Upper-mantle Xenoliths Research Articles

Fossil metasomatized and newly-accreted fertile lithospheric mantle volumes beneath the Bakony-Balaton Highland Volcanic Field (central Carpathian-Pannonian region)

This study focuses on upper mantle xenoliths from Sabar-hill (Bakony-Balaton Highland Volcanic Field), a newly discovered locality of mantle xenoliths, situated in the central Carpathian-Pannonian region (CPR). The investigated seven peridotite and one pyroxenite xenoliths record two episodes in the geochemical evolution of the local subcontinental lithospheric mantle. The moderately deformed Group I xenoliths reveal modal contents (≥9 vol% orthopyroxene), major element characteristics (depletion in Al2O3 and CaO in orthopyroxenes) and trace element features (e.g., enrichment in U, Pb and Sr in clinopyroxenes) typical in supra-subduction zones (i.e., mantle wedge) xenoliths. All these suggest that the studied xenoliths were formed by silica-rich fluid/melt - peridotitic wall rock interactions. The tectonic background to the formation of Group I xenoliths is likely linked to the subduction of an oceanic slab during the Mesozoic-Paleogene. This may have happened far from the current position of Sabar-hill, to where the lithosphere, including the metasomatized mantle volume, was transferred via plate extrusion. The less deformed, dominantly protogranular and porphyroclastic Group II xenoliths are depleted in light rare earth elements (LREE). In contrast, they are enriched in clinopyroxene (≥11 vol%), incompatible major elements (e.g., Al and Na) and heavy rare earth elements (HREE), by a minimum of four times compared to primitive mantle. All these suggest that Group II xenoliths represent a geochemically fertile mantle partition and the degree of partial melting affected this mantle section was limited (≤7% based on trace elements). Group II xenoliths have higher equilibrium temperatures (1088–1168 °C) compared to Group I xenoliths (1018–1089 °C). The lack of petrographic and geochemical evidence pointing to metasomatism-related annealing in Group II xenoliths suggests that they are derived from a greater depth. It follows that Group II xenoliths could represent prior asthenosphere volumes which recently accreted to the lithosphere. The lithospherization of the upper part of the asthenosphere may have initiated after the tectonic inversion of the region, when compressional tectonic regime beneath the CPR gradually overtook the former extensional one in the last ∼8 Ma. The high bulk structural hydroxyl content in both Group I (22–1699 ppm) and II (55–320 ppm) xenoliths is likely linked to the subduction events that took place in the CPR from the Mesozoic onwards. These events transported significant amounts of fluid (H2O) back to the upper mantle, affecting both the mantle wedge and the asthenosphere.

Nanoscale hydrous silicate melt inclusions at the clinopyroxene-amphibole interface in a mantle xenolith from the Perșani Mountains Volcanic Field

We studied amphibole lamellae and associated hydrous nano-silicate melt inclusions (NSMI) in upper mantle xenoliths from the Perșani Mountains Volcanic Field, southeastern Transylvania (Romania). Transmission Electron Microscope (TEM) results revealed submicron-scale pieces of evidence of escaped fluids in the form of nano-silicate melt inclusions along clinopyroxene-amphibole interfaces. These NSMIs consist of ∼80 vol% silicate glass and ∼ 20 vol% volatile bubble from which the former has a high SiO2 (>60 wt%) and Al2O3 (>20 wt%) and low CaO, FeO and MgO (<8 wt%) content determined by SDD-EDS analyses. We calculated the original bulk composition of the nano-silicate melt inclusions with Monte Carlo simulation, using hydrated fluid molecules and suggest that originally the nano-silicate melt inclusions had most probably low SiO2 (∼ 43.6 wt%) and high Al2O3 (∼ 15.5 wt%), Na2O (∼11.9 wt%) and H2O (∼ 30.3 wt%) contents. Using petrographic evidence, we propose that the amphibole lamellae formed as a result of post-entrapment reaction between clinopyroxene and the trapped fluid of the fluid inclusion. The presence of the hydrous nano-silicate melt inclusions suggest fluid migration along the clinopyroxene-amphibole interface, supporting the continuous growth of the studied amphibole. The association of the studied amphibole with hydrous nano-silicate melt inclusions suggests that H2O consumption from the fluid found in the micrometer-scale fluid inclusion continued at the nanoscale after a metasomatic event in the lithospheric mantle. This nanoscale process may also give information about the behavior of H2O globally in the lithospheric mantle where amphibole is stable, and along the lithosphere-asthenosphere boundary in younger oceanic and continental plates.

