Upper-crustal Levels Research Articles

Heat pulse−dominated magmatic storage: The 33 ka dacite dome eruption at Taápaca volcano (Central Andes)

We present 40Ar/39Ar ages of dacite domes and rare volcanic sanidine megacrysts from Taápaca volcano (northern Chile) that record 1.3 m.y. of activity. Our focus is on 20 megacrysts from a single 32.9 ka eruption. We interpret that their surprisingly correlated Ba-rich and Ba-poor growth zones separated by resorption surfaces reflect frequent heat pulses with a uniform thermal history over >300 k.y. of growth. We infer extended storage in small (<400 m), shallow “hot” domains within a larger magma system. Our findings bear on the origin of K-feldspar megacrysts in plutonic rocks, thus linking volcanic and plutonic processes in shallow silicic magma systems, and support protracted residence of hot magma in small batches at upper-crustal levels to produce megacryst-bearing granitoid intrusive complexes.

Assessing the geological relationships between the mafic-ultramafic intrusion in the Haib area and the Vuurdood Subsuite, Richtersveld Subprovince

Abstract The Haib porphyry copper deposit is situated in the Richtersveld Subprovince and is host to unique Palaeoproterozoic porphyry copper mineralisation in Namibia. Several lines of evidence, including machine-learning geothermobarometry, indicate that the deposit is exposed at mid- to upper-crustal levels, as constrained from average pressure and temperature estimates of 4 kbar and 870°C, respectively. The Haib porphyry copper deposit is associated with, and is in close proximity to, a mafic-ultramafic intrusion named the Kokerboom Intrusion (KI) in this study. Together with several other mafic intrusions in this region, these intrusions are known collectively as the Vuurdood Subsuite of the Richtersveld Subprovince. The purpose of this study is to demonstrate a genetic link between the KI and the Vuurdood Subsuite using lithological characteristics, mineral and alteration assemblages, major and trace element geochemistry and U-Pb geochronology. Pyroxenites from the KI contain magmatic sulphides and have a geochemical affinity with shallow plutonic and volcanic rocks of the Haib porphyry, providing a unique mid-crustal perspective on porphyry copper deposit metallogenesis.

Inclusions in magmatic zircon from Slavonian mountains (eastern Croatia): anatase, kumdykolite and kokchetavite and implications for the magmatic evolution

Abstract. Micro-Raman spectroscopy was used to determine the inclusions in magmatic zircon from the Late Cretaceous A-type acid igneous rocks in the Slavonian mountains (Mt. Papuk and Mt. Požeška Gora), in the southwestern part of the Pannonian Basin (Croatia). The mineral inclusions detected in the early-crystallised zircon are anatase, apatite, hematite, ilmenite and possibly magnetite. Numerous melt inclusions comprise albite, cristobalite, hematite, kaolinite, K-feldspar, kokchetavite, kumdykolite muscovite and quartz, where this mineral association is characteristic of so-called nanorocks (nanogranites), commonly found in peritectic garnets from high-grade metamorphic rocks. Here we present the first finding of kokchetavite and kumdykolite in a magmatic zircon. Together with anatase and hematite, these polymorphs are likely evidence of rapid uplift and consequent rapid cooling of hot oxidised magma generated in the lower crust and its emplacement in the upper crustal level. This finding provides further confirmation that kumdykolite and kokchetavite do not require ultra-high pressure (UHP) to form and should not be considered exclusively UHP phases. The rapid uplift was possible due to the formation of accompanying extensional deep rifts during the tectonic transition from compression to extension, associated with the closure of the Neotethys Ocean in the area of present-day Slavonian mountains in the Late Cretaceous (∼82 Ma).

