We present results from an experiment that wasdesigned to investigate turbulent transportrelationships in a nearly homogeneous boundary layerdisturbed by unsteady wind swings, as found at thebase of an advective inversion with a convectiveboundary layer overhead. In such a situation wemeasured vertical gradients and eddy fluxes of temperature andhumidity at two heights. From these, the turbulentdiffusivities of heat and water vapour are obtained,and compared to the predictions of Monin–Obukhovsimilarity theory and those of a numericalsecond-order closure model. It is found that themeasured diffusivities exceed both predictions. Thisis interpreted as a consequence of the unsteadyconditions. It is also found that the diffusivity forheat is roughly 10% larger than that for watervapour. This is in agreement with a theoreticaltreatment of the unsteadiness effects that wedeveloped in an earlier publication. This result isnot reproduced by the numerical model because themodel has no provision for unsteady conditions. Ourresult disagrees with that from an earlier, verysimilar, field experiment, which may be due to asystematic underestimation of sensible heat flux inthe older experiment.
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