In this paper, the effect of RS-AAT (Reverse-seepage and Saturation based Active Anti-corrosion Technology) on chloride ion erosion and saturation of unsaturated concrete is studied. The design of partially opening of permeable pipes is proposed for partial purpose. The infiltration of chloride ions in cylindrical concrete by RS-AAT is experimentally and numerically analyzed. Based on the water vapor adsorption and adsorption isotherm test and chloride ion erosion test, a convection-diffusion model of chloride ions with varying saturation is established by using simultaneous V-G model and Richards' equation. It can be used for characterizing the effect of pore opening on saturation change and chloride ion erosion. The results show that the use of RS-AAT can accelerate the growth of concrete saturation in the alternating wet and dry zones, and keep the area in a saturated state, under the effect of reverse seepage and saturation, the durability of the structure is increased. Moreover, the opening size and spacing of the permeable pipe are especially investigated. The results recommend 8 mm opening diameter and 2 mm opening spacing, by which the opening spacing is reduced as much as possible, and the ability to resist chloride ion erosion for a long time can be improved s under the combined action of reverse seepage and saturation. The significance of these results is immense for the continued utilization of the novel anti-chloride attack technology in engineering applications.