Thermodynamic modelling of continental arc-adjacent magmatism: the Loicas Trough, N. Patagonia, Argentina

Continental arcs are associated with volcanism concentrated into two main belts—the main arc and back arc, often separated by fold and thrust belts. The Loicas Trough, Argentina, is a post-orogenic extensional feature that obliquely cuts the fold and thrust belts. The trough hosts large Pliocene–Holocene volcanic centres, including Domuyo and Tromen, that lie between the main arc and back arc and thus provide a rare window into this setting. We present major and trace element data for the Loicas Trough, which we combine with geochemical modelling using the Magma Chamber Simulator (MCS) to explore the origin and evolution of the volcanism. The lavas display a wide continuous range from alkaline basalts to subalkaline rhyolites. Trace elements reveal variable extents of arc enrichment (2 < Nb/U < 28), which correlate with proximity to the trench and differentiation indices. Our results and MCS models indicate that the Loicas Trough parental magmas formed from compositionally zoned mantle. Best-fit models indicate that the differentiation occurs at middle and upper crustal levels, in sharp contrast to lower crustal hot zones beneath main arcs. Assimilation of partial crustal melts drives compositional evolution and obscures source signatures. Pure or high fraction end-member partial crustal melts are also identified at Domuyo based on their low Ba (~ 250 ppm) and moderate Sc contents (~ 8 ppm). We find evidence of similar lavas in transtensional settings adjacent to continental arcs worldwide, which do not adhere to the main versus back arc volcanism binary. We suggest the term arc-adjacent magmatism, where compositions are mainly controlled by extensive assimilation and reworking in the middle to upper crust.

A COMBINED MODEL OF THE DIAPIRIC AND COLLISIONAL FORMATION MECHANISM OF THE PALEOPROTEROZOIC GRANITE-MIGMATITE-GNEISS DOMES OF THE SVECOFENNIAN BELT

Geological examples of the development of thermal dome structures in the Svecofennian belt demonstrate the relationship between plutonic and metamorphic events and metamorphic strengthening towards the core parts of the structures. The corresponding 2D geological model has been created to make a quantitative assessment of the effect of mantle magmas temperature at the base of the crust and the formation of the diapiric cores surrounded by high-temperature areas with a degree of granulite facies metamorphism. Modeling shows that there is a possibility of melting of the lower crust in the presence of a water fluid under the influence of mantle magmas. After melting, there occurs an ascent of partially molten material towards the upper crustal levels. An absorbed aqueous fluid changes to hydrous melt, thus lowering its viscosity and density. The ascending height of high-temperature cores is determined by the depth of viscous-to-elastoplastic transition in the crustal matter rheology. These materials ascend to upper levels in a partially molten state in the process of overthrusting due to "collisional" tectonics.

Wet calc-alkaline magmatic fractionation in the middle−upper crustal sections of the continental arc: Insights from the Neoproterozoic Nanba intrusive complex, western Yangtze Block, South China

Elucidating the petrological and geochemical characteristics of continental arc crustal fragments can provide unique insights into the magmatic evolutional path and physicochemical conditions (e.g., P−T−H2O) of continental magmatic arcs. This contribution provides a comprehensive set of petrological, mineralogical, geochronological, and geochemical data for the Neoproterozoic Nanba intrusive complex of the western Yangtze Block, South China, which features well-exposed middle−upper crustal sections of the Neoproterozoic continental magmatic arc, to evaluate their magmatic source and fractionation process. The Neoproterozoic Nanba intrusive complex, composed of cumulate gabbros, hornblende gabbros, gabbro-diorites, diorites, granodiorites, K-feldspar granites, and monzogranites, was emplaced at ca. 796−790 Ma. The different lithologies of the Nanba intrusive complex display relatively homogeneous Sr-Nd-Hf isotopes, which indicates a cogenetic evolutional process. The predominantly depleted isotopic characteristics, together with high values of Ba, Rb/Y, and Ba/La, demonstrate that these rocks mainly originated from a subduction fluid−metasomatized mantle source. Petrological and geochemical characteristics, as well as hornblende thermobarometric data, collectively support that the ca. 796−790 Ma Nanba intrusive complex, following the calc-alkaline trend, was dominated by the wet cogenetic fractionation of hornblende accompanied by plagioclase and accessory minerals beneath the middle−upper crustal levels (2.4−4.7 kbar). The cumulate gabbros represent the residue of accumulated hornblende + plagioclase + Fe-Ti oxides from fractionated basaltic melts. The high-SiO2 K-feldspar granites and monzogranites display complementary trace elements, which represent residual silicic cumulates and extracted interstitial liquids in the shallower crystal mush reservoir, respectively. In combination with previous studies, we propose that the middle−upper crustal sections of the Neoproterozoic continental arc of the western Yangtze Block underwent hornblende-dominated fractionation that was followed by significant crystal-liquid separation, which led to the genesis of high-SiO2 melts at the shallower crustal level. The cogenetic evolution played a significant role in molding the petrological and geochemical diversity of Neoproterozoic igneous rocks and the differentiation process of continental arc crust in the western Yangtze Block.

