics

The use of ultra-short laser pulses to pump and probe materials activates a wealth of processes which involve the coherent and non coherent dynamics of interacting electrons out of equilibrium. Non equilibrium (NEQ) many body perturbation theory (MBPT) offers an equation of motion for the density-matrix of the system which well describes both coherent and non coherent processes. In the non correlated case there is a clear relation between these two regimes and the matrix elements of the density-matrix. The same is not true for the correlated case, where the potential binding of electrons and holes in excitonic states need to be considered. In the present work we discuss how NEQ-MBPT can be used to describe the dynamics of both coherent and non-coherent excitons in the low density regime. The approach presented is well suited for an ab initio implementation.

Surface Activation of Polymers Assisted By Picosecond Laser Pulses for Selective Metallization Via Electroless Deposition

The preparation of metallic tracks on non-conductive or semi-conductive substrates is attracting a strong scientific interest due to its useful applications in integrated circuit technology and its potential for miniaturization. The selective metallization on dielectric substrates can be carried out via laser-assisted direct writing techniques These involve processes such as thermally induced deposition, surface modification for subsequent electroless deposition as well as photocatalysis-mediated deposition among others [1]. Furthermore, a well-known methodology for producing metal tracks onto polymeric substrates is the so-called laser direct structuring (LDS) technology and is widely used for producing molded interconnect devices (MIDs). Conventional LDS uses polymeric materials loaded with a small amount of metallic compound (e.g. Pd particles) which after laser ablation can be released for catalyzing a further electroless plating process. Organometallic complexes based on palladium (Pd2+), copper (Cu2+) [2] as well as metal oxide composites of copper−chromium oxide (CuO·Cr2O3) or antimony-doped tin oxide (ATO) [3] have been used as catalyst sources for LDS technology in the last years. The active material is finely dispersed in the polymeric matrix and can be chemically modified by laser ablation in order to play a role as catalyst in a subsequent electroless deposition process. However, although the LDS method offers flexibility and freedom for 3D patterning design, the addition of those special additives (catalyst sources) is required in order to make the polymeric material suitable for LDS. This paper will discuss a simple methodology for patterning metal tracks onto the polymeric substrate polybutylene terephthalate (PBT). The selective metallization process consists of three main steps: (1) surface patterning and activation with picosecond-laser pulses in a dry processing environment; (2) treatment of the substrate in PdCl2 seeding solution, and (3) selective metallization of the substrate via electroless copper deposition. It was found that, besides a significant surface roughening, the use of ultra-short laser pulses promoted the chemical modification of the polymeric surface in a manner that the surface acquires the ability to reduce Pd-ions into metallic Pd clusters during a subsequent treatment in PdCl2 solution. The laser parameters as well as the concentration and the temperature of the PdCl2 solution were investigated and correlated with the surface morphology, the formation of Pd clusters as well as with the characteristics of the copper layers. The copper features were homogeneous and exhibited well defined geometries. Moreover, the adhesive properties of the copper structures were investigated. Tape tests showed that the copper structures exhibited good adhesion to the PBT substrate and this is ascribed to the high roughness obtained via laser patterning. The copper layers exhibit low electrical resistivity values and therefore show great potential for applications in electronic devices even with 3D complex geometries.

Selective laser melting of hypereutectic Al-Si40-powder using ultra-short laser pulses

We investigate the use of ultra-short laser pulses for the selective melting of Al-Si40-powder to fabricate complex light-weight structures with wall sizes below 100,upmu text {m} combined with higher tensile strength and lower thermal expansion coefficient in comparison to standard Al–Si alloys. During the cooling process using conventional techniques, large primary silicon particles are formed which impairs the mechanical and thermal properties. We demonstrate that these limitations can be overcome using ultra-short laser pulses enabling the rapid heating and cooling in a non-thermal equilibrium process. We analyze the morphology characteristics and micro-structures of single tracks and thin-walled structures depending on pulse energy, repetition rate and scanning velocity utilizing pulses with a duration of 500,text {fs} at a wavelength of 1030,text {nm}. The possibility to specifically change and optimize the microstructure is shown.