Deciphering metasomatic events beneath Mindszentkálla (Bakony-Balaton Highland Volcanic Field, western Pannonian Basin) revealed by single-lithology and composite upper mantle xenoliths

Single-lithology and composite xenoliths from Mindszentkálla (Bakony-Balaton Highland Volcanic Field) in the Carpathian-Pannonian region record geochemical evolution of the subcontinental lithospheric mantle. The dominant single-lithology xenoliths are orthopyroxene-rich (22 vol% on average) harzburgites. Three composite xenoliths contain either two or more domains including dunite, olivine-orthopyroxenite, orthopyroxenite, apatite-bearing websterite and amphibole-phlogopite-bearing vein. The presence of different lithologies is a result of at least two metasomatic events that affected the lithospheric mantle. The first event resulted in orthopyroxene enrichment thus formed harzburgitic mantle volumes (Group I xenoliths). Major- and trace element distributions of the bulk harzburgites differ from the geochemical trends expected in residues of mantle melting. In contrast, petrographic and geochemical attributes suggest that the harzburgite was formed by silica-rich melt - peridotitic wall rock interactions in a supra-subduction zone. Within the Group I xenoliths, two subgroups were identified based on the presence or lack of enrichment in U, Pb and Sr. Since these elements are fluid mobile, their enrichment in certain Group I xenoliths indicate reaction with a subduction-related fluid, subsequent to the harzburgite formation. The effect of a second event overprints the features of the Group I xenoliths and is evidenced in all domains of two composite xenoliths (Group II xenoliths). The general geochemical character involves enrichment of basaltic major and minor elements (Fe, Mn, Ti, Ca) in the rock-forming minerals and convex-upward rare earth element (REE) patterns in clinopyroxenes. We suggest that the different domains represent reaction products with variably evolved basaltic melts of a single magmatic event. The tectonic background to the formation of Group I xenoliths is likely linked to the subduction of oceanic crust during the Mesozoic–Paleogene. This happened far from the current position of Mindszentkálla, to where the lithosphere, including the metasomatized mantle volume, was transferred via plate extrusion. The Group II xenoliths appear to bear the geochemical signature of a younger (Neogene) basaltic magmatic event, likely the same that produced the host basalt transporting the xenoliths to the surface.

Major and Trace-Element Chemistry of Cr-Spinel in Upper Mantle Xenoliths from East Antarctica

Cr-spinels in the upper mantle peridotite xenoliths from two Late Mesozoic intrusions of alkaline-ultramafic rocks in Jetty Peninsula (East Antarctica) were studied in situ for their major and trace-element compositions by SEM and LA-ICP-MS. The upper mantle xenoliths were collected from the magmatic bodies “sampled” from different upper mantle domains. One domain was represented by mostly lherzolites (Cpx-poor Spl, Cpx-rich Spl and Spl-Grt) and another one by Spl harzburgites and dunites. Spinels occur as grains of different shapes, sizes and origins. Three main textural types of spinel were identified: primary spinel represented by clean homogeneous grains, a rim of recrystallization/resorption surrounding primary spinel grains and irregular interstitial resorbed grains. Primary spinels are characterized by the concentrations of Al2O3 21–51 wt%, MgO 15–20 wt%, FeO 10–24 wt% and Cr2O3 14–37 wt% with the Cr# of 0.16–0.54. Most trace elements are present in spinels in very low amounts. Only Ti, V, Mn, Co, Ni, Zn and Ga display concentrations in the range of tens to hundreds (up to thousands) ppm. Concentrations of other trace elements vary from below the detection limit to &lt;10 ppm. Spinel major oxide and trace element features allowed the suggestion that the studied upper mantle peridotites represent both simple melt residues and residues strongly influenced by the MORB-like and the SSZ-related melts. The MORB-like melts may be related to the beginning of the Lambert–Amery rift system development, whereas SSZ-like melts could be related to reactivation of SSZ material buried during much earlier amalgamation of East Antarctica.

Petrology of Koko Rift basalts: Hawai‘i's most recent and atypical rejuvenation stage eruptive sequence

Rejuvenated volcanism is a worldwide phenomena occurring on many volcanic oceanic islands in all of the major ocean basins (e.g., Samoa, Madeira, Mauritius). This plume-related volcanism follows the main edifice-building stage after a hiatus of variable duration (e.g., 0.6–2 Myrs in Hawai‘i). Hawaiian rejuvenated basalts typically have high MgO contents (>10 wt%) and carry upper mantle xenoliths. Thus, these magmas are assumed to have ascended rapidly through the crust. The basalts erupted along the Koko Rift in Honolulu, Hawai‘i are unusual in their large range in MgO (5.4–11.4 wt%), absence of mantle xenoliths and history of magma mixing. The Koko Rift is the youngest area of rejuvenated volcanism in Hawai‘i (67 ± 2 ka) and its best developed rejuvenation-stage rift system (15-km long rift with 12 major and several minor subaerial and submarine eruptive centers). Here we report on the first systematic petrologic investigation of the Koko Rift basalts to better understand this most recent example of Hawaiian rejuvenated volcanism. New textural and mineral chemical evidence indicates magma was stored along the rift and later mixed to produce the subaerial lavas with 10–11 wt% MgO. The lower MgO (5–6 wt%) subaerial lavas were probably byproducts of the initial hybrid magma, subsequent crystal fractionation and then a second magma mixing event. The absence of mantle xenoliths in Koko Rift lavas and the relatively moderate forsterite contents (84–85%) in the higher MgO lavas may be related to the development of a crustal magma system within the rift. The record of crustal magma storage and crystal fractionation, and two magma mixing episodes in the Koko Rift lavas is unique among Hawaiian rejuvenated volcanism.

