Insufficient long-term durability of civil engineering infrastructure, especially concrete structures, has been a major problem causing enormous economic loss to many countries. Concrete structures are plagued by reinforcement corrosion, cracking due to drying shrinkage and nonuniform creep, alkali-silica reaction, sulfate attack, carbonation, leaching, freeze-thaw, etc. Short-term resistance of concrete structures exposed to fire has become a major question for high-strength concrete in recent years. At the same time, it would be highly beneficial to devise ways of incorporating into concrete certain industrial wastes, such as blast furnace slag and crushed bottle glass from curbside recycling. A rational approach to all these problems requires realistic mathematical models and computer simulations of chemical reactions, diffusion processes for heat and transport of various chemical agents, expansive processes in the microstructure, and fracture and long-term deformations of the material. Since durability problems generally involve large uncertainties, stochastic modeling and predictions of statistical scatter are very important. The durability problems represent a major challenge for mathematical modeling. The diffusion processes involved are generally nonlinear and coupled. Along with the diffusion process, complex chemical reactions take place at reaction fronts as well as in the bulk. Characterization of reaction rates as functions of pressure, temperature, and concentrations can be accomplished only by comprehensive models, which must capture capillarity as well as adsorption phenomena on the surfaces of nanopores, calling for the use of surface thermodynamics aside from bulk thermodynamics. In addition, volume changes caused by chemical reactions, surface adsorption, etc., are sensitive to pressure, and the volumetric changes result in damage in the form of distributed microcracking. In the case of chemical reactions on surfaces, the reaction rates depend not only on pressure but also on such surface stress components as crystal growth pressure, which gives rise to reaction anisotropy. Ion transport gives rise to electric current and electrochemical cells. The damage localizes into macrocracks. This causes interaction of the diffusion-chemical reaction problem and ion transport with structural stress analysis, and calls for the use of energy methods of fracture mechanics. In fact, fracture mechanics is generally coupled with the diffusion and chemical reaction problems. Furthermore, all these phenomena exhibit considerable randomness, which makes it necessary to approach the problem probabilistically and take into account both the randomness of the process and the uncertainty in the properties of the material and the reacting chemical involved.
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