Modelling SiO2 solubility over wide P-T conditions: advances and open problems

Fluids in the Earth’s crust and upper mantle constantly change chemically, physically, and catalyze different processes, such as mass transfer, with implications for large-scale geodynamics. Silica solubilization has profound implications for mass transfer over a wide range of geologic environments, from upper crustal levels down to the deepest portion of subducting slabs and at the hot base of large orogens. Here I investigate, by using electrolytic fluid thermodynamic modelling, the solubility and speciation of SiO2 in H2O at 100–1400 °C and 0–10 GPa, with a particular focus on the geothermal gradients typical in subduction zones and collisional orogens. I show how SiO2 solubility strongly increases with temperature, reaching dissolved loads between 5 wt% and >70 wt%, within subducting slabs. Results indicate that fluids with dissolved SiO2 ranging from 3 to 57 wt% along Barrovian and Buchan-type P-T gradients, strongly question the long-standing assumption of the isochemical nature of regional metamorphism. A by-product of this investigation is the tracking of the source of mineralizing fluids responsible for widespread quartz veins back to the deeper and hotter roots of orogens where amphibolitic to granulitic-facies conditions are encountered.

Oxygen and radiogenic isotopes require different contamination paths in the Azufre volcano, Central Andes, northern Chile

Azufre Volcano (21°47′S, 68°15′W), located in the Altiplano-Puna Volcanic Complex of the Andean Central Volcanic Zone (CVZ), is formed by two coalescent edifices (Northern and Southern) constructed between 120 and 1300 kaExtensive hydrothermal alteration occurred within a host sequence of andesites/dacites (120–700 ka in age) in the Northern edifice. The silica content of the erupted lavas of this volcano range from ∼60% m/m (andesite) to ∼67% m/m (dacite). These lavas have 87Sr/87Sr ratios ranging from 0.7066 to 0.7074, 143Nd/144Nd ratios ranging from 0.51229 to 0.51239, and quartz δ18O values ranging from 7.9 to 9.8‰. The original magmas had δ18O values from 7.4 to 9.4‰ (average ∼8.0‰) assuming that Δquartz-melt = 0.5‰.A three-stage magmatic evolution is proposed for Azufre. In the first stage, a mantle-derived magma (87Sr/86Sr = 0.70376; δ18O ∼5.7‰) ascended to plagioclase-dominated felsic crustal levels (25–50 km depth), assimilating up to 21% of crustal material. This generated a sub-arc parental melt with 87Sr/86Sr ∼0.705 and δ18O ∼6.5‰. The second stage involves contamination of the parental magma by assimilation of up to 25% of crust with higher 87Sr/86Sr ratios (0.714) and δ18O (6.4–11.8‰) at upper crustal levels (10–25 km depth). This upper crust corresponds to partially molten zones which coincides with the location of the Altiplano-Puna Magma Body. The generated melts have 87Sr/86Sr ratios up to ∼0.7075 and δ18Omelt 8.5–9.4‰, which fractionates high-δ18O quartz (9.0–9.8‰). The final stage occurred at shallow crustal levels (<10 km depth) where the magmas underwent fractional crystallization during assimilation of crustal material, which due to high-temperature hydrothermal alteration had low δ18O value (δ18Omelt 7.4–8.5‰). During this stage, high-δ18O quartz of the previous stage remains as antecrysts, coexisting with the low-δ18O quartz (δ18Oquartz 7.9–9.0‰) fractionated at shallow depths.