Geophysical and Geochemical Constraints on Neogene‐Recent Volcanism in the North American Cordillera

AbstractWidespread recent volcanic rocks occur across the Cordillera landward of the current/recent volcanic arc Mexico to Alaska and most other subduction backarcs. We conclude that most are produced by partial melt in the upper asthenosphere where two conditions are met: (1) thin lithosphere, shallow hot asthenosphere. Most of the Cordillera is uniformly hot with thin lithosphere such that the hot asthenosphere extends up to a sufficiently shallow depth to intersects the wet solidus; (2) wet upper asthenosphere. There is substantial water in the upper asthenosphere that reduces the solidus sufficiently for partial melting. We integrate geochemical analyses that constrain the partial melt source temperature and depth, seismic velocities that define the upper mantle temperature and partial melt zones, and seismic receiver functions that define the lithosphere‐asthenosphere boundary (LAB). Geochemical data for the Canadian Cordillera are integrated with data from the western United States. Upper mantle xenoliths indicate a dry strong lithosphere, &lt;50 ppm H2O. A wet asthenosphere source, &gt;250 ppm, is indicated by the volcanics, facilitating small‐scale convection. Geochemical equilibration averages ∼1,350°C, at ∼65 km. Receiver functions also define the LAB at ∼65 km for the western Cordillera, deeper in the eastern US Cordillera, and asthenosphere tomography velocities indicate ∼1,350°C. Low velocities above ∼150 km suggest a few percent partial melt that percolates upward and ponds at the base of the lithosphere until enough accumulates to locally penetrate upward. The 65‐km depth may be controlled by the spinel‐garnet phase transition. Mechanisms are discussed for the spatial distribution of recent volcanics.

Effect of metasomatism on the electrical resistivity of the lithospheric mantle – An integrated research using magnetotelluric sounding and xenoliths beneath the Nógrád-Gömör Volcanic Field

Long period magnetotelluric (MT) data were collected at 14 locations along a ~50 km long NNW-SSE profile in the Nógrád-Gömör Volcanic Field (NGVF), which is one of the five mantle xenolith bearing Neogene alkali basalt locations in the Carpathian-Pannonian region. As a result, a low resistivity anomaly (<10 Ωm) was observed approximately at 30–60 km depth beneath the central part of the NGVF, indicating the presence of a conductive body beneath the Moho. This is the same area where upper mantle xenoliths with wehrlitic modal composition were collected from six quarries. The wehrlites were formed as a result of mantle metasomatism involving the peridotite wall rock and a mafic melt. The spatial coincidence of the geophysical anomaly and the petrographic-geochemical alteration in the upper mantle suggests their probable relationship. To test this assumption, we estimated the electrical resistivity of the wehrlites. The outcome reveals lower electrical resistivity for wehrlites (~132 Ωm) compared to the non-metasomatized lherzolites (~273 Ωm) from the same localities. However, it is still higher than the values acquired with long period MT soundings. Thus, further modelling was implemented in order to test the possible role of melt. The models revealed that even ~2–3 vol.% of interconnected melt is enough to lower the electrical resistivity below 1 Ωm in the wehrlites. The interconnected glass phase found in the wehrlites may be the evidence for this later solidified melt. All these suggest that melts may still be present in small amounts beneath the cooling NGVF. The intensive melt upwelling in the central part of the NGVF resulting in a wehrlitized mantle portion with low electrical resistivity, as well as the extensive basalt flows on the surface, can be explained by deep deformation zones, which provide excellent migration pathways for melts through the entire lithosphere. • Magnetotelluric and xenolith data are compared in the Nógrád-Gömör Volcanic Field. • The appearance of a low resistivity anomaly coincides with metasomatized xenoliths. • Metasomatized xenoliths with 2–3 vol.% melt result in a resistivity of ~1 Ωm. • Small amount of melt is likely still present beneath the study area. • Tectonic features may facilitate the intensive upward melt migration and volcanism.

Effect of water on the rheology of the lithospheric mantle in young extensional basin systems as shown by xenoliths from the Carpathian-Pannonian region

Incorporation of hydrogen as structural hydroxyl (commonly referred to as water) in nominally anhydrous mantle minerals is known for the ‘hydrolytic weakening’ effect, which decreases the strength and electrical resistivity of the rock. Recent models have provided means of calculating rheological properties from geochemical data of upper mantle xenoliths. In the Carpathian-Pannonian region, upper mantle xenoliths can be found on the surface at five locations, both at marginal and central regions of the basin system. In this study we present a comprehensive overview of water contents in these xenoliths, including previously lacking data from two outcrops (Füzes-tó and Tihany) from the Bakony-Balaton Highland Volcanic Field for the first time. The Tihany xenoliths have significantly higher water contents (< 1–5, 116–353 and 327–1394 ppm in olivine, orthopyroxene and clinopyroxene, respectively) than the Füzes-tó xenoliths (0–2.7, 6.2–114 and 3.1–213 ppm in olivine, orthopyroxene and clinopyroxene, respectively). This can be explained with the older eruption age of their host basalt and greater depth of origin, as they likely represent an asthenospheric layer that became part of the lower lithosphere during thermal relaxation. In contrast, the Füzes-tó xenoliths represent a lot dryer mantle portion and are assumed to have been more affected by decompression-induced water loss resulting from decreased water activity during the extension. In general, the marginal xenolith locations of the Carpathian-Pannonian region, associated to prior supra-subduction environment, contain more water than xenoliths from central locations (with the exception of Tihany locality) which were significantly affected by extension-related lithospheric thinning. To reveal the differences in rheology inferred from the different water contents, we calculated effective viscosities and electrical resistivities for the xenoliths of the Bakony-Balaton Highland and other locationss in the Carpathian-Pannonian region using previously published data for input. Based on the results, the central locations have higher effective viscosities (1.4∙10 20 –2.2∙10 21 Pa s) and electrical resistivities (48–913 Ωm) compared to the marginal locations (9.3∙10 19 –6.8∙10 20 Pa s and 36–182 Ωm, respectively), suggesting that the lithospheric mantle is more rigid in the former than in the latter areas. This may be a common feature for extensional basins, as the extension leads to the ‘drying’ of the upper mantle, whereas subduction zones keep hydrating their overlying mantle wedge. However, for more accurate estimations, other factors such as regional differences in strain rate or the potential presence of melts or fluids in the mantle need to be considered as well. • Water lowers effective viscosity and electrical resistivity in mantle xenoliths • Water contents of xenoliths from different tectonic environments were compared • Central regions of the back-arc basin are drier compared to marginal areas • Rheological differences are present in distinct parts of extension-subduction systems • Decompression related water loss results in strengthening of the lithosphere

