Purpose: This study investigates the effectiveness of polymeric flocculation in removing heavy metals from leachate through filtration, sedimentation, and precipitation, aiming to separate and eliminate particulate matter. to separate and remove particulate matter. Method: This study investigated the use of alum and chitosan to remove heavy metals from leachate. The addition of a polymeric flocculant, chitosan, promoted the formation of stable flocs, which effectively removed heavy metals. Chitosan, a natural biopolymer, was found to be a promising alternative to synthetic polymers. Main Findings: The experimental results demonstrated that alum outperformed chitosan in terms of removing heavy metals. Under optimal conditions, an alum dosage of 6 mg/l at a pH of 6.23 resulted in copper and magnesium removal efficiencies of 84% and 92%, respectively. In contrast, the optimal chitosan dosage was 8 mg/l at a pH of 7.5, with copper and magnesium removal efficiencies of 43.1% and 91.8%, respectively. Implications: Leachate treatment reduces heavy metals and organic compounds, controls odors, and generates foam indicating the presence of gases like carbon dioxide and methane. These gases can be harnessed for clean energy production and green hydrogen development. harnessed for clean energy production and green hydrogen development. Novelty: This study is the first to scientifically analyze leachate treatment at the Barka landfill. Chitosan, a natural polymer, effectively removes suspended matter and heavy metals, reducing their concentrations. removes suspended matter and heavy metals, reducing their concentrations.
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