Experimental investigation of recoil-momentum-generation efficiency under near-IR femtosecond laser ablation of refractory metals in vacuum

The use of ultrashort laser pulses is a way to increase recoil momentum under laser ablation of materials, because, in this case, the energy deposition per unit volume of the target material is substantially higher due to reduced heat dissipation. By using methods of combined interferometry, we estimated the specific impulse (∼200–900 s), momentum coupling coefficient (∼2 × 10−5−3 × 10−4 Ns/J), laser-energy conversion efficiency to kinetic energy of the gas-plasma flow (∼0.05–0.82), and degree of the gas-plasma flow monochromaticity (∼0.72–0.92) under femtosecond (τ ∼ 45 fs, λ ∼ 800 nm) ablation of refractory metals (Ti, Zr, Mo, and Nb) in vacuum.

Femtosecond pulse written fiber gratings: a new avenue to integrated fiber technology

AbstractThe use of ultrashort laser pulses for fiber grating inscription has many advantages in comparison to continuous wave and long pulse lasers. The most important one is that it allows inscription in nonphotosensitive fiber materials. In this paper the principal inscription techniques and the physical properties of femtosecond (fs) pulse written in‐fiber gratings are reviewed. The role of focusing and order walk‐off on the inscribed structures is emphasized. A fs pulse written fiber Bragg grating (FBG) also has a unique coupling behavior, due to a refractive index change that is independent from the fiber geometry. Selected applications of such gratings for sensing and fiber lasers are discussed.

Ultrafast lasers in ophthalmology

Ultrafast laser pulses have become a promising tool for microsurgery of the eye. Due to the low energy threshold, side effects are limited to the micrometer range This precision enables the use of ultrashort laser pulses in a broad field of medical applications. Especially, the interaction process based on nonlinear absorption offers the opportunity to process transparent tissue not only on top of a surface but three dimensionally inside the bulk. This mechanism is used in refractive eye surgery, where fs pulses create flaps into the corneal tissue to remodel the curvature of the eye and to improve visual acuity. Moreover, fs pulses could be used to influence the biomechanics of the crystalline lens of the eye and improve accommodation on eyes who suffer from presbyopia.

Femtosecond vs. Picosecond Laser Material Processing

AbstractLaser materials processing has been an intensive research topic since the invention of the laser. nowadays, lasers are used as efficient and qualified tools in many industrial processes, like heavy industrial cutting, hardening, and welding. however, as the miniaturization of components and devices is progressing, finer structures are required. here, the flexible laser processing with conventional laser sources is typically limited by thermal or mechanical damage (melting, formation of burr and cracks, changes in the morphology etc.), which is especially true if metals have to be processed. In order to overcome these limitations and to minimize collateral damage various research activities based on the use of ultrashort laser pulses with picosecond or femtosecond duration have been started in the early 1990s (e.g. [1–8]).

Application of Bessel beams for ultrafast laser volume structuring of non transparent media

The use of ultrashort laser pulses has been shown to be an attractive option for high quality micromachining. In these applications low energy laser pulses are tightly focused to achieve high light intensities. While this approach has been demonstrated to be successful, its application is challenged by the short Rayleigh range of a tightly focused laser beam. Precise positioning of material samples becomes crucial imposing extra requirements on sample flatness, tilt, and irregularities. To overcome some of these limitations an application of non-diffractive Bessel beams for laser material processing has been attempted recently. The non-diffractive focus of Bessel beams can have the depth of field significantly longer than the Rayleigh range of a Gaussian beam of a comparable diameter. With sub mJ laser pulse energy the light intensity along the line focus can reach and exceed the required threshold levels making laser Bessel beams suitable for material processing. Preliminary numerical simulations show that truncated by a micron size aperture Bessel beam still has the propagation depth sufficiently long to be suitable for volumetric micro structuring of non transparent media. The paper aims to demonstrate feasibility of ultrafast laser structuring of non transparent media using Bessel beam focusing geometry.