Three-dimensional distribution of glass and vesicles in metasomatized xenoliths: A micro-CT case study from Nógrád–Gömör Volcanic Field (Northern Pannonian Basin)

In this study, three clinopyroxene-enriched upper mantle xenoliths, petrographically classified as wehrlite, were investigated from the Nograd–Gomor Volcanic Field with the use of X-ray microtomography. Our main goal was to quantify the volume of the glass phase and the vesicles to reveal their three-dimensional distribution. Among the studied wehrlite xenoliths, one is weakly and two are strongly metasomatized. The two latter wehrlite xenoliths are characterized by higher modal amount of glass and vesicles, which suggests a genetic connection between glass and concomitant vesicles, and the metasomatic agent. The glass, which was a melt at mantle conditions, forms an interconnected network. This may explain the presence of the electromagnetic anomaly with high electrical conductivity beneath the study area. Our study contributes to the better understanding of melt migration and its metasomatic effect in the lithospheric mantle beneath monogenetic volcanic fields

In search for the missing arc root of the Southern California Batholith: P-T-t evolution of upper mantle xenoliths of the Colorado Plateau Transition Zone

Xenolith and seismic studies provide evidence for tectonic erosion and eastward displacement of lower crust-subcontinental mantle lithosphere (LC-SCML) underlying the Mojave Desert Region (i.e. southern California batholith (SCB)). Intensified traction associated with the Late Cretaceous flattening of the subducting Farallon plate, responsible for deforming the SW U.S., likely played a key role in “bulldozing” the tectonically eroded LC-SCML ∼500 km eastwards, to underneath the Colorado Plateau Transition Zone (CPTZ) and further inboard. The garnet clinopyroxenite xenoliths from two CPTZ localities, Chino Valley and Camp Creek (central Arizona), provide a rare glimpse of the material underlying the CPTZ. Thermodynamic modeling, in addition to major and trace element thermobarometry, suggests that the xenoliths experienced peak conditions of equilibration at 600-900°C and 12-28 kbar. These peak conditions, along with the composition of the xenoliths (type “B” garnet and diopsidic clinopyroxene) strongly suggest a continental arc residue (“arclogite”), rather than a lower plate subduction (“eclogite”), origin. A bimodal zircon U-Pb age distribution with peaks at ca. 75 and 150 Ma, and a Jurassic Sm-Nd garnet age (154 ± 16 Ma, with initial εNd value of +8) overlaps eastern SCB pluton ages and suggests a consanguineous relationship. Cenozoic zircon U-Pb ages, REE geochemistry of zircon grains, and partially re-equilibrated Sm-Nd garnet ages indicate that displaced arclogite remained at elevated PT conditions (>700°C) for 10s of Myr following its dispersal until late Oligocene entrainment in host latite. With a ∼100 Myr long thermal history overlapping that of the SCB and the CPTZ, these assemblages also contain evidence for late-stage hydration (e.g. secondary amphibole), potentially driven by de-watering of the Laramide slab.In light of these results, we suggest that the CPTZ arclogite originates from beneath the eastern half of the SCB, where it began forming in Late Jurassic time as mafic keel to continental arc magmas. The displacement and re-affixation of the arclogites further inboard during the Late Cretaceous flat slab subduction, might have contributed to the tectonic stability of the Colorado Plateau relative to adjacent geologic provinces through Laramide time and likely preconditioned the region to Cenozoic tectonism, e.g. present-day delamination beneath the plateau, high-magnitude extension and formation of metamorphic core complexes.