Anatomy of a craton: Isotopic heterogeneity across an Archean crustal cross-section

The formation of granitoids, predominantly tonalite-trondhjemite-granodiorite (TTG) suites was a key process in the differentiation of Earth’s earliest crust. However, the relative importance of intracrustal reworking versus input from external sources remains unclear. U–Pb and Hf isotopic data collected from zircon in Archean granitoids frequently support reworking and partial melting of a common crustal reservoir over time to produce subsequent generations of melt. A less frequently observed isotopic signature, in a single region, implies the production of different generations of TTGs from unrelated sources. These end-member scenarios of granitoid generation have quite different implications for Archean crustal evolution. Here, we investigate TTGs from across a crustal cross-section known as the Kapuskasing Uplift in the Neoarchean Wawa terrane of the southern Superior Province. We report U–Pb and Hf isotopic data from zircon in TTGs from the lower, middle, and upper crust to evaluate their sources. Results indicate three groups of TTGs: a ca. 2885 Ma upper-crustal TTG with chondritic εHf, ca. 2835–2820 Ma lower-crustal TTGs with subchondritic εHf, and ca. 2750–2685 Ma TTGs with suprachondritic εHf emplaced at middle- to upper-crustal levels. Each group was derived from an isotopically distinct source. We propose that the Mesoarchean rocks exposed in the Kapuskasing Uplift represent a crustal fragment rifted from the margin of existing Mesoarchean terranes in the Superior Province. Subsequent Neoarchean juvenile magmatism dominates the upper and middle crust resulting in isotopic stratification of the Kapuskasing Uplift, as only the lower crust contains evidence of all three isotopic sources. Inferences about Archean crustal evolution in general rely on upper- to middle-crustal rocks (i.e., greenstone belts and grey gneiss), as these represent the majority of exposed Archean crust worldwide. The potential for the lower crust to be decoupled from overlying rocks implies that some parts of the Archean geological record may be preserved only at the deepest crustal levels—particularly rocks related to the most ancient sources.

Inferring the depth and magnitude of pre-instrumental earthquakes from intensity attenuation curves

Abstract. The Italian historical earthquake record is among the richest worldwide; as such it allows for the development of advanced techniques for retrieving quantitative information by calibration with recent earthquakes. Building on a pilot elaboration of northern Italian earthquakes, we developed a procedure for determining the hypocentral depth of all Italian earthquakes from macroseismic intensity data alone. In a second step the procedure calculates their magnitude, taking into account the inferred depth. Hypocentral depth exhibits substantial variability countrywide but has so far received little attention: pre-instrumental earthquakes were routinely “flattened” at the upper-crustal level (∼10 km), on the grounds that the calculation of hypocentral depth is heavily dependent on the largely unknown local propagation properties. We gathered a learning set of 42 earthquakes documented by reliable instrumental data and by numerous macroseismic intensity observations. We observe (1) that within 50 km from the epicenter the ground motion attenuation rate is primarily controlled by hypocentral depth and largely independent of magnitude, (2) that within this distance the fluctuations in crustal attenuation properties are negligible countrywide, and (3) that knowing both the depth and the expected epicentral intensity makes it possible to estimate a reliable magnitude.

Petrogenesis of potassic granite suites along the southern margin of the Zimbabwe Craton

AbstractAn integrated approach embracing field studies, petrographic and geochemical investigations together with zircon U-Pb-Hf data was used to investigate the petrogenesis of potassic granite suites along the southern margin of the Zimbabwe Craton. Zircon U-Pb geochronology identifies age relationships, revealing coeval magmatism of the ca. 2 635 ± 5 to 2 625 ± 3 Ma Chilimanzi Suite, and the ca. 2 627 ± 7 Ma Razi Suite. Both suites represent syn- to late-tectonic, high-K, calc-alkaline, and metaluminous to weakly peraluminous granites and granodiorites with I-type affinity. The granite suites contain xenocrystic zircons, with the Chikwanda Pluton of the Chilimanzi Suite yielding a grain of up to 3 206 Ma old. Both granite suites exhibit eHf values of between -5.6 ± 1.3 and -7.3 ± 1.6 and TDM model ages of ca. 3.4 to 3.5 Ga which suggests a similar crustal source. The unradiogenic zircon Hf isotopic compositions are consistent with formation of the granite suites through partial melting of pre-existing crustal protoliths, including Palaeoarchaean tonalite-trondhjemite-granodiorites (TTGs) of the Zimbabwe proto-craton. Partial melting of lower crust gave rise to granitic melts that became emplaced over a relatively short time interval from 2 635 to 2 625 Ma and heralded the stabilisation of the Zimbabwe Craton.In addition to virtually identical ages, the Razi and Chilimanzi suites have similar geochemistry. Small geochemical differences between the Chilimanzi and the Razi suites are attributed to the crustal level at which they are preserved, the modal mineralogy and the extent to which the melts are evolved. The Razi Suite melts were generated from lower crust partial melting of thickened charnockite-enderbite source rocks rich in heat producing elements. The partial melting occurred under fluid-absent conditions and magmas were emplaced at lower to mid crustal levels. The Chilimanzi Suite magmas were similarly derived by the partial melting of TTG lower crust and were emplaced at upper crustal levels. Accordingly, the Chilimanzi Suite exhibits more evolved magmatic fractionation indices indicated by high Rb/Sr, as well as low K/Rb ratios relative to the Razi Suite. Both suites reveal varying degrees of enrichment in incompatible elements including Rb, Th, and U, as well simultaneous depletions in Ba, Sr, and Hf which underscores the role of fractional crystallisation in the evolution of the granitic magmas.