Ultrashort laser ablation of PMMA and intraocular lenses

The use of intraocular lenses (IOLs) is the most promising method to restore vision after cataract surgery. Several new materials, techniques, and patterns have been studied for forming and etching IOLs to improve their optical properties and reduce diffractive aberrations. This study is aimed at investigating the use of ultrashort laser pulses to ablate the surface of PMMA and intraocular lenses, and thus provide an alternative to conventional techniques. Ablation experiments were conducted using various polymer substrates (PMMA samples, hydrophobic acrylic IOL, yellow azo dye doped IOL, and hydrophilic acrylic IOL consist of 25% H2O). The irradiation was performed using 100 fs pulses of 800 nm radiation from a regeneratively amplified Ti:sapphire laser system. We investigated the ablation efficiency and the phenomenology of the ablated patterns by probing the ablation depth using a profilometer. The surface modification was examined using a high resolution optical microscope (IOLs) or atomic force microscope—AFM (PMMA samples). It was found that different polymers exhibited different ablation characteristics, a result that we attribute to the differing optical properties of the materials. In particular, it was observed that the topography of the ablation tracks created on the hydrophilic intraocular lenses was smoother in comparison to those created on the PMMA and hydrophobic lens. The yellow doped hydrophobic intraocular lenses show higher ablation efficiency than undoped hydrophobic acrylic lenses.

Peculiar properties of nanogranular NixSi100-x magnetic films obtained by ultrashort pulsed laser deposition

The use of ultrashort laser pulses enables the deposition of films composed of mono-component nanoparticles exhibiting similar shape and size. Films made of nickel (Ni) and silicon (Si) nanoparticles have been produced and investigated in view of the expected interesting properties, resulting from the uniform distribution of metallic, magnetic Ni particles among semiconductive, non-magnetic Si particles. The morphology of the deposited nanoparticles and the related magnetic and magneto-transport characteristics of the films have been studied for different Ni contents, evidencing properties deriving from the peculiar deposition technique and in particular the important role of the free volume inclusions and the particles tendency to not coalesce.

Direct analysis of solid samples by fs-LA-ICP-MS

We review the emerging potential of femtosecond laser-ablation inductively-coupled-plasma mass spectrometry (fs-LA-ICP-MS) for the direct analysis of solid materials. Although LA-ICP-MS has been widely explored and is highly accepted for the determination of major and trace elements, as well as for the measurement of isotope ratios, it still suffers from several limitations that restrain its development as a potential alternative to other, more established techniques. The occurrence of non-stoichiometric effects in the transient signals, defined as elemental fractionation, together with the lack of reference materials for the wide variety of samples of interest often restricts the quantitative analysis to a few elements of identical fractionation behavior. In this sense, significant improvements in the processes responsible for fractionation effects have been recently observed with the use of ultra-short laser pulses. The confinement of pulse energy guarantees better performances in spatial resolution and improves the analytical figures of merit. This review aims to summarize the main differences between the LA mechanisms of short (>1 ps) and ultra-short (<1 ps) laser pulses based on fundamental understanding of the LA process and the most relevant parameters governing the quality of analysis. In order to show the state of the art in fs-LA-ICP-MS, we present a variety of examples for elemental and depth-profiling analysis of solid samples in biological, geological, and materials applications.

Ultrafast optical power limiting in free-standing Pt–polyvinyl alcohol nanocomposite films synthesized in situ

Free-standing platinum–polyvinyl alcohol nanocomposite films have been prepared by a simple in situ method. By thermal annealing, Pt nanoparticles of different sizes and shapes have been obtained. Their optical nonlinearity is measured using ultrafast (100 fs) laser pulses at 404 nm, in the absorption wing region. A strong optical power limiting is found in the films. The timescale of this limiting action is ultrafast, as it happens within the incident laser pulsewidth. Experimental results and numerical simulation indicate that the sign of the nonlinearity can be controlled by varying the film composition and annealing temperature. Use of ultrashort laser pulses in the free-standing film configuration permits a direct and unambiguous determination of the electronic nonlinearity of the material, since accumulative effects occur at later times lying outside the sharp measurement window.