The effect of host magma infiltration on the Pb isotopic systematics of lower crustal xenolith: An in-situ study from Hannuoba, North China

The Pb isotopic compositions of granulite xenoliths are crucial to constrain the formation and evolution of the lower continental crust (LCC) and are potentially the key to resolve the first Pb paradox of the Earth. However, it remains unclear how host magma infiltration affects the Pb isotopic compositions of LCC xenoliths and how different this effect is for different xenoliths in composition (from mafic to felsic). To address these issues, here we provide an in-situ chemical and PbSr isotopic study on feldspars and clinopyroxenes for a suite of fresh mafic and felsic granulite xenoliths from the Hannuoba region in the northern margin of the North China Craton (NCC), which have been previously well characterized for bulk-rock chemical and Sr–Nd–Pb isotopic compositions. Our study shows that the in-situ plagioclase and bulk-rock Pb isotopic compositions of the Hannuoba mafic granulite xenoliths are significantly decoupled. Such decoupling is demonstrated to have been caused by host magma infiltration through contributing the main Pb budget into the grain boundaries and cracks. However, this process appears to have relatively less or negligible effect on the Pb isotopic systematics of feldspar-rich intermediate-felsic granulite xenoliths, which is reflected by their consistent in-situ (feldspar) and bulk-rock Pb isotopic compositions. Such different effects on Pb isotopic systematics for different LCC xenoliths in composition are highly related to the Pb contents or abundances of feldspar in LCC xenoliths. Furthermore, our data suggest that the effect of host magma infiltration on the Pb isotopic systematics of LCC xenoliths may be not easily eliminated by the leaching technique and thus it should be prudent to use the bulk-rock Pb isotopic data of low-Pb LCC and potentially upper mantle xenoliths, such as peridotite, pyroxenite and garnet−/pyroxene-rich mafic granulite. Instead, in-situ analyses of minerals (e.g., feldspar, clinopyroxene) could provide a more convenient and reliable method to obtain the pristine Pb isotopic compositions of these low-Pb xenoliths.

Genesis of Diamondiferous Rocks from Upper-Mantle Xenoliths in Kimberlite

The conditions of genesis of diamondiferous ultrabasic and basic rocks from xenoliths in kimberlite were studied by combining the data from analytical investigations of their mineral phases and experimental results of the study of melting relations in the diamond-forming mineral systems of the upper mantle. The compositions of minerals in some samples of metasomatized diamondiferous eclogite associated with diamond-free eclogite from kimberlite of the Udachnaya pipe (Yakutia) were studied for the first time. The new results obtained in addition to the literature data were applied for generalization of estimates of genetically important characteristics of the chemical compositions of garnets, Ca-clinopyroxenes, and omphacites from diamond-bearing peridotite, pyroxenite, and eclogite. As a result, it was found that quite “fresh” minerals of diamondiferous rocks have typomorphic differences from the same minerals of diamond-free upper-mantle rocks. At the same time, it is significant that the compositions of minerals from diamondiferous rocks and paragenetic inclusions in diamonds are identical. These peculiarities of mineralogy of diamondiferous rocks are genetically significant; based on the mantle–carbonatite theory of the origin of diamond and associated mineral phases, this provides support for the same physicochemical origin of diamonds, minerals of diamondiferous rocks, and paragenetic inclusions in diamonds. Finally, the following genetic conclusions are made. (1) Completely miscible silicate (±oxide)–carbonate melts with dissolved carbon are the parental medium in petrogenesis of diamondiferous ultrabasic and basic rocks. (2) The physicochemically consistent formation of diamondiferous rocks and paragenetic inclusions of peridotitic and eclogitic minerals in diamonds occurred in the common diamond-forming chambers/reservoirs of parental melts; diamond-free peridotite, pyroxenite, and eclogite were the host mantle rocks for such chambers. (3) The origin of continuous series of diamondiferous peridotite–pyroxenite–eclogite rocks is controlled by the fractional ultrabasic–basic evolution of parental melts with exhaustion of olivine and orthorhombic pyroxene via the peritectic reactions. (4) Ascending flows of kimberlite magmas destroyed the parental chambers and captured diamonds with inclusions, individual minerals, their intergrowths, diamondiferous ultrabasic and basic rocks; at the entrance and exit from the chambers, they captured differentiated diamond-free host rocks of the mantle as well. (5) With further ascent from the mantle to the Earth’s crust, the material of diamond-forming chambers and diamond-free mantle was mixed in convecting kimberlite magma and was transported from the mantle to cumulative crustal chambers. (6) Kimberlite magmas were gradually solidified in stationary cumulative chambers with the release of highly compressed fluids; with an increase of pressure up to the critical values, they intruded into the rocks of the roof and ejected kimberlite with xenoliths of diamondiferous and mantle rocks to the surface with the formation of explosion pipes.

Metasomatism-induced wehrlite formation in the upper mantle beneath the Nógrád-Gömör Volcanic Field (Northern Pannonian Basin): Evidence from xenoliths

Clinopyroxene-enriched upper mantle xenoliths classified as wehrlites are common (~20% of all xenoliths) in the central part of the Nógrád-Gömör Volcanic Field (NGVF), situated in the northern margin of the Pannonian Basin in northern Hungary and southern Slovakia. In this study, we thoroughly investigated 12 wehrlite xenoliths, two from each wehrlite-bearing occurrence, to determine the conditions of their formation. Specific textural features, including clinopyroxene-rich patches in an olivine-rich lithology, orthopyroxene remnants in the cores of newly-formed clinopyroxenes and vermicular spinel forms all suggest that wehrlites were formed as a result of intensive interaction between a metasomatic agent and the peridotite wall rock. Based on the major and trace element geochemistry of the rock-forming minerals, significant enrichment in basaltic (Fe, Mn, Ti) and high field strength elements (Nb, Ta, Hf, Zr) was observed, compared to compositions of common lherzolite xenoliths. The presence of orthopyroxene remnants and geochemical trends in rock-forming minerals suggest that the metasomatic process ceased before complete wehrlitization was achieved. The composition of the metasomatic agent is interpreted to be a mafic silicate melt, which was further confirmed by numerical modelling of trace elements using the plate model. The model results also show that the melt/rock ratio played a key role in the degree of petrographic and geochemical transformation. The lack of equilibrium and the conclusions drawn by using variable lherzolitic precursors in the model both suggest that wehrlitization was the last event that occurred shortly before xenolith entrainment in the host mafic melt. We suggest that the wehrlitization and the Plio–Pleistocene basaltic volcanism are related to the same magmatic event.