Early Triassic Monzonite–Granite Series in Eastern Kazakhstan as a Reflection of Siberian Large Igneous Province Activity

We provide the results of studying the internal structure and composition of the rocks of the Semeitau and Delbegetei massifs located in Eastern Kazakhstan. It was previously believed that these massifs have different ages and were formed in different geodynamic settings. The U-Pb zircon age from the monzonites and quartz monzonites was determined to be 249 ± 2 Ma, which showed the same Early Triassic age of the massifs. Both massifs are composed of rocks of the same monzonite–granite series of rocks with a significant proportion of high-silica rocks (leucocratic granites). Intermediate rocks are formed due to the differentiation of subalkaline mafic magmas, and the felsic rocks (rhyolites and granites) are the result of partial melting of crustal substrates. The massif formation model assumes the intrusion of mafic magmas into the crust, their differentiation and mixing with crustal melts, and then the intrusion of various rocks into the upper crustal levels. Analysis of the geological position, age and composition of the rocks allows us to conclude that the Semeitau and Delbegetei massifs were formed in an intraplate geodynamic setting. The activity of the mantle plume is the most probable reason for their formation. The Semeitau and Delbegetei massifs can be included in the southern part of the range of the Early Triassic Siberian Large Igneous Province.

Slip distribution and block rotation of the Indo-South China region inferred from GNSS analyses

Indo-South China lying between the Indian Plate and the rigid South China Block is characterized by intense crustal deformation with severe seismic hazards. How deformation is partitioned through slip on various structural features provides key insights into understanding the regional geodynamic processes. Based on the up-to-date GPS velocity data together with the existing active tectonic, seismological, and geophysical data, we find that the relative motion between India and South China is mainly accommodated by two parts: ∼47 mm/yr dextral slip and 15–18 mm/yr contraction to the west of the Shan Plateau, and ∼ 10 mm/yr sinistral slip and ∼ 10 mm/yr extension to the east of it. The Burmese Range takes up ∼ 22 mm/yr dextral slip and 10–13 mm/yr contraction, while the Sagaing Fault accommodates ∼ 18 mm/yr dextral slip and 5–6 mm/yr contraction. The Shan Plateau Shear Zone absorbs ∼ 8 mm/yr dextral slip and 5–6 mm/yr extension. The Chuandian Terrane from east of the Red River Fault to the Xiaojiang Fault manifests 8–10 mm/yr sinistral slip and 5–6 mm/yr extension. The block motion inversion reveals that the clockwise rotation and deformation are caused by the northeastward motion of the India Plate and the clockwise lithospheric flow around the Eastern Himalayan Syntaxis. The Shan Plateau Shear Zone may be a newly formed dextral shear zone at depth of the middle and lower crust, driving the sinistral slip and extension along the ENE-trending faults in upper crustal level. The Shan Plateau Shear Zone might have replaced the Red River Fault as the western boundary to cause the southeastward coherent movement of the Chuandian Terrane. The complex pattern of active tectonic deformation in the region results from interactions among hyper-oblique subduction beneath the Burmese Range, clockwise rotation of lithospheric material around the Eastern Himalayan Syntaxis, and the apparently rigid Sundaland Block separating the two systems in between.

Pluton incremental growth by multi-stage magma pulsations: Evidence from the Fangshan pluton, North China Craton

The Fangshan intrusive suite is a composite pluton in the North China Craton that resulted from incremental assembly of small magma batches. The pluton consists of four intrusive units with abundant mafic enclaves. Here we clarify its crystallisation history through zircon UPb dating, which indicates prolonged crystallisation of each intrusive unit at upper-crustal levels between 132.5 and 128.7 Ma. The magmas were episodically extracted from a deep storage area and ascended to the final intrusion level at a palaeo-depth of 10–16 km. Zircon trace element and Hf isotopic compositions and Ti-in-zircon temperature of the four intrusive units and mafic enclaves show significant differences and suggest that their crystallisation occurred in isotopically and chemically diverse magma batches. These magma batches formed in the lower crust from the mingling and mixing of various proportions of residual melts, derived from the fractional crystallisation of mafic magmas, with crustal partial melts at high temperatures. Four type of zircons were observed in mafic enclaves based on a simple textural classification, including antecrysts (type 1), xenocrysts (type 2 and type 3), and recrystallised zircon (type 4). Type 1 zircons were not formed at the emplacement level and are “antecrystic”, having formed at a deeper, hotter level and been entrained into the ascending melts. Most type 2 zircons were captured from coarse-grained monzonite, and a very small number of grains were sourced from porphyritic granodiorite. Type 3 zircons display a core-rim texture, illustrating that xenocrysts may successively grow in mafic melts. Type 4 zircons display patchy zoning that represents a disequilibrium texture, manifested by the replacement of U–Th–REE-rich zircon by U–Th–REE-poor zircon, which occurred in response to magma mixing between mafic and felsic melts. This study shows that zircon chemistry coupled with detailed textural analyses can provide a powerful tool to elucidate the complex evolution of a magmatic system.

Pegmatites as geological expressions of spontaneous crustal flow localisation

Amongst the silicate-rich crystalline rocks that are produced in the continental crust, pegmatites are characterised by their large crystals which give them both an aesthetic and economic interest. Pegmatites crystallise either from fractionated magma derived from a parent granitic body or from the partial melting of meta-sediments or meta-igneous rocks (e.g. amphibolite). The mechanism of residual magma (or fluid) extraction from the parent granitic body has been thoroughly studied, but pegmatitic melt extraction after partial melting has received less attention. We present here a series of non-dimensional numerical experiments using a two-phase flow formulation that couples the Stokes problem to/with non-linear Darcy flow. This approach makes it possible to predict the movement of fluid inclusions (named porosity) in a deformable of a viscous rocks (named porous matrix). We find that the simulation produces either clusters or an isolated body of fluid inclusion depending on the compaction/decompaction ratio of the effectively viscous matrix in which they rise. Using a review of pegmatite natural properties, we propose a scaling of our numerical simulations that describes the ascent of a pegmatite-forming melt produced by partial melting. We then discuss possible travel distances and temperature effects. To discuss our results in light of field observations, we assume that the compaction-decompaction ratio is an accurate proxy for the influence of brittle processes at a scale smaller than the representative volume element, and therefore corresponds structural level variations at which pegmatites are emplaced. We find that our numerical simulation explain the statistical organisation, in terms of level of emplacement, of real fields of pegmatites possibly derived from partial melting of meta-sediments. Pegmatites in fact tend to organise as clusters around brittle faults in upper crustal levels, whereas they present a scattered distribution at mid to lower crustal levels. Our results therefore show that porosity waves are a possible mechanism for rapidly extracting and transporting pegmatite melts formed during low-degree (ca. 10%) partial melting at distances up to a few kilometres in the crust.

Embryos of TTGs in Gore Mountain garnet megacrysts from water-fluxed melting of the lower crust

The garnet megacrysts of Gore Mountain (Adirondacks, US) are world-renown crystals due to their size, up to 1 m in historical record, which makes them the largest known garnets on the planet. We show here that they are also host to the first primary inclusions of trondhjemitic melt found in natural mafic rocks. The petrological and experimental investigation of the inclusions, coupled with phase equilibrium modelling, shows that this melt is the result of H2O-fluxed partial melting at T>900°C of a lower crustal gabbro. The compositional similarity between the trondhjemitic melt inclusions and tonalitic–trondhjemitic–granodioritic (TTGs) melts makes these inclusions a direct natural evidence that melting of mafic rocks generates TTG-like melts, and provides us with the possibility to clarify processes responsible for the formation of the early continental crust. These TTG embryos represent the trondhjemitic end-member of the melts whose emplacement at upper crustal levels, after being modified by mixing and crystallization-related processes, leads to the formation of the TTG terranes. Moreover, our study shows how the melt from H2O-fluxed melting of mafic lower crust has mismatched major and trace element signatures, previously interpreted as evidence of melting at very different pressures. This poses serious limitations to the established use of some chemical features to identify the geodynamic settings (e.g. subduction versus thickened crust) responsible for TTGs generation and the growth of early crust.

Calcite pseudomorphs after aragonite: A tool to unravel the structural history of high-pressure marbles (Evia Island, Greece)

Calcite pseudomorphs after aragonite were recorded throughout the high-pressure marbles of the Basal Unit (Evia Island, Greece). The pseudomorphs form a columnar microstructure oriented normal to the foliation, which developed at peak metamorphic conditions within the stability field of aragonite. Modification of the columnar microstructure by bending of the long axis of the calcite pseudomorph and dynamic recrystallization, was mainly dependent on the intensity of subsequent, exhumation-related deformation. We used the degree of preservation or modification of the columnar microstructure observed in shear zones, to distinguish between the subduction- and exhumation-related nature of the studied shear zones. The degree of modification of the columnar microstructure was also used as a tool to investigate variations in strain intensity, recrystallization mechanism and kinematics during the exhumation of the high-pressure marbles. Combined field and microstructural data suggest that subduction-related ductile deformation preceded the growth of the columnar microstructure and was associated with internal imbrication by SE-directed thrusting. The ductile stage of the exhumation was characterized by strain localization at the middle and upper structural levels of the Basal Unit, and E-directed thrusting (i.e., northeast in pre-Neogene configuration). Final exhumation of the Basal Unit was achieved by top-to-the-E ductile to brittle thrusting, which was accompanied by syn-orogenic extension at the upper crustal levels.

Thermometry and Microstructural Analysis Imply Protracted Extensional Exhumation of the Tso Morari UHP Nappe, Northwestern Himalaya: Implications for Models of UHP Exhumation

AbstractDocumenting the processes that facilitate exhumation of ultrahigh‐pressure (UHP) rocks at convergent margins is critical for understanding orogen dynamics. Here, we present structural and temperature data from the Himalayan UHP Tso Morari nappe (TMN) and overlying nappes, which we integrate with published pressure‐temperature‐time constraints to refine interpretations for their structural evolution and exhumation history. Our data indicate that the 5.5‐km‐thick TMN is the upper portion of a penetratively deformed ductile slab, which was extruded via distributed, pure shear‐dominated, top‐down‐to‐east shearing. Strain in the TMN is recorded by high‐strength quartz fabrics (density norms between 1.74 and 2.86) and finite strain data that define 63% transport‐parallel lengthening and 46% transport‐normal shortening. The TMN attained peak temperatures of ~500–600°C, which decrease in the overlying Tetraogal and Mata nappes to ~150–300°C, defining a field gradient as steep as 67°C/km. Within the overlying nappes, quartz fabric strength decreases (density norms between 1.14 and 1.21) and transport‐parallel lengthening and transport‐normal shortening decrease to 14% and 18%, respectively. When combined with published 40Ar/39Ar thermochronometry, quartz fabric deformation temperatures as low as ~330°C indicate that the top‐to‐east shearing that exhumed the TMN continued until ~30 Ma. Peak temperatures constrain the maximum depth of the overlying Mata nappe to 12.5–17.5 km; when combined with published fission‐track thermochronometry, this provides further support that the TMN was not underplated at upper crustal levels until ~30 Ma. The long‐duration, convergence‐subnormal shearing that exhumed the TMN outlasted rapid India‐Asia convergence by ~15 Myr and may be the consequence of strain partitioning during oblique convergence.

Reassessing zircon-monazite thermometry with thermodynamic modelling: insights from the Georgetown igneous complex, NE Australia

Accessory mineral thermometry and thermodynamic modelling are fundamental tools for constraining petrogenetic models of granite magmatism. U–Pb geochronology on zircon and monazite from S-type granites emplaced within a semi-continuous, whole-crust section in the Georgetown Inlier (GTI), NE Australia, indicates synchronous crystallisation at 1550 Ma. Zircon saturation temperature (Tzr) and titanium-in-zircon thermometry (T(Ti–zr)) estimate magma temperatures of ~ 795 ± 41 °C (Tzr) and ~ 845 ± 46 °C (T(Ti-zr)) in the deep crust, ~ 735 ± 30 °C (Tzr) and ~ 785 ± 30 °C (T(Ti-zr)) in the middle crust, and ~ 796 ± 45 °C (Tzr) and ~ 850 ± 40 °C (T(Ti-zr)) in the upper crust. The differing averages reflect ambient temperature conditions (Tzr) within the magma chamber, whereas the higher T(Ti-zr) values represent peak conditions of hotter melt injections. Assuming thermal equilibrium through the crust and adiabatic ascent, shallower magmas contained 4 wt% H2O, whereas deeper melts contained 7 wt% H2O. Using these H2O contents, monazite saturation temperature (Tmz) estimates agree with Tzr values. Thermodynamic modelling indicates that plagioclase, garnet and biotite were restitic phases, and that compositional variation in the GTI suites resulted from entrainment of these minerals in silicic (74–76 wt% SiO2) melts. At inferred emplacement P–T conditions of 5 kbar and 730 °C, additional H2O is required to produce sufficient melt with compositions similar to the GTI granites. Drier and hotter magmas required additional heat to raise adiabatically to upper-crustal levels. S-type granites are low-T mushes of melt and residual phases that stall and equilibrate in the middle crust, suggesting that discussions on the unreliability of zircon-based thermometers should be modulated.

Magmatic Evolution following Damp Tholeiitic and Wet Calc-alkaline Liquid Lines of Descent: an Eastern Pontides (NE Turkey) Example

AbstractAssociations between tholeiitic and calc-alkaline arc magmatism with close spatial and temporal relationships can provide critical constraints on magma genesis and allow the reconstruction of subduction polarity at convergent margins. This study identifies two compositionally distinct intrusive series from the Yusufeli region in the Eastern Pontides arc, NE Turkey. The intrusive rocks from the Yusufeli intrusive complex were emplaced at 179–170 Ma and are dominated by the low- to medium-K tholeiitic series, with depleted Hf isotopic compositions. In contrast, the intrusive rocks from the Camlikaya intrusive complex were emplaced at 151–147 Ma and are characterized by the medium- to high-K calc-alkaline series, with relatively enriched Hf isotopic compositions. The Al-in-hornblende geobarometer reveals that the magmas of both intrusive complexes crystallized at upper crustal levels (∼150–250 MPa, ∼5–8 km). The presence of patchy-textured plagioclase and the widespread occurrence of coeval dykes and magmatic mafic enclaves indicate that the two intrusive complexes are derived from multiple magma pulses in open magmatic systems. The mineral crystallization order of amphibole and plagioclase, the trace elemental signatures (e.g. Sr/Y and Y), and rare earth element modeling collectively suggest that the Yusufeli intrusive complex was dominated by plagioclase and clinopyroxene fractionation with earlier plagioclase crystallization than amphibole, whereas the Camlikaya intrusive complex was dominated by the fractionation of amphibole accompanied by co-crystallization of plagioclase. Such significant differences in the fractionating mineral assemblages at comparable intrusion pressures can be attributed to different initial H2O contents of the Yusufeli and Camlikaya parental magmas, which ultimately control their distinct liquid lines of descent. In accord with thermodynamic modeling results derived using the Rhyolite-MELTS software, we propose that the Yusufeli intrusive rocks are derived from damp (∼1–2 wt% H2O) parental magmas formed dominantly by decompression melting of mantle wedge in a back-arc setting. In contrast, the wet parental magmas (&amp;gt;∼2 wt% H2O) of Camlikaya intrusive rocks are more hydrous and formed through flux melting of suprasubduction-zone mantle wedge. This conclusion, combined with the back-arc basin related Jurassic sedimentary and structural records previously determined in the Southern Zone of the Eastern Pontides, indicates that the geochemical compositions and spatial relationship of the Yusufeli and Camlikaya intrusive complexes are preferably explained by the southward subduction of the Paleotethys oceanic lithosphere in the Early to Late Jurassic.