Extremely low structural hydroxyl contents in upper mantle xenoliths from the Nógrád-Gömör Volcanic Field (northern Pannonian Basin): Geodynamic implications and the role of post-eruptive re-equilibration

The structural hydroxyl content of the nominally anhydrous minerals (olivine and pyroxenes) in the upper mantle is among the important attributes that influence the physical and chemical features of the upper mantle. In this study, we provide detailed Fourier-transform infrared (FTIR) data on 63 petrographically and geochemically well-defined upper mantle xenoliths from the Nógrád-Gömör Volcanic Field (Pannonian Basin, Central Europe). These xenoliths show extremely low average structural hydroxyl contents (~0, 31 and 185 ppm for olivine, orthopyroxene and clinopyroxene, respectively) compared to values reported regionally and worldwide. The studied xenoliths have anomalous types of FTIR spectra and high structural hydroxyl ratios between clinopyroxenes and orthopyroxenes (an average of ~8). Furthermore, there is usually no correlation between the structural hydroxyl content and other physical or chemical properties of the xenoliths. These specific FTIR characteristics suggest that the Nógrád-Gömör upper mantle xenoliths were exposed to significant modification of their structural hydroxyl contents, which may be linked to pre- and post-eruptive processes. Decompression during extension leads to lower ‘water’ activity, which is most likely to have played a key role. However, pre-eruptive mantle metasomatism with an agent having low water activity cannot be excluded either. The post-eruptive cooling can be significant as well, as suggested by the higher structural hydroxyl content in xenoliths hosted in more rapidly cooled volcanic facies (i.e. pyroclastics).Our study reveals how FTIR characteristics may evolve in continental rift settings in young extensional basins. Furthermore, novel applications of our study are the diagnostic features that indicate significant changes in structural hydroxyl properties. This contributes to distinguishing low structural hydroxyl contents linked to the pre-eruptive (i.e., low structural hydroxyl content in pyroxenes, anomalous partitioning and anomalous band characteristic in pyroxenes) or the post-eruptive (completely ‘dry’ olivines) periods.

Xenocrysts and megacrysts of alkali olivine-basalt-basanite-nephelinite association makhtesh ramon (israel): interaction with transporting magmas and morphological adjustment

Xenocrysts and megacrysts hosted in the rocks of Early Cretaceous olivine-basalt-basanite-nephelinite association that outcropped in erosion crater of Makhtesh Ramon (Natural Reserve of Mishmar ha-Nagev, Israel) are the topic of the current research. Magmatic rock association contains the wide spectrum of xenoliths trapped at different crustal levels. These are upper mantle, lower, and upper crustal xenoliths. Mantle xenoliths are represented by peridotites, olivine clinopyroxenites, clinopyroxenites, olivine websterites, websterites and their amphibole-bearing analogs. Lower crustal xenoliths are mafic granulites, such as metagabbros and plagioclasites, upper crustal xenoliths are the fragments of Neoproterozoic tuffs. Xenocrysts and megacrysts are fragments of xenoliths that chipped from them during their transportation to the surface. Different rate of xenoliths, xenocrysts, and megacrysts alteration by host magma and late fluids is a common petrographic particularity. The fluid alteration occurred at phreatomagmatic stage of magma crystallization. Alteration is observed by the appearance of new textures and products of reactional interaction. Xenocrysts and megacrysts are mainly represented by minerals that compatible with rock magmatic association. These are olivine, clinopyroxene, amphibole, nepheline, plagioclase, anorthoclase, apatite, magnetite, and spinel. Xenocrysts of quartz and orthopyroxene are incompatible to host rock magmatic association under-saturated in SiO 2 . Main reasons determining interaction between magma and xenolith are rapid decompression, metamorphism and metasomatism. Xenocrysts are subjected to metamorphism that corresponds to high-temperature facies of contact metamorphism, up to the partial melting of xenocrysts. Metasomatism is smoothing out the composition of xenocrysts to the composition of the same minerals that crystallized from host melt. There are several important criterions, which permit to identify xenocrysts and divide them from phenocrysts. These are partial melting, solid-state decomposition, recrystallization of primary (before-trapping) textures, recrystallization and self-faceting of initially anhedral grains into the crystals with perfect habit. Chemical composition of xenocrysts has both mineral - geochemical indications of xenogenic origin and new-formed sings of alteration.

Upper mantle xenoliths as sources of geophysical information: the Perşani Mts. area as a case study

The aim is to give an overview on how geochemical and petrological data, obtained from upper mantle xenoliths, could be utilized to provide information on the geophysical properties of the upper mantle at their origin. First we demonstrate how a tentative lithospheric column may be constructed based on the equilibrium temperature of upper mantle xenoliths and the area specific depth-temperature curves. Then it is described how the speed of seismic waves at the given pressure and temperature conditions could be calculated from the modal composition and geochemistry of major rock forming minerals of upper mantle xenoliths (e.g. olivine and orthopyroxene). It is also discussed how the lattice preferred orientation of minerals in upper mantle xenoliths provides information on the seismic anisotropy of the upper mantle, and how this information could be used to calculate the orientation and thickness of the anisotropic layer in the upper mantle if one anisotropic layer is assumed. Structural hydroxyl (or most commonly referred to as ‘water’) incorporated in nominally anhydrous minerals plays a critical role in determining the electrical conductivity and rheology of the upper mantle. Finally, it is presented how electrical conductivity and effective viscosity of the upper mantle could be approximated based on the structural hydroxyl content in olivine, the most abundant mineral constituent of the upper mantle. Our study area, the Persani Mountains is situated in the Carpathian Bend area (Romania) which is geologically one of the most active areas in Europe. Abundant upper mantle xenoliths from the Persani Mountains (Eastern Carpathians) will serve as examples how meaningful geophysical information can be obtained for the upper mantle. Furthermore, it is shown how these pieces of information may be utilized in interpreting geophysical and geodynamic challenges of this area.

The role of mantle-hybridization and crustal contamination in the petrogenesis of lithospheric mantle-derived alkaline rocks: constraints from Os and Hf isotopes

The Rhon area as part of the Central European Volcanic Province (CEVP) hosts an unusual suite of Tertiary 24-Ma old hornblende-bearing alkaline basalts that provide insights into melting and fractionation processes within the lithospheric mantle. These chemically primitive to slightly evolved and isotopically (Sr, Nd, Pb) depleted basalts have slightly lower Hf isotopic compositions than respective other CEVP basalts and Os isotope compositions more radiogenic than commonly observed for continental intraplate alkaline basalts. These highly radiogenic initial 187Os/188Os ratios (0.268–0.892) together with their respective Sr–Nd–Pb isotopic compositions are unlikely to result from crustal contamination alone, although a lack of Os data for lower crustal rocks from the area and limited data for CEVP basalts or mantle xenoliths preclude a detailed evaluation. Similarly, melting of the same metasomatized subcontinental lithospheric mantle as inferred for other CEVP basalts alone is also unlikely, based on only moderately radiogenic Os isotope compositions obtained for upper mantle xenoliths from elsewhere in the province. Another explanation for the combined Nd, Sr and Os isotope data is that the lavas gained their highly radiogenic Os isotope composition through a mantle “hybridization”, metasomatism process. This model involves a mafic lithospheric component, such as an intrusion of a sublithospheric primary alkaline melt or a melt derived from subducted oceanic material, sometime in the past into the lithospheric mantle where it metasomatized the ambient mantle. Later at 24 Ma, thermal perturbations during rifting forced the isotopically evolved parts of the mantle together with the peridotitic ambient mantle to melt. This yielded a package of melts with highly correlated Re/Os ratios and radiogenic Os isotope compositions. Subsequent movement through the crust may have further altered the Os isotope composition although this effect is probably minor for the majority of the samples based on radiogenic Nd and unradiogenic Sr isotope composition of the lavas. If the radiogenic Os isotope composition can be explained by a mantle-hybridization and metasomatism model, the isotopic compositions of the hornblende basalts can be satisfied by ca. 5–25% addition of the mafic lithospheric component to an asthenospheric alkaline magma. Although a lack of isotope data for all required endmembers make this model somewhat speculative, the results show that the Re–Os isotope system in continental basalts is able to distinguish between crustal contamination and derivation of continental alkaline lavas from isotopically evolved peridotitic lithosphere that was contaminated by mafic material in the past and later remelted during rifting. The Hf isotopic compositions are slightly less radiogenic than in other alkaline basalts from the province and indicate the derivation of the lavas from low Lu–Hf parts of the lithospheric mantle. The new Os and Hf isotope data constrain a new light of the nature of such metasomatizing agents, at least for these particular rocks, which represent within the particular volcanic complex the first product of the volcanism.

Lithospheric mantle processes beneath Kurose islet, Southwest Japan

Upper mantle xenoliths enclosed in Cenozoic alkali basalts in Southwest Japan were found at Kurose Islet. The xenoliths consist primarily of harzburgite and minor lherzolite and exhibit a porphyroclastic texture. Trace element data showing relative depletion in light rare earth elements (REEs) and general spoon‐shaped patterns suggest that xenoliths experienced depletion and slight enrichment processes. Incompatible trace element patterns for the spinel peridotite xenoliths indicate varying degrees of modification by fractional melting (from 6 to 11%). The Kurose spinel peridotites appear to have undergone melt extraction followed by an episode of cryptic mantle metasomatism. A nearby silicate melt may have been the metasomatic agent affecting spinel peridotites. The spinel peridotites originated from depths of 48 to 51 km at equilibrium temperatures ranging from 1030 to 1082 °C.

제주도 암석권의 성분과 진화(I): 리뷰

제주도 현무암에 포획된 맨틀 페리도타이트에 대한 암석학적/지화학적 연구는 한반도 상부맨틀 암석권 진화에 대한 우리의 지식을 한층 높이고 있다. 제주도의 페리도타이트 포획암은 대부분 첨정석 레졸라이트이며, 그 외 하즈버가이트와 휘석암으로 이루어져 있다. 제주도 페리도타이트 포획암은 부분용융, 재결정변형작용, 교대작용을 경험한 후 맨틀에 남아있던 잔류맨틀물질임을 나타낸다. 이 포획암은 맨틀웨지 환경에 있었던 암석으로 분별부분용융에 의해 일차적으로 결핍과정을 겪었으며, 소규모의 전단대내 특정한 편압에서 소량의 반상쇄성-압쇄조직이 형성되는 재결정작용도 경험했다. 그 이후 페리도타이트는 섭입하는 슬랩 기원의 <TEX>$SiO_2$</TEX>, K, <TEX>$H_2O$</TEX>, LREE에 포화된 유체(혹은 용융체)에 의해 다양하게 교대/부화되었다. 슬랩 기원의 이 유체는감람석과 반응하여 사방휘석과 금운모를 이차적으로 형성하였다. 교대작용은 제4기 제주도 마그마 시스템보다 충분히 앞선 사건이었으며, 모마그마와는 성인적으로 관련이 없다. 이러한 교대작용에도 불구하고 제주도 상부맨틀 암석권은 비교적 높은 온도와 교대작용 이후에 주어진 충분한 시간에 의해 지화학적으로 완전한 평형상태에 도달하였다. 그 이후에 동해가 열리고 동아시아 암석권은 확장되어지면서 원시 제주암석권도 맨틀웨지 환경에서 판내부환경으로 변환되어진다. 제4기 판내부환경에서 제주도가 형성되면서 이때 상승하는 알칼리 현무암에 포획된 맨틀 페리도타이트가 지표면에 운반되어졌다. 제주 상부맨틀 암석권에서 일어난 이런 종류의 물질순환은 대륙지각하부 암석권맨틀의 진화에 상당히 중요한 역할을 했었을 것이며, 동아시아 아래 상부맨틀 암석권에 EM I, EM II와 같은 부화된 영역을 형성하는데 기여했을 수도 있다. Our knowledge of the lithosphere beneath the Korean Peninsula has been improved through petrologic and geochemical studies of upper mantle xenoliths hosted by Quaternary intraplate alkali basalts from Jeju Island. The xenoliths are mostly spinel lherzolites, accompanied by subordinate harzburgite and pyroxenites. The mantle xenoliths represent residual mantle material showing textural and geochemical evidence for at least a three-stage evolution, fractional partial melting, recrystallization, and metasomatism. Their composition primarily controlled by early fractional melt extraction and porphyroclastic and mylonitic fabrics formed in a shear-dominated environment, which was subsequently modified by residual slab-derived fluids (or melts). Modal metasomatic products occur as both anhydrous phase(orthopyroxene) and hydrous phase (phlogopite). Late-stage orthopyroxene is more common than phlogopite. However, chemical equilibrium is evident between the primary and secondary orthopyroxene, implying that the duration of post-metasomatic high temperatures enabled complete resetting/reequilibration of the mineral compositions. The metasomatic enrichment pre-dates the host Jeju Quaternary magmatism, and a genetic relationship with the host magmas is considered unlikely. Following enrichment in the peridotite protolith in the mantle wedge, the upper mantle beneath proto-Jeju Island was transformed from a subarc environment to an intraplate environment. The Jeju peridotites, representing old subarc fragments, were subsequently transported to the surface, incorporated into ascending Quaternary intraplate alkali basalt. The result of this study implies that long term material transfer in the transformation of geotectonic setting from a subarc to intraplate may have played a significant role in the evolution of lithospheric mantle, resulting in the enriched mantle domains, such as EM I or EM II in the lithospheric mantle beneath East Asia.

Experimental formation of pyroxenite veins by reactions between olivine and Si, Al, Ca, Na, and Cl-rich fluids at 800 ºC and 800 MPa: Implications for fluid metasomatism in the mantle wedge

Fluids buffered by a plagioclase matrix are experimentally reacted with olivine megacrysts at 800 oC and 800 MPa (piston-cylinder press, CaF2 assembly) to form secondary veins of orthopyroxene ± clinopyroxene in the olivine. Fluids utilized were varied in both amount (0–2 wt%) and salinity (0–8 M NaCl). Assuming equilibrium with the plagioclase matrix, they are presumed enriched in Si, Al, Ca, Na, and Cl and are thereby similar in composition to slab-derived fluids. The experiments provide controlled, multi-component analogs of Si-metasomatism in the mantle wedge above subduction zones. The veins are dominated by orthopyroxene with minor clinopyroxene and form complex interconnected networks along fractures in the olivine. The reaction is rate limited by interfacial process of dissolution and precipitation. Porosity is developed throughout the veins and along sub-grain boundaries in the olivine megacrysts. These veins strongly resemble the textures observed in secondary metasomatic orthopyroxene veins widely reported in upper mantle xenoliths within arc magmas. A review of literature data on natural samples and experiments suggests that orthopyroxene ± clinopyroxene veins primarily form between 750–950 oC and over a large pressure range from 0.8–3.4 GPa. The abundance and composition of these metasomatic veins may vary as a function of pressure, variances in the fluid-rock partition coefficients, and/or by modification of the metasomatic fluid during